Preparation of Polyurea Elastomer with Flame Retardant, Insulation and Thermal Conductivity Properties

By using 6,6-((sulfonylbis(4,1-phenylene)bis(azanediyl))bis(thiophen-2-ylm-ethylene))bis6H-di-benzo[c,e][1,2]oxaphosphinine 6-oxide(DOPO-N)as phosphorus-nitrogen flame retardant,the polyurea(PUA)with flame retardant properties(PUA/DOPO-N)was prepared.In addition,organically modified montmorillonite(OMMT)and magnesium hydroxide(MH)were used as co-effectors respectively,and the flame retardant PUA(PUA/DOPO-N/OMMT and PUA/DOPO-N/MH)were also prepared.Thermal properties,flame retardant properties,flame retardant mechanism and mechanical properties of PUA/DOPO-N,PUA/DOPO-N/OMMT and PUA/DOPO-N/MH were investigated by thermogravimetric(TG)analysis,limiting oxygen index(LOI),UL 94,cone calorimeter test,scanning electron microscopy(SEM),and tensile test.The results show that the LOI value of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH are 27.1%,27.7%,and 28.3%,respectively,and UL 94 V-0 rating is attained.Compared with PUA,the peak heat release rate(pk-HRR),total heat release(THR)and average effective heat combustion(av-EHC)of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH decrease significantly.SEM results indicate that the residual chars of PUA/20%DOPO-N,PUA/18%DOPO-N/2%OMMT and PUA/15%DOPO-N/5%MH are completer and more compact.The complex of DOPO-N/OMMT and DOPO-N/MH have synergistic flame retardancy.The mechanical properties of PUA can be improved by the addition of DOPO-N,DOPO-N/OMMT and DOPO-N/MH,respectively.The insulation performance test shows that the volume resistivity of PUA/20%DOPO-N is 6.25×10^(16)Ω.cm.Furthermore,by using modified boron nitride(MBN)as heat dissipating material,the complex of PUA/MBN was prepared,and the thermal conductivity of PUA/MBN was investigated.The thermal conductivity of PUA/8%MBN complex coating at room temperature is 0.166 W/(M·K),which is a 163%improvement over pure PUA.

Superior and safer lithium sulfur batteries realized by robust polysulfides-retarding dam with high flame retardance

The unparalleled energy density has granted lithium-sulfur batteries(LSBs)with attractive usages.Unfortunately,LSBs still face some unsurpassed challenges in industrialization,with polysulfides shuttling,dendrite growth and thermal hazard as the major problems triggering the cycling instability and low safety.With the merit of convenience,the method of designing functional separator has been adapted.Concretely,the carbon aerogel confined with CoS_(2)(CoS_(2)-NCA)is constructed and coated on Celgard separator surface,acquiring CoS_(2)-NCA modified separator(CoS_(2)-NCA@C),which holds the promoted electrolyte affinity and flame retardance.As revealed,CoS_(2)-NCA@C cell gives a high discharge capacity 1536.9 mAh/g at 1st cycle,much higher than that of Celgard cell(987.1 mAh/g).Moreover,the thermal runaway triggering time is dramatically prolonged by 777.4 min,corroborating the promoted thermal safety of cell.Noticeably,the higher coulombic efficiency stability and lower overpotential jointly confirm the efficacy of CoS_(2)-NCA@C in suppressing the lithium dendrite growth.Overall,this work can provide useful inspirations for designing functional separator,coping with the vexing issues of LSBs.

Synthesis of Organic-Inorganic Hybrid Aluminum Hypophosphite Microspheres Flame Retardant and Its Flame Retardant Research on Thermoplastic Polyurethane

Aluminum hypophosphite microspheres(AHP) were synthesized by hydrothermal method using NaH2PO2·H2O and AlCl3·6H2O as raw materials, and then the AHP microspheres were polymerized by surface polymerization of micro-nanospheres with cyclic cross-linked poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol)(PZS). A new organic-inorganic poly(phosphonitrile)-modified aluminum hypophosphite microspheres(PZS-AHP) were synthesized by encapsulation and applied to flame retardant thermoplastic polyurethane(TPU). The microstructure and chemical composition of the PZS-AHP microsphere were characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy and X-ray spectroscopy. The thermal stability of PZS-AHP microsphere was explored with thermogravimetric analysis. Thermogravimetric data indicate that the PZS-AHP microspheres have excellent thermal stability. The thermal and flame-retarding properties of the TPU composites were evaluated by thermogravimetric(TG), limited oxygen index tests(LOI), and cone calorimeter test(CCT). The TPU composite achieved vertical burning(UL-94) V-0 grade and LOI value reached 29.2% when 10 wt% PZS-AHP was incorporated. Compared with those of pure TPU, the peak heat release rate(pHRR) and total heat release(THR) of TPU/10%PZS-AHP decreased by 82.2% and 42.5%, respectively. The results of CCT indicated that PZS-AHP microsphere could improve the flame retardancy of TPU composites.

Numerical Simulation on Radon Retardation Behavior of Covering Floats in Radon-Containing Water

Objective This study aimed to efficiently reduce the release of radon from water bodies to protect the environment.Methods Based on the sizes of the experimental setup and modular float,computational fluid dynamics(CFD)was used to assess the impact of the area coverage rate,immersion depth,diffusion coefficient,and radon transfer velocity at the gas–liquid interface on radon migration and exhalation of radon-containing water.Based on the numerical simulation results,an estimation model for the radon retardation rate was constructed.The effectiveness of the CFD simulation was evaluated by comparing the experimental and simulated variation values of the radon retardation rate with the coverage area rates.Results The effect of radon transfer velocity on radon retardation in water bodies was minor and insignificant according to the appropriate value;therefore,an estimation model of the radon retardation rate of the coverage of a radon-containing water body was constructed using the synergistic impacts of three factors:area coverage rate,immersion depth,and diffusion coefficient.The deviation between the experimental and simulated results was<4.3%.Conclusion Based on the numerical simulation conditions,an estimation model of the radon retardation rate of covering floats in water bodies under the synergistic effect of multiple factors was obtained,which provides a reference for designing covering floats for radon retardation in radoncontaining water.

Characterization of Flame Retardancy and Oil-Water Separation Capacity of Superhydrophobic Silylated Melamine Sponges

A silylated melamine sponge(SMS)was prepared by two simple steps,namely,immersion and dehydration of a melamine sponge coated with methyltrichlorosilane.The silylated structure of SMS was characterized by FT-IR(Fourier-transform infrared)spectroscopy,SEM(Scanning electron microscopy)and in terms of water contact angles.Its oil-water absorption and separation capacities were measured by FT-IR and UV-visible spectrophoto-metry.The experimental results have shown that oligomeric silanol covalently bonds by Si-N onto the surface of melamine sponge skeletons.SMS has shown superhydrophobicity with a water contact angle exceeding 150°±1°,a better separation efficiency with regard to diesel oil(by 99.31%(wt/wt%)in oil-water mixture and even up to 99.99%(wt/wt%)for diesel oil in its saturated aqueous solution.Moreover,SMS inherited the intrinsicflame retardancy of the melamine sponge.In general,SMS has shown superhydrophobicity,high porosity,excellent selectivity,remarkable recyclability,and better absorption capacity for various oils and organic solvents,and a high separation efficiency for oil in saturated aqueous solutions.

Research Progress in Flame Retardant in Flame Retardant Coatings

Flame retardant coatings are functional materials that can serve as decorative and protec-tive substrates in the event of a fire.Flame retardant coatings generally consist of two parts:a base material and a flame retardant agent.A detailed introduction was given to the development of flame retardant coatings in recent years and the flame retardants used in flame retardant coatings.Flame retardants mainly include halogen flame retar-dants,phosphorus nitrogen flame retardants,expansion flame retardants,biomass flame retardants,and graphene flame retardants.The application of flame retardant coatings in the fields of epoxy resin,polyurethane,etc.was elaborated.In addition,the application of new biomass flame retardants and graphene flame retardants was introduced,and the future development of flame retardant coatings and flame retardants was described.

The Electrical Resistivity of Cement Paste Incorporated with Retarder

A non contacting electrical resistivity measurement device was used for measuring the electrical resistivity of cement paste incorporated with retarder.The hydration process was divided into dissolving period,setting period,hardening period.With the increase of the retarder,the dissolution time will increase.The setting time happens between minimum point time and inflexion point time based on the electrical resistivity curve.The strength isoline was proposed to predict the strength trend.

NUMERICAL ANALYSIS AND EXPERI-MENT OF UNSTEADY THERMAL FIELD OF ROTOR PLATE FOR EDDY CURRENT RETARDER

The physical model based on heat transfer theory and virtual boundary method for analyzing unsteady thermal field of rotor plate for eddy current retarder used in automobile is established and boundary conditions are also defined. The finite element governing equation is derived by Galerkin method. The time differential item is discrete based on Galerkin format that is stable at any condition. And a new style of varying time step method is used in iteration process. The thermal field on the rotor plate at the radial and axle directions is analyzed and varying temperature at appointed points on two side-surfaces is measured. The testing and analytical data are uniform approximately. Finite element method can be used for estimating thermal field of the rotor plate at initial design stage of eddy current retarder.

Research on the use of sintering flue gas desulphurization gypsum as a cement retarder

The characteristics of the desulphurized gypsum produced in the flue gas desulphurization （FGD） process of the Baosteel sintering plant are investigated in this study. According to the technical and quality requirements of gypsum in the cement industry ,the feasibility of using desulphurized gypsum as a cement retarder is also studied. The results show that desulphurized gypsum can be used as a cement retarder instead of natural gypsum.

Ellipsometric configurations using a phase retarder and a rotating polarizer and analyzer at any speed ratio

In this paper, we propose an ellipsometer using a phase retarder and rotating polarizer and analyzer at a speed ratio I：N. Different ellipsometric configurations are presented by assuming N = 1, 2, and 3. Moreover, two values of the offset angle of the retarder are considered for each ellipsometric configuration. The Mueller formalism is employed to extract the Stokes parameters, from which the intensity received by the detector is obtained. The optical properties of c-Si are calculated using all configurations. A comparison between different configurations is carried out considering the effect of the noise on the results and the uncertainties in the ellipsometric parameters as functions of the uncertainties of the Fourier coefficients. It is found that the alignment of the phase retarder has a crucial impact on the results and the ellipsometric configuration with speed ratio 1：1 is preferred over the other configurations.

Irradiation study of liquid crystal variable retarder for Full-disk Magneto-Graph payload onboard ASO-S mission

The Advanced Space-based Solar Observatory(ASO-S)is a mission proposed by the Chinese Solar Physics Community.As one of the three payloads of ASO-S,the Full-disc Magneto-Graph(FMG)will measure the photospheric magnetic fields of the entire solar disk with high spatial and temporal resolution,and high magnetic sensitivity,where liquid crystal variable retarder(LCVR)is the key to whether FMG can achieve its scientific goal.So far,there is no space flight experience for LCVR.Therefore,irradiation study for LCVRs becomes more important and urgent in order to make sure their safety and reliability in space application.In this paper,γirradiation,proton irradiation,and ultra-violet(UV)irradiation are tested for LCVRs respectively.The optical and chemical properties during irradiation tests are measured and analyzed.For optical properties,there is no significant change in those parameters FMG payload concerned except the retardation.Although there is no drastic degradation in the retardation versus voltage during irradiations,the amount of retardation variation is much higher than the instrument requirements.Thus,an in-flight retardation versus voltage should be added in FMG payload,reducing or even avoiding the impact of retardation change.For chemical properties,the clearing point and birefringence of the LC materials almost have no change;the ion density dose not change below 60 krad[Si],but begin to increase dramatically above 60 krad[Si].

General series expression of eddy-current impedance for coil placed above multi-layer plate conductor

This paper presents a closed expression of the layered-plate factor used to calculate the coil eddy-current impedance over the multi-layer plate conductor. By using this expression, the general series of eddy-current impedance can be written directly without solving the undetermined constant equations. The series expression is easy to use for theoretical analysis and programming. Experimental results show that calculated values and measured values are in agreement. As an application, when the bottom layer of the layered plate is a non-ferromagnetic thin layer conductor and the product of the thickness and conductivity of the layer remains unchanged, using the layered-plate factor expression proposed in this paper, it can be theoretically predicted that the eddy-current impedance curves corresponding to different thin layer thickness values will coincide.

Numerical Simulation of the Demagnetization of a Permanent Magnet Retarder in High Temperature

As a auxiliary brake, Permanent Magnet Retarder （PMR） generates lots of energy and has greater temperature-rise when PMR works, so that it has a direct impact on PMR work performance and even causes demagnetization seriously. In order to analyze permanent magnet （PM） demagnetization in high-temperature in PMR, PMR mathematical model is established firstly, and the boundary conditions of finite element analysis are determined. Then the eddy current field distribution in the rotor is determined by solving eddy current demagnetization field, and PM dynamic permeance coefficient is obtained. Combined with PM demagnetization curve analysis, PMR permanent magnet demagnetization properties are analyzed. The analysis result is validated by the bench test. It shows that part of PM is demagnetized when PRM continues working for about 15 minutes, and the braking performance is declined. Finally, three PMR optimization design methods are proposed.

Design of broad angular phase retarders for the complete polarization analysis of extreme ultraviolet radiation

A method of designing broad angular phase retarders in the extreme ultraviolet （EUV） region is presented. The design is based on a standard Levenberg-Marquardt algorithm combined with a common merit function. Using this method, a series of broad angular EUV phase retarders were designed using aperiodic Mo/Si multilayers. At photon energy of 90 eV, broad angular phase retarders with 30°, 60°, and 90° phase retardations have been realized in the angular range of 39°-51°. By analyzing and comparing the performances of the designed broad angular phase retarders, we found that the Mo/Si multilayer with more layers could obtain higher phase retardation in broader angular range when used to design the broad angular phase retarder. Broad angular phase retarders possess lower sensitivity toward changing incident angle compared with the traditional phase retarders designed with transmission periodic multilayers, and can be used for the polarization control of broad angular EUV sources.

Modification of Fluorgypsum as Cement Retarder

化学作文；象它到在水泥的申请的伤害一样的 fluorgypsum 的矿物质结构精心地被分析。主要 fluorgypsum 被修改；它在水泥的生产的应用被学习。准备修改 fluorgypsum 的技术流动图表被给。试验性的结果显示那水和比率通过补充说为 14d 添加剂的化合物是大约 70% 的修改 fluorgypsum。水泥阻滞剂有某些刺激飞灰的修改 fluorgypsum；增加复合水泥的力量。另外，它的增加的数量比自然石膏的低。修改 fluorgypsum 是为自然石膏的一个好代用品。

Broadband achromatic phase retarder based on metal-multilayer dielectric grating

A new achromatic phase retarder based on a metal-multilayer dielectric grating structure is designed using the rigorous coupled wave analysis method and the genetic algorithm. The optimized phase retarder can maintain phase retardation around 90°from 900 nm to 1200 nm, and the maximum deviation is less than 4.5% while the diffraction efficiencies of TE and TM waves are both higher than 95%. Numerical analysis shows the designed phase retarder has a high fabrication tolerance of groove depth, duty cycle and incident angle. This achromatic phase retarder is simple in design and stable in performance, and can be widely used in optical systems.

Crack Length Quantification Based on Planar Eddy-Current Sensor Array and Two-Dimensional Image

Eddy-current (EC) testing is an effective electromagnetic non-destructive testing (NDT) technique.Planar eddy-current sensor arrays have several advantages such as good coherence,fast response speed,and high sensitivity,which can be used for micro-damage inspection of crucial parts in mechanical equipments and aerospace aviation.The main purpose of this research is to detect the defect in a metallic material surface and identify the length of a crack using planar eddy-current sensor arrays in different directions.The principle and characteristics of planar eddy-current sensor arrays are introduced,and a crack length quantification algorithm in different directions is investigated.A damage quantitative detection system is established based on a field programmable gate array and ARM processor.The system is utilized to inspect the micro defect in a metallic material,which is carved to micro crack with size of 7mm(length)×0.1mm(width)×1mm(depth).The experimental data show that the sensor arrays can be used for the length measurement repeatedly,and that the uncertainty of the length measurement is below ±0.2mm.

Thermal Runaway of Lithium-Ion Batteries Employing Flame-Retardant Fluorinated Electrolytes

Fluorinated electrolytes possess good antioxidant capacity that provides high compatibility to high-voltage cathode and flame retardance;thus,they are considered as a promising solution for advanced lithium-ion batteries carrying both high-energy density and high safety.Moreover,the fluorinated electrolytes are widely used to form stable electrolyte interphase,due to their chemical reactivity with lithiated graphite or lithium.However,the influence of this reactivity on the thermal safety of batteries is seldom discussed.Herein,we demonstrate that the flame-retardant fluorinated electrolytes help to reduce the flammability,while the lithium-ion batteries with flame-retardant fluorinated electrolytes still undergo thermal runaway and disclose their different thermal runaway pathway from that of battery with conventional electrolyte.The reduction in fluorinated components(e.g.,LiPF 6 and fluoroethylene carbonate(FEC))by fully lithiated graphite accounts for a significant heat release during battery thermal runaway.The 13%of total heat is sufficient to trigger the chain reactions during battery thermal runaway.This study deepens the understanding of the thermal runaway mechanism of lithium-ion batteries employing flame-retardant fluorinated electrolytes,providing guidance on the concept of electrolyte design for safer lithium-ion batteries.

An Investigation into the Influence of the Airflow Path on the Convective Heat Transfer for an Eddy Current Retarder Turntable

In order to improve the convective heat transfer relating to an eddy current retarder,the finite element model has been used to assess the performances of different possible designs.In particular,assuming the steady running state of retarder as the working condition,flow and temperature fields have been obtained for the rotor.The influence of airflow path on heat dissipation has been analysed,and the influence of the temperature field distribution on the performance of retarder has been discussed accordingly.The results show that when the steady running state of the turntable is considered,the maximum temperature is lower,the level of turbulence flow is mitigated,and the temperature distribution becomes more regular.These factors contribute to improve the heat dissipation ability of the retarder.

Modification of waste fluorgypsum and its applications as a cement retarder

The waste fluorgypsum was modified and applied as a cement retarder.The main chemical composition and mineral structure of the waste fluorgypsum were analyzed.Scanning electron microscopy (SEM) and eight-channel micro-calorimeter (TAM Air) were employed to analyze the changes in morphology and study the application performance of the modified fluorgypsum,respectively.Experimental results indicate that the flexural strength and compressive strength of the modified fluorgypsum are roughly equal to those of the natural gypsum.The morphology of the crystal of the fluorgypsum changes from block particle into trimetric short column.The fluorgypsum crystals stagger mutually and improve the strength of the hardened body.The modified fluorgypsum as cement retarder could delay the hydration,reduce the heat of the hydration and make the setting time,volume stability,and the SO3 content of the cement meet the national standards.The modified fluorgypsum is a good substitute for the natural gypsum.