Corrosion inhibitor is one of the most important technologies to enhance the durability of steel reinforced concrete. A kind of time-saving method was developed to assess the inhibitor efficiency by using a 16 voltage...Corrosion inhibitor is one of the most important technologies to enhance the durability of steel reinforced concrete. A kind of time-saving method was developed to assess the inhibitor efficiency by using a 16 voltage electric field to accelerate the chloride ion diffusion in concrete and inducing corrosion. Both macrocell and microcell current measurements were used to confirm the corrosion initiation status of steel. The comprehensive efficiency of inhibitor shall be assessed in three aspects. The results clearly show the efficiency of different inhibitors, which indicate the reliability of this time-saving method.展开更多
Corrosion inhibition of Al and Al-3.5Mg alloy by organic compounds, namely chalcones in hydrochloric acid solutions has been investigated by rapid polarization technique and weight loss method. Polarization measuremen...Corrosion inhibition of Al and Al-3.5Mg alloy by organic compounds, namely chalcones in hydrochloric acid solutions has been investigated by rapid polarization technique and weight loss method. Polarization measurements show that, the inhibitors act cathodically both in case of Al and Al-3.5Mg alloy. It was found from the weight loss measurements that, the inhibition efficiency depends on the substituent in the chalcone compound. The relative inhibitive efficiency of these compounds has been explained on the basis of structure dependent electron donor properties of the inhibitors and the metal inhibitor interaction on the surface. The inhibition efficiency ranges from 16 to 64% for Al and from 30% to 91% for Al-3.5Mg alloy展开更多
Precipitation of calcium carbonate （CaCOs） scale on heat transfer surfaces is a serious and expensive problem widely occurring in numerous industrial processes. In this study, we compared the scale inhibition effect...Precipitation of calcium carbonate （CaCOs） scale on heat transfer surfaces is a serious and expensive problem widely occurring in numerous industrial processes. In this study, we compared the scale inhibition effect of six kinds of commercial scale inhibitors and screened out the best one （scale inhibitor SQ-1211） to investigate its scale inhibition performance in highly saline conditions at high temperature through static scale inhibition tests. The influences of scale inhibitor dosage, temperature, heating time and pH on the inhibition efficiency of the optimal scale inhibitor were investigated. The morphologies and crystal structures of the precipitates were characterized by Scanning Electron Microscopy and X-ray Diffraction analysis. Results showed that the scale inhibition efficiency of the optimal scale inhibitor decreased with the increase of the reaction temperature. When the concentration of Ca^2＋ was 1600 mg/L, the scale inhibition rate could reach 90.7% at 80℃ at pH 8. The optimal scale inhibitor could effectively retard scaling at high temperature. In the presence of the optimal scale inhibitor, the main crystal structure of CaCOs changed from calcite to aragonite.展开更多
文摘Corrosion inhibitor is one of the most important technologies to enhance the durability of steel reinforced concrete. A kind of time-saving method was developed to assess the inhibitor efficiency by using a 16 voltage electric field to accelerate the chloride ion diffusion in concrete and inducing corrosion. Both macrocell and microcell current measurements were used to confirm the corrosion initiation status of steel. The comprehensive efficiency of inhibitor shall be assessed in three aspects. The results clearly show the efficiency of different inhibitors, which indicate the reliability of this time-saving method.
文摘Corrosion inhibition of Al and Al-3.5Mg alloy by organic compounds, namely chalcones in hydrochloric acid solutions has been investigated by rapid polarization technique and weight loss method. Polarization measurements show that, the inhibitors act cathodically both in case of Al and Al-3.5Mg alloy. It was found from the weight loss measurements that, the inhibition efficiency depends on the substituent in the chalcone compound. The relative inhibitive efficiency of these compounds has been explained on the basis of structure dependent electron donor properties of the inhibitors and the metal inhibitor interaction on the surface. The inhibition efficiency ranges from 16 to 64% for Al and from 30% to 91% for Al-3.5Mg alloy
基金supported by the Major Bidding Projects in Shandong Province (No. SDZS-2012-SHBT01)
文摘Precipitation of calcium carbonate （CaCOs） scale on heat transfer surfaces is a serious and expensive problem widely occurring in numerous industrial processes. In this study, we compared the scale inhibition effect of six kinds of commercial scale inhibitors and screened out the best one （scale inhibitor SQ-1211） to investigate its scale inhibition performance in highly saline conditions at high temperature through static scale inhibition tests. The influences of scale inhibitor dosage, temperature, heating time and pH on the inhibition efficiency of the optimal scale inhibitor were investigated. The morphologies and crystal structures of the precipitates were characterized by Scanning Electron Microscopy and X-ray Diffraction analysis. Results showed that the scale inhibition efficiency of the optimal scale inhibitor decreased with the increase of the reaction temperature. When the concentration of Ca^2＋ was 1600 mg/L, the scale inhibition rate could reach 90.7% at 80℃ at pH 8. The optimal scale inhibitor could effectively retard scaling at high temperature. In the presence of the optimal scale inhibitor, the main crystal structure of CaCOs changed from calcite to aragonite.
