Visible light responsive spiropyran derivatives based on dynamic coordination bonds

Spiropyrans(SPs) are a well-known class of photochromic compounds and have found widespread application due to their unique properties. However, for many conventional SPs, high energy ultraviolet(UV)light is commonly essential to drive photoisomerization, leading to poor fatigue resistance. Moreover, the practical application of spiropyrans is hindered by their fast fading speed due to the instability of closed forms(SP) or open forms(MC). Herein, we disclose a novel strategy to address these challenges through introducing both electron-donating substituents to stabilize the SP and dynamic coordination bonds to stabilize the MC. The resulting new spiropyrans complexes exhibit negative photochromic properties, with fast visible light response, good stability of both SP and MC, and significantly improved fatigue resistance.

Dynamic modeling and simulation for the flexible spacecraft with dynamic stiffening

A rigid flexible coupling physical model which can represent a flexible spacecraft is investigated in this paper. By applying the mechanics theory in a non-inertial coordinate system,the rigid flexible coupling dynamic model with dynamic stiffening is established via the subsystemmodeling framework. It is clearly elucidated for the first time that,dynamic stiffening is produced by the coupling effect of the centrifugal inertial load distributed on the beamand the transverse vibration deformation of the beam. The modeling approach in this paper successfully avoids problems which are caused by other popular modeling methods nowadays： the derivation process is too complex by using only one dynamic principle; a clearly theoretical explanation for dynamic stiffening can＇t be provided. First,the continuous dynamic models of the flexible beamand the central rigid body are established via structural dynamics and angular momentumtheory respectively. Then,based on the conclusions of orthogonalization about the normal constrained modes,the finite dimensional dynamic model suitable for controller design is obtained. The numerical simulation validations showthat： dynamic stiffening is successfully incorporated into the dynamic characteristics of the first-order model established in this paper,which can indicate the dynamic responses of the rigid flexible coupling system with large overall motion accurately,and has a clear modeling mechanism,concise expressions and a good convergence.

Contact dynamics of elasto-plastic thin beams simulated via absolute nodal coordinate formulation

Under the frame of multibody dynamics, the contact dynamics of elasto-plastic spatial thin beams is numerically studied by using the spatial thin beam elements of absolute nodal coordinate formulation（ANCF）. The internal force of the elasto-plastic spatial thin beam element is derived under the assumption that the plastic strain of the beam element depends only on its longitudinal deformation.A new body-fixed local coordinate system is introduced into the spatial thin beam element of ANCF for efficient contact detection in the contact dynamics simulation. The linear isotropic hardening constitutive law is used to describe the elasto-plastic deformation of beam material, and the classical return mapping algorithm is adopted to evaluate the plastic strains. A multi-zone contact approach of thin beams previously proposed by the authors is also introduced to detect the multiple contact zones of beams accurately, and the penalty method is used to compute the normal contact force of thin beams in contact. Four numerical examples are given to demonstrate the applicability and effectiveness of the proposed elasto-plastic spatial thin beam element of ANCF for flexible multibody system dynamics.

Combined Control Allocation and Sliding Mode Control in the Dynamic Control of a Vehicle with Eight In-Wheel Motors

An eight wheel independently driving steering（8 WIDBS）electric vehicle is studied in this paper.The vehicle is equipped with eight in-wheel motors and a steer-by-wire system.A hierarchically coordinated vehicle dynamic control（HCVDC）system,including a high-level vehicle motion controller,a control allocation,an inverse tire model and a lower-level slip/slip angle controller,is proposed for the over-actuated vehicle system.The high-level sliding mode vehicle motion controller is designed to produce desired total forces and yaw moment,distributed to longitudinal and lateral forces of each tire by an advanced control allocation method.And the slip controller is designed to use a sliding mode control method to follow the desired slip ratios by manipulating the corresponding in-wheel motor torques.Evaluation of the overall system is accomplished by sine maneuver simulation.Simulation results confirm that the proposed control system can coordinate among the redundant and constrained actuators to achieve the vehicle dynamic control task and improve the vehicle stability.

A first-order dynamical model of hierarchical triple stars and its application

For most hierarchical triple stars, the classical double two-body model of zeroth-order cannot describe the motions of the components under the current observational accuracy. In this paper, Marchal＇s first-order analytical solution is implemented and a more efficient simplified version is applied to real triple stars. The results show that, for most triple stars, the proposed first-order model is preferable to the zerothorder model both in fitting observational data and in predicting component positions.

OPTIMAL DYNAMIC LOAD DISTRIBUTION OF MULTIPLE COOPERATING ROBOT MANIPULATORS

For the situation of multiple cooperating manipulators handling a single object,an equilibrium equation is presented in which the manipulator dynamics and control forces/torques are taken into account,and a expression is derived to allow the optimal dynamic load distribution of the combined system can be made.

Coupling and coordinated evolution characteristics of regional economy-energy-carbon emission multiple systems:A case study of main China's Basin

Comprehensive analysis of the Economy-Energy-Carbon Emission(EECE)system is beneficial for promoting sustainable social development.This study analyzes the system development of major watersheds in China from 2010 to 2019.The research fully considers the system’s internal and external inputs and outputs and proposes an evaluation index system for regional EECE coupling and coordinated development.Then,using the difference in system weight allocation to improve the coupling and coordination model,the study explores the dynamic system’s coupling and coordination.The results show that(1)The development of the system structure is relatively stable,but the overall development status is not ideal;(2)The downstream of China’s main river basins has obvious economic advantages,while the energy system fluctuates greatly.The efficiency of the carbon emission system will decrease in areas with rapid economic development.The coupling and coordination level of the EECE system is better in the Yangtze River Basin than in the Yellow River Basin;(3)From the perspective of dynamic coordinated development,the main river basins have been divided into two states since 2012,but it is relatively stable overall.Regional dynamic coordination is often at a disadvantage in regions with rapid economic and energy development;(4)The coupling coordination degree of the two river basins has significant positive spatial autocorrelation.Most provinces’significant spatial clustering characteristics of the coupling coordination degree are High-High type.Low-Low type provinces are mainly concentrated downstream.The research process has certain reference significance for the collaborative governance of complex regional systems.

Dynamic Coordinated Management Model of Programme in Large-Scale Construction Company

Large-scale construction companies develop rapidly when facing more and more opportunities and challenges of programme contracting. However, project management technology, not meeting the requirements of firm growth, still stands proud, while relevant programme management methods have not been well studied. Therefore, this paper commences innovative application of coordinated management theory to programme management according to the need of changing the existing management mode in large-scale construction companies,then puts forward the dynamic coordinated management model composed of the dynamic coordination of function module, interface module, support module and evaluation module. Besides, coordination degree was introduced to make auxiliary analysis, so that companies can utilize internal and external resources more effectively to realize the goals of programme management as well as enterprise strategy.

Research on uplink coordinated transmission schemes in LTE-advanced systems

The investigation of inter-cell interference mitigation techniques is a key area in wireless communications.Coordinated multiple points（CoMP） transmission/reception is a candidate technique for interference cancellation in 3GPP LTE-Advanced system.However,the coordination scheme in CoMP remains a key research problem to be solved,which will have a strong influence on the performance of CoMP.In this paper,a novel coordinated transmission scheme is proposed for the uplink LTE-Advanced system.In our scheme,several base transceiver stations（BTS） and users are selected as coordination partners which form a CoMP cluster.Joint processing is used at the receiver to mitigate interference.From the perspective of coordinated partner selection,our scheme can be divided into static and dynamic coordination which are both considered to fully exploit the throughput gain of CoMP.The proposed schemes are evaluated by system level simulation and compared with the conventional LTE system based upon single cell processing.Our simulation results demonstrate that the proposed schemes attain superior performance as opposed to the conventional system in terms of cell average and cell edge throughput.

A fast on-demand preparation of injectable self-healing nanocomposite hydrogels for efficient osteoinduction

Injectable hydrogels have been considered as promising materials for bone regeneration,but their osteoinduction and mechanical performance are yet to be improved.In this study,a novel biocompatible injectable and self-healing nano hybrid hydrogel was on-demand prepared via a fast(within 30 s)and easy gelation approach by reversible Schiff base formed between-CH=O of oxidized sodium alginate(OSA)and-NH2 of glycol chitosan(GCS)mixed with calcium phosphate nanoparticles(CaP NPs).Its raw materials can be ready in large quantities by a simple synthesis process.The mechanical strength,degradation and swelling behavior of the hydrogel can be readily controlled by simply controlling the molar ratio of-CH=O and-NH2.This hydrogel exhibits pH responsiveness,good degradability and biocompatibility.The hydrogel used as the matrix for mesenchymal stem cells can significantly induce the proliferation,differentiation and osteoinduction in vitro.These results showed this novel hydrogel is an ideal candidate for applications in bone tissue regeneration and drug delivery.

A New Stable Version of the SPH Method in Lagrangian Coordinates

The purpose of this paper is to solve some of the trouble spots of the classical SPH method by proposing an alternative approach.First,we focus on the problem of the stability for two different SPH schemes,one is based on the approach of Vila[25]and another is proposed in this article which mimics the classical 1D LaxWendroff scheme.In both approaches the classical SPH artificial viscosity term is removed preserving nevertheless the linear stability of the methods,demonstrated via the von Neumann stability analysis.Moreover,the issue of the consistency for the equations of gas dynamics is analyzed.An alternative approach is proposed that consists of using Godunov-type SPH schemes in Lagrangian coordinates.This not only provides an improvement in accuracy of the numerical solutions,but also assures that the consistency condition on the gradient of the kernel function is satisfied using an equidistant distribution of particles in Lagrangian mass coordinates.Three different Riemann solvers are implemented for the first-order Godunov type SPH schemes in Lagrangian coordinates,namely the Godunov flux based on the exact Riemann solver,the Rusanov flux and a new modified Roe flux,following the work of Munz[17].Some well-known numerical 1D shock tube test cases[22]are solved,comparing the numerical solutions of the Godunov-type SPH schemes in Lagrangian coordinates with the first-order Godunov finite volume method in Eulerian coordinates and the standard SPH scheme with Monaghan’s viscosity term.