The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the ...The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the application of temporary plugging agents(TPAs)for their efficient development.TPAs can expand the stimulated reservoir volume(SRV)and facilitate the flow of oil and gas to the bottom of the well.Particle-gels used as temporary plugging agents have the characteristics of the simple injection process,good deformation,high plugging strength,and complete self-degradation performance,which have been widely applied in recent years.In this paper,five samples of DPPG polymerized by different molecular weights of cross-linking agents were prepared.In addition,infrared spectroscopy analysis,differential calorimetry scanning(DSC)analysis,static particle gel swelling and degradation performance evaluation experiments,and dynamic temporary plugging performance experiments in cores were conducted at 34°C.Results show that as the molecular weight of the cross-linking agent(at 0.01 g)in the DPPG molecule decreased from 1,000 to 200 Da,the fewer cross-linking sites of DPPG,the looser the microscopic three-dimensional mesh structure formed.The swelling ratio increased from 7 to 33 times.However,the complete degradation time increased from 40 to 210 min.Moreover,the DSC results confirmed that the higher the molecular weight of the cross-linking agent,the worse is chemical stability and the more prone it to self-degradation.DPPG samples had good temporary plugging performance in reservoir cores.DPPGs prepared by the cross-linking agent with smaller molecular weight has a stronger swelling ratio,higher gel strength,and greater plugging strength in the core permeabilities.Moreover,the degraded DPPG is less damaging to the cores.However,their slower degradation rates take a slightly longer times to reach complete degradation.The results of this paper can provide new ideas and a theoretical basis for the development of particle gel-type temporary plugging agents(TPA)with controllable degradation time in low-temperature reservoirs.It can help to expand the application range of existing DPPG reservoir conditions.展开更多
On the basis of summarizing the research on disaster risk at home and abroad, Shenyang, one of the cities with the most frequent meteorological disasters, was taken as an example. Cold chilling injury is one of the ma...On the basis of summarizing the research on disaster risk at home and abroad, Shenyang, one of the cities with the most frequent meteorological disasters, was taken as an example. Cold chilling injury is one of the major agricultural meteorological disasters, which poses a serious threat to the sustainable development of agriculture and food security in Jilin and Shenyang. Based on meteorological observation data of recent 65 years in Shenyang and microclimate monitoring data of agricultural facilities in two years, this paper makes statistical analysis by mathematical statistics and calculates the highest outdoor temperature, the lowest indoor air temperature and the highest ceiling temperature according to the meteorological grade index of agricultural facilities’ low temperature chilling damage, low temperature and other meteorological elements of grade indicators, analysis of greenhouse production trend of greenhouse climate change, and to discuss the relationship between temperature inside and outside the greenhouse and the facility microclimate conditions in agricultural cold weather disastrous and early warning services. The results showed that in the 21st century, the number of days with low temperature of ≤-20°C increased significantly compared with those in the 1970s, 1980s and 1990s. The risk of low temperature chilling injury in facility agriculture in Shenyang was dominated by mild and moderate low temperature risk. Shenyang low temperature cold damage warning services standards to reduce the impact of chilling injury on agricultural facilities and development.展开更多
Zirconia-based bioceramics have been widely applied in the field of prosthodontics owing to its desir- able mechanical performance, biocompatibility and aesthetics. However, the low-temperature degradation （LTD） of ...Zirconia-based bioceramics have been widely applied in the field of prosthodontics owing to its desir- able mechanical performance, biocompatibility and aesthetics. However, the low-temperature degradation （LTD） of tetragonal zirconia （ZrOJ under intraoral condition can lead to the deterioration of mechanical properties of ZrO2 dental crowns, which contribute to many clinical failures in long-term observations. The long-term tetragonal phase stability and mechanical properties of yttria-stabilized tetragonal zir- conia polycrystal （Y-TZP） are influenced by grain size of ZrO2 crystals, distribution and properties of stabilizers, the humid environment, etc. However, it is still difficult to control the abovementioned factors at the same time. This review summarizes the major advances in researches dealing with LTD and clari- fies the obstacles to stabilization of the tetragonal ZrO2. Furthermore, the suggestions on improving the LTD resistance of tetragonal ZrO2 are proposed, which is the catalyst to promote the long-term stability of ZrO2-based all-ceramic crowns.展开更多
Tie-series sediment trap materials at different water depths and surface sediments in northern and central South China Sea (SCS) were analyzed for organic carbon, amino acids, amino sugars and carbohydrates. Results s...Tie-series sediment trap materials at different water depths and surface sediments in northern and central South China Sea (SCS) were analyzed for organic carbon, amino acids, amino sugars and carbohydrates. Results show that particulate organic carbon (POC) is mainly derived from marine plankton, only 1.4%–1.6% of primary production sinks into deep SCS water column and less than 0.22 % of primary production ultimately reaches the sediments. The ranineralization and dissolution of organic matter as well as the compositional alterations of organic matter mixtures may mainly take place in the upper few hundred meters of water column, deep carbonate (opal) lysocline zones, and interface layers between sediments and water column, rather than in mid-waters. The organic geochemical parameters such as (T aa +T sug )OC%, AA/AS, Gluam/Galam, Arom. AA/non-prot. AA, ASP/b-ALA, Glu/g-ABA decrease from living marine plankton (or planktonic shells), to settling particulate matter and to sediments suggesting that they appear to be gad early degraded indicators of organic matter.展开更多
基金supported by the Research Foundation of China University of Petroleum-Beijing at Karamay (No. YJ2018B02002 and XQZX20200010)the Natural Science Foundation of Xinjiang Uygur Autonomous Region (No. 2021D01E23 and 2019D01B57)+3 种基金the University Scientific Research Project of Xinjiang Uygur Autonomous Region (No. XJEDU2019Y067)the Xinjiang Uygur Autonomous Region Innovation Environment Construction Project (No. 2019Q025)the Sichuan Province Regional Innovation Cooperation Project (No. 2020YFQ0036)the CNPC Strategic Cooperation Science and Technology Project (ZLZX2020-01-04-04)
文摘The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the application of temporary plugging agents(TPAs)for their efficient development.TPAs can expand the stimulated reservoir volume(SRV)and facilitate the flow of oil and gas to the bottom of the well.Particle-gels used as temporary plugging agents have the characteristics of the simple injection process,good deformation,high plugging strength,and complete self-degradation performance,which have been widely applied in recent years.In this paper,five samples of DPPG polymerized by different molecular weights of cross-linking agents were prepared.In addition,infrared spectroscopy analysis,differential calorimetry scanning(DSC)analysis,static particle gel swelling and degradation performance evaluation experiments,and dynamic temporary plugging performance experiments in cores were conducted at 34°C.Results show that as the molecular weight of the cross-linking agent(at 0.01 g)in the DPPG molecule decreased from 1,000 to 200 Da,the fewer cross-linking sites of DPPG,the looser the microscopic three-dimensional mesh structure formed.The swelling ratio increased from 7 to 33 times.However,the complete degradation time increased from 40 to 210 min.Moreover,the DSC results confirmed that the higher the molecular weight of the cross-linking agent,the worse is chemical stability and the more prone it to self-degradation.DPPG samples had good temporary plugging performance in reservoir cores.DPPGs prepared by the cross-linking agent with smaller molecular weight has a stronger swelling ratio,higher gel strength,and greater plugging strength in the core permeabilities.Moreover,the degraded DPPG is less damaging to the cores.However,their slower degradation rates take a slightly longer times to reach complete degradation.The results of this paper can provide new ideas and a theoretical basis for the development of particle gel-type temporary plugging agents(TPA)with controllable degradation time in low-temperature reservoirs.It can help to expand the application range of existing DPPG reservoir conditions.
文摘On the basis of summarizing the research on disaster risk at home and abroad, Shenyang, one of the cities with the most frequent meteorological disasters, was taken as an example. Cold chilling injury is one of the major agricultural meteorological disasters, which poses a serious threat to the sustainable development of agriculture and food security in Jilin and Shenyang. Based on meteorological observation data of recent 65 years in Shenyang and microclimate monitoring data of agricultural facilities in two years, this paper makes statistical analysis by mathematical statistics and calculates the highest outdoor temperature, the lowest indoor air temperature and the highest ceiling temperature according to the meteorological grade index of agricultural facilities’ low temperature chilling damage, low temperature and other meteorological elements of grade indicators, analysis of greenhouse production trend of greenhouse climate change, and to discuss the relationship between temperature inside and outside the greenhouse and the facility microclimate conditions in agricultural cold weather disastrous and early warning services. The results showed that in the 21st century, the number of days with low temperature of ≤-20°C increased significantly compared with those in the 1970s, 1980s and 1990s. The risk of low temperature chilling injury in facility agriculture in Shenyang was dominated by mild and moderate low temperature risk. Shenyang low temperature cold damage warning services standards to reduce the impact of chilling injury on agricultural facilities and development.
基金?nancially supported by the National Natural Science Foundation of China(No.81500897)China Scholarship Council(No.201408210385)+1 种基金Foundation of the Education Department of Liaoning Province in China(No.L2013285)Science and Technology Planning Project of Shenyang City(No.F11-262-9-16)
文摘Zirconia-based bioceramics have been widely applied in the field of prosthodontics owing to its desir- able mechanical performance, biocompatibility and aesthetics. However, the low-temperature degradation （LTD） of tetragonal zirconia （ZrOJ under intraoral condition can lead to the deterioration of mechanical properties of ZrO2 dental crowns, which contribute to many clinical failures in long-term observations. The long-term tetragonal phase stability and mechanical properties of yttria-stabilized tetragonal zir- conia polycrystal （Y-TZP） are influenced by grain size of ZrO2 crystals, distribution and properties of stabilizers, the humid environment, etc. However, it is still difficult to control the abovementioned factors at the same time. This review summarizes the major advances in researches dealing with LTD and clari- fies the obstacles to stabilization of the tetragonal ZrO2. Furthermore, the suggestions on improving the LTD resistance of tetragonal ZrO2 are proposed, which is the catalyst to promote the long-term stability of ZrO2-based all-ceramic crowns.
基金Project supported by the National Natural Science Foundation of China (Grant No. 49776297)Cruises financially supported by State Oceanic Administration and German Federal Ministry of Research and Technology
文摘Tie-series sediment trap materials at different water depths and surface sediments in northern and central South China Sea (SCS) were analyzed for organic carbon, amino acids, amino sugars and carbohydrates. Results show that particulate organic carbon (POC) is mainly derived from marine plankton, only 1.4%–1.6% of primary production sinks into deep SCS water column and less than 0.22 % of primary production ultimately reaches the sediments. The ranineralization and dissolution of organic matter as well as the compositional alterations of organic matter mixtures may mainly take place in the upper few hundred meters of water column, deep carbonate (opal) lysocline zones, and interface layers between sediments and water column, rather than in mid-waters. The organic geochemical parameters such as (T aa +T sug )OC%, AA/AS, Gluam/Galam, Arom. AA/non-prot. AA, ASP/b-ALA, Glu/g-ABA decrease from living marine plankton (or planktonic shells), to settling particulate matter and to sediments suggesting that they appear to be gad early degraded indicators of organic matter.
