The mass energy absorption coefficient (len=q), effective atomic number (ZPEAeff ), and electron density (NPEAeff ) of some biomolecules with potential application in radiation dosimetry were calculated for their phot...The mass energy absorption coefficient (len=q), effective atomic number (ZPEAeff ), and electron density (NPEAeff ) of some biomolecules with potential application in radiation dosimetry were calculated for their photon energy absorption (PEA) in the energy region of 1–20 MeV. It was noticed that the values of len=q, ZPEAeff , and NPEAeff vary with the energy and composition of the biomolecules. The results for ZPEAeff were compared with effective atomic numbers (ZPIeff ) owing to the photon interaction (PI). Significant differences were noted between ZPEAeff and ZPIeff in the energy region of 10–150 keV for all of the biomolecules involved. A maximum difference of 45.36% was observed at 50 keV for creatinine hydrochloride. Moreover, the studied attenuation parameters were found to be sharply affected at the K-absorption edge of relatively high-Z elements present in the biomolecules.展开更多
Polarization upconversion luminescence(PUCL)of lanthanide ions(Ln^(3+))has been widely used in single particle tracking,microfluidics detection,three-dimensional displays,and so on.However,no effective strategy has be...Polarization upconversion luminescence(PUCL)of lanthanide ions(Ln^(3+))has been widely used in single particle tracking,microfluidics detection,three-dimensional displays,and so on.However,no effective strategy has been developed for modulating PUCL.Here we report a strategy to regulate PUCL in Ho^(3+)-doped NaYF4single nanorods based on the number of upconversion photons.By constructing a multiphoton upconversion system for Ho^(3+),we regulate the degree of polarization(DOP)of PUCL from 0.590 for two-photon luminescence to 0.929 for three-photon upconversion luminescence(UCL).Furthermore,our strategy is verified from cross-relaxation between Ho^(3+)and Yb^(3+),excitation wavelength,excitation power density,and local site symmetry.And this regulation strategy of PUCL has also been achieved in Tm^(3+),with the DOP ranging from 0.233 for two-photon luminescence to 0.925 for four-photon UCL Besides,multi-dimensional anti-counterfeiting display has been explored with PUCL.This work provides an effective strategy for regulating PUCL and also provides more opportunities for the development of polarization display optical encoding,anti-counterfeiting,and integrated optical devices.展开更多
文摘The mass energy absorption coefficient (len=q), effective atomic number (ZPEAeff ), and electron density (NPEAeff ) of some biomolecules with potential application in radiation dosimetry were calculated for their photon energy absorption (PEA) in the energy region of 1–20 MeV. It was noticed that the values of len=q, ZPEAeff , and NPEAeff vary with the energy and composition of the biomolecules. The results for ZPEAeff were compared with effective atomic numbers (ZPIeff ) owing to the photon interaction (PI). Significant differences were noted between ZPEAeff and ZPIeff in the energy region of 10–150 keV for all of the biomolecules involved. A maximum difference of 45.36% was observed at 50 keV for creatinine hydrochloride. Moreover, the studied attenuation parameters were found to be sharply affected at the K-absorption edge of relatively high-Z elements present in the biomolecules.
基金financially supported by the National Natural Science Foundation of China(Nos.11704081,52125205,52250398,U20A20166,52192614 and 52003101)Guangxi Natural Science Foundation(Nos.2020GXNSFAA297182,2020GXNSFAA297041 and 2017GXNSFBA19-8229)+5 种基金the special fund for Guangxi Bagui ScholarsNational Science and Technology Innovation Talent Cultivation Program(No.2023BZRC016)National Key R&D Program of China(Nos.2021YFB3200302 and2021YFB3200304)the Natural Science Foundation of Beijing Municipality(No.2222088)Shenzhen Science and Technology Innovation Program(No.KQTD20170810105439418)the Fundamental Research Funds for the Central Universities。
文摘Polarization upconversion luminescence(PUCL)of lanthanide ions(Ln^(3+))has been widely used in single particle tracking,microfluidics detection,three-dimensional displays,and so on.However,no effective strategy has been developed for modulating PUCL.Here we report a strategy to regulate PUCL in Ho^(3+)-doped NaYF4single nanorods based on the number of upconversion photons.By constructing a multiphoton upconversion system for Ho^(3+),we regulate the degree of polarization(DOP)of PUCL from 0.590 for two-photon luminescence to 0.929 for three-photon upconversion luminescence(UCL).Furthermore,our strategy is verified from cross-relaxation between Ho^(3+)and Yb^(3+),excitation wavelength,excitation power density,and local site symmetry.And this regulation strategy of PUCL has also been achieved in Tm^(3+),with the DOP ranging from 0.233 for two-photon luminescence to 0.925 for four-photon UCL Besides,multi-dimensional anti-counterfeiting display has been explored with PUCL.This work provides an effective strategy for regulating PUCL and also provides more opportunities for the development of polarization display optical encoding,anti-counterfeiting,and integrated optical devices.
