Some elements normally occur at trace levels while the majority of natural geological materials may be exceedingly enriched in some special cases, such as the Bayan Obo ore deposit where REE and Nb are extremely enric...Some elements normally occur at trace levels while the majority of natural geological materials may be exceedingly enriched in some special cases, such as the Bayan Obo ore deposit where REE and Nb are extremely enriched. These elements may not be removed completely during purification. Therefore, matrix effects will be caused during stable isotope ratio measurement in the MC-ICP-MS. Experiments have shown that the established methods of chromatographic separation of Cu, Fe, and Zn using AG MP-1 Anion Exchange Resin cannot make ef-fective separation of Nb, W, and Cu from Fe using 20 mL 6 M HCl. It is also observed that the elution curves of W and Cu overlap at working conditions and thus W is present in measurable amounts in some sample solutions. Matrix effects in the MC-ICP-MS induced by Nb, W, and Cu during Fe isotope ratio measurements and by W during Cu isotope ratio measurements were thus investigated by examining their changes in delta values between doped and undoped standards. The results show that the effects of the matrix elements Nb, W, or Cu on Fe isotope ratio measurements are minimal in the case of m(Nb)/m(Fe)<0.005, m(W)/m(Fe)<0.01, or m(Cu)/m(Fe)<0.6. This finding, combined with the extremely low levels of W and Cu, and the fact that nearly 90% of Nb can be removed during purification, demonstrates that the methods of chromatographic separation of Fe established before are suitable for Bayan Obo ore samples and that the methods can be simplified when Cu elution is unnecessary. The effects of the matrix element W on Cu isotope determinations are minimal in the case of m(W)/m(Cu)<0.7. Therefore, W exerts no significant effect on the measurements of Cu isotopes for the majority of natural geological materials.展开更多
Based on ground-based Atmospheric Emitted Radiance Interferometer (AERI) observations in Shouxian, Anhui province, China, the authors retrieve the cloud base height (CBH) and effective cloud emissivity by using the mi...Based on ground-based Atmospheric Emitted Radiance Interferometer (AERI) observations in Shouxian, Anhui province, China, the authors retrieve the cloud base height (CBH) and effective cloud emissivity by using the minimum root-mean-square difference method. This method was originally developed for satellite remote sensing. The high-temporal-resolution retrieval results can depict the trivial variations of the zenith clouds continu-ously. The retrieval results are evaluated by comparing them with observations by the cloud radar. The comparison shows that the retrieval bias is smaller for the middle and low cloud, especially for the opaque cloud. When two layers of clouds exist, the retrieval results reflect the weighting radiative contribution of the multi-layer cloud. The retrieval accuracy is affected by uncertainties of the AERI radiances and sounding profiles, in which the role of uncertainty in the temperature profile is dominant.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No. 40973037)the MLR Public Benefit Research Foundation of China (Grant No.200911043-14)
文摘Some elements normally occur at trace levels while the majority of natural geological materials may be exceedingly enriched in some special cases, such as the Bayan Obo ore deposit where REE and Nb are extremely enriched. These elements may not be removed completely during purification. Therefore, matrix effects will be caused during stable isotope ratio measurement in the MC-ICP-MS. Experiments have shown that the established methods of chromatographic separation of Cu, Fe, and Zn using AG MP-1 Anion Exchange Resin cannot make ef-fective separation of Nb, W, and Cu from Fe using 20 mL 6 M HCl. It is also observed that the elution curves of W and Cu overlap at working conditions and thus W is present in measurable amounts in some sample solutions. Matrix effects in the MC-ICP-MS induced by Nb, W, and Cu during Fe isotope ratio measurements and by W during Cu isotope ratio measurements were thus investigated by examining their changes in delta values between doped and undoped standards. The results show that the effects of the matrix elements Nb, W, or Cu on Fe isotope ratio measurements are minimal in the case of m(Nb)/m(Fe)<0.005, m(W)/m(Fe)<0.01, or m(Cu)/m(Fe)<0.6. This finding, combined with the extremely low levels of W and Cu, and the fact that nearly 90% of Nb can be removed during purification, demonstrates that the methods of chromatographic separation of Fe established before are suitable for Bayan Obo ore samples and that the methods can be simplified when Cu elution is unnecessary. The effects of the matrix element W on Cu isotope determinations are minimal in the case of m(W)/m(Cu)<0.7. Therefore, W exerts no significant effect on the measurements of Cu isotopes for the majority of natural geological materials.
基金supported by the National Natural Science Foundation of China (Grant No. 40710059003)
文摘Based on ground-based Atmospheric Emitted Radiance Interferometer (AERI) observations in Shouxian, Anhui province, China, the authors retrieve the cloud base height (CBH) and effective cloud emissivity by using the minimum root-mean-square difference method. This method was originally developed for satellite remote sensing. The high-temporal-resolution retrieval results can depict the trivial variations of the zenith clouds continu-ously. The retrieval results are evaluated by comparing them with observations by the cloud radar. The comparison shows that the retrieval bias is smaller for the middle and low cloud, especially for the opaque cloud. When two layers of clouds exist, the retrieval results reflect the weighting radiative contribution of the multi-layer cloud. The retrieval accuracy is affected by uncertainties of the AERI radiances and sounding profiles, in which the role of uncertainty in the temperature profile is dominant.
