Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challengin...Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challenging.Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with Y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching properties.As a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance improvements.Our findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells.展开更多
Local production of rice has struggled to meet local demand despite its suitability for cultivation in many parts of Nigeria.Using data from 240 rice farmers, this study examined the economic efficiency of rice produc...Local production of rice has struggled to meet local demand despite its suitability for cultivation in many parts of Nigeria.Using data from 240 rice farmers, this study examined the economic efficiency of rice production and the effects of financial inclusion on the economic efficiency of rice farming in Ogun State, Nigeria. Data were analyzed using the Stochastic Cost Frontier model with inefficiency effects.展开更多
The spatial and temporal variation of green economic efficiency and its driving factors are of great significance for the construction of high-efficiency and low-consumption green development model and sustainable soc...The spatial and temporal variation of green economic efficiency and its driving factors are of great significance for the construction of high-efficiency and low-consumption green development model and sustainable socio-economic development.The research focused on the Yangtze River Economic Belt(YREB)and employed the miniumum distance to strong efficient frontier DEA(MinDs)model to measure the green economic efficiency of the municipalities in the region between 2008 and 2020.Then,the spatial autocorrelation model was used to analyze the evolution characteristics of its spatial pattern.Finally,Geodetector was applied to reveal the drivers and their interactions on green economic efficiency.It is found that:1)the overall green economic efficiency of the YREB from 2008 to 2020 shows a W-shaped fluctuating upward trend,green economic efficiency is greater in the downstream and smallest in the upstream;2)the spatial distribution of green economic efficiency shows clustering characteristics,with multi-core clustering based on‘city clusters-central cities'becoming more obvious over time;the High-High agglomeration type is mainly clustered in Jiangsu and Zheji-ang,while the Low-Low agglomeration type is clustered in the western Sichuan Plateau area and southwestern Yunnan;3)from input-output factors,whether it is the YREB as a whole or the upper,middle and lower reaches regions,the economic development level,labor input,and capital investment are the leading factors in the spatial-temporal evolution of green economic efficiency,with the com-prehensive influence of economic development level and pollution index being the most important interactive driving factor;4)from so-cio-economic factors,information technology drivers such as government intervention,transportation accessibility,information infra-structure,and Internet penetration are always high impact influencers and dominant interaction factors for green economic efficiency in the YREB and the three major regions in the upper,middle and lower reaches.Accordingly,the article puts forward relevant policy re-commendations in terms of formulating differentiated green transformation strategies,strengthening network leadership and informa-tion technology construction and coordinating multi-factor integrated development,which could provide useful reference for promoting synergistic green economic efficiency in the YREB.展开更多
This study estimates the technical, allocative, and economic efficiency of maize-producing farms in Benin and identifies the determining factors of these efficiencies in the context of adaptation to climate change. To...This study estimates the technical, allocative, and economic efficiency of maize-producing farms in Benin and identifies the determining factors of these efficiencies in the context of adaptation to climate change. To achieve this, data was collected from a sample of 402 corn farmers randomly selected from the municipalities most vulnerable to the effects of climate change and located within the Okpara watershed perimeters. The parametric stochastic frontier approach was adopted to estimate a seedling-log stochastic frontier and a dual cost function of corn farms using the Frontier program of Stata 13 software. The Tobit regression model was used to identify the factors determining the efficiency of producers. The results show that the operators are all technically efficient and have significant random effects. However, the results from the cost frontier show the presence of allocative inefficiency within production units. The estimated technical, allocative, and economic efficiencies are, respectively, 0.94, 0.60 and 0.57 on average. Finally, estimation of the determinants of efficiency has shown that the supply of mineral manure, experience in maize production, crop rotation as well as the level of education are the main determinants of efficiency. It is necessary to support corn producers on cultivation techniques, subsidize fertilizers, and promote literacy in the face of the effects of climate change.展开更多
Controlled-release urea(CRU)is commonly used to improve the crop yield and nitrogen use efficiency(NUE).However,few studies have investigated the effects of CRU in the ratoon rice system.Ratoon rice is the practice of...Controlled-release urea(CRU)is commonly used to improve the crop yield and nitrogen use efficiency(NUE).However,few studies have investigated the effects of CRU in the ratoon rice system.Ratoon rice is the practice of obtaining a second harvest from tillers originating from the stubble of the previously harvested main crop.In this study,a 2-year field experiment using a randomized complete block design was conducted to determine the effects of CRU on the yield,NUE,and economic benefits of ratoon rice,including the main crop,to provide a theoretical basis for fertilization of ratoon rice.The experiment included four treatments:(i)no N fertilizer(CK);(ii)traditional practice with 5 applications of urea applied at different crop growth stages by surface broadcasting(FFP);(iii)one-time basal application of CRU(BF1);and(iv)one-time basal application of CRU combined with common urea(BF2).The BF1 and BF2 treatments significantly increased the main crop yield by 17.47 and 15.99%in 2019,and by 17.91 and 16.44%in 2020,respectively,compared with FFP treatment.The BF2 treatment achieved similar yield of the ratoon crop to the FFP treatment,whereas the BF1 treatment significantly increased the yield of the ratoon crop by 14.81%in 2019 and 12.21%in 2020 compared with the FFP treatment.The BF1 and BF2 treatments significantly improved the 2-year apparent N recovery efficiency,agronomic NUE,and partial factor productivity of applied N by 11.47-16.66,27.31-44.49,and 9.23-15.60%,respectively,compared with FFP treatment.The BF1 and BF2 treatments reduced the chalky rice rate and chalkiness of main and ratoon crops relative to the FFP treatment.Furthermore,emergy analysis showed that the production efficiency of the BF treatments was higher than that of the FFP treatment.The BF treatments reduced labor input due to reduced fertilization times and improved the economic benefits of ratoon rice.Compared with the FFP treatment,the BF1 and BF2 treatments increased the net income by 14.21-16.87 and 23.76-25.96%,respectively.Overall,the one-time blending use of CRU and common urea should be encouraged to achieve high yield,high nitrogen use efficiency,and good quality of ratoon rice,which has low labor input and low apparent N loss.展开更多
This paper considers a high energy efficiency dynamic connected(HEDC)structure,which promotes the practicability and reduces the power consumption of hybrid precoding system by lowresolution phase shifters(PSs).Based ...This paper considers a high energy efficiency dynamic connected(HEDC)structure,which promotes the practicability and reduces the power consumption of hybrid precoding system by lowresolution phase shifters(PSs).Based on the proposed structure,a new hybrid precoding algorithm is presented to optimize the energy efficiency,namely,HP-HEDC algorithm.Firstly,via a new defined effective optimal precoding matrix,the problem of optimizing the analog switch precoding matrix is formulated as a sparse representation problem.Thus,the optimal analog switch precoding matrix can be readily obtained by the branch-and-bound method.Then,the digital precoding matrix optimization problem is modeled as a dictionary update problem and solved by the method of optimal direction(MOD).Finally,the diagonal entries of the analog PS precoding matrix are optimized by exhaustive search independently since PS and antenna is one-to-one.Simulation results show that the HEDC structure enjoys low power consumption and satisfactory spectral efficiency.The proposed algorithm presents at least 50%energy efficiency improvement compared with other algorithms when the PS resolution is set as 3-bit.展开更多
Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency ...Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency changes and analyze the impact mechanism and realization path of industrial transformation on green economic efficiency. The research results show that advanced industrial structure has a positive influence on green economic efficiency nationwide, while energy utilization structure and energy utilization efficiency have positive partial intermediary effects in the influence path;industrial structure rationalization is also significantly positively related to green economic efficiency nationwide, and the mediating effect of energy utilization is positive. The impact of industrial transformation on green economic efficiency has regional heterogeneity, and the mediating effect of energy use also differs. Among them, the impact effect in the eastern region is basically consistent with the national sample, but is negative in the central and western regions. This paper proposes countermeasures in terms of adjusting the industrial structure, improving energy efficiency, and perfecting industrial and energy policies, which can provide theoretical and practical references for promoting the transformation and upgrading of regional industrial structure, optimizing energy utilization, and advancing the efficiency of the national and regional green economy.展开更多
A well-developed financial market system is crucial for supporting high-quality development in the new era.Initial Public Offerings(IPOs)are essential for enabling financial markets to facilitate new industrialization...A well-developed financial market system is crucial for supporting high-quality development in the new era.Initial Public Offerings(IPOs)are essential for enabling financial markets to facilitate new industrialization while accelerating the development of a manufacturing powerhouse.Therefore,research on IPO mechanism reform holds significant practical implications.This paper examines the impact of China’s IPO mechanism reform by studying the equilibrium relationship between the primary market and the lending market.Using empirical analysis,we compare the average return on online subscriptions for newly listed shares using the risk-free rate before and after China’s 2015 IPO mechanism reform,as well as analyze the underlying mechanisms driving excess returns during both periods.Our findings indicate a gradual alignment of returns in the primary and lending markets,with institutional arbitrage opportunities between them diminishing.The reforms have effectively enhanced market mechanisms,improved pricing capabilities,rationalized participant behavior,and optimized the securities market ecosystem.These improvements have contributed to the market’s equilibrium and enhanced the market’s ability to interpret information.However,further improvements to the IPO mechanism are necessary,including deeper market-oriented reforms,standardization of participant behavior,acceleration of a comprehensive registration system,and stronger information disclosure and quality management.展开更多
The national independent innovation demonstration zone(NIIDZ)is an independent innovation policy that plays a crucial role in implementing strategies.Given the importance of the NIIDZ,this study uses panel data of 278...The national independent innovation demonstration zone(NIIDZ)is an independent innovation policy that plays a crucial role in implementing strategies.Given the importance of the NIIDZ,this study uses panel data of 278 prefecture-level cities in China from 2006 to 2020 and empirically examines the effect and internal mechanism of the NIIDZ on green economic efficiency(GEE)using the difference-in-difference model(DID).The results show that the NIIDZ effectively enhances the growth of GEE,and the results remain valid through several robustness tests,such as year-by-year propensity score matching.The transmission mechanism suggests that the NIIDZ indirectly drives GEE by accelerating scientific and technological investment,promoting talent concentration,and optimizing the industrial structure.Moreover,heterogeneity analysis reveals that the promotion effect of the NIIDZ on GEE is more prominent in the eastern region and high green development level areas.The study’s findings can serve as a reference for China to further utilize the policy effectiveness of the NIIDZ and accelerate the high-quality development of the green economy in the future.展开更多
This paper adopts the non-expected output-super-efficiency SBM(Slacks-Based Model)model and principal component analysis to calculate the green economy efficiency and the digital economy level of 27 prefecture-level c...This paper adopts the non-expected output-super-efficiency SBM(Slacks-Based Model)model and principal component analysis to calculate the green economy efficiency and the digital economy level of 27 prefecture-level cities in China’s Yangtze River Delta urban agglomeration between 2011 and 2019,respectively,and examines the impact of the digital economy on the green economy efficiency by using benchmark regression and mechanism analysis.The findings show that,first,the digital economy has a significant contribution to the green economic efficiency of cities,and this conclusion still holds after robustness tests such as replacing explanatory and interpreted variables and introducing province-fixed effects.Second,through the mechanism test,it is found that the digital economy can indirectly promote urban green economic efficiency through the positive mechanism effect of promoting industrial structure upgrading.展开更多
Major plant species in the Xilin River Basin were grouped into six plant functional groups (PFGs) based on their water ecological groups: xerophytes, mesoxerophytes, xeromesophytes, mesophytes, hygromesophytes and hyg...Major plant species in the Xilin River Basin were grouped into six plant functional groups (PFGs) based on their water ecological groups: xerophytes, mesoxerophytes, xeromesophytes, mesophytes, hygromesophytes and hygrophytes. We surveyed the composition, delta(13)C values and proline concentration of PFGs in eight different plant communities along a soil moisture gradient. Results show that: (1) PFGs occurred variously in eight steppe communities with different soil moisture status. In wetter habitats, hygromesophytes and hygrophytes were more abundant and accounted for the majority of aboveground biomass, whereas xerophytes and mesoxerophytes became more conspicuous in dryer habitats; (2) the numerical order of the mean delta(13)C values of PFGs is as follows: xerophytes (-26.38parts per thousand) = mesoxerophytes (-26.51parts per thousand) > xeromesophytes (-27.02parts per thousand) > mesophytes (-27.56parts per thousand) = hygromesophytes and hygrophytes (-27.80parts per thousand); (3) xerophytes maintained relative higher delta(13)C values and water use efficiency (WUE) in habitats of different water availability, whereas delta(13)C values of xeromesophytes were more sensitive to change in soil water availability; (4) From xerophytes to hygrophytes, their proline content markedly increased. Significantly positive correlations existed between proline and biomass or delta(13)C values of different water ecological groups.展开更多
[Objective] The study aimed at investigating the effects of different geographic sites,soil chemical characteristics and nitrogen application levels on nitrogen accumulation and distribution in different organs and ut...[Objective] The study aimed at investigating the effects of different geographic sites,soil chemical characteristics and nitrogen application levels on nitrogen accumulation and distribution in different organs and utilization efficiency for mid-season hybrid rice.[Method] By using mid-season rice varieties II-you 7 and Yuxiangyou203 as the experimental materials,field experiment was conducted at seven ecological sites in four provinces or cities in Southwestern China in 2009.A total of four nitrogen application levels were set as follows:by using 75 kg/hm2 of P2O5 and 75 kg/hm2 of K2O as the base fertilizer,extra 0,90,150 and 210 kg/hm2 of nitrogen fertilizer(in which,base fertilizer,base-tillering fertilizer and base-earing fertilizer respectively accounted for 60%,20% and 20%.) was applied,respectively.In the split-plot design,fertilizer was considered as the main factor while rice variety was taken as the secondary factor.A total of eight treatments were set with three replications.[Result] Highly significant differences of grain yield were found among seven locations,two varieties,four nitrogen application levels,interactions of site × variety and site × nitrogen application level,but the interaction of variety ×nitrogen application level had no significant influence on rice yield.There were highly significant effects of site,varieties and nitrogen application level on dry matter production,nitrogen content,nitrogen utilization efficiency.Highly significant negative correlations between uptake efficiency and utilization efficiency for nitrogen were found;and multiple stepwise regression analysis showed that nitrogen uptake-utilization efficiency were significantly influenced by different ecological sites,chemical quality of soil and the levels of nitrogen application.[Conclusion] The research will provide theoretical and practical basis for the highly efficient application of nitrogen in mid-season hybrid rice cultivation.展开更多
[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structur...[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structure, function and efficien- cy of Hunan agricultural ecosystem were analyzed based on input/output data in Hunan Province in 2009 as per emergy theory. [Result] The structure characters of agricultural ecosystem were as follows: Hunan is characterized with traditional agri- culture, depending greatly on both human and animal labor. For industrial accessory emergy, chemical fertilizers make most contribution to the system, and agricultural mechanization is not satisfied. Furthermore, renewable ratio of industrial accessory emergy is lower, and development and potential of green energy is promising. In addition, prices of the products are lower, without consideration of contribution made by natural resources and environment. It also suggested that Hunan agricultural chain is short and added value of products is not high. In general, emergy output of farming and animal husbandry dominates and the prices are lower than those of forestry and fishery. The function of the system was as follows: With lower environ- mental load ratio, the system is overloaded by population and the index of sustain- able development was 5.96, suggesting that the system enjoys vitality and potential, but the economy is undeveloped and the pressure from natural resources and envi- ronment is not high. The emergy output ratio was a little lower than national level in 2009, suggesting Hunan agricultural production is extensive. [Conclusion] The re- search indicated that rapid increase of population should be controlled; surplus labor should be transferred; agricultural structure and products structure should be further adjusted; agricultural technology should be further developed; agdcultural mechaniza- tion and modernization should be improved.展开更多
The high efficient eco-agricultural zone in Eco-economic Region of Poyang Lake was divided into three different areas. 12 indicators including per capita cultivated land,forest coverage,comprehensive utilization rate ...The high efficient eco-agricultural zone in Eco-economic Region of Poyang Lake was divided into three different areas. 12 indicators including per capita cultivated land,forest coverage,comprehensive utilization rate of straw,the ratio of the effective irrigation area to the arable land,amount of pesticide usage per unit area of arable land,the output value ratio of planting industry,the output value ratio of forestry and fruit industry,the output value ratio of stock farming,the output value ratio of fishery,the proportion of sown area of crop,proportion of sown area of oil plants and the proportion of sown area of vegetable were screened to construct the indicator system of regionalization of high efficient eco-agriculture. The average index values of the high efficient eco-agricultural regionalization of three regions were obtained,the development direction of the efficient eco-agriculture construction of three areas were analyzed according to the natural resources characteristics f eco-agricultural and requirements of high efficient eco-agricultural development of the regions.展开更多
The study aims at exploring the possibility of using the recovery ability af- ter drought stress-rewatering at vegetative growth stage as the evaluating index in water use efficiency (WUE) of winter wheat varieties....The study aims at exploring the possibility of using the recovery ability af- ter drought stress-rewatering at vegetative growth stage as the evaluating index in water use efficiency (WUE) of winter wheat varieties. 'Jing 411 ', 'Jinmai 47' and their 34 near isogenic lines (NILs) were used as test materials. Semi-automatic rainproof shelter and the percolating pools were used for simulating drought treat- ment. After suffering severe drought stress, winter wheat crops were rewatered at early jointing stage. The biomass accumulation after rewatering was determined as recovery ability index. In the meanwhile, plant height in the end of vegetative growth stage was measured, and WUE of varieties/lines was also determined. Thereafter, the differences in recovery ability, plant height and the population WUE, together with the correlation between recovery ability and population WUE were analyzed, respectively. The results showed that there were significant differences in recovery ability among some varieties/lines. The recovery ability was affected by both geno- type and environment, and the interaction existed in these two factors. Significant differences existed in plant height and population WUE among the 34 NILs along with their parents. There was a significantly positive correlation between recovery ability and plant height of varieties/lines. Recovery ability and plant height were very significantly and positively correlated with population yield WUE respectively. The re- sults indicated that recovery ability after drought stress-rewatering could be used as an evaluating index of population WUE under drought condition.展开更多
We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in...We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in S_(v)–In_(2)S_(3)@2H–MoTe_(2).The X-ray absorption near-edge structure shows that the formation of S_(v)–In_(2)S_(3)@2H–MoTe_(2) adjusts the coordination environment via interface engineering and forms Mo–S polarized sites at the interface.The interfacial dynamics and catalytic behavior are clearly revealed by ultrafast femtosecond transient absorption,time-resolved,and in situ diffuse reflectance–Infrared Fourier transform spectroscopy.A tunable electronic structure through steric interaction of Mo–S bridging bonds induces a 1.7-fold enhancement in S_(v)–In_(2)S_(3)@2H–MoTe_(2)(5)photogenerated carrier concentration relative to pristine S_(v)–In_(2)S_(3).Benefiting from lower carrier transport activation energy,an internal quantum efficiency of 94.01%at 380 nm was used for photocatalytic CO_(2)RR.This study proposes a new strategy to design photocatalyst through bridging sites to adjust the selectivity of photocatalytic CO_(2)RR.展开更多
The redox couple of I^(0)/I^(-)in aqueous rechargeable iodine–zinc(I^(2)-Zn)batteries is a promising energy storage resource since it is safe and cost-effective,and provides steady output voltage.However,the cycle li...The redox couple of I^(0)/I^(-)in aqueous rechargeable iodine–zinc(I^(2)-Zn)batteries is a promising energy storage resource since it is safe and cost-effective,and provides steady output voltage.However,the cycle life and efficiency of these batteries remain unsatisfactory due to the uncontrolled shuttling of polyiodide(I_(3)^(-)and I_(5)^(-))and side reactions on the Zn anode.Starch is a very low-cost and widely sourced food used daily around the world.“Starch turns blue when it encounters iodine”is a classic chemical reaction,which results from the unique structure of the helix starch molecule–iodine complex.Inspired by this,we employ starch to confine the shuttling of polyiodide,and thus,the I^(0)/I^(-)conversion efficiency of an I^(2)-Zn battery is clearly enhanced.According to the detailed characterizations and theoretical DFT calculation results,the enhancement of I^(0)/I^(-)conversion efficiency is mainly originated from the strong bonding between the charged products of I_(3)^(-)and I_(5)^(-)and the rich hydroxyl groups in starch.This work provides inspiration for the rational design of high-performance and low-cost I^(2)-Zn in AZIBs.展开更多
Elevation is one of many components that influence agriculture, and this in turn affects the level of both inputs and outputs of farmers. This article focuses on the productivity and technical efficiency of 100 cocoa ...Elevation is one of many components that influence agriculture, and this in turn affects the level of both inputs and outputs of farmers. This article focuses on the productivity and technical efficiency of 100 cocoa farms using cross-sectional data from areas ranging from 190 to 1021 m above sea level which were classified as low, medium, and high elevation in Davao City, considered as the chocolate capital of the Philippines. Using stochastic frontier analysis, the results showed that the cost of inputs per ha and the number of cocoa trees per ha significantly increase yield. Farms at high elevations were less technically efficient, as this entails lower temperatures and increased rainfall, and cocoa farming in those areas and conditions can be more challenging, especially with changes in farming practices, terrain, and distance to markets. Other significant variables were age of cocoa farms, married farmers, and age of the farmers. Older farms may be more developed, farmers who are married benefit from their spouses being able to readily contribute as farm labor, and lastly, older farmers' inefficiency may likely stem from nonadaptation of newer farming practices. With an average technical efficiency of 0.61, 0.63, and 0.26 in low, medium, and high elevation areas, respectively, farmers therefore have an incentive to improve farm practices and consider topographical variations found in high elevation areas. Recommendations for the improvement of technical efficiency of cocoa farms are better connectivity to markets, enhancing farm practices, and continuation and improvement of government programs on cocoa with an added emphasis on research. For farmers in high elevation areas, mitigating solutions such as sustainable agriculture practices and ecolabelling are key to improving efficiency and minimizing the potential negative impact on upland farming systems. Moreover, such adaptation measures may also contribute to sustainability of cocoa farming in high elevation areas.展开更多
This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydro...This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydrogen bond kinetics and adsorption efficiency were studied through simulation and experimental verification.The results show that the presence of iron in the kaolinite structure significantly improves the adsorption capacity of sodium oleate.Kaolinite samples with high iron content have better adsorption properties,lower adsorption energy levels and shorter and stronger hydrogen bonds than pure kaolinite.The optimal concentration of oleic acid ions for achieving maximum adsorption efficiency was identified as 1.2 mmol/L across different kaolinite samples.At this concentration,the adsorption rates and capacities reach their peak,with Fe-enriched kaolinite samples exhibiting notably higher flotation recovery rates.This optimal concentration represents a balance between sufficient oleic acid ion availability for surface interactions and the prevention of self-aggregation phenomena that could hinder adsorption.This study offers promising avenues for optimizing the flotation process in mineral processing applications.展开更多
The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved ...The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved into the traits of tight sandstone reservoirs in the 8th member of the Shihezi Formation(also referred to as the He 8 Member)in the study area,as well as their effects on fracturing fluid imbibition.Utilizing experimental techniques such as nuclear magnetic resonance(NMR),high-pressure mercury intrusion(HPMI),and gas adsorption,this study elucidated the reservoir characteristics and examined the factors affecting the imbibition through imbibition experiments.The findings reveal that:①The reservoir,with average porosity of 8.40%and average permeability of 0.642×10^(-3)μm^(2),consists principally of quartz,feldspar,and lithic fragments,with feldspathic litharenite serving as the primary rock type and illite as the chief clay mineral;②Nano-scale micro-pores and throats dominate the reservoir,with dissolution pores and intercrystalline pores serving as predominant pore types,exhibiting relatively high pore connectivity;③Imbibition efficiency is influenced by petrophysical properties,clay mineral content,and microscopic pore structure.Due to the heterogeneity of the tight sandstone reservoir,microscopic factors have a more significant impact on the imbibition efficiency of fracturing fluids;④A comparative analysis shows that average pore size correlates most strongly with imbibition efficiency,followed by petrophysical properties and clay mineral content.In contrast,the pore type has minimal impact.Micropores are vital in the imbibition process,while meso-pores and macro-pores offer primary spaces for imbibition.This study offers theoretical insights and guidance for enhancing the post-fracturing production of tight sandstone reservoirs by examining the effects of these factors on the imbibition efficiency of fracturing fluids in tight sandstones.展开更多
基金support from the National Natural Science Foundation of China(62275057)the Guangxi Natural Science Foundation(2023GXNSFFA026004 and 2022GXNSFDA035066)+2 种基金the Innovation Project of Guangxi Graduate Education(YCBZ2024034)Natural Science Foundation of Ningbo under grant(2022J149)Natural Science Foundation of Ningbo under grant(2022A-230-G)
文摘Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challenging.Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with Y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching properties.As a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance improvements.Our findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells.
文摘Local production of rice has struggled to meet local demand despite its suitability for cultivation in many parts of Nigeria.Using data from 240 rice farmers, this study examined the economic efficiency of rice production and the effects of financial inclusion on the economic efficiency of rice farming in Ogun State, Nigeria. Data were analyzed using the Stochastic Cost Frontier model with inefficiency effects.
基金Under the auspices of the National Natural Science Foundation of China(No.71974070)‘CUG Scholar'Scientific Research Funds at China University of Geosciences(Wuhan)(No.2022005)。
文摘The spatial and temporal variation of green economic efficiency and its driving factors are of great significance for the construction of high-efficiency and low-consumption green development model and sustainable socio-economic development.The research focused on the Yangtze River Economic Belt(YREB)and employed the miniumum distance to strong efficient frontier DEA(MinDs)model to measure the green economic efficiency of the municipalities in the region between 2008 and 2020.Then,the spatial autocorrelation model was used to analyze the evolution characteristics of its spatial pattern.Finally,Geodetector was applied to reveal the drivers and their interactions on green economic efficiency.It is found that:1)the overall green economic efficiency of the YREB from 2008 to 2020 shows a W-shaped fluctuating upward trend,green economic efficiency is greater in the downstream and smallest in the upstream;2)the spatial distribution of green economic efficiency shows clustering characteristics,with multi-core clustering based on‘city clusters-central cities'becoming more obvious over time;the High-High agglomeration type is mainly clustered in Jiangsu and Zheji-ang,while the Low-Low agglomeration type is clustered in the western Sichuan Plateau area and southwestern Yunnan;3)from input-output factors,whether it is the YREB as a whole or the upper,middle and lower reaches regions,the economic development level,labor input,and capital investment are the leading factors in the spatial-temporal evolution of green economic efficiency,with the com-prehensive influence of economic development level and pollution index being the most important interactive driving factor;4)from so-cio-economic factors,information technology drivers such as government intervention,transportation accessibility,information infra-structure,and Internet penetration are always high impact influencers and dominant interaction factors for green economic efficiency in the YREB and the three major regions in the upper,middle and lower reaches.Accordingly,the article puts forward relevant policy re-commendations in terms of formulating differentiated green transformation strategies,strengthening network leadership and informa-tion technology construction and coordinating multi-factor integrated development,which could provide useful reference for promoting synergistic green economic efficiency in the YREB.
文摘This study estimates the technical, allocative, and economic efficiency of maize-producing farms in Benin and identifies the determining factors of these efficiencies in the context of adaptation to climate change. To achieve this, data was collected from a sample of 402 corn farmers randomly selected from the municipalities most vulnerable to the effects of climate change and located within the Okpara watershed perimeters. The parametric stochastic frontier approach was adopted to estimate a seedling-log stochastic frontier and a dual cost function of corn farms using the Frontier program of Stata 13 software. The Tobit regression model was used to identify the factors determining the efficiency of producers. The results show that the operators are all technically efficient and have significant random effects. However, the results from the cost frontier show the presence of allocative inefficiency within production units. The estimated technical, allocative, and economic efficiencies are, respectively, 0.94, 0.60 and 0.57 on average. Finally, estimation of the determinants of efficiency has shown that the supply of mineral manure, experience in maize production, crop rotation as well as the level of education are the main determinants of efficiency. It is necessary to support corn producers on cultivation techniques, subsidize fertilizers, and promote literacy in the face of the effects of climate change.
基金supported by the Key R&D Plan of Hubei Province,China(2022BBA002)the Carbon Account Accounting and Carbon Reduction and Sequestration Technology Research of Quzhou City of China(2022-31).
文摘Controlled-release urea(CRU)is commonly used to improve the crop yield and nitrogen use efficiency(NUE).However,few studies have investigated the effects of CRU in the ratoon rice system.Ratoon rice is the practice of obtaining a second harvest from tillers originating from the stubble of the previously harvested main crop.In this study,a 2-year field experiment using a randomized complete block design was conducted to determine the effects of CRU on the yield,NUE,and economic benefits of ratoon rice,including the main crop,to provide a theoretical basis for fertilization of ratoon rice.The experiment included four treatments:(i)no N fertilizer(CK);(ii)traditional practice with 5 applications of urea applied at different crop growth stages by surface broadcasting(FFP);(iii)one-time basal application of CRU(BF1);and(iv)one-time basal application of CRU combined with common urea(BF2).The BF1 and BF2 treatments significantly increased the main crop yield by 17.47 and 15.99%in 2019,and by 17.91 and 16.44%in 2020,respectively,compared with FFP treatment.The BF2 treatment achieved similar yield of the ratoon crop to the FFP treatment,whereas the BF1 treatment significantly increased the yield of the ratoon crop by 14.81%in 2019 and 12.21%in 2020 compared with the FFP treatment.The BF1 and BF2 treatments significantly improved the 2-year apparent N recovery efficiency,agronomic NUE,and partial factor productivity of applied N by 11.47-16.66,27.31-44.49,and 9.23-15.60%,respectively,compared with FFP treatment.The BF1 and BF2 treatments reduced the chalky rice rate and chalkiness of main and ratoon crops relative to the FFP treatment.Furthermore,emergy analysis showed that the production efficiency of the BF treatments was higher than that of the FFP treatment.The BF treatments reduced labor input due to reduced fertilization times and improved the economic benefits of ratoon rice.Compared with the FFP treatment,the BF1 and BF2 treatments increased the net income by 14.21-16.87 and 23.76-25.96%,respectively.Overall,the one-time blending use of CRU and common urea should be encouraged to achieve high yield,high nitrogen use efficiency,and good quality of ratoon rice,which has low labor input and low apparent N loss.
基金supported by the National Natural Science Foundation of China(Grant No.61971117)the Natural Science Foundation of Hebei Province(Grant No.F2020501007)the S&T Program of Hebei(No.22377717D)。
文摘This paper considers a high energy efficiency dynamic connected(HEDC)structure,which promotes the practicability and reduces the power consumption of hybrid precoding system by lowresolution phase shifters(PSs).Based on the proposed structure,a new hybrid precoding algorithm is presented to optimize the energy efficiency,namely,HP-HEDC algorithm.Firstly,via a new defined effective optimal precoding matrix,the problem of optimizing the analog switch precoding matrix is formulated as a sparse representation problem.Thus,the optimal analog switch precoding matrix can be readily obtained by the branch-and-bound method.Then,the digital precoding matrix optimization problem is modeled as a dictionary update problem and solved by the method of optimal direction(MOD).Finally,the diagonal entries of the analog PS precoding matrix are optimized by exhaustive search independently since PS and antenna is one-to-one.Simulation results show that the HEDC structure enjoys low power consumption and satisfactory spectral efficiency.The proposed algorithm presents at least 50%energy efficiency improvement compared with other algorithms when the PS resolution is set as 3-bit.
基金supported by National Natural Science Foundation of China [grant numbers 42371194]。
文摘Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency changes and analyze the impact mechanism and realization path of industrial transformation on green economic efficiency. The research results show that advanced industrial structure has a positive influence on green economic efficiency nationwide, while energy utilization structure and energy utilization efficiency have positive partial intermediary effects in the influence path;industrial structure rationalization is also significantly positively related to green economic efficiency nationwide, and the mediating effect of energy utilization is positive. The impact of industrial transformation on green economic efficiency has regional heterogeneity, and the mediating effect of energy use also differs. Among them, the impact effect in the eastern region is basically consistent with the national sample, but is negative in the central and western regions. This paper proposes countermeasures in terms of adjusting the industrial structure, improving energy efficiency, and perfecting industrial and energy policies, which can provide theoretical and practical references for promoting the transformation and upgrading of regional industrial structure, optimizing energy utilization, and advancing the efficiency of the national and regional green economy.
基金funded by the Shanghai Planning Office of Philosophy and Social Science under the project“Evaluation of Shanghai’s Practices in Modernizing the National Economic Governance System and Governance Capacity”(No.2020BJB020)。
文摘A well-developed financial market system is crucial for supporting high-quality development in the new era.Initial Public Offerings(IPOs)are essential for enabling financial markets to facilitate new industrialization while accelerating the development of a manufacturing powerhouse.Therefore,research on IPO mechanism reform holds significant practical implications.This paper examines the impact of China’s IPO mechanism reform by studying the equilibrium relationship between the primary market and the lending market.Using empirical analysis,we compare the average return on online subscriptions for newly listed shares using the risk-free rate before and after China’s 2015 IPO mechanism reform,as well as analyze the underlying mechanisms driving excess returns during both periods.Our findings indicate a gradual alignment of returns in the primary and lending markets,with institutional arbitrage opportunities between them diminishing.The reforms have effectively enhanced market mechanisms,improved pricing capabilities,rationalized participant behavior,and optimized the securities market ecosystem.These improvements have contributed to the market’s equilibrium and enhanced the market’s ability to interpret information.However,further improvements to the IPO mechanism are necessary,including deeper market-oriented reforms,standardization of participant behavior,acceleration of a comprehensive registration system,and stronger information disclosure and quality management.
基金supported by the National Natural Science Foundation of China[Grant No.72163018]the Yunnan College Students’Innovation and Entrepreneurship Training Program[Grant No.S202310674173]the Yunnan Province Basic Research Program General Project[Grant No.202401AT070393].
文摘The national independent innovation demonstration zone(NIIDZ)is an independent innovation policy that plays a crucial role in implementing strategies.Given the importance of the NIIDZ,this study uses panel data of 278 prefecture-level cities in China from 2006 to 2020 and empirically examines the effect and internal mechanism of the NIIDZ on green economic efficiency(GEE)using the difference-in-difference model(DID).The results show that the NIIDZ effectively enhances the growth of GEE,and the results remain valid through several robustness tests,such as year-by-year propensity score matching.The transmission mechanism suggests that the NIIDZ indirectly drives GEE by accelerating scientific and technological investment,promoting talent concentration,and optimizing the industrial structure.Moreover,heterogeneity analysis reveals that the promotion effect of the NIIDZ on GEE is more prominent in the eastern region and high green development level areas.The study’s findings can serve as a reference for China to further utilize the policy effectiveness of the NIIDZ and accelerate the high-quality development of the green economy in the future.
基金Jiangxi Provincial Social Science Foundation Project“Research on the Impact of Digital Economy Development on Employment Structure and Quality in Jiangxi Province and Countermeasures”(Grant No.23YJ55D)Jiangxi Province University Humanities and Social Sciences Research Project“Research on the Dynamic Mechanism and Countermeasures of Industrial Digitalization to Promote the High-Quality Development of Jiangxi’s Manufacturing Industry”(Grant No.JJ22218).
文摘This paper adopts the non-expected output-super-efficiency SBM(Slacks-Based Model)model and principal component analysis to calculate the green economy efficiency and the digital economy level of 27 prefecture-level cities in China’s Yangtze River Delta urban agglomeration between 2011 and 2019,respectively,and examines the impact of the digital economy on the green economy efficiency by using benchmark regression and mechanism analysis.The findings show that,first,the digital economy has a significant contribution to the green economic efficiency of cities,and this conclusion still holds after robustness tests such as replacing explanatory and interpreted variables and introducing province-fixed effects.Second,through the mechanism test,it is found that the digital economy can indirectly promote urban green economic efficiency through the positive mechanism effect of promoting industrial structure upgrading.
文摘Major plant species in the Xilin River Basin were grouped into six plant functional groups (PFGs) based on their water ecological groups: xerophytes, mesoxerophytes, xeromesophytes, mesophytes, hygromesophytes and hygrophytes. We surveyed the composition, delta(13)C values and proline concentration of PFGs in eight different plant communities along a soil moisture gradient. Results show that: (1) PFGs occurred variously in eight steppe communities with different soil moisture status. In wetter habitats, hygromesophytes and hygrophytes were more abundant and accounted for the majority of aboveground biomass, whereas xerophytes and mesoxerophytes became more conspicuous in dryer habitats; (2) the numerical order of the mean delta(13)C values of PFGs is as follows: xerophytes (-26.38parts per thousand) = mesoxerophytes (-26.51parts per thousand) > xeromesophytes (-27.02parts per thousand) > mesophytes (-27.56parts per thousand) = hygromesophytes and hygrophytes (-27.80parts per thousand); (3) xerophytes maintained relative higher delta(13)C values and water use efficiency (WUE) in habitats of different water availability, whereas delta(13)C values of xeromesophytes were more sensitive to change in soil water availability; (4) From xerophytes to hygrophytes, their proline content markedly increased. Significantly positive correlations existed between proline and biomass or delta(13)C values of different water ecological groups.
基金Supported by Construction of Southwestern Rice Innovation System,Science and Technology Project on Food Production (2006BAD02-A05)Agriculture Science Technology Achievement TransformationFund (2006GB2F000256)+2 种基金Sichuan Provincial Foundation for Lead-ers of Disciplines in ScienceProject of Rice Breeding Technology ofSichuanProgram Promoted by Sichuan Financial Administration~~
文摘[Objective] The study aimed at investigating the effects of different geographic sites,soil chemical characteristics and nitrogen application levels on nitrogen accumulation and distribution in different organs and utilization efficiency for mid-season hybrid rice.[Method] By using mid-season rice varieties II-you 7 and Yuxiangyou203 as the experimental materials,field experiment was conducted at seven ecological sites in four provinces or cities in Southwestern China in 2009.A total of four nitrogen application levels were set as follows:by using 75 kg/hm2 of P2O5 and 75 kg/hm2 of K2O as the base fertilizer,extra 0,90,150 and 210 kg/hm2 of nitrogen fertilizer(in which,base fertilizer,base-tillering fertilizer and base-earing fertilizer respectively accounted for 60%,20% and 20%.) was applied,respectively.In the split-plot design,fertilizer was considered as the main factor while rice variety was taken as the secondary factor.A total of eight treatments were set with three replications.[Result] Highly significant differences of grain yield were found among seven locations,two varieties,four nitrogen application levels,interactions of site × variety and site × nitrogen application level,but the interaction of variety ×nitrogen application level had no significant influence on rice yield.There were highly significant effects of site,varieties and nitrogen application level on dry matter production,nitrogen content,nitrogen utilization efficiency.Highly significant negative correlations between uptake efficiency and utilization efficiency for nitrogen were found;and multiple stepwise regression analysis showed that nitrogen uptake-utilization efficiency were significantly influenced by different ecological sites,chemical quality of soil and the levels of nitrogen application.[Conclusion] The research will provide theoretical and practical basis for the highly efficient application of nitrogen in mid-season hybrid rice cultivation.
基金Supported by National Social Science Foundation (11BJY029)Hunan Social ScienceFoundation (2010YBB348)+1 种基金Innovation Platform Funds of Hunan High Institutions(10K080)Hunan Soft Science Key Project (2011ZK2046)~~
文摘[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structure, function and efficien- cy of Hunan agricultural ecosystem were analyzed based on input/output data in Hunan Province in 2009 as per emergy theory. [Result] The structure characters of agricultural ecosystem were as follows: Hunan is characterized with traditional agri- culture, depending greatly on both human and animal labor. For industrial accessory emergy, chemical fertilizers make most contribution to the system, and agricultural mechanization is not satisfied. Furthermore, renewable ratio of industrial accessory emergy is lower, and development and potential of green energy is promising. In addition, prices of the products are lower, without consideration of contribution made by natural resources and environment. It also suggested that Hunan agricultural chain is short and added value of products is not high. In general, emergy output of farming and animal husbandry dominates and the prices are lower than those of forestry and fishery. The function of the system was as follows: With lower environ- mental load ratio, the system is overloaded by population and the index of sustain- able development was 5.96, suggesting that the system enjoys vitality and potential, but the economy is undeveloped and the pressure from natural resources and envi- ronment is not high. The emergy output ratio was a little lower than national level in 2009, suggesting Hunan agricultural production is extensive. [Conclusion] The re- search indicated that rapid increase of population should be controlled; surplus labor should be transferred; agricultural structure and products structure should be further adjusted; agricultural technology should be further developed; agdcultural mechaniza- tion and modernization should be improved.
文摘The high efficient eco-agricultural zone in Eco-economic Region of Poyang Lake was divided into three different areas. 12 indicators including per capita cultivated land,forest coverage,comprehensive utilization rate of straw,the ratio of the effective irrigation area to the arable land,amount of pesticide usage per unit area of arable land,the output value ratio of planting industry,the output value ratio of forestry and fruit industry,the output value ratio of stock farming,the output value ratio of fishery,the proportion of sown area of crop,proportion of sown area of oil plants and the proportion of sown area of vegetable were screened to construct the indicator system of regionalization of high efficient eco-agriculture. The average index values of the high efficient eco-agricultural regionalization of three regions were obtained,the development direction of the efficient eco-agriculture construction of three areas were analyzed according to the natural resources characteristics f eco-agricultural and requirements of high efficient eco-agricultural development of the regions.
文摘The study aims at exploring the possibility of using the recovery ability af- ter drought stress-rewatering at vegetative growth stage as the evaluating index in water use efficiency (WUE) of winter wheat varieties. 'Jing 411 ', 'Jinmai 47' and their 34 near isogenic lines (NILs) were used as test materials. Semi-automatic rainproof shelter and the percolating pools were used for simulating drought treat- ment. After suffering severe drought stress, winter wheat crops were rewatered at early jointing stage. The biomass accumulation after rewatering was determined as recovery ability index. In the meanwhile, plant height in the end of vegetative growth stage was measured, and WUE of varieties/lines was also determined. Thereafter, the differences in recovery ability, plant height and the population WUE, together with the correlation between recovery ability and population WUE were analyzed, respectively. The results showed that there were significant differences in recovery ability among some varieties/lines. The recovery ability was affected by both geno- type and environment, and the interaction existed in these two factors. Significant differences existed in plant height and population WUE among the 34 NILs along with their parents. There was a significantly positive correlation between recovery ability and plant height of varieties/lines. Recovery ability and plant height were very significantly and positively correlated with population yield WUE respectively. The re- sults indicated that recovery ability after drought stress-rewatering could be used as an evaluating index of population WUE under drought condition.
基金the Natural Science Foundation of China(11922415,12274471)Guangdong Basic and Applied Basic Research Foundation(2022A1515011168,2019A1515011718,2019A1515011337)the Key Research and Development Program of Guangdong Province,China(2019B110209003).
文摘We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in S_(v)–In_(2)S_(3)@2H–MoTe_(2).The X-ray absorption near-edge structure shows that the formation of S_(v)–In_(2)S_(3)@2H–MoTe_(2) adjusts the coordination environment via interface engineering and forms Mo–S polarized sites at the interface.The interfacial dynamics and catalytic behavior are clearly revealed by ultrafast femtosecond transient absorption,time-resolved,and in situ diffuse reflectance–Infrared Fourier transform spectroscopy.A tunable electronic structure through steric interaction of Mo–S bridging bonds induces a 1.7-fold enhancement in S_(v)–In_(2)S_(3)@2H–MoTe_(2)(5)photogenerated carrier concentration relative to pristine S_(v)–In_(2)S_(3).Benefiting from lower carrier transport activation energy,an internal quantum efficiency of 94.01%at 380 nm was used for photocatalytic CO_(2)RR.This study proposes a new strategy to design photocatalyst through bridging sites to adjust the selectivity of photocatalytic CO_(2)RR.
基金financially supported by the National Natural Science Foundation of China(Nos.U20A20246 and 51872108)the Fundamental Research Funds for the Central Universitiesthe Advanced Talents Incubation Program of Hebei University(521100221039)
文摘The redox couple of I^(0)/I^(-)in aqueous rechargeable iodine–zinc(I^(2)-Zn)batteries is a promising energy storage resource since it is safe and cost-effective,and provides steady output voltage.However,the cycle life and efficiency of these batteries remain unsatisfactory due to the uncontrolled shuttling of polyiodide(I_(3)^(-)and I_(5)^(-))and side reactions on the Zn anode.Starch is a very low-cost and widely sourced food used daily around the world.“Starch turns blue when it encounters iodine”is a classic chemical reaction,which results from the unique structure of the helix starch molecule–iodine complex.Inspired by this,we employ starch to confine the shuttling of polyiodide,and thus,the I^(0)/I^(-)conversion efficiency of an I^(2)-Zn battery is clearly enhanced.According to the detailed characterizations and theoretical DFT calculation results,the enhancement of I^(0)/I^(-)conversion efficiency is mainly originated from the strong bonding between the charged products of I_(3)^(-)and I_(5)^(-)and the rich hydroxyl groups in starch.This work provides inspiration for the rational design of high-performance and low-cost I^(2)-Zn in AZIBs.
文摘Elevation is one of many components that influence agriculture, and this in turn affects the level of both inputs and outputs of farmers. This article focuses on the productivity and technical efficiency of 100 cocoa farms using cross-sectional data from areas ranging from 190 to 1021 m above sea level which were classified as low, medium, and high elevation in Davao City, considered as the chocolate capital of the Philippines. Using stochastic frontier analysis, the results showed that the cost of inputs per ha and the number of cocoa trees per ha significantly increase yield. Farms at high elevations were less technically efficient, as this entails lower temperatures and increased rainfall, and cocoa farming in those areas and conditions can be more challenging, especially with changes in farming practices, terrain, and distance to markets. Other significant variables were age of cocoa farms, married farmers, and age of the farmers. Older farms may be more developed, farmers who are married benefit from their spouses being able to readily contribute as farm labor, and lastly, older farmers' inefficiency may likely stem from nonadaptation of newer farming practices. With an average technical efficiency of 0.61, 0.63, and 0.26 in low, medium, and high elevation areas, respectively, farmers therefore have an incentive to improve farm practices and consider topographical variations found in high elevation areas. Recommendations for the improvement of technical efficiency of cocoa farms are better connectivity to markets, enhancing farm practices, and continuation and improvement of government programs on cocoa with an added emphasis on research. For farmers in high elevation areas, mitigating solutions such as sustainable agriculture practices and ecolabelling are key to improving efficiency and minimizing the potential negative impact on upland farming systems. Moreover, such adaptation measures may also contribute to sustainability of cocoa farming in high elevation areas.
基金supported by the Natural Science Foundation of China(No.52174232)the Project was supported by Open Research Grant of Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining(Nos.EC2022003 and EC2023005)+1 种基金Anhui University of Science and Technology 2023 Graduate Student Innovation Fund(No.2023cx2106)Open Research Grant of Anhui Engineering Research Center for Coal Clean Processing and Carbon Emission Reduction(No.CCCE-2023003).
文摘This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydrogen bond kinetics and adsorption efficiency were studied through simulation and experimental verification.The results show that the presence of iron in the kaolinite structure significantly improves the adsorption capacity of sodium oleate.Kaolinite samples with high iron content have better adsorption properties,lower adsorption energy levels and shorter and stronger hydrogen bonds than pure kaolinite.The optimal concentration of oleic acid ions for achieving maximum adsorption efficiency was identified as 1.2 mmol/L across different kaolinite samples.At this concentration,the adsorption rates and capacities reach their peak,with Fe-enriched kaolinite samples exhibiting notably higher flotation recovery rates.This optimal concentration represents a balance between sufficient oleic acid ion availability for surface interactions and the prevention of self-aggregation phenomena that could hinder adsorption.This study offers promising avenues for optimizing the flotation process in mineral processing applications.
基金funded by the National key R&D Program of China(No.2023YFE0120700)the National Natural Science Foundation of China(No.51934005)+2 种基金the Shaanxi Province 2023 Innovation Capability Support Plan(No.2023KJXX-122)the Technology Innovation Leading Program of Shaanxi(No.2022 PT-08)the Project of Youth Innovation Team of Shaanxi Universities(No.22JP063).
文摘The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved into the traits of tight sandstone reservoirs in the 8th member of the Shihezi Formation(also referred to as the He 8 Member)in the study area,as well as their effects on fracturing fluid imbibition.Utilizing experimental techniques such as nuclear magnetic resonance(NMR),high-pressure mercury intrusion(HPMI),and gas adsorption,this study elucidated the reservoir characteristics and examined the factors affecting the imbibition through imbibition experiments.The findings reveal that:①The reservoir,with average porosity of 8.40%and average permeability of 0.642×10^(-3)μm^(2),consists principally of quartz,feldspar,and lithic fragments,with feldspathic litharenite serving as the primary rock type and illite as the chief clay mineral;②Nano-scale micro-pores and throats dominate the reservoir,with dissolution pores and intercrystalline pores serving as predominant pore types,exhibiting relatively high pore connectivity;③Imbibition efficiency is influenced by petrophysical properties,clay mineral content,and microscopic pore structure.Due to the heterogeneity of the tight sandstone reservoir,microscopic factors have a more significant impact on the imbibition efficiency of fracturing fluids;④A comparative analysis shows that average pore size correlates most strongly with imbibition efficiency,followed by petrophysical properties and clay mineral content.In contrast,the pore type has minimal impact.Micropores are vital in the imbibition process,while meso-pores and macro-pores offer primary spaces for imbibition.This study offers theoretical insights and guidance for enhancing the post-fracturing production of tight sandstone reservoirs by examining the effects of these factors on the imbibition efficiency of fracturing fluids in tight sandstones.