The measurement on radial profile of electrostatic Reynolds stress, plasma poloidal rotations, radial and poloidal electric field have been performed in the plasma boundary region of the HL-IM Tokamak using a multi-ar...The measurement on radial profile of electrostatic Reynolds stress, plasma poloidal rotations, radial and poloidal electric field have been performed in the plasma boundary region of the HL-IM Tokamak using a multi-array of Mach/Langmuir probes. In the experiments of Lower Hybrid Current Drive (LHCD), Supersonic Molecular Beam injection (SMBI), Multi-shot Pellet Injection (MPI) and Neutral Beam injection (NBI), the correlation between the Reynolds stress and poloidal flow in the edge plasma is presented. The results indicate that a sheared poloidal flow can be generated in Tokamak plasma due to radially varying Reynolds stress.展开更多
This paper reports how pyrite films were prepared by thermal sulfurization of magnetron sputtered iron films and characterized by X-ray absorption near edge structure spectra and X-ray photoelectron spectroscopy on a ...This paper reports how pyrite films were prepared by thermal sulfurization of magnetron sputtered iron films and characterized by X-ray absorption near edge structure spectra and X-ray photoelectron spectroscopy on a 4B9B beam line at the Beijing Synchrotron Radiation Facility. The band gap of the pyrite agrees well with the optical band gap obtained by a spectrophotometer. The octahedral symmetry of pyrite leads to the splitting of the d orbit into t2g and eg levels. The high spin and low spin states were analysed through the difference of electron exchange interaction and the orbital crystal field. Only when the crystal field splitting is higher than 1.5 eV, the two weak peaks above the white lines can appear, and this was approved by experiments in the present work.展开更多
Connecting three zigzag graphene nanoribbons(ZGNRs) together through the sp^3 hybrid bonds forms a star-like ZGNR(S-ZGNR). Its band structure shows that there are four edge states at k = 0.5, in which the three el...Connecting three zigzag graphene nanoribbons(ZGNRs) together through the sp^3 hybrid bonds forms a star-like ZGNR(S-ZGNR). Its band structure shows that there are four edge states at k = 0.5, in which the three electrons distribute at three outside edge sites, and the last electron is shared equally(50%) by two sites near the central site. The lowest conductance step in the valley is 2, two times higher than that of monolayer ZGNR(M-ZGNR). Furthermore, in one quasithree-dimensional hexagonal lattice built, both of the Dirac points and the zero-energy states appear in the band structure along the z-axis for the fixed zero k-point in the x-y plane. In addition, it is an insulator in the x-y plane due to band gap 4 eV, however, for any k-point in the x-y plane the zero-energy states always exist at kz = 0.5.展开更多
Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distribut...Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distributed at the edge of faults,in poor sand bodies,and in insufficiently injected and produced areas.Therefore,the edge of faults is a major target for remaining oil enrichment and potential tapping.Based on the dynamic change of production from development wells determined by the injection-recovery relationship at the edge of faults,we analyzed the control of structural features of faults on remaining oil enrichment at the edge.Our results show that the macroscopic structural features and their geometric relationship with sand bodies controlled remaining oil enrichment zones like the edges of NNE-striking faults,the footwalls of antithetic faults,the hard linkage segments(two faults had linked together with each other to form a bigger through-going fault),the tips of faults,and the oblique anticlines of soft linkages.Fault edges formed two types of forward microamplitude structures:(1) the tilted uplift of footwalls controlled by inverse fault sections and(2) the hanging-wall horizontal anticlines controlled by synthetic fault points.The remaining oil distribution was controlled by microamplitude structures.Consequently,such zones as the tilted uplift of the footwall of the NNW-striking antithetic faults with a fault throw larger than 40 m,the hard linkage segments,the tips of faults,and the oblique anticlines of soft linkage were favorable for tapping the remaining oil potential.Multi-target directional drilling was used for remaining oil development at fault edges.Reasonable fault spacing was determined on the basis of fault combinations and width of the shattered zone.Well core and log data revealed that the width of the shattered zone on the side of the fault core was less than 15 m in general;therefore,the distance from a fault to the development target should be larger than 15 m.Vertically segmented growth faults should take the separation of the lateral overlap of faults into account.Therefore,the safe distance of remaining oil well deployment at the fault edge should be larger than the sum of the width of shattered zone in faults and the separation of growth faults by vertical segmentation.展开更多
The Mn Fe P0.56Si0.44 compound is investigated by x-ray diffraction, magnetic measurements, and x-ray absorption fine structure spectroscopy. It crystallizes in Fe2P-type structure with the lattice parameters a = b = ...The Mn Fe P0.56Si0.44 compound is investigated by x-ray diffraction, magnetic measurements, and x-ray absorption fine structure spectroscopy. It crystallizes in Fe2P-type structure with the lattice parameters a = b = 5.9823(0) and c = 3.4551(1) and undergoes a first-order phase transition at the Curie temperature of 255 K. The Fe K edge and Mn K edge x-ray absorption fine structure spectra show that Mn atoms mainly reside at 3g sites, while 3f sites are occupied by Fe atoms. The distances between the absorbing Fe atom and the first and second nearest neighbor Fe atoms in a 3f-layer shift from 2.65 and 4.01 in the ferromagnetic state to 2.61 and 3.96 in the paramagnetic phase. On the other hand, the distance between the 3g-layer and 3f-layer changes a little as 2.66 –2.73 below the Curie temperature and2.68 –2.75 above it.展开更多
As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile an...As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.展开更多
The synthesis of stable open-shell hydrocarbon system comprising of pentagon defects and zigzag edges remains unexplored,which can be considered as model compounds for unraveling the spin-localized states in graphene ...The synthesis of stable open-shell hydrocarbon system comprising of pentagon defects and zigzag edges remains unexplored,which can be considered as model compounds for unraveling the spin-localized states in graphene edges.With concise synthetic approaches,twoπ-extended fluorenyl radicals were synthesized and isolated in their crystalline state.X-ray crystallographic analysis and studies on the magnetic,optical and electrochemical properties of neutral and charged species have revealed an interesting edge-dependence of the spin/charge distribution,that is,the spin and charge distribution shifted from the pentagon defects to the zigzag edges with the elongation of conjugation.Such phenomenon was unprecedented for hydrocarbon radicals and can be rationalized by the recovery of Clar Sextets in the dominant resonance structures.Remarkably,one of the radicals exhibited exceptional stability in air-saturated solutions with the half-life time up to 260 d,thus providing opportunities for the applications as electronic materials.展开更多
Visual odometry,which aims to estimate relative camera motion between sequential video frames,has been widely used in the fields of augmented reality,virtual reality,and autonomous driving.However,it is still quite ch...Visual odometry,which aims to estimate relative camera motion between sequential video frames,has been widely used in the fields of augmented reality,virtual reality,and autonomous driving.However,it is still quite challenging for stateof-the-art approaches to handle low-texture scenes.In this paper,we propose a robust and efficient visual odometry algorithm that directly utilizes edge pixels to track camera pose.In contrast to direct methods,we choose reprojection error to construct the optimization energy,which can effectively cope with illumination changes.The distance transform map built upon edge detection for each frame is used to improve tracking efficiency.A novel weighted edge alignment method together with sliding window optimization is proposed to further improve the accuracy.Experiments on public datasets show that the method is comparable to stateof-the-art methods in terms of tracking accuracy,while being faster and more robust.展开更多
Analyzing and understanding the effects of ambient pollution on plants is getting more and more attention as a topic of environmental biology.A method based on synchrotron radiation X-ray fluorescence and X-ray absorp...Analyzing and understanding the effects of ambient pollution on plants is getting more and more attention as a topic of environmental biology.A method based on synchrotron radiation X-ray fluorescence and X-ray absorption near edge structure spectroscopy was established to analyze the sulfur concentration and speciation in mature camphor tree leaves (CTLs),which were sampled from 5 local fields in Shanghai,China.Annual SO2 concentration,SO42-concentration in atmospheric particulate,SO42-and sulfur concentration in soil were also analyzed to explore the relationship between ambient sulfur sources and the sulfur nutrient cycling in CTLs.Total sulfur concentration in mature camphor tree leaves was 766-1704 mg/kg.The mainly detected sulfur states and their corresponding compounds were +6 (sulfate,include inorganic sulfate and organic sulfate),+5.2 (sulfonate),+2.2 (suloxides),+0.6 (thiols and thiothers),+0.2 (organic sulfides).Total sulfur concentration was strongly correlated with sulfate proportion with a linear correlation coefficient up to 0.977,which suggested that sulfur accumulated in CTLs as sulfate form.Reduced sulfur compounds (organic sulfides,thiols,thioethers,sulfoxide and sulfonate) assimilation was sufficed to meet the nutrient requirement for growth at a balanced level around 526 mg/kg.The sulfate accumulation mainly caused by atmospheric sulfur pollution such as SO2 and airborne sulfate particulate instead of soil contamination.From urban to suburb place,sulfate in mature CTLs decreased as the atmospheric sulfur pollution reduced,but a dramatic increase presented near the seashore,where the marine sulfate emission and maritime activity pollution were significant.The sulfur concentration and speciation in mature CTLs effectively represented the long-term biological accumulation of atmospheric sulfur pollution in local environment.展开更多
Highly efficient and durable water oxidation electrocatalysts are critically important in a wide range of clean energy technologies,including water electrolyzers and rechargeable metal-air batteries.Here,we report a n...Highly efficient and durable water oxidation electrocatalysts are critically important in a wide range of clean energy technologies,including water electrolyzers and rechargeable metal-air batteries.Here,we report a novel sonochemical approach to synthesize amorphous nickel-iron oxides/carbon nanohybrids with tunable compositions for the oxygen evolution reaction (OER).The sonochemically synthesized amorphous electrocatalysts with optimal composition exhibit a low overpotential of 290 mV at 10 mA·cm-2 and a Tafel slope of 31 mV·decade-1 in a 0.1 M KOH electrolyte,outperforming the benchmark RuO2 catalyst.Meanwhile,these nanohybrids are also highly stable and remain amorphous even after prolonged cycling.In addition to amorphism,sonochemistry endows as-prepared nickel-iron oxides/carbon nanohybrids with a simultaneously formed carbon scaffold and internal Ni(0),which can enhance the stability and activity for the OER.This work demonstrates that sonochemistry is a unique method for synthesizing amorphous metal oxides toward an efficient and durable OER.展开更多
The total electron yield (TEY) mode has been developed successfully for XANES measurements at Beamline 4BTA of BSRF (Beijing Synchrotron Radiation Facility). Its performance was studied by measuring sulphur K-edge...The total electron yield (TEY) mode has been developed successfully for XANES measurements at Beamline 4BTA of BSRF (Beijing Synchrotron Radiation Facility). Its performance was studied by measuring sulphur K-edge XANES of three CdS samples (mixed with graphite powder as an electric conductor) with different concentration: 75%, 50~ and 25%. The data are collected in TEY mode and fluorescence yield (FY) mode respectively for comparison. The results demonstrate that the TEY spectra of three samples agree well with each other after the background is subtracted and normalized. The measured XANES spectra by TEY mode without bias and with 100V bias are almost identical to one another, but the signal-to-noise ratio of spectra measured without bias is better than that with 100V bias. The consistency of the self-absorption corrected FY spectra and TEY spectra are within 10% for the three samples.展开更多
As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni(OH)2 nanoparticles as the cathode material, nano-sized β-Ni(OH)2 particles with well-controlled particle size...As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni(OH)2 nanoparticles as the cathode material, nano-sized β-Ni(OH)2 particles with well-controlled particle size and morphology were synthesized via the one-step precipitation of a NiCl2 precursor. The composition and morphology of the nanoparticles were characterized by scanning electronic microscopy (SEM) and X-ray diffraction (XRD). The XRD patterns confirmed that β-Ni(OH)2 was successfully synthesized, while SEM results showed that the particle sizes range from 70 to 150 nm. To ensure that Ni(OH)2 could be employed in the nano-suspension flow battery, the electrochemical performance of the synthesized 13-Ni(OH)2 was initially tested in pouch cells through charge/discharge cycling. The phase transformations occurring during charge/discharge were investigated using in-situ X-ray absorption spectroscopy to obtain the shift in the oxidation state of Ni (X-ray adsorption near edge structure, XANES) and the distances between Ni and surrounding atoms in charged and discharged states (extended X-ray absorption fine structure, EXAFS). XANES results indicated that the electrode in the discharged state was a mixture of phases because the edge position did not shift back completely. XAFS results further proved that the discharge capacity was provided by β-NiOOH and the ratio between β-Ni(OH)2 and γ-NiOOH in the electrode in the discharged state was 71:29. Preliminary nano-suspension tests in a lab-scale cell were conducted to understand the behavior of the nano-suspension during charge/discharge cycling and to optimize the operating conditions.展开更多
Thin silicon phthalocyanine dichloride films on HOPG were prepared and the sample was heated in the vacuum with laser. The thickness of the thin sample on HOPG was checked by X-ray photoemission spectroscopy. The orie...Thin silicon phthalocyanine dichloride films on HOPG were prepared and the sample was heated in the vacuum with laser. The thickness of the thin sample on HOPG was checked by X-ray photoemission spectroscopy. The orientation of the molecules in respect to the substrate plane was investigated by measuring the silicon K-edge near edge X-ray absorption fine structure (NEXAFS). In the NEXAFS spectra of the thin sample, two clear peaks which were assigned to Is → σ^*Si-N and 1s→ σ^*Si-Cl appeared around 1847.2 eV and 1843.1 eV respectively. The intensities of the resonance peaks showed strong polarization dependence. A quantitative analysis of the polarization dependence revealed that the Si-N bond tended to lie down while the Si-Cl bond was out of the molecular plane.展开更多
文摘The measurement on radial profile of electrostatic Reynolds stress, plasma poloidal rotations, radial and poloidal electric field have been performed in the plasma boundary region of the HL-IM Tokamak using a multi-array of Mach/Langmuir probes. In the experiments of Lower Hybrid Current Drive (LHCD), Supersonic Molecular Beam injection (SMBI), Multi-shot Pellet Injection (MPI) and Neutral Beam injection (NBI), the correlation between the Reynolds stress and poloidal flow in the edge plasma is presented. The results indicate that a sheared poloidal flow can be generated in Tokamak plasma due to radially varying Reynolds stress.
基金Project supported by the National Natural Science Foundation of China (Grant No 102750770)
文摘This paper reports how pyrite films were prepared by thermal sulfurization of magnetron sputtered iron films and characterized by X-ray absorption near edge structure spectra and X-ray photoelectron spectroscopy on a 4B9B beam line at the Beijing Synchrotron Radiation Facility. The band gap of the pyrite agrees well with the optical band gap obtained by a spectrophotometer. The octahedral symmetry of pyrite leads to the splitting of the d orbit into t2g and eg levels. The high spin and low spin states were analysed through the difference of electron exchange interaction and the orbital crystal field. Only when the crystal field splitting is higher than 1.5 eV, the two weak peaks above the white lines can appear, and this was approved by experiments in the present work.
基金Project supported by the National Natural Science Foundation of China(Grant No.10947004)the Jiangsu Government Scholarship for Overseas Studies,China
文摘Connecting three zigzag graphene nanoribbons(ZGNRs) together through the sp^3 hybrid bonds forms a star-like ZGNR(S-ZGNR). Its band structure shows that there are four edge states at k = 0.5, in which the three electrons distribute at three outside edge sites, and the last electron is shared equally(50%) by two sites near the central site. The lowest conductance step in the valley is 2, two times higher than that of monolayer ZGNR(M-ZGNR). Furthermore, in one quasithree-dimensional hexagonal lattice built, both of the Dirac points and the zero-energy states appear in the band structure along the z-axis for the fixed zero k-point in the x-y plane. In addition, it is an insulator in the x-y plane due to band gap 4 eV, however, for any k-point in the x-y plane the zero-energy states always exist at kz = 0.5.
基金financial support from the Natural Science Foundation of China (Grant No. 41272151, 41472126)the Natural Science Foundation for Distinguished Young Scholars of Heilongjiang Province, China (Grant No. JC201304)+1 种基金the Joint Funds of the National Natural Science Foundation of China (Grant No. U1562214)the Program for Huabei Oilfield (Grant No. HBYT-CY5-2015-JS-127)
文摘Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distributed at the edge of faults,in poor sand bodies,and in insufficiently injected and produced areas.Therefore,the edge of faults is a major target for remaining oil enrichment and potential tapping.Based on the dynamic change of production from development wells determined by the injection-recovery relationship at the edge of faults,we analyzed the control of structural features of faults on remaining oil enrichment at the edge.Our results show that the macroscopic structural features and their geometric relationship with sand bodies controlled remaining oil enrichment zones like the edges of NNE-striking faults,the footwalls of antithetic faults,the hard linkage segments(two faults had linked together with each other to form a bigger through-going fault),the tips of faults,and the oblique anticlines of soft linkages.Fault edges formed two types of forward microamplitude structures:(1) the tilted uplift of footwalls controlled by inverse fault sections and(2) the hanging-wall horizontal anticlines controlled by synthetic fault points.The remaining oil distribution was controlled by microamplitude structures.Consequently,such zones as the tilted uplift of the footwall of the NNW-striking antithetic faults with a fault throw larger than 40 m,the hard linkage segments,the tips of faults,and the oblique anticlines of soft linkage were favorable for tapping the remaining oil potential.Multi-target directional drilling was used for remaining oil development at fault edges.Reasonable fault spacing was determined on the basis of fault combinations and width of the shattered zone.Well core and log data revealed that the width of the shattered zone on the side of the fault core was less than 15 m in general;therefore,the distance from a fault to the development target should be larger than 15 m.Vertically segmented growth faults should take the separation of the lateral overlap of faults into account.Therefore,the safe distance of remaining oil well deployment at the fault edge should be larger than the sum of the width of shattered zone in faults and the separation of growth faults by vertical segmentation.
基金supported by the National Natural Science Foundation of China(Grant Nos.51461035,51161017,and 11404176)the Scientific Research Projects of the Higher Educational Department of Inner Mongolian Autonomous Region,China(Grant No.NJZZ14033)The XAFS measurement was performed under the approval of Photon Factory Program Advisory Committee(Proposal Nos.2012G095 and 2014G047)
文摘The Mn Fe P0.56Si0.44 compound is investigated by x-ray diffraction, magnetic measurements, and x-ray absorption fine structure spectroscopy. It crystallizes in Fe2P-type structure with the lattice parameters a = b = 5.9823(0) and c = 3.4551(1) and undergoes a first-order phase transition at the Curie temperature of 255 K. The Fe K edge and Mn K edge x-ray absorption fine structure spectra show that Mn atoms mainly reside at 3g sites, while 3f sites are occupied by Fe atoms. The distances between the absorbing Fe atom and the first and second nearest neighbor Fe atoms in a 3f-layer shift from 2.65 and 4.01 in the ferromagnetic state to 2.61 and 3.96 in the paramagnetic phase. On the other hand, the distance between the 3g-layer and 3f-layer changes a little as 2.66 –2.73 below the Curie temperature and2.68 –2.75 above it.
基金One of us (Z.Y. Wu) was supported by 100-Talent Research Program of The Chinese Academy of Sciences. One of the authors (K. Ibrahim) is grateful to the National Natural Science Foundation of China (NSFC) for financial support (Grant No. 10074063) The
文摘As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.
基金support from the National Natural Science Foundation of China(Grant No.21971187)the Natural ScienceFoundationof Tianjin(19JCJQJC62700)the Haihe Laboratory of Sustainable Chemical Transformations。
文摘The synthesis of stable open-shell hydrocarbon system comprising of pentagon defects and zigzag edges remains unexplored,which can be considered as model compounds for unraveling the spin-localized states in graphene edges.With concise synthetic approaches,twoπ-extended fluorenyl radicals were synthesized and isolated in their crystalline state.X-ray crystallographic analysis and studies on the magnetic,optical and electrochemical properties of neutral and charged species have revealed an interesting edge-dependence of the spin/charge distribution,that is,the spin and charge distribution shifted from the pentagon defects to the zigzag edges with the elongation of conjugation.Such phenomenon was unprecedented for hydrocarbon radicals and can be rationalized by the recovery of Clar Sextets in the dominant resonance structures.Remarkably,one of the radicals exhibited exceptional stability in air-saturated solutions with the half-life time up to 260 d,thus providing opportunities for the applications as electronic materials.
基金National Key R&D Program of China under Grant No.2018YFB2100601National Natural Science Foundation of China under Grant Nos.61872024 and 61702482。
文摘Visual odometry,which aims to estimate relative camera motion between sequential video frames,has been widely used in the fields of augmented reality,virtual reality,and autonomous driving.However,it is still quite challenging for stateof-the-art approaches to handle low-texture scenes.In this paper,we propose a robust and efficient visual odometry algorithm that directly utilizes edge pixels to track camera pose.In contrast to direct methods,we choose reprojection error to construct the optimization energy,which can effectively cope with illumination changes.The distance transform map built upon edge detection for each frame is used to improve tracking efficiency.A novel weighted edge alignment method together with sliding window optimization is proposed to further improve the accuracy.Experiments on public datasets show that the method is comparable to stateof-the-art methods in terms of tracking accuracy,while being faster and more robust.
基金supported by the National Natural Science Foundation of China(No.11079049,11005141,10775150)the Major Project of Knowledge Innovation Program of Chinese Academy of Sciences(No.KJCX3.SYW.N3)
文摘Analyzing and understanding the effects of ambient pollution on plants is getting more and more attention as a topic of environmental biology.A method based on synchrotron radiation X-ray fluorescence and X-ray absorption near edge structure spectroscopy was established to analyze the sulfur concentration and speciation in mature camphor tree leaves (CTLs),which were sampled from 5 local fields in Shanghai,China.Annual SO2 concentration,SO42-concentration in atmospheric particulate,SO42-and sulfur concentration in soil were also analyzed to explore the relationship between ambient sulfur sources and the sulfur nutrient cycling in CTLs.Total sulfur concentration in mature camphor tree leaves was 766-1704 mg/kg.The mainly detected sulfur states and their corresponding compounds were +6 (sulfate,include inorganic sulfate and organic sulfate),+5.2 (sulfonate),+2.2 (suloxides),+0.6 (thiols and thiothers),+0.2 (organic sulfides).Total sulfur concentration was strongly correlated with sulfate proportion with a linear correlation coefficient up to 0.977,which suggested that sulfur accumulated in CTLs as sulfate form.Reduced sulfur compounds (organic sulfides,thiols,thioethers,sulfoxide and sulfonate) assimilation was sufficed to meet the nutrient requirement for growth at a balanced level around 526 mg/kg.The sulfate accumulation mainly caused by atmospheric sulfur pollution such as SO2 and airborne sulfate particulate instead of soil contamination.From urban to suburb place,sulfate in mature CTLs decreased as the atmospheric sulfur pollution reduced,but a dramatic increase presented near the seashore,where the marine sulfate emission and maritime activity pollution were significant.The sulfur concentration and speciation in mature CTLs effectively represented the long-term biological accumulation of atmospheric sulfur pollution in local environment.
基金We thank the Photoemission Endstation (BL10B) in National Synchrotron Radiation Laboratory (NSRL) for collecting X-ray data. This work was supported by the National Key Basic Research Program of China (Nos. 2015CB351903 and 2014CB848900), the National Natural Science Foundation of China (Nos. 21474095, 11574280, 11605201, and U1532112), CAS Key Research Program of Frontier Sciences (No. QYZDB-SSW-SLH018), and the Fundamental Research Funds for the Central Universities.
文摘Highly efficient and durable water oxidation electrocatalysts are critically important in a wide range of clean energy technologies,including water electrolyzers and rechargeable metal-air batteries.Here,we report a novel sonochemical approach to synthesize amorphous nickel-iron oxides/carbon nanohybrids with tunable compositions for the oxygen evolution reaction (OER).The sonochemically synthesized amorphous electrocatalysts with optimal composition exhibit a low overpotential of 290 mV at 10 mA·cm-2 and a Tafel slope of 31 mV·decade-1 in a 0.1 M KOH electrolyte,outperforming the benchmark RuO2 catalyst.Meanwhile,these nanohybrids are also highly stable and remain amorphous even after prolonged cycling.In addition to amorphism,sonochemistry endows as-prepared nickel-iron oxides/carbon nanohybrids with a simultaneously formed carbon scaffold and internal Ni(0),which can enhance the stability and activity for the OER.This work demonstrates that sonochemistry is a unique method for synthesizing amorphous metal oxides toward an efficient and durable OER.
基金Supported by National Natural Science Foundation of China (10775150)
文摘The total electron yield (TEY) mode has been developed successfully for XANES measurements at Beamline 4BTA of BSRF (Beijing Synchrotron Radiation Facility). Its performance was studied by measuring sulphur K-edge XANES of three CdS samples (mixed with graphite powder as an electric conductor) with different concentration: 75%, 50~ and 25%. The data are collected in TEY mode and fluorescence yield (FY) mode respectively for comparison. The results demonstrate that the TEY spectra of three samples agree well with each other after the background is subtracted and normalized. The measured XANES spectra by TEY mode without bias and with 100V bias are almost identical to one another, but the signal-to-noise ratio of spectra measured without bias is better than that with 100V bias. The consistency of the self-absorption corrected FY spectra and TEY spectra are within 10% for the three samples.
文摘As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni(OH)2 nanoparticles as the cathode material, nano-sized β-Ni(OH)2 particles with well-controlled particle size and morphology were synthesized via the one-step precipitation of a NiCl2 precursor. The composition and morphology of the nanoparticles were characterized by scanning electronic microscopy (SEM) and X-ray diffraction (XRD). The XRD patterns confirmed that β-Ni(OH)2 was successfully synthesized, while SEM results showed that the particle sizes range from 70 to 150 nm. To ensure that Ni(OH)2 could be employed in the nano-suspension flow battery, the electrochemical performance of the synthesized 13-Ni(OH)2 was initially tested in pouch cells through charge/discharge cycling. The phase transformations occurring during charge/discharge were investigated using in-situ X-ray absorption spectroscopy to obtain the shift in the oxidation state of Ni (X-ray adsorption near edge structure, XANES) and the distances between Ni and surrounding atoms in charged and discharged states (extended X-ray absorption fine structure, EXAFS). XANES results indicated that the electrode in the discharged state was a mixture of phases because the edge position did not shift back completely. XAFS results further proved that the discharge capacity was provided by β-NiOOH and the ratio between β-Ni(OH)2 and γ-NiOOH in the electrode in the discharged state was 71:29. Preliminary nano-suspension tests in a lab-scale cell were conducted to understand the behavior of the nano-suspension during charge/discharge cycling and to optimize the operating conditions.
基金Nuclear Researchers Exchange Program 2005Photon Factory Program Advisory Committee (2004G340)
文摘Thin silicon phthalocyanine dichloride films on HOPG were prepared and the sample was heated in the vacuum with laser. The thickness of the thin sample on HOPG was checked by X-ray photoemission spectroscopy. The orientation of the molecules in respect to the substrate plane was investigated by measuring the silicon K-edge near edge X-ray absorption fine structure (NEXAFS). In the NEXAFS spectra of the thin sample, two clear peaks which were assigned to Is → σ^*Si-N and 1s→ σ^*Si-Cl appeared around 1847.2 eV and 1843.1 eV respectively. The intensities of the resonance peaks showed strong polarization dependence. A quantitative analysis of the polarization dependence revealed that the Si-N bond tended to lie down while the Si-Cl bond was out of the molecular plane.