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Multi-Objective Optimization of Multi-Product Parallel Disassembly Line Balancing Problem Considering Multi-Skilled Workers Using a Discrete Chemical Reaction Optimization Algorithm
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作者 Xiwang Guo Liangbo Zhou +4 位作者 Zhiwei Zhang Liang Qi Jiacun Wang Shujin Qin Jinrui Cao 《Computers, Materials & Continua》 SCIE EI 2024年第9期4475-4496,共22页
This work investigates a multi-product parallel disassembly line balancing problem considering multi-skilled workers.A mathematical model for the parallel disassembly line is established to achieve maximized disassemb... This work investigates a multi-product parallel disassembly line balancing problem considering multi-skilled workers.A mathematical model for the parallel disassembly line is established to achieve maximized disassembly profit and minimized workstation cycle time.Based on a product’s AND/OR graph,matrices for task-skill,worker-skill,precedence relationships,and disassembly correlations are developed.A multi-objective discrete chemical reaction optimization algorithm is designed.To enhance solution diversity,improvements are made to four reactions:decomposition,synthesis,intermolecular ineffective collision,and wall invalid collision reaction,completing the evolution of molecular individuals.The established model and improved algorithm are applied to ball pen,flashlight,washing machine,and radio combinations,respectively.Introducing a Collaborative Resource Allocation(CRA)strategy based on a Decomposition-Based Multi-Objective Evolutionary Algorithm,the experimental results are compared with four classical algorithms:MOEA/D,MOEAD-CRA,Non-dominated Sorting Genetic Algorithm Ⅱ(NSGA-Ⅱ),and Non-dominated Sorting Genetic Algorithm Ⅲ(NSGA-Ⅲ).This validates the feasibility and superiority of the proposed algorithm in parallel disassembly production lines. 展开更多
关键词 Parallel disassembly line balancing problem MULTI-PRODUCT multiskilled workers discrete chemical reaction optimization algorithm
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Shock-induced chemical reaction characteristics of PTFE-Al-Bi_(2)O_(3)reactive materials
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作者 Chunlan Jiang Rong Hu +2 位作者 Jingbo Zhang Zaicheng Wang Liang Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第6期1-12,共12页
A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PT... A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PTFE/Al/Bi_(2)O_(3)on both mechanical properties and the energy release were investigated through various tests such as thermogravimetry-differential scanning calorimetry,adiabatic oxygen bomb test and split Hopkinson pressure bar test.The microstructure observed through scanning electron microscope and Xray diffraction results are used to analyze the ignition and reaction mechanism of PTFE/Al/Bi_(2)O_(3).The results indicate that the PTFE/Al/Bi_(2)O_(3)are capable of triggering the exothermic reaction of molten PTFE/Bi_(2)O_(3)and Al/Bi_(2)O_(3)over the PTFE/Al reactive materials,thereby promoting reactions.The excessive aluminum in the ternary system is beneficial for increasing energy release.The ignition of shock-induced chemical reactions in PTFE/Al/Bi_(2)O_(3)is closely related to the material fracture.The dominant mechanism for hot-spot generation under Split Hopkinson Pressure Bar test is the frictional temperature rise at the microcrack after failure. 展开更多
关键词 PTFE/Al/Bi_(2)O_(3) Shock-induced chemical reaction Energy release
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Melting Flow Analyzation of Radiative Riga Plate Two-Phase Nano-Fluid Across Non-Flatness Plane with Chemical Reaction
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作者 Jupudi Lakshmi Rama Prasad F.Mebarek-Oudina +2 位作者 G.Dharmaiah Putta Babu Rao H.Vaidya 《Frontiers in Heat and Mass Transfer》 EI 2024年第5期1515-1532,共18页
There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of... There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions. 展开更多
关键词 Non-flat sheet melting surface chemical reaction 2-phase nano fluid
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Casson Nanofluid Flow with Cattaneo-Christov Heat Flux and Chemical Reaction Past a Stretching Sheet in the Presence of Porous Medium
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作者 Mahzad Ahmed Raja Mussadaq Yousaf +1 位作者 Ali Hassan B.Shankar Goud 《Frontiers in Heat and Mass Transfer》 EI 2024年第4期1261-1276,共16页
In the current work,inclined magnetic field,thermal radiation,and the Cattaneo-Christov heat flux are taken into account as we analyze the impact of chemical reaction on magneto-hydrodynamic Casson nanofluid flow on a... In the current work,inclined magnetic field,thermal radiation,and the Cattaneo-Christov heat flux are taken into account as we analyze the impact of chemical reaction on magneto-hydrodynamic Casson nanofluid flow on a stretching sheet.Modified Buongiorno’s nanofluid model has been used to model the flow governing equations.The stretching surface is embedded in a porousmedium.By using similarity transformations,the nonlinear partial differential equations are transformed into a set of dimensionless ordinary differential equations.The numerical solution of transformed dimensionless equations is achieved by applying the shooting procedure together with Rung-Kutta 4th-order method employing MATLAB.The impact of significant parameters on the velocity profile f(ζ),temperature distributionθ(ζ),concentration profileϕ(ζ),skin friction coefficient(Cf),Nusselt number(Nux)and Sherwood number(Shx)are analyzed and displayed in graphical and tabular formats.With an increase in Casson fluid 0.5<β<2,the motion of the Casson fluid decelerates whereas the temperature profile increases.As the thermal relation factor expands 0.1<γ1<0.4,the temperature reduces,and consequently thermal boundary layer shrinks.Additionally,by raising the level of thermal radiation 1<Rd<7,the temperature profile significantly improves,and an abrupt expansion has also been observed in the associated thermal boundary with raise thermal radiation strength.It was observed that higher permeability 0<K<4 hinders the acceleration of Casson fluid.Higher Brownian motion levels 0.2<Nb<0.6 correspond to lower levels of the Casson fluid concentration profile.Moreover,it is observed that chemical reaction 0.2<γ2<0.5 has an inverse relation with the concentration level of Casson fluid.The current model’s significant uses include heat energy enhancement,petroleum recovery,energy devices,food manufacturing processes,and cooling device adjustment,among others.Furthermore,present outcomes have been found in great agreementwith already publishedwork. 展开更多
关键词 NANofLUID Cattaneo-Christov heat flux stretching sheet porous medium rosseland radiation and first order chemical reaction
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Hydromagnetic Squeezing Nanofluid Flow between Two Vertical Plates in Presence of a Chemical Reaction
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作者 Benjamin Matur Madit Jackson K. Kwanza Phineas Roy Kiogora 《Journal of Applied Mathematics and Physics》 2024年第1期126-146,共21页
In this study, Hydromagnetic Squeezing Nanofluid flow between two vertical plates in presence of a chemical reaction has been investigated. The governing equations were transformed by similarity transformation and the... In this study, Hydromagnetic Squeezing Nanofluid flow between two vertical plates in presence of a chemical reaction has been investigated. The governing equations were transformed by similarity transformation and the resulting ordinary differential equations were solved by collocation method. The velocity, temperature, concentration and magnetic induction profiles were determined with help of various flow parameters. The numerical scheme was simulated with aid of MATLAB. The results showed that increasing the squeeze number only boosts velocity and concentration while lowering temperature. Conversely, increasing the Hartmann number, Reynold’s magnetic number, Eckert number and Thermal Grashof number generally increases temperature but decreases both velocity and concentration. Chemical reaction rate and Soret number solely elevate concentration while Schmidt number only reduces it. The results of this study will be useful in the fields of oil and gas industry, plastic processing industries, filtration, food processing, lubrication system in machinery, Microfluidics devices for drug delivery and other related fields of nanotechnology. 展开更多
关键词 HYDROMAGNETIC Squeezing Flow NANofLUID Variable Magnetic Field chemical reaction
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Numerical investigation of variable viscosities and thermal stratification effects on MHD mixed convective heat and mass transfer past a porous wedge in the presence of a chemical reaction 被引量:2
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作者 I. Muhaimin R. Kandasamy Azme B. Khamis 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第11期1353-1364,共12页
An analysis is presented to investigate the effects of variable viscosities and thermal stratification on the MHD mixed convective heat and mass transfer of a viscous, incompressible, and electrically conducting fluid... An analysis is presented to investigate the effects of variable viscosities and thermal stratification on the MHD mixed convective heat and mass transfer of a viscous, incompressible, and electrically conducting fluid past a porous wedge in the presence of a chemical reaction. The wall of the wedge is embedded in a uniform nonDarcian porous medium in order to allow for possible fluid wall suction or injection. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically with finite difference methods. Numerical calculations up to the thirdorder level of truncation are carried out for different values of dimensionless parameters. The results are presented graphically, and show that the flow field and other quantities of physical interest are significantly influenced by these parameters. The results are compared with those available in literature, and show excellent agreement. 展开更多
关键词 variable viscosity chemical reaction non-Darcy flow mixed convection thermal stratification magnetic effect
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Effects of chemical reactions on MHD micropolar fluid flow past a vertical plate in slip-flow regime 被引量:2
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作者 R.C.Chaudhary Abhay Kumar Jha 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2008年第9期1179-1194,共16页
Heat and mass transfer effects on the unsteady flow of a micropolar fluid through a porous medium bounded by a semi-infinite vertical plate in a slip-flow regime are studied taking into account a homogeneous chemical ... Heat and mass transfer effects on the unsteady flow of a micropolar fluid through a porous medium bounded by a semi-infinite vertical plate in a slip-flow regime are studied taking into account a homogeneous chemical reaction of the first order. A uniform magnetic field acts perpendicular to the porous surface absorb micropolar fluid with a suction velocity varying with time. The free stream velocity follows an exponentially increasing or decreasing small perturbation law. Using the approximate method, the expressions for the velocity microrotation, temperature, and concentration are obtained. Futher, the results of the skin friction coefficient, the couple stress coefficient, and the rate of heat and mass transfer at the wall are presented with various values of fluid properties and flow conditions. 展开更多
关键词 micropolar fluid MICROROTATION chemical reaction SLIP-FLOW magnetohy-drodynamics heat and mass transfer
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Simultaneous effects of chemical reaction and Ohmic heating with heat and mass transfer over a stretching surface: A numerical study 被引量:2
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作者 S.R.Mishra M.M.Bhatti 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第9期1137-1142,共6页
In this article, we have considered the simultaneous influence of ohmic heating and chemical reaction on heat and mass transfer over a stretching sheet. The effects of applied magnetic field are also taken into consid... In this article, we have considered the simultaneous influence of ohmic heating and chemical reaction on heat and mass transfer over a stretching sheet. The effects of applied magnetic field are also taken into consideration while the induced magnetic field is not considered due to very small magnetics Reynolds number. The governing flow problem comprises of momentum, continuity, thermal energy and concentration equation which are transformed into highly nonlinear coupled ordinary differential equations by means of similarity transforms, which are then, solved numerically with the help of Successive Linearization method(SLM) and Chebyshev Spectral collocation method. Numerical values of skin friction coefficient, local Nusselt number, and Sherwood number are also taken into account with the help of tables. The physical influence of the involved parameters of flow velocity, temperature and concentration distribution is discussed and demonstrated graphically. The numerical comparison is also presented with the existing published results and found that the present results are in excellent agreement which also confirms the validity of the present methodology. 展开更多
关键词 Ohmic heating Heat and mass transfer chemical reaction Successive linearization method
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Entropy analysis in electrical magnetohydrodynamic(MHD) flow of nanofluid with effects of thermal radiation,viscous dissipation,and chemical reaction 被引量:5
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作者 Yahaya Shagaiya Daniel Zainal Abdul Aziz +1 位作者 Zuhaila Ismail Faisal Salah 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2017年第4期235-242,共8页
The unsteady mixed convection flow of electrical conducting nanofluid and heat transfer due to a permeable linear stretching sheet with the combined effects of an electric field, magnetic field, thermal radiation, vis... The unsteady mixed convection flow of electrical conducting nanofluid and heat transfer due to a permeable linear stretching sheet with the combined effects of an electric field, magnetic field, thermal radiation, viscous dissipation, and chemical reaction have been investigated. A similarity transformation is used to transform the constitutive equations into a system of nonlinear ordinary differential equations.The resultant system of equations is then solved numerically using implicit finite difference method.The velocity, temperature, concentration, entropy generation, and Bejan number are obtained with the dependence of different emerging parameters examined. It is noticed that the velocity is more sensible with high values of electric field and diminished with a magnetic field. The radiative heat transfer and viscous dissipation enhance the heat conduction in the system. Moreover, the impact of mixed convection parameter and Buoyancy ratio parameter on Bejan number profile has reverse effects. A chemical reaction reduced the nanoparticle concentration for higher values. 展开更多
关键词 Entropy generation MHD nanofluid Thermal radiation Bejan number chemical reaction Viscous dissipation
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New Analytical Study of the Effects Thermo-Diffusion, Diffusion-Thermo and Chemical Reaction of Viscous Fluid on Magneto Hydrodynamics Flow in Divergent and Convergent Channels 被引量:1
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作者 Abdul-Sattar J. A. Al-Saif Abeer Majeed Jasim 《Applied Mathematics》 2019年第4期268-300,共33页
In this paper, the magneto hydrodynamic (MHD) flow of viscous fluid in a channel with non-parallel plates is studied. The governing partial differential equation was transformed into a system of dimensionless non-simi... In this paper, the magneto hydrodynamic (MHD) flow of viscous fluid in a channel with non-parallel plates is studied. The governing partial differential equation was transformed into a system of dimensionless non-similar coupled ordinary differential equation. The transformed conservations equations were solved by using new algorithm. Basically, this new algorithm depends mainly on the Taylor expansion application with the coefficients of power series resulting from integrating the order differential equation. Results obtained from new algorithm are compared with the results of numerical Range-Kutta fourth-order algorithm with help of the shooting algorithm. The comparison revealed that the resulting solutions were excellent agreement. Thermo-diffusion and diffusion-thermo effects were investigated to analyze the behavior of temperature and concentration profile. Also the influences of the first order chemical reaction and the rate of mass and heat transfer were studied. The computed analytical solution result for the velocity, temperature and concentration distribution with the effect of various important dimensionless parameters was analyzed and discussed graphically. 展开更多
关键词 Thermo-Diffusion Diffusion-Thermo chemical reaction ANALYTICAL Approximate Solution Mass and Heat Transfer MAGNETO HYDRODYNAMICS
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Effects of Chemical Reactions in the Hypersonic Reacting Flow around Blunt Bodies
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作者 ZHAO Faming WANG Jiangfeng +1 位作者 FAN Xiaofeng YANG Tianpeng 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2019年第1期71-79,共9页
The effects of chemical reactions in the hypersonic reacting flow are investigated using an integrated algorithm considering simultaneously two different reaction mechanisms,i.e.,including the high temperature air non... The effects of chemical reactions in the hypersonic reacting flow are investigated using an integrated algorithm considering simultaneously two different reaction mechanisms,i.e.,including the high temperature air nonequilibrium chemical reactions and the H_2-air combustion reactions. The program is validated by the air non-equilibrium flow at Mach number of 25.9 with the RAM C-II configuration and the shock-induced combustion flow at Mach number of 4.512 6 around a sphere,respectively. Furthermore,the mixed reacting flow with the Mach number of 10.0 with an opposing jet of hydrogen is numerically analyzed. The results show that the program is reliable,and the effects of chemical reactions engender in the decrease of peak temperature along characteristic lines,as well as on the surface. The production of water is augmented in the region with high ratio of oxygen to hydrogen and weakened in the area with low ratio of oxygen to hydrogen by the air chemical non-equilibrium effects. 展开更多
关键词 HYPERSONIC air chemical NON-EQUILIBRIUM combustion effects of chemical reaction
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Effects of Chemical Reaction on the Unsteady Free Convection Flow past an Infinite Vertical Permeable Moving Plate with Variable Temperature
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作者 Fayza Mohammed Nasser El-Fayez 《Journal of Surface Engineered Materials and Advanced Technology》 2012年第2期100-109,共10页
Analytical solutions for the effect of chemical reaction on the unsteady free convection flow past an infinite vertical permeable moving plate with variable temperature has been studied. The plate is assumed to move w... Analytical solutions for the effect of chemical reaction on the unsteady free convection flow past an infinite vertical permeable moving plate with variable temperature has been studied. The plate is assumed to move with a constant velocity in the direction of fluid flow. The highly nonlinear coupled differential equations governing the boundary layer flow, heat and mass transfer are solved using two-term harmonic and non-harmonic functions. The parameters that arise in the perturbation analysis are Prandtl number (thermal diffusivity), Schmidt number (mass diffusivity), Grashof number (free convection), modified Grashof number, Chemical reaction parameter (rate constant), Skin friction coefficient and Sherwood number (wall mass transfer coefficient). The study has been compared with available exact solution in the literature and they are found to be in good agreement. It is observed that: The concentration increases during generative reaction and decreases in destructive reaction. The concentration increases with decreasing Schmidt number. The effect of increasing values of K leads to a fall in velocity profiles. The velocity decreases with increasing values of the Schmidt number. An increase in modified Grashof number leads to an increase in velocity profiles. The skin friction increases with decreasing Schmidt number. In generative reaction the skin friction decreases and in destructive reaction the skin friction increases. 展开更多
关键词 Heat and Mass Transfer chemical reaction PERTURBATION Technique
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Effects of Thermal Radiation and Radiation Absorption on Flow Past an Impulsively Started Infinite Vertical Plate with Newtonian Heating and Chemical Reaction
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作者 Swetha Ravi Jagdish Prakash +1 位作者 Viswanatha Reddy Gottam Vijaya Kumar Varma Sibyala 《Open Journal of Fluid Dynamics》 2015年第4期364-379,共16页
A perfect solution to the present natural convective flow problem of a vertical transfinite plate owing to the impulsive motion in the ubiety of first ordered chemical reaction, radiation absorption, radiation, Newton... A perfect solution to the present natural convective flow problem of a vertical transfinite plate owing to the impulsive motion in the ubiety of first ordered chemical reaction, radiation absorption, radiation, Newtonian heating and species concentration in its plane is evolved by applying the method of Laplace transforms in closed form at the plate. Exact results for velocity, temperature, concentration fields are prevailed and expressions for heat and mass transfer rates are also found. The effects are analyzed for the respective invariables for both ammonia and water vapor. 展开更多
关键词 NEWTONIAN HEATING Natural Convection chemical reaction INCOMPRESSIBLE Fluid RADIATION Absorption and RADIATION
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MHD Mixed Convection Flow of a Casson Fluid over an Exponentially Stretching Surface with the Effects of Soret, Dufour, Thermal Radiation and Chemical Reaction
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作者 Kankanala Sharada Bandari Shankar 《World Journal of Mechanics》 2015年第9期165-177,共13页
The present study deals with MHD (magneto hydrodynamics) mixed convection flow of a Casson fluid over an exponentially stretching sheet with the effects of Soret and Dufour, thermal radiation, chemical reaction. The g... The present study deals with MHD (magneto hydrodynamics) mixed convection flow of a Casson fluid over an exponentially stretching sheet with the effects of Soret and Dufour, thermal radiation, chemical reaction. The governing partial differential equations are converted into ordinary differential equations by using similarity transformations. These equations are then solved numerically by applying finite difference scheme known as the Keller Box method. The effects of various parameters on velocity, temperature and concentration profiles are presented graphically to interpret and the results are discussed. 展开更多
关键词 Casson Fluid Magneto Hydrodynamics MIXED Convection EXPONENTIALLY STRETCHING Surface SORET and Dufour effects Thermal Radiation chemical reaction
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Effects of transpiration on unsteady MHD flow of an upper convected Maxwell (UCM) fluid passing through a stretching surface in the presence of a first order chemical reaction
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作者 Swati Mukhopadhyay M.Golam Arif M.Wazed Ali Pk 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第12期315-322,共8页
The aim of this article is to present the effects of transpiration on the unsteady two-dimensional boundary layer flow of non-Newtonian fluid passing through a stretching sheet in the presence of a first order constru... The aim of this article is to present the effects of transpiration on the unsteady two-dimensional boundary layer flow of non-Newtonian fluid passing through a stretching sheet in the presence of a first order constructive/destructive chemical reaction. The upper-convected Maxwell (UCM) model is used here to characterize the non-Newtonian behavior of the fluid. Using similarity solutions, the governing nonlinear partial differential equations are transformed into ordinary ones and are then solved numerically by the shooting method. The flow fields and mass transfer are significantly influenced by the governing parameters. The fluid velocity initially decreases as the unsteadiness parameter increases and the concentration decreases significantly due to the increase in the unsteadiness. The effect of increasing values of transpiration (suction) and the Maxwell parameter is to suppress the velocity field; however, the concentration is enhanced as transpiration (suction) and the Maxwell parameter increase. Also, it is found that the fluid velocity decreases as the magnetic parameter increases; however, the concentration increases in this case. 展开更多
关键词 unsteady flow MHD upper convected Maxwell fluid stretching surface transpiration chemical reaction
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Substituent Effects on 13C NMR and 1H NMR Chemical Shifts of CH=N in Multi-substituted Benzylideneanilines
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作者 曹朝暾 王琳艳 曹晨忠 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第1期45-51,I0001,共8页
Fifty-three samples of multi-substituted benzylideneanilines XArCH=NArYs (abbreviated XBAYs) were synthesized and their NMR spectra were determined. An extensional study of substituent effects on the 1H NMR chemical... Fifty-three samples of multi-substituted benzylideneanilines XArCH=NArYs (abbreviated XBAYs) were synthesized and their NMR spectra were determined. An extensional study of substituent effects on the 1H NMR chemical shifts (δH(CH=N)) and 13C NMR chemical shifts (δc(CH=N)) of the CH=N bridging group from di-substituted to multi-substituted XBAYs was made based on a total of 182 samples of XBAYs, together with the NMR data of other 129 samples of di-substituted XBAYs quoted from literatures. The results show thatthe substituent specific cross-interaction effect parameter (△(∑σ)2) plays an important role in quantifying the δc(CH=N) values of XBAYs, but it is negligible for quantifying the δH (CH=N) values; the other substituent parameters also present different influences on the δc (CH=N) and (δH (CH=N). On the whole, the contributions of X and Y to the δc (CH=N) of XBAYs are balanced, but the δH(CH=N) values of XBAYs mainly rely on the contributions of X. 展开更多
关键词 Multi-substituted benzylideneanilines Substituent effects 1H NMR chemicalshifts 13C NMR chemical shifts Substituent specific cross-interaction effect
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Strong synergy between physical and chemical properties:Insight into optimization of atomically dispersed oxygen reduction catalysts 被引量:5
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作者 Yifan Zhang Linsheng Liu +4 位作者 Yuxuan Li Xueqin Mu Shichun Mu Suli Liu Zhihui Dai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期36-49,共14页
Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utiliz... Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered. 展开更多
关键词 Atomically dispersed catalysts Coordination environment Electronic orbitals Inter-site distance effect Oxygen reduction reaction
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Promoting effects of Fe_2O_3 to Pt electrocatalysts toward methanol oxidation reaction in alkaline electrolyte 被引量:1
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作者 宋桂花 杨海芳 +5 位作者 孙雅飞 王静怡 曲卫东 张强 马令娟 冯媛媛 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2017年第3期554-563,共10页
Fe_2O_3 nanorods and hexagonal nanoplates were synthesized and used as the promoters for Pt electrocatalysts toward the methanol oxidation reaction(MOR) in an alkaline electrolyte.The catalysts were characterized by... Fe_2O_3 nanorods and hexagonal nanoplates were synthesized and used as the promoters for Pt electrocatalysts toward the methanol oxidation reaction(MOR) in an alkaline electrolyte.The catalysts were characterized by scanning electron microscopy,transmission electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,cyclic voltammetry and chronoamperometry.The results show that the presence of Fe_2O_3 in the electrocatalysts can promote the kinetic processes of MOR on Pt,and this promoting effect is related to the morphology of the Fe_2O_3 promoter.The catalyst with Fe_2O_3 nanorods as the promoter(Pt-Fe_2O_3/C-R) exhibits much higher catalytic activity and stability than that with Fe_2O_3 nanoplates as the promoter(Pt-Fe_2O_3/C-P).The mass activity and specific activity of Pt in a Pt-Fe_2O_3/C-R catalyst are 5.32 A/mgpt and 162.7 A/m^2_(Pt),respectively,which are approximately 1.67 and 2.04 times those of the Pt-Fe_2O_3/C-P catalyst,and 4.19 and 6.16 times those of a commercial PtRu/C catalyst,respectively.Synergistic effects between Fe_2O_3 and Pt and the high content of Pt oxides in the catalysts are responsible for the improvement.These findings contribute not only to our understanding of the MOR mechanism but also to the development of advanced electrocatalysts with high catalytic properties for direct methanol fuel cells. 展开更多
关键词 PLATINUM Ferric oxide Promoting effect Methanol electrooxidation reaction Alkaline electrolyte
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“Buckets effect”in the kinetics of electrocatalytic reactions 被引量:2
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作者 Haowen Cui Yan-Xia Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期388-396,I0010,共10页
In this study,we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction(ORR)on Pt(111)in acidic solutions.Experimental results demonstrate a rectangular hyperbo... In this study,we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction(ORR)on Pt(111)in acidic solutions.Experimental results demonstrate a rectangular hyperbolic relationship,i.e.,the ORR current excluding the effect of other variables increases with proton concentration and then tends to a constant value.We consider that this is caused by the limitation of ORR kinetics by the trace oxygen concentration in the solution,which determines the upper limit of ORR kinetics.A model of effective concentration is further proposed for rectangular hyperbolic relationships:when the reactant concentration is high enough to reach a critical saturation concentration,the effective reactant concentration will become a constant value.This could be due to the limited concentration of a certain reactant for reactions involving more than one reactant or the limited number of active sites available on the catalyst.Our study provides new insights into the kinetics of electrocatalytic reactions,and it is important for the proper evaluation of catalyst activity and the study of structureperformance relationships. 展开更多
关键词 Oxygen reduction reaction KINETICS Zero order Rectangular hyperbolic relationship pH effect
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A study of fire propagation in coal seam with numerical simulation of heat transfer and chemical reaction rate in mining field 被引量:11
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作者 Moisés Oswaldo Bustamante Rúa Alan José Daza Aragón Pablo Bustamante Baena 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2019年第6期873-879,共7页
Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and pro... Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and propagation.Fire propagation develops in coal seams because of a set of factors such as direction and wind speed,fracturing and temperature.In this work,heat transfer and chemical kinetics are studied from conservation equations of energy and species,respectively,using the software COMSOL Multiphysics to simulate the propagation of fires in coal seams.Two possible scenarios were analyzed that usually occur in the walls of the coal seams,such as fire focus and fire complete screens.It was found that the propagation kinetics of the fire changes depending on the temperature,the fractur-ing of rock mass and the area of fire influence.For temperature values lower than 300℃,there is con-sumption around 250 cm^3/h,values around 700℃,the consumption is 1500 cm^3/h,and for fires of 1200℃ have values of 3000 cm^3/h.Depending on the speed of propagation can vary from 4 to 17cm/day,considering on the level and fracturing of the final wall of the open pit. 展开更多
关键词 SPONTANEOUS combustion of COAL Open PIT mines Simulation Heat transfer chemical reaction COMSOL
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