To obtain high-quality dissimilar weld joints, the processes of metal inert gas (MIG) welding and tungsten inert gas (TIG) welding for duplex stainless steel (DSS) and low alloy steel were compared in this paper...To obtain high-quality dissimilar weld joints, the processes of metal inert gas (MIG) welding and tungsten inert gas (TIG) welding for duplex stainless steel (DSS) and low alloy steel were compared in this paper. The microstructure and corrosion morphology of dissimilar weld joints were observed by scanning electron microscopy (SEM); the chemical compositions in different zones were detected by en- ergy-dispersive spectroscopy (EDS); the mechanical properties were measured by microhardness test, tensile test, and impact test; the corro- sion behavior was evaluated by polarization curves. Obvious concentration gradients of Ni and Cr exist between the fusion boundary and the type II boundary, where the hardness is much higher. The impact toughness of weld metal by MIG welding is higher than that by TIG weld- ing. The corrosion current density of TIG weld metal is higher than that of MIG weld metal in a 3.5wt% NaC1 solution. Galvanic corrosion happens between low alloy steel and weld metal, revealing the weakness of low alloy steel in industrial service. The quality of joints pro- duced by MIG welding is better than that by TIG welding in mechanical performance and corrosion resistance. MIG welding with the filler metal ER2009 is the suitable welding process for dissimilar metals jointing between UNS $31803 duplex stainless steel and low alloy steel in practical application.展开更多
The 2205 duplex stainless + DH36 clad steel plate was welded by gas metal arc welding(GMAW), and the welding performance of the clad steel plate was investigated. The results show that the adaptability of the weldi...The 2205 duplex stainless + DH36 clad steel plate was welded by gas metal arc welding(GMAW), and the welding performance of the clad steel plate was investigated. The results show that the adaptability of the welding procedure for the base metal of carbon steel, the transition layer, and the cladding material is excellent. The test results indicate that the phase proportion and component dilution of the GMAW-welded joints of clad steel plate can be effectively controlled to yield joints with good mechanical properties and corrosion resistance.展开更多
Multi-layer narrow-gap welding of thick S32101 duplex stainless steel was conducted using laser welding with beam wobble process.The phase transition,grain size,phase proportion and crystal texture of welded joint wer...Multi-layer narrow-gap welding of thick S32101 duplex stainless steel was conducted using laser welding with beam wobble process.The phase transition,grain size,phase proportion and crystal texture of welded joint were also studied and compared with gas metal arc welding process.The microhardness and tensile strength were measured and fracture surface was analyzed to evaluate the mechanical properties of welded joints.The results showed that beam wobble technology improved the misalignment of laser beam and filler wire in narrow groove and helped to avoid incomplete fusion defects.Compared to arc welding process,the groove size and heat input were reduced,while welding efficiency was increased.The faster cooling rate and lower temperature gradient of laser wobble welding favored grain refinement,while the austenite content in weld zone decreased.Both the beam wobble and swing arc were conducive to stir weld pool,optimizing the weld microstructure and joint formation.The microstructural variance in various weld passes was caused by the heat input and heat dissipation ability.The microhardness of laser welded joint was lower,while the tensile strength and elongation percentage were higher.The fracture surface of arc welded joint was featured with shallower dimples and cleavage steps.展开更多
Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as...Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as well as Cr_2N and M_(23)C_6,etc.These processes are not only influenced by temperature and cooling speed, but also are affected by alloy element content.The purpose of the research was to work out the qualitative and quantitative analysis of precipitate phases in 2 205 duplex stainless steel with different isothermal heat treatment situation.After choosing the electrolyte and electrolytic systems,we use electrochemical method to extract precipitate phases from the matrix.Scanning electron microscope(SEM) and X-ray diffraction(XRD) were used to examine their modality and structure.Particle size distribution was performed by dynamic laser scattering sizer (DLS-Sizer).Furthermore,oxygen-nitrogen analyzer and carbon-sulfur analyzer were applied to measure the content of nitrogen and carbon in precipitate phases.Separation and quantitative analysis of precipitate phases were carried out by wet chemical analysis and inductively coupled plasma spectrometry(ICP).In a word,combining chemical and physical methods,our research reveals the transformation of precipitate phases'species,content, elemental composition and particle size distribution during different isothermal heat treatment situation.展开更多
A novel joining method,double-stage diffusion-brazing of an AZ31 magnesium alloy and a 304L austenitic stainless steel,was carried out using a pure copper interlayer.The solid-state diffusion bonding of 304L to copper...A novel joining method,double-stage diffusion-brazing of an AZ31 magnesium alloy and a 304L austenitic stainless steel,was carried out using a pure copper interlayer.The solid-state diffusion bonding of 304L to copper was conducted at 850 ℃ for 20 min followed by brazing to AZ31 at 520 ℃ and 495 ℃ for various time.Microstructural characteristics of the diffusion-brazed joints were investigated in detail.A defect free interface of Fe-Cu diffusion area appeared between the Cu alloy and the 304L steel.Cu-Mg reaction products were formed between AZ31 and Cu alloys.A layered structure including AZ31/Cu-Mg compounds/Cu/Fe-Cu diffusion layer/304L was present in the joint.With time prolonging,the reduction in the width of Cu layer was balanced by the increase in the width of Cu-Mg compounds zone.Microhardness peaks in the zone between AZ31 and Cu layer were attributed to the formation of Mg-Cu compounds in this zone.展开更多
This paper presents the study carried out to study the microstructure and mechanical properties of AISI 304 stainless steel and gray iron, in order to recognize the effect of welding parameters on the joint. The shiel...This paper presents the study carried out to study the microstructure and mechanical properties of AISI 304 stainless steel and gray iron, in order to recognize the effect of welding parameters on the joint. The shielded metal arc welding technique was applied with a 3.2 mm diameter nickel coated electrode under preheating and post heat conditions at 350°C. Vickers hardness test and metallographic analysis were carried out at the heat affected zone and at the interface to determine the effect on mechanical and metallurgical characteristics. Vickers hardness differences among joint areas were directly related to microstructural changes. There are no significant differences in AISI 304 hardness, but the hardness increased at the heat affected zone and decreased at the filler metal. Grey iron hardness at the heat affected zone was even lower and more slightly superior than grey iron hardness.展开更多
Dissimilar metal joining between NiTi shape memory alloy(SMA) and stainless steel was conducted.A cluster of NiTi SMA wires were first joined with tungsten inert gas(TIG) welding process,then the NiTi SMA TIG weld...Dissimilar metal joining between NiTi shape memory alloy(SMA) and stainless steel was conducted.A cluster of NiTi SMA wires were first joined with tungsten inert gas(TIG) welding process,then the NiTi SMA TIG weld was welded to a stainless steel pipe with laser spot welding process.The microstructure of the welds was examined with an optical microscope and the elemental distribution in the welds was measured by electron probe microanalysis(EPMA).The results show that TiC compounds dispersively distribute in the NiTi SMA TIG weld.However,the amount of TiC compounds greatly decreases around the fusion boundary of the laser spot weld between the NiTi SMA and stainless steel.Mutual diffusion between NiTi shape memory alloy and stainless steel happen within a short distance near the fusion boundary,and intermetallic compounds such as Ni3Ti+(Fe,Ni)Ti appear around the fusion boundary.展开更多
7075-T6 aluminum alloy/low carbon steel joint was carried out via a novel friction plug−riveting spot welding process.This process utilized uniquely designed steel rivets with a tip and groove shape.The macro-morpholo...7075-T6 aluminum alloy/low carbon steel joint was carried out via a novel friction plug−riveting spot welding process.This process utilized uniquely designed steel rivets with a tip and groove shape.The macro-morphology formation,microstructure,microhardness and lap shear performance of joints were investigated.As the spindle down distance increased,the rivet tip was friction welded with the lower steel sheet,resulting in the formation of a solid phase welding zone exhibiting metallurgical bonding.Additionally,a hook was formed in the joint,providing the mechanical locking.The results showed that under optimal parameters of spindle down distance of 3.4 mm,rotation speed of 4000 r/min,and spindle down speed of 2.4 mm/s,the lap shear load of the joints reached a maximum of 14.36 kN.Failure occurred at the aluminum alloy base metal.展开更多
The dissimilar combinations of Inconel 625 and duplex stainless steel SAF 2205 obtained from manual GTA welding process employing ER2209 and ERNi CrMo-3 filler metals have been investigated. Formation of secondary pha...The dissimilar combinations of Inconel 625 and duplex stainless steel SAF 2205 obtained from manual GTA welding process employing ER2209 and ERNi CrMo-3 filler metals have been investigated. Formation of secondary phases at the HAZ of Inconel 625 and grain coarsening at the HAZ of SAF 2205 were witnessed while using these filler wires. The average hardness of ER2209 weldments was found to be greater than ERNi CrMo-3 weld. Tensile fracture was observed at the weld zones for both the fillers. Impact test trials showed brittle mode of fracture on employing ER2209 filler and mixed(ductile–brittle) mode of fracture while using ERNi CrMo-3 filler. Further optical microscopy and SEM/EDS analysis were carried out across the weldments to investigate the structure–property relationships.展开更多
使用镍基焊缝连接铁素体基耐热钢和奥氏体不锈钢(或镍基合金)形成的异种金属焊接接头(DMWs,Dissimilar Metal Welds)在核电、火电、石化等行业有着广泛的应用。DMWs在高温低应力服役条件下经常会出现早期失效,导致机组非正常停机,带来...使用镍基焊缝连接铁素体基耐热钢和奥氏体不锈钢(或镍基合金)形成的异种金属焊接接头(DMWs,Dissimilar Metal Welds)在核电、火电、石化等行业有着广泛的应用。DMWs在高温低应力服役条件下经常会出现早期失效,导致机组非正常停机,带来巨大的经济损失和安全隐患,故DMWs的早期失效问题一直受到工程界和学术界的重点关注。围绕DMWs的早期失效问题,回顾并总结了近几十年来该领域的相关研究成果。首先,介绍了DMWs的组织特点,重点关注了铁素体基耐热钢与焊缝界面附近区域的冶金特点,包括界面马氏体层、碳迁移、Ⅰ/Ⅱ型碳化物等;其次,简要总结了DMWs焊接残余应力的特点及其影响因素;再次,汇总了DMWs的高温蠕变数据,针对DMWs蠕变断裂位置转移的特点进行了分析,其中沿铁素体基耐热钢与焊缝界面断裂是DMWs失效的显著特征,这种失效方式与界面处应变集中、热应力、基体组织退化、碳化物粗化以及氧化等有关;最后,给出了若干种延长DMWs服役寿命的方法和建议。展开更多
基金supported by the National Science and Technology Major Project of China (Grant No.2011ZX05056)
文摘To obtain high-quality dissimilar weld joints, the processes of metal inert gas (MIG) welding and tungsten inert gas (TIG) welding for duplex stainless steel (DSS) and low alloy steel were compared in this paper. The microstructure and corrosion morphology of dissimilar weld joints were observed by scanning electron microscopy (SEM); the chemical compositions in different zones were detected by en- ergy-dispersive spectroscopy (EDS); the mechanical properties were measured by microhardness test, tensile test, and impact test; the corro- sion behavior was evaluated by polarization curves. Obvious concentration gradients of Ni and Cr exist between the fusion boundary and the type II boundary, where the hardness is much higher. The impact toughness of weld metal by MIG welding is higher than that by TIG weld- ing. The corrosion current density of TIG weld metal is higher than that of MIG weld metal in a 3.5wt% NaC1 solution. Galvanic corrosion happens between low alloy steel and weld metal, revealing the weakness of low alloy steel in industrial service. The quality of joints pro- duced by MIG welding is better than that by TIG welding in mechanical performance and corrosion resistance. MIG welding with the filler metal ER2009 is the suitable welding process for dissimilar metals jointing between UNS $31803 duplex stainless steel and low alloy steel in practical application.
文摘The 2205 duplex stainless + DH36 clad steel plate was welded by gas metal arc welding(GMAW), and the welding performance of the clad steel plate was investigated. The results show that the adaptability of the welding procedure for the base metal of carbon steel, the transition layer, and the cladding material is excellent. The test results indicate that the phase proportion and component dilution of the GMAW-welded joints of clad steel plate can be effectively controlled to yield joints with good mechanical properties and corrosion resistance.
基金supported by the Science and Technology Innovation Program of Hunan Province(2022RC1060 and 2022GK4046)。
文摘Multi-layer narrow-gap welding of thick S32101 duplex stainless steel was conducted using laser welding with beam wobble process.The phase transition,grain size,phase proportion and crystal texture of welded joint were also studied and compared with gas metal arc welding process.The microhardness and tensile strength were measured and fracture surface was analyzed to evaluate the mechanical properties of welded joints.The results showed that beam wobble technology improved the misalignment of laser beam and filler wire in narrow groove and helped to avoid incomplete fusion defects.Compared to arc welding process,the groove size and heat input were reduced,while welding efficiency was increased.The faster cooling rate and lower temperature gradient of laser wobble welding favored grain refinement,while the austenite content in weld zone decreased.Both the beam wobble and swing arc were conducive to stir weld pool,optimizing the weld microstructure and joint formation.The microstructural variance in various weld passes was caused by the heat input and heat dissipation ability.The microhardness of laser welded joint was lower,while the tensile strength and elongation percentage were higher.The fracture surface of arc welded joint was featured with shallower dimples and cleavage steps.
文摘Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as well as Cr_2N and M_(23)C_6,etc.These processes are not only influenced by temperature and cooling speed, but also are affected by alloy element content.The purpose of the research was to work out the qualitative and quantitative analysis of precipitate phases in 2 205 duplex stainless steel with different isothermal heat treatment situation.After choosing the electrolyte and electrolytic systems,we use electrochemical method to extract precipitate phases from the matrix.Scanning electron microscope(SEM) and X-ray diffraction(XRD) were used to examine their modality and structure.Particle size distribution was performed by dynamic laser scattering sizer (DLS-Sizer).Furthermore,oxygen-nitrogen analyzer and carbon-sulfur analyzer were applied to measure the content of nitrogen and carbon in precipitate phases.Separation and quantitative analysis of precipitate phases were carried out by wet chemical analysis and inductively coupled plasma spectrometry(ICP).In a word,combining chemical and physical methods,our research reveals the transformation of precipitate phases'species,content, elemental composition and particle size distribution during different isothermal heat treatment situation.
基金Project(51205428) supported by the National Natural Science Foundation of ChinaProject(CDJRC10130011) supported by the Fundamental Research Funds for the Central Universities,China
文摘A novel joining method,double-stage diffusion-brazing of an AZ31 magnesium alloy and a 304L austenitic stainless steel,was carried out using a pure copper interlayer.The solid-state diffusion bonding of 304L to copper was conducted at 850 ℃ for 20 min followed by brazing to AZ31 at 520 ℃ and 495 ℃ for various time.Microstructural characteristics of the diffusion-brazed joints were investigated in detail.A defect free interface of Fe-Cu diffusion area appeared between the Cu alloy and the 304L steel.Cu-Mg reaction products were formed between AZ31 and Cu alloys.A layered structure including AZ31/Cu-Mg compounds/Cu/Fe-Cu diffusion layer/304L was present in the joint.With time prolonging,the reduction in the width of Cu layer was balanced by the increase in the width of Cu-Mg compounds zone.Microhardness peaks in the zone between AZ31 and Cu layer were attributed to the formation of Mg-Cu compounds in this zone.
文摘This paper presents the study carried out to study the microstructure and mechanical properties of AISI 304 stainless steel and gray iron, in order to recognize the effect of welding parameters on the joint. The shielded metal arc welding technique was applied with a 3.2 mm diameter nickel coated electrode under preheating and post heat conditions at 350°C. Vickers hardness test and metallographic analysis were carried out at the heat affected zone and at the interface to determine the effect on mechanical and metallurgical characteristics. Vickers hardness differences among joint areas were directly related to microstructural changes. There are no significant differences in AISI 304 hardness, but the hardness increased at the heat affected zone and decreased at the filler metal. Grey iron hardness at the heat affected zone was even lower and more slightly superior than grey iron hardness.
基金Project(50974046/E041607) supported by the National Natural Science Foundation of China
文摘Dissimilar metal joining between NiTi shape memory alloy(SMA) and stainless steel was conducted.A cluster of NiTi SMA wires were first joined with tungsten inert gas(TIG) welding process,then the NiTi SMA TIG weld was welded to a stainless steel pipe with laser spot welding process.The microstructure of the welds was examined with an optical microscope and the elemental distribution in the welds was measured by electron probe microanalysis(EPMA).The results show that TiC compounds dispersively distribute in the NiTi SMA TIG weld.However,the amount of TiC compounds greatly decreases around the fusion boundary of the laser spot weld between the NiTi SMA and stainless steel.Mutual diffusion between NiTi shape memory alloy and stainless steel happen within a short distance near the fusion boundary,and intermetallic compounds such as Ni3Ti+(Fe,Ni)Ti appear around the fusion boundary.
基金supported by the National Natural Science Foundation of China(No.51875037).
文摘7075-T6 aluminum alloy/low carbon steel joint was carried out via a novel friction plug−riveting spot welding process.This process utilized uniquely designed steel rivets with a tip and groove shape.The macro-morphology formation,microstructure,microhardness and lap shear performance of joints were investigated.As the spindle down distance increased,the rivet tip was friction welded with the lower steel sheet,resulting in the formation of a solid phase welding zone exhibiting metallurgical bonding.Additionally,a hook was formed in the joint,providing the mechanical locking.The results showed that under optimal parameters of spindle down distance of 3.4 mm,rotation speed of 4000 r/min,and spindle down speed of 2.4 mm/s,the lap shear load of the joints reached a maximum of 14.36 kN.Failure occurred at the aluminum alloy base metal.
文摘The dissimilar combinations of Inconel 625 and duplex stainless steel SAF 2205 obtained from manual GTA welding process employing ER2209 and ERNi CrMo-3 filler metals have been investigated. Formation of secondary phases at the HAZ of Inconel 625 and grain coarsening at the HAZ of SAF 2205 were witnessed while using these filler wires. The average hardness of ER2209 weldments was found to be greater than ERNi CrMo-3 weld. Tensile fracture was observed at the weld zones for both the fillers. Impact test trials showed brittle mode of fracture on employing ER2209 filler and mixed(ductile–brittle) mode of fracture while using ERNi CrMo-3 filler. Further optical microscopy and SEM/EDS analysis were carried out across the weldments to investigate the structure–property relationships.
文摘使用镍基焊缝连接铁素体基耐热钢和奥氏体不锈钢(或镍基合金)形成的异种金属焊接接头(DMWs,Dissimilar Metal Welds)在核电、火电、石化等行业有着广泛的应用。DMWs在高温低应力服役条件下经常会出现早期失效,导致机组非正常停机,带来巨大的经济损失和安全隐患,故DMWs的早期失效问题一直受到工程界和学术界的重点关注。围绕DMWs的早期失效问题,回顾并总结了近几十年来该领域的相关研究成果。首先,介绍了DMWs的组织特点,重点关注了铁素体基耐热钢与焊缝界面附近区域的冶金特点,包括界面马氏体层、碳迁移、Ⅰ/Ⅱ型碳化物等;其次,简要总结了DMWs焊接残余应力的特点及其影响因素;再次,汇总了DMWs的高温蠕变数据,针对DMWs蠕变断裂位置转移的特点进行了分析,其中沿铁素体基耐热钢与焊缝界面断裂是DMWs失效的显著特征,这种失效方式与界面处应变集中、热应力、基体组织退化、碳化物粗化以及氧化等有关;最后,给出了若干种延长DMWs服役寿命的方法和建议。