The methanol to olefins （MTO） reaction was performed over ZSM‐5 zeolite at 300℃ under various methanol weight hourly space velocity （WHSV） values. During these trials, the catalytic perfor‐mance was assessed, i...The methanol to olefins （MTO） reaction was performed over ZSM‐5 zeolite at 300℃ under various methanol weight hourly space velocity （WHSV） values. During these trials, the catalytic perfor‐mance was assessed, in addition to the formation and function of organic compounds retained in the zeolite. Analysis of reaction effluents and confined organics demonstrated a dual‐cycle reaction mechanism when employing ZSM‐5. The extent of the hydrogen transfer reaction, a secondary reac‐tion in the MTO process, varied as the catalyst‐methanol contact time was changed. In addition, 12C/13C‐methanol switch experiments indicated a relationship between the dual‐cycle mechanism and the extent of the hydrogen transfer reaction. Reactions employing a low methanol WHSV in conjunction with a long contact time favored the hydrogen transfer reaction to give alkene products and promoted the generation and accumulation of retained organic species, such as aromatics and methylcyclopentadienes, which enhance the aromatic cycle. When using higher WHSV values, the reduced contact times lessened the extent of the hydrogen transfer reaction and limited the genera‐tion of methylcyclopentadienes and aromatic species. This suppressed the aromatic cycle, such that the alkene cycle became the dominant route during the MTO reaction.展开更多
针对AGV(Automated Guided Vehicle)叉车处于环境信息未知或环境动态变化情况下的路径规划及导航问题,文中提出了一种由YOLOv5(You Only Look Once version 5)目标检测算法获取目标位置。根据目标位置规划出全局基础路径,再融合DWA(Dyna...针对AGV(Automated Guided Vehicle)叉车处于环境信息未知或环境动态变化情况下的路径规划及导航问题,文中提出了一种由YOLOv5(You Only Look Once version 5)目标检测算法获取目标位置。根据目标位置规划出全局基础路径,再融合DWA(Dynamic Window Approach)局部动态路径规划算法进行AGV路径规划与导航,使AGV叉车在未知环境或局部环境信息未知的环境中能快速识别目标位置并完成路径规划到达目标位置。实验结果表明,相较于改进前方法,文中所提方法在路径长度、耗费时间以及AGV叉车航向误差方面均有良好表现,路径长度平均减少12%,耗费时间平均减少约5%且AGV航向与目标航向的平均误差在5°以内。所提方法提高了AGV叉车在未知环境中的工作效率以及工作灵活性。展开更多
基金supported by the National Natural Science Foundation of China (91545104,21576256,21473182,21273230,21273005)the Youth Innovation Promotion Association of the Chinese Academy of Sciences~~
文摘The methanol to olefins （MTO） reaction was performed over ZSM‐5 zeolite at 300℃ under various methanol weight hourly space velocity （WHSV） values. During these trials, the catalytic perfor‐mance was assessed, in addition to the formation and function of organic compounds retained in the zeolite. Analysis of reaction effluents and confined organics demonstrated a dual‐cycle reaction mechanism when employing ZSM‐5. The extent of the hydrogen transfer reaction, a secondary reac‐tion in the MTO process, varied as the catalyst‐methanol contact time was changed. In addition, 12C/13C‐methanol switch experiments indicated a relationship between the dual‐cycle mechanism and the extent of the hydrogen transfer reaction. Reactions employing a low methanol WHSV in conjunction with a long contact time favored the hydrogen transfer reaction to give alkene products and promoted the generation and accumulation of retained organic species, such as aromatics and methylcyclopentadienes, which enhance the aromatic cycle. When using higher WHSV values, the reduced contact times lessened the extent of the hydrogen transfer reaction and limited the genera‐tion of methylcyclopentadienes and aromatic species. This suppressed the aromatic cycle, such that the alkene cycle became the dominant route during the MTO reaction.
文摘针对AGV(Automated Guided Vehicle)叉车处于环境信息未知或环境动态变化情况下的路径规划及导航问题,文中提出了一种由YOLOv5(You Only Look Once version 5)目标检测算法获取目标位置。根据目标位置规划出全局基础路径,再融合DWA(Dynamic Window Approach)局部动态路径规划算法进行AGV路径规划与导航,使AGV叉车在未知环境或局部环境信息未知的环境中能快速识别目标位置并完成路径规划到达目标位置。实验结果表明,相较于改进前方法,文中所提方法在路径长度、耗费时间以及AGV叉车航向误差方面均有良好表现,路径长度平均减少12%,耗费时间平均减少约5%且AGV航向与目标航向的平均误差在5°以内。所提方法提高了AGV叉车在未知环境中的工作效率以及工作灵活性。
