Inherent brittleness and low heat resistance are the two major obstacles that hinder the wide applications of poly（L-lactide）（PLLA）. In this study,we report a fully biobased,highly toughened and heat-resistant PLL...Inherent brittleness and low heat resistance are the two major obstacles that hinder the wide applications of poly（L-lactide）（PLLA）. In this study,we report a fully biobased,highly toughened and heat-resistant PLLA ternary blend,which was prepared by dynamic vulcanization of PLLA with poly（D-lactide）（PDLA） and an unsaturated bioelastomer（UBE）. The results indicated that during dynamic vulcanization PDLA cocrystallized with PLLA to form stereocomplex（SC） crystallites,which not only enhanced the molecular entanglement but also accelerated the crystallization rate of PLLA matrix. With increase in the content of PDLA,the matrix molecular entanglement increased while phase-separation was enhanced,which enabled the impact strength to increase first and then decrease. The ternary blends containing 10 wt.% PDLA showed the highest impact strength. The presence of SC crystallites makes it possible to achieve a fully sustainable PLLA/VUB/PDLA ternary blend with highly crystalline matrix under conventional injection molding,due to the high nucleation efficiency of SC towards crystallization of PLLA. The highly crystalline ternary blend showed excellent heat resistance and better impact toughness than high impact polystyrene.展开更多
Positron annihilation spectroscopy (PAS) was utilized to investigate the relationship between the free-volume hole properties and miscibility of dynamically vulcanized EPDM/PP blend. The results showed that the noncry...Positron annihilation spectroscopy (PAS) was utilized to investigate the relationship between the free-volume hole properties and miscibility of dynamically vulcanized EPDM/PP blend. The results showed that the noncrystalline region of PP and EPDM in the blend was partially miscible and the miscibility of the blend became worse when the weight percent of EPDM was <50%. This was also demonstrated by DMTA and mechanical properties of the blends with various compositions.展开更多
基金supported by the National Science Foundation of China (51673158)the Opening Project of Key Laboratory of Polymer Processing Engineering (South China University of Technology),Ministry of Education (KFKT02)the Fundamental Research Funds for the Central Universities (XDJK2017A016 and XDJK2017C022)
文摘Inherent brittleness and low heat resistance are the two major obstacles that hinder the wide applications of poly（L-lactide）（PLLA）. In this study,we report a fully biobased,highly toughened and heat-resistant PLLA ternary blend,which was prepared by dynamic vulcanization of PLLA with poly（D-lactide）（PDLA） and an unsaturated bioelastomer（UBE）. The results indicated that during dynamic vulcanization PDLA cocrystallized with PLLA to form stereocomplex（SC） crystallites,which not only enhanced the molecular entanglement but also accelerated the crystallization rate of PLLA matrix. With increase in the content of PDLA,the matrix molecular entanglement increased while phase-separation was enhanced,which enabled the impact strength to increase first and then decrease. The ternary blends containing 10 wt.% PDLA showed the highest impact strength. The presence of SC crystallites makes it possible to achieve a fully sustainable PLLA/VUB/PDLA ternary blend with highly crystalline matrix under conventional injection molding,due to the high nucleation efficiency of SC towards crystallization of PLLA. The highly crystalline ternary blend showed excellent heat resistance and better impact toughness than high impact polystyrene.
基金This work was financially supported by 863 Programme of China No.863-715-012-0160
文摘Positron annihilation spectroscopy (PAS) was utilized to investigate the relationship between the free-volume hole properties and miscibility of dynamically vulcanized EPDM/PP blend. The results showed that the noncrystalline region of PP and EPDM in the blend was partially miscible and the miscibility of the blend became worse when the weight percent of EPDM was <50%. This was also demonstrated by DMTA and mechanical properties of the blends with various compositions.
