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Tremendous change of the earth surface system and tectonic setting of salt-lake formation in Yuncheng Basin since 7.1 Ma 被引量:6
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作者 王强 张文治 +6 位作者 岳军 李彩光 刘椿 程自刚 田国强 宁联元 何翠英 《Science China Earth Sciences》 SCIE EI CAS 2002年第2期110-122,共13页
The Yuncheng salt lake has formed under the setting of stepped subsidence of fault-blocks from the north to the south in Yuncheng Basin. In the phase of red clay accumulation during 7.1–3.6 Ma, the size of palaeo-lak... The Yuncheng salt lake has formed under the setting of stepped subsidence of fault-blocks from the north to the south in Yuncheng Basin. In the phase of red clay accumulation during 7.1–3.6 Ma, the size of palaeo-lake was larger than the present salt lake, and palaeo-monsoon had formed. At 3.6 Ma, the northern basement in the basin raised abruptly due to the radiative effect of Qinghai-Tibet Plateau uplifting, and palaeo-lake was contracting southwards. At ca. 2.6 Ma ancient river flowed into the northern part of the basin. During ca. 2.0–1.9 Ma aerolian effect strengthened and loess started to accumulate on the most part of the basin. Since ca. 1.8–1.0 Ma the subsidence of the lake fault-block has been speeding up abruptly. As under the natural hydrogradient the salt lake received enough groundwater supply, and the rate of loess accumulation in the lake area was lower than that of subsidence of the lake fault-block, the lake could be preserved and becomes the only modern lake on Chinese Loess Plateau. Four large strengthening change records of the monsoon were found in the lake sequence of 5.8–1.9 Ma B.P. 展开更多
关键词 Yuncheng salt lake tremendous change of the earth surface system loess and lake palaeomonsoon PALAEOLIMNOLOGY
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Understanding the Interactions between Climate Change,Landscape Evolution,Surface Processes and Tectonics in the Earth System:What Can the Studies of Chinese Deserts Contribute? 被引量:5
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作者 YANG Xiaoping Bernhard EITEL 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第4期1444-1454,共11页
Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in de... Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in deserts are, however, diverse and different over the globe with regard to their geomorphological nature, human activities and geological histories. In the last decades a great number of efforts have been put to the investigation of the initial timing of the occurrence of arid climate, e. g. in northwestern China. Silty sediments in the downwind directions have been used to deduce the histories of deserts. In general, there is a lack of knowledge about processes and landscapes in Chinese drylands between the initial Miocene silt sedimentation at desert margins and the late Quaternary multiple occurrences of wetter climate with assumed large lakes in many of the deserts in northern China. The geomorphological concept of three primary triggering factors, i.e., the sediment supply, sediment availability and transport capacity of wind, and additionally the underground geology need to be fully considered for a better understanding of the environmental histories of sand seas which should not be viewed as equivalent for deserts because sand seas cover between 〈 1% and ca. 45% of the desert areas in various continents dependent on a complex interaction between various processes of both exogenous and endogenous origins. 展开更多
关键词 DESERT sand sea earth surface process global change Quaternary geology GEOMORPHOLOGY
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Pretreatment of Chrysotile With Rare Earth Compounds Lowered Its Cytotoxicity by Lessening Surface Charges 被引量:1
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作者 FAN JING-GUANG WANG QI-EN +3 位作者 LIU SHI-JIE WU WEI-DONG JIA GUANG AND ZHOU LI-LI(National Institute for Occupational Safety and Health, Ministry of Labour, Beijing 100029, China Department of Occupational Health, School of Public Health, Beijing Medical Univers 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 1998年第2期125-132,共8页
Pathological effects of asbestos are probably dependent on the special surface properties of the fibers, such as surface charge, surface metal ions. The present study was designed to determine whether the pretreatment... Pathological effects of asbestos are probably dependent on the special surface properties of the fibers, such as surface charge, surface metal ions. The present study was designed to determine whether the pretreatment of chrysotile asbestos fibers (CAF) with rare earth compounds (REC) solution can reduce their pathogenicity. The results showed that REC-pretreated CAF induced less nitrogen oxide (NO) production by alveolar macrophages (AM). In addition, the pretreatment lowered the capacity of hemolysis and the methylene blue (MB) adsorption of the native CAF. These findings suggested that the pretreatment of CAF with REC solution reduced the in vitro toxicity of CAF by lessening its surface charges. Nevertheless, the pathogenicity and the carcinogenicity of REC-pretreated CAF in vivo remain to be investigated. 展开更多
关键词 BR Pretreatment of Chrysotile With Rare earth Compounds Lowered Its Cytotoxicity by Lessening surface Charges
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Limit analysis method for active earth pressure on laggings between stabilizing piles 被引量:2
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作者 WANG Ming-min WU Shu-guang WANG Gui-lin 《Journal of Mountain Science》 SCIE CSCD 2017年第1期196-204,共9页
Stabilizing pile is a kind of earth shoring structure frequently used in slope engineering. When the piles have cantilever segments above the ground,laggings are usually installed to avoid collapse of soil between pil... Stabilizing pile is a kind of earth shoring structure frequently used in slope engineering. When the piles have cantilever segments above the ground,laggings are usually installed to avoid collapse of soil between piles. Evaluating the earth pressure acting on laggings is of great importance in design process.Since laggings are usually less stiff than piles,the lateral pressure on lagging is much closer to active earth pressure. In order to estimate the lateral earth pressure on lagging more accurately,first,a model test of cantilever stabilizing pile and lagging systems was carried out. Then,basing the experimental results a three-dimensional sliding wedge model was established. Last,the calculation process of the total active force on lagging is presented based on the kinematic approach of limit analysis. A comparison is made between the total active force on lagging calculated by the formula presented in this study and the force on a same-size rigid retaining wall obtained from Rankine's theory. It is found that the proposed method fits well with the experimental results.Parametric studies show that the total active force on lagging increases with the growth of the lagging height and the lagging clear span; while decreases asthe soil internal friction angle and soil cohesion increase. 展开更多
关键词 Stabilizing pile Lagging Active earth pressure Limit analysis method Sliding surface
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Evidences of the expanding Earth from space-geodetic data over solid land and sea level rise in recent two decades 被引量:2
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作者 Shen Wenbin Shen Ziyu +1 位作者 Sun Rong Barkin Yuri 《Geodesy and Geodynamics》 2015年第4期248-252,共5页
According to the space-geodetic data recorded at globally distributed stations over solid land spanning a period of more than 20-years under the International Terrestrial Reference Frame 2008,our previous estimate of ... According to the space-geodetic data recorded at globally distributed stations over solid land spanning a period of more than 20-years under the International Terrestrial Reference Frame 2008,our previous estimate of the average-weighted vertical variation of the Earth's solid surface suggests that the Earth's solid part is expanding at a rate of 0.24 ± 0.05 mm/a in recent two decades.In another aspect,the satellite altimetry observations spanning recent two decades demonstrate the sea level rise(SLR) rate 3.2 ± 0.4 mm/a,of which1.8 ± 0.5 mm/a is contributed by the ice melting over land.This study shows that the oceanic thermal expansion is 1.0 ± 0.1 mm/a due to the temperature increase in recent half century,which coincides with the estimate provided by previous authors.The SLR observation by altimetry is not balanced by the ice melting and thermal expansion,which is an open problem before this study.However,in this study we infer that the oceanic part of the Earth is expanding at a rate about 0.4 mm/a.Combining the expansion rates of land part and oceanic part,we conclude that the Earth is expanding at a rate of 0.35 ± 0.47 mm/a in recent two decades.If the Earth expands at this rate,then the altimetry-observed SLR can be well explained. 展开更多
关键词 ITRF2008 coordinates Ice melting Thermal expansion earth expansion Sea level rise (SLR)Space-geodetic data Velocities altimetry earth's solid surface
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Estimate Totel Number of the Earth Atmospheric Particle with Standard Atmosphere model
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作者 GAOChong-Yi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2001年第5期639-640,共2页
The total number of atmospheric particle (AP) is an important datum for planetary science and geoscience. Estimating entire AP number is also a familiar question in general physics. With standard atmosphere model, con... The total number of atmospheric particle (AP) is an important datum for planetary science and geoscience. Estimating entire AP number is also a familiar question in general physics. With standard atmosphere model, considering the number difference of AP caused by rough and uneven in the earth surface below, the sum of dry clean atmosphere particle is . So the whole number of AP including water vapor is . The rough estimation for the total number of AP on other planets (or satellites) in condensed state is also discussed on the base of it. 展开更多
关键词 planetary atmosphere earth atmosphere neutral atmosphere total number of atmospheric particle standard atmosphere model effect of uneven in the earth surface estimation
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Comparison of TMI and AMSR-E sea surface temperatures with Argo near-surface temperatures over the global oceans 被引量:1
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作者 CHEN Xingrong LIU Zenghong +1 位作者 SUN Chaohui WANG Haiyan 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第3期52-59,共8页
Satellite-derived sea surface temperatures(SSTs) from the tropical rainfall measuring mission(TRMM)microwave imager(TMI) and the advanced microwave scanning radiometer for the earth observing system(AMSR-E) we... Satellite-derived sea surface temperatures(SSTs) from the tropical rainfall measuring mission(TRMM)microwave imager(TMI) and the advanced microwave scanning radiometer for the earth observing system(AMSR-E) were compared with non-pumped near-surface temperatures(NSTs) obtained from Argo profiling floats over the global oceans. Factors that might cause temperature differences were examined, including wind speed, columnar water vapor, liquid cloud water, and geographic location. The results show that both TMI and AMSR-E SSTs are highly correlated with the Argo NSTs; however, at low wind speeds, they are on average warmer than the Argo NSTs. The TMI performs slightly better than the AMSR-E at low wind speeds, whereas the TMI SST retrievals might be poorly calibrated at high wind speeds. The temperature differences indicate a warm bias of the TMI/AMSR-E when columnar water vapor is low, which can indicate that neither TMI nor AMSR-E SSTs are well calibrated at high latitudes. The SST in the Kuroshio Extension region has higher variability than in the Kuroshio region. The variability of the temperature difference between the satellite-retrieved SSTs and the Argo NSTs is lower in the Kuroshio Extension during spring. At low wind speeds, neither TMI nor AMSR-E SSTs are well calibrated, although the TMI performs better than the AMSR-E. 展开更多
关键词 Argo near-surface temperature tropical rainfall measuring mission(TRMM) microwave imager advanced microwave scanning radiometer for the earth observing system sea surface temperature
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Watershed systems science—A new paradigm to understand and govern the impact of human activities on the earth's surface in the Anthropocene
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作者 Ray ISON YongPing WEI 《Science China Earth Sciences》 SCIE EI CAS CSCD 2017年第12期2225-2227,共3页
Recent scholars’work in Vol 58 Issue 1(2015)and Cheng and Li’s paper in Vol 58 Issue 7(2015)in Science China Earth Sciences propose development of"Watershed science"by"Bridging new advances in hydrological sc... Recent scholars’work in Vol 58 Issue 1(2015)and Cheng and Li’s paper in Vol 58 Issue 7(2015)in Science China Earth Sciences propose development of"Watershed science"by"Bridging new advances in hydrological science with good management of river basins". 展开更多
关键词 human activities the earth's surface the Anthropocene
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Earth surface processes and their effects on human behavior in monsoonal China during the Pleistocene-Holocene epochs 被引量:12
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作者 LU Huayu ZHUO Haixin +6 位作者 ZHANG Wenchao WANG Shejiang ZHANG Hongyan SUN Xuefeng JIA Xin XU Zhiwei WANG Xianyan 《Journal of Geographical Sciences》 SCIE CSCD 2017年第11期1311-1324,共14页
There is a wide diversity of landforms in China. The topography of three major ter- races, decreasing in height stepwise from west to east, was formed by the early Miocene. With the commencement of the Great Northern ... There is a wide diversity of landforms in China. The topography of three major ter- races, decreasing in height stepwise from west to east, was formed by the early Miocene. With the commencement of the Great Northern Hemisphere Glaciations (GHGs) and the glacial-interglacial cycles in the Pleistocene, thick loess deposits accumulated in north China, and fluvial terraces were formed and lakes expanded and contracted in eastern and central China. The earliest evidence of hominins in China is dated to ~1.7 Ma; they occupied the monsoon-dominated region for a long interval, until the late Pleistocene, ~50 ka. In this study, we investigated a large area rich in the relics and artifacts of early man. The results indicate that the early humans occupied riverine areas, especially medium-sized fluvial basins, and lake shores. Even in the relatively recent geological past, the occupation and abandonment of settlements were directly forced by the shifting of sand dune fields in the desert-loess transi- tional zone, which in turn was closely associated with variations in the monsoon climate and vegetation patterns. Our observations indicate that landforms were one of the main determi- nants of early human behavior, in that loess tableland, large alluvial plains, desert-Gobi areas, and the Tibetan Plateau, were not suitable environments for early human settlement. We infer that the early humans in China adapted their behavior to specific landforms and landform processes. The monsoon climate, which shapes the large-scale step-like pattern of fluvial landforms, promotes vegetation coverage and dominates soil formation, provides a crucial context for early human adaptation. The adaptation of early humans to earth surface proc- esses in East Asia is investigated for the first time in this study. Future investigations will provide further information that will increase our understanding of the linkage between early human behavior and landform processes in East Asia. 展开更多
关键词 earth surface processes early human behavior MONSOON PLEISTOCENE HOLOCENE China
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From Physical Space to Visual Image Space 被引量:1
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作者 YE Zetian LIN Hui LIU Xianlin YE Zetian, Ph.D, Chinese Academy of Surveying and Mapping, 16 Beitaiping Road, Haidian District, Beijing 100039, China. 《Geo-Spatial Information Science》 2003年第2期42-47,共6页
The theoretical framework of visual simulation in virtual reality is discussed. The new concept of visual image space is supposed. On the basis of visual image space, in visual perceptive sense, VR is considered as a ... The theoretical framework of visual simulation in virtual reality is discussed. The new concept of visual image space is supposed. On the basis of visual image space, in visual perceptive sense, VR is considered as a spatial simulation. The objective of the spatial simulation is to transform physical space to visual image space. Last, the prototype system, surveying & mapping virtual Reality (SMVR), is developed, and the space simulation above is realized. By use of SMVR, the real 3D representation, 3D visual analysis, virtual plan and designs can be implemented. 展开更多
关键词 virtual reality physical space visual image space space of earth surface space simulation
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A holistic framework for facilitating environmental and human health 被引量:1
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作者 Yihe Lv Da Lv +1 位作者 Guangyao Gao Bojie Fu 《Geography and Sustainability》 2021年第4期298-303,共6页
In the Anthropocene,health is necessary to achieve global sustainable development.This is a challenge because health issues are complex and span from humans to ecosystems and the environment through dynamic interac-ti... In the Anthropocene,health is necessary to achieve global sustainable development.This is a challenge because health issues are complex and span from humans to ecosystems and the environment through dynamic interac-tions across scales.We find that the health issues have been mainly addressed by disciplinary endeavors which unfortunately will not result in panoramic theories or effective solutions.We recommend focusing on the intri-cate interactions between humans,ecosystems and the environment for developing common theoretical under-standings and practical solutions for safeguarding planetary health,with human health as the key indicator and endpoint.To facilitate this paradigm shift,a holistic framework is formulated that incorporates disturbances from inner Earth and our solar system,and accommodates interactions between humans,ecosystems and the environ-ment in a nested hierarchy.An integrative and transdisciplinary health science is advocated along with holistic thinking to resolve our current health challenges and to achieve the health-related sustainable development goals. 展开更多
关键词 Health science surface earth system Human environment interactions Environmental pollution Sustainable development
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Decomposition of the mixed rare earth concentrate by microwave-assisted method 被引量:10
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作者 黄宇坤 张廷安 +2 位作者 刘江 豆志河 田俊行 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第5期529-535,共7页
A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the... A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the leaching behavior of rare earth elements(REEs),and an interpretation of the interrelationship between mineralogy,decomposition process,and leaching process were provided in this study.The influences of the temperature,time of microwave heating and contents of NaO H(mass ratio of NaO H to mixed rare earth concentrate)on the decomposition of mixed rare earth concentrate were investigated.The results revealed that the temperature was the main factor affecting the decomposition process.The recovery of REEs by hydrochloric acid leaching reached 93.28% under the microwave heating conditions:140 oC,30 min and 35.35% NaO H.The BET specific surface area and SEM analysis indicated that the particles of mixed rare earth concentrate were non-hole,while the particles presented a porous structure after heating the concentrate by microwave radiation.For the microwave treated sample after water leaching,the BET specific surface area was 11.04 m^2/g,which was higher than the corresponding values(6.94 m^2/g)for the mixed rare earth concentrate.This result could be attributed to the phase changes of bastnaesite and monazite,and a number of cracks induced by thermal stress.The increase of BET specific surface area resulted in an increase of the recovery of REEs by promoting interaction within the system of acid leaching. 展开更多
关键词 mixed rare earth microwave heating leaching behavior specific surface area microstructure
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Surface characteristics of Y3Al5O12:Ce^3+ phosphor with greatly enhanced photoluminescence after chemical defect-selective etching 被引量:2
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作者 孔荀 何志江 梁荣庆 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第10期972-977,共6页
The surface of a commercial Y3Al5O12:Ce^3+ phosphor was modified by 99% NH_4F+CH_3COOH solution in a supersonic bath with water temperature of 80 oC for 4 h. The scanning electron microscopy(SEM) results showed t... The surface of a commercial Y3Al5O12:Ce^3+ phosphor was modified by 99% NH_4F+CH_3COOH solution in a supersonic bath with water temperature of 80 oC for 4 h. The scanning electron microscopy(SEM) results showed that the edge angles were not as sharp as the unmodified particles and the flat surfaces turned rough with many micro-structures covered. Positron lifetime measurements quantitatively showed that surface defects were removed away by more than 50%. As a result, the photoluminescence determinations showed that the backscatter loss was reduced by 4.2% and the emission power was enhanced by 5.6% after the surface modification. The conversion efficiency was greatly improved from 47.3% to 51.1%, as presented by the fluorescence images. Therefore, it would be greatly helpful for the improvement of efficiency, transparency and stability of pc-LED. Moreover, this method was significantly suitable for mass production due to its easy operation and low cost. 展开更多
关键词 YAG phosphor surface modification wet etching solid state reaction rare earths
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Retrospect and prospect of Geographical Sciences in China: A comparison with the Strategic Directions for Geography in the USA 被引量:4
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作者 SUN Jun PAN Yujun +1 位作者 TANG Maolin WU Youde 《Journal of Geographical Sciences》 SCIE CSCD 2013年第6期963-977,共15页
Understanding the Changing Planet: Strategic Directions for the Geographical Sciences (UCP), published by the National Research Council (USA), and its comments in The Professional Geographer propose that uppercas... Understanding the Changing Planet: Strategic Directions for the Geographical Sciences (UCP), published by the National Research Council (USA), and its comments in The Professional Geographer propose that uppercase and plural "Geographical Sciences" (GS) is the strategic direction for geography in the next decade for better understanding of our rapidly changing planet. According to these comments, UCP valued technologies and tools exces- sively ("task"), and did not pay much attention to methodology ("discipline"). Actually, both "task" and "discipline" are geographical wings, especially in the time of "big science". Enlightenment from UCP and its comments is the strategic direction that should be balanced between "task" and "discipline", GS should be a three-dimensional construct of a disciplinary system, methodology, and technologies and tools, and this system should be scientific hu- manism based on scientific spirit and directed by humanism. During the last 60 years, Chi- nese geographers devoted themselves to GS, including practice and theory. Obviously pro- gress and outlook are proposed as interdisciplinary GS, Earth Surface Sciences (ESS) and Geographical Construction (GC). The disciplinary system of GS is very complex, and is composed of such human knowledge domains as sciences, technologies, engineering, and philosophy. The main mission is to research the open, complex, and macro earth system (not only scientifically, but also humanistically), and one significant methodology is "comprehen- sive integration of qualitative and quantitative means" (CIQQM). At the same time, another changing direction in Chinese geography is Human-Economic Geography (HEG). 展开更多
关键词 strategic directions for geography geographical sciences earth surface sciences geographical con-struction human-economic geography China
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Barium isotope cosmochemistry and geochemistry 被引量:2
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作者 Quentin Charbonnier Frederic Moynier Julien Bouchez 《Science Bulletin》 SCIE EI CSCD 2018年第6期385-394,共10页
While the isotopic variations of barium were reported for the first time fourty years ago, the number of studies on barium isotopes significantly increased only after 2010. Barium isotope anomalies in meteorites have ... While the isotopic variations of barium were reported for the first time fourty years ago, the number of studies on barium isotopes significantly increased only after 2010. Barium isotope anomalies in meteorites have been successfully used to provide constraints about the origin of presolar Si C grains. In carbonaceous chondrites Ba isotope anomalies are indicative of the heterogeneity of the early solar system, possibly resulting from of a later injection of material after the cooling of solar system. Barium isotope fractionation in the same carbonaceous chondrites suggests that a strong magnetic field was present in the innermost part of the early solar system. Barium mass-dependent isotope fractionation has also been detected throughout Earth surface materials. While igneous rocks show limited Ba isotopic variations, relatively large isotopic variations are observed amongst and within soils, rivers, and biological materials. Indeed, plants seem to fractionate Ba isotopes during Ba uptake from soil solutions.Therefore, Ba isotope signatures have the potential to provide clues on the biological cycling of Ba at the Earth surface. In seawater, Ba isotopic variations have been mapped out, and are mainly related to barite precipitation, which is in turn related to organic matter remineralization in the water column.This makes Ba isotopes a potentially powerful tool to reconstruct past ocean productivity, although constraints are still lacking regarding the inputs of dissolved Ba to the oceans by rivers or hydrothermalism. 展开更多
关键词 BARIUM METEORITES earth surface Critical zone
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Tribological properties of nanometer cerium oxide as additives in lithium grease 被引量:7
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作者 Qiang He Anling Li +3 位作者 Yachen Guo Songfeng Liu Yong Zhang Linghao Kong 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第2期209-214,共6页
This paper presents a comparative study of the influence of nanometer-CeO_2(nano-CeO_2) and temperature on tribological and lubricating properties of lithium grease. The morphology and structure of nanocrystals were... This paper presents a comparative study of the influence of nanometer-CeO_2(nano-CeO_2) and temperature on tribological and lubricating properties of lithium grease. The morphology and structure of nanocrystals were characterized by means of transmission electron microscopy(TEM) and X-ray diffraction(XRD), respectively. Friction and wear tests were conducted on the friction and wear tester.Results show that the lithium grease with addition of nanometer-CeO_2 has much better friction-reducing and anti-wear performance than that of base grease. When the additive in grease is 0.6 wt%, the friction coefficient(COF) and wear scar diameter(WSD) decrease by 28% and 13% comparing with base grease,respectively. The base grease and grease with 0.6 wt% nanometer-CeO_2 both possess the lowest average COF and wear width at 50 ℃. The worn surface morphology after friction test was analyzed by scanning electron microscopy(SEM) and NANOVEA three-dimensional profilometer. Under the lubrication of the lithium grease containing 0.6 wt% nano-CeO_2. few shallow furrows can be observed on the quite smoothed surface and the WSD decreased. Moreover, It was found that the nano-CeO_2 has been incorporated into the surface protective and lubricious layer by energy dispersive spectrometer(EDS) analysis. 展开更多
关键词 Nano-CeO2 Tribological properties Lithium grease Worn surface Rare earths Additive
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Modification of Cu/ZSM-5 catalyst with CeO_2 for selective catalytic reduction of NO_x with ammonia 被引量:15
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作者 刘雪松 吴晓东 +1 位作者 翁端 石磊 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第10期1004-1009,共6页
Cu/ZSM-5 and CeO_2-modified Cu/ZSM-5 catalysts were prepared by a wetness impregnation method. The addition of CeO_2 was found to enhance the NO_x selective catalytic reduction(SCR) activity of the catalyst at low t... Cu/ZSM-5 and CeO_2-modified Cu/ZSM-5 catalysts were prepared by a wetness impregnation method. The addition of CeO_2 was found to enhance the NO_x selective catalytic reduction(SCR) activity of the catalyst at low temperatures, but the high-temperature activity was weakened. The catalysts were characterized by X-ray diffraction(XRD), nitrogen physisorption, inductively coupled plasma optical emission spectrometry(ICP-OES), X-ray photoelectron spectroscopy(XPS), electron paramagnetic resonance(EPR), H_2 temperature-programmed reduction(TPR) and NH_3 temperature-programmed desorption(TPD). The results showed that more CuO clusters instead of isolated Cu^(2+) species were obtained on the modified catalyst. These active CuO clusters, as well as the Cu-Ce synergistic effect, improved the redox property of the catalyst and low-temperatures SCR activity via promoting the oxidation of NO to NO_2 and fast SCR reaction. The loss in high-temperatures activity was attributed to the enhanced competitive oxidation of NH_3 by O_2 and decreased surface acidity of the catalyst. 展开更多
关键词 Cu/ZSM-5 CeO_2 modification NH3-SCR CuO clusters surface acid sites rare earths
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