Coke is an important medium for connecting reaction and regeneration of the methanol to propylene process on the ZSM5 catalyst.Coke grows in the meso and macro pores,it gradually worsens the diffusion inside the catal...Coke is an important medium for connecting reaction and regeneration of the methanol to propylene process on the ZSM5 catalyst.Coke grows in the meso and macro pores,it gradually worsens the diffusion inside the catalyst particle.Furthermore,pore plugging is inevitable which causes the deactivation of ZSM5 catalyst.However,current continuum model cannot reflect the changes in pore structure with clear physical concepts.A discrete model that is verified by the carbon deposition experiments is introduced to indicate the behavior of pore plugging effects.Results show that the pore plugging has a significant effect on the performance of the catalyst.The time varying profile of effectiveness factor is obtained,indicating a regular reduction with the increase of the pore plugging effect.Spatial distributions of pore size that would significantly enhance the plugging effect are also identified.展开更多
Long steel piles with large diameters have been more widely used in the field of ocean engineering. Owing to the pile with a large diameter, soil plug development during pile driving has great influences on pile drive...Long steel piles with large diameters have been more widely used in the field of ocean engineering. Owing to the pile with a large diameter, soil plug development during pile driving has great influences on pile driveability and bearing capacity. The response of soil plug developed inside the open-ended pipe pile during the dynamic condition of pile-driving is different from the response under the static condition of loading during service. This paper addresses the former aspect. A numerical procedure for soil plug effect prediction and pile driveabihty analysis is proposed and described. By taking into consideration of the pile dimension effect on side and tip resistance, this approach introduces a dimensional coefficient to the conventional static eqnihbrium equations for the plug differential unit and proposes an improved static equity method for the plug effect prediction. At the same time, this approach introduces a simplified model by use of one-dimensional stress wave equation to simulate the interaction between soil plug and pile inner wall. The proposed approach has been applied in practical engineering analyses. Results show that the calculated plug effect and pile driveabihty based on the proposed approach agree well with the observed data.展开更多
基金the Project of National Natural Science Foundation of China(21822809&21978256)the National Science Fund for Distinguished Young(21525627)+1 种基金the Fundamental Research Funds for the Central Universi-ties(2019XZZX004-03)Ningxia Collaborative Innovation Center for Value Upgrading of Coal-based Synthetic Resin(2017DC57)are gratefully acknowledged.Dr.Zuwei Liao express their dedication to Prof.Xingtian Shu on the occasion of his 80th birthday.
文摘Coke is an important medium for connecting reaction and regeneration of the methanol to propylene process on the ZSM5 catalyst.Coke grows in the meso and macro pores,it gradually worsens the diffusion inside the catalyst particle.Furthermore,pore plugging is inevitable which causes the deactivation of ZSM5 catalyst.However,current continuum model cannot reflect the changes in pore structure with clear physical concepts.A discrete model that is verified by the carbon deposition experiments is introduced to indicate the behavior of pore plugging effects.Results show that the pore plugging has a significant effect on the performance of the catalyst.The time varying profile of effectiveness factor is obtained,indicating a regular reduction with the increase of the pore plugging effect.Spatial distributions of pore size that would significantly enhance the plugging effect are also identified.
基金supported by the National Natural Science Foundation of China (Grant No.50309009)the National High Technology Research and Development Program of China(863 Program,Grant No.2004AA616100)
文摘Long steel piles with large diameters have been more widely used in the field of ocean engineering. Owing to the pile with a large diameter, soil plug development during pile driving has great influences on pile driveability and bearing capacity. The response of soil plug developed inside the open-ended pipe pile during the dynamic condition of pile-driving is different from the response under the static condition of loading during service. This paper addresses the former aspect. A numerical procedure for soil plug effect prediction and pile driveabihty analysis is proposed and described. By taking into consideration of the pile dimension effect on side and tip resistance, this approach introduces a dimensional coefficient to the conventional static eqnihbrium equations for the plug differential unit and proposes an improved static equity method for the plug effect prediction. At the same time, this approach introduces a simplified model by use of one-dimensional stress wave equation to simulate the interaction between soil plug and pile inner wall. The proposed approach has been applied in practical engineering analyses. Results show that the calculated plug effect and pile driveabihty based on the proposed approach agree well with the observed data.
