Laser-induced breakdown spectroscopy (LIBS) was used to decipher the unique multi-elemental characteristics of Juncus effusus L. The spectral fingerprints of Juncus effusus L. were established based on elemental mic...Laser-induced breakdown spectroscopy (LIBS) was used to decipher the unique multi-elemental characteristics of Juncus effusus L. The spectral fingerprints of Juncus effusus L. were established based on elemental microanalysis via LIBS. Microanalysis and multimode sampling methodologies were designed in this study. The relative standard deviation (RSD) approach was performed to optimize the multi-shot measurements. Taking advantage of the capability with no or minimal sample pre-treatment of LIBS, a thermodynamic chart of four elements (Mg, Ca, Ba, and Na) was created from twelve collection regions. The diagram of elemental distribution on a micro-scale was generated to explore the nature of Juncus effusus L. by LIBS. The results demon- strated that LIBS is a promising technique for rapid elemental microanalysis of heterogeneous samples.展开更多
Two new phenanthrenoid dimers, named dijuncuenins A (1) and B (2), were isolated from the ethanolic extract of the whole plant of Juncus effusus. Their structures were determined by 1D and 2D NMR spectroscopic ana...Two new phenanthrenoid dimers, named dijuncuenins A (1) and B (2), were isolated from the ethanolic extract of the whole plant of Juncus effusus. Their structures were determined by 1D and 2D NMR spectroscopic analysis and mass spectrometry. The plausible biosynthetic pathways of compounds 1 and 2 were proposed.展开更多
基金supported by National Natural Science Foundation of China(No.81303218)Beijing Municipal Government for the University Affiliated with the Party Central CommitteeDoctoral Fund of Ministry of Education of China(No.20130013120006)
文摘Laser-induced breakdown spectroscopy (LIBS) was used to decipher the unique multi-elemental characteristics of Juncus effusus L. The spectral fingerprints of Juncus effusus L. were established based on elemental microanalysis via LIBS. Microanalysis and multimode sampling methodologies were designed in this study. The relative standard deviation (RSD) approach was performed to optimize the multi-shot measurements. Taking advantage of the capability with no or minimal sample pre-treatment of LIBS, a thermodynamic chart of four elements (Mg, Ca, Ba, and Na) was created from twelve collection regions. The diagram of elemental distribution on a micro-scale was generated to explore the nature of Juncus effusus L. by LIBS. The results demon- strated that LIBS is a promising technique for rapid elemental microanalysis of heterogeneous samples.
基金the financial support of the National Science & Technology Major Project "Key New Drug Creation and Manufacturing Program"(No.2012ZX09301001-001)the National Natural Science Foundation of China(Nos.81302657,81473112,81573305)+1 种基金Youth Innovation Promotion Association CAS and for grants from the Chinese Academy of Sciences(No.KSZD-EW-Z-004-01)the State Key Laboratory of Drug Research(No.SIMM1501ZZ-03)
文摘Two new phenanthrenoid dimers, named dijuncuenins A (1) and B (2), were isolated from the ethanolic extract of the whole plant of Juncus effusus. Their structures were determined by 1D and 2D NMR spectroscopic analysis and mass spectrometry. The plausible biosynthetic pathways of compounds 1 and 2 were proposed.
基金supported by the Brazilian National Council for Scientific and Technological Development(CNPq).M.C.M.received the grant number 205031/2014-5.A.B.G.and L.G.S.were supported by grants from the Spanish Ministerio de Economía y Competitividad(BES-2013-062945 and CTM2015-64728-C2-1-R,respectively).