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Elastic responses of underground circular arches considering dynamic soil-structure interaction:A theoretical analysis 被引量:11
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作者 Hai-Long Chen Feng-Nian Jin Hua-Lin Fan 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2013年第1期110-122,共13页
Due to the wide applications of arches in underground protective structures, dynamic analysis of circular arches including soil-structure interactions is important. In this paper, an exact solution of the forced vibra... Due to the wide applications of arches in underground protective structures, dynamic analysis of circular arches including soil-structure interactions is important. In this paper, an exact solution of the forced vibration of circular arches subjected to subsurface denotation forces is obtained. The dynamic soil-structure interaction is considered with the introduction of an interfacial damping between the structure element and the surrounding soil into the equa- tion of motion. By neglecting the influences of shear, rotary inertia and tangential forces and assuming the arch incompressible, the equations of motion of the buried arches were set up. Analytical solutions of the dynamic responses of the protective arches were deduced by means of modal super- position. Arches with different opening angles, acoustic impedances and rise-span ratios were analyzed to discuss their influences on an arch. The theoretical analysis suggests blast loads for elastic designs and predicts the potential failure modes for buried protective arches. 展开更多
关键词 Underground protective arches - Dynamic soilstructure interaction Dynamic responses Analytical solution
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Elastic interaction between inclusions and tunable periodicity of superlattice structure in nanowires 被引量:1
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作者 Yang YANG Yong NI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2020年第10期1461-1478,共18页
The elastic stress distribution and the variation of the elastic energy with spacing between two inclusions of arbitrary sizes in an infinite isotropic cylindrical rod are obtained by an analytical approach and the ph... The elastic stress distribution and the variation of the elastic energy with spacing between two inclusions of arbitrary sizes in an infinite isotropic cylindrical rod are obtained by an analytical approach and the phase field microelasticity(PFM)simulation.The results show a near-attraction and far-repulsion elastic interaction between two inclusions with hydrostatic dilatation.The critical spacing,at which the interaction changes from attraction to repulsion,is on the order of the radius of the rod,dependent on the length and Poisson’s ratio of inclusions.Furthermore,the elastic energy calculations and PFM simulation results indicate that applying the local radial stress on the rod surface can modulate the elastic interaction between inclusions and adjust the periodicity of the superlattice nanowire structure.This can provide some guidelines for the tunable construction of superlattice nanowire structures. 展开更多
关键词 elastic interaction INCLUSION critical spacing superlattice structure
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Macroscopic Elastic Constants of Pure Metal Based on the Interactions between Microscopic Particles
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作者 LU Ming NIU Yongsheng FAN Rui 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第2期356-364,共9页
The research activities of the calculation of the elastic constants of metal are mainly focused on the elastic constants of crystal at the micro level. To the calculation of the macroscopic elastic constants of metal,... The research activities of the calculation of the elastic constants of metal are mainly focused on the elastic constants of crystal at the micro level. To the calculation of the macroscopic elastic constants of metal, although molecular dynamics method and quasicontinuum method can be used, but there are shortcomings in them, such as a large amount of computation and that the spatial scale of the study model is limited. Therefore, with a pure metal thin plate composed of a single layer of microscopic particles as research object, a new mechanical model is established after the interactions between microscopic particles of the thin plate are applied on the continuum mechanics model of the thin plate. According to this model, the calculation formulas for the microscopic elastic constants, which are the elastic constants of any triangle region in the model, are obtained. After the concept of the ideal micro structure is presented, the calculation formulas for the macroscopic elastic constants, the elastic modulus and the Poisson’s ratio of pure metal are obtained, where the Poisson's ratio is the constant that is equal to 1?3. As an example, the elastic constants and the elastic modulus of pure copper are solved, where c11 is 175.811 GPa, c12 is 58.604 GPa, c33 is 58.604 GPa and E is 156.277 GPa, the rationality and the correctness of the model are verified. The model presented fully embodies the discreteness of the microstructure of solid, is a development to the continuum model, and is more suitable to reality, more simplified and more new to the study of the macroscopic elastic constants of pure metal. 展开更多
关键词 pure metal elastic constants interaction mechanical model microscopic particle
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Stress in Thin Films; Diffraction Elastic Constants and Grain Interaction
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作者 U.Welzel, M.Leoni, P.Lamparter and E.J.MittemeijerMax Planck Institute for Metals Research, Seestrasse 92, D-70174 Stuttgart, Germany 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2002年第2期121-124,共4页
Untextured bulk polycrystals usually possess macroscopically isotropic elastic properties whereas for most thin films transverse isotropy is expected, owing to the limited dimensionality. The usually applied models fo... Untextured bulk polycrystals usually possess macroscopically isotropic elastic properties whereas for most thin films transverse isotropy is expected, owing to the limited dimensionality. The usually applied models for the calculation of elastic constants of polycrystals from single crystal elastic constants (so-called grain interaction models) erroneously predict macroscopic isotropy for an (untextured) thin film. This paper presents a summary of recent work where it has been demonstrated for the first time by X-ray diffraction analysis of stresses in thin films that elastic grain interaction can lead to macroscopically elastically anisotropic behaviour (shown by non-linear sin2ψ plots). A new grain interaction model, predicting the macroscopically anisotropic behaviour of thin films, is proposed. 展开更多
关键词 Thin film elastic constant Grain interaction X-ray diffraction
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THE INTERACTION PROBLEM BETWEEN THE ELASTIC LINE INCLUSIONS
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作者 陶昉敏 张明焕 汤任基 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2002年第4期371-379,共9页
Using the engineering model of elastic line inclusion and the basic solutions of a single inclusion, the interaction problem between line inclusions in an elastic solid it-as investigated. A set of standard Cauchy-typ... Using the engineering model of elastic line inclusion and the basic solutions of a single inclusion, the interaction problem between line inclusions in an elastic solid it-as investigated. A set of standard Cauchy-type singular equations of the problem was presented. The stress intensity factors at points of inclusions and the interface stresses of two sides of the inclusion were calculated. Several numerical examples were given. The results could be regarded as a reference to engineering. 展开更多
关键词 elastic inclusion interaction stress intensity factor interface stress
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An Elastic Interaction Model of Vortices
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作者 贾曼 黄菲 +2 位作者 楼森岳 孙即霖 唐晓艳 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第10期615-618,共4页
Soliton theory plays an important role in nonlinear physics.The elastic interaction among solitons is oneof the most important properties for integrable systems.In this Letter, an elastic vortex interaction model is p... Soliton theory plays an important role in nonlinear physics.The elastic interaction among solitons is oneof the most important properties for integrable systems.In this Letter, an elastic vortex interaction model is proposed.It is found that the momenta, vortex momenta and the energies of every one vortex and the interaction energies of everytwo vortices are conserved. 展开更多
关键词 VORTICES elastic interactions Euler equation
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Elastic Behaviors of Adsorbed Protein-like Chains
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作者 孙婷婷 马海珠 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第1期11-17,I0001,共8页
Elastic behaviors of protein-like chains are investigated by Pruned-Enriched-Rosenbluth method and modified orientation-dependent monomer-monomer interactions model. The protein-like chain is pulled away from the attr... Elastic behaviors of protein-like chains are investigated by Pruned-Enriched-Rosenbluth method and modified orientation-dependent monomer-monomer interactions model. The protein-like chain is pulled away from the attractive surface slowly with elastic force acting on it. Strong adsorption interaction and no adsorption interaction are both considered. We calculate the characteristic ratio and shape factor of protein-like chains in the process of elongation. The conformation change of the protein-like chain is well depicted. The shape of chain changes from “rod” to “sphere” at the beginning of elongation. Then, the shape changes from “sphere” to “rod”. In the end, the shape becomes a “sphere” as the chain leaves away from the surface. In the meantime, we discuss average Helmoholtz free energy per bond, average energy per bond, average adsorbed energy per bond, average α-helical energy per bond, average β-sheet energy per bond and average contact energy per bond. On the other hand, elastic force is also studied. It is found that elastic force has a long plateau during the tensile elongation when there exists adsorption interaction. This result is consistent with SMFS experiment of general polymers. Energy contribution to elastic force and contact energy contribution to elastic force are both discussed. These investigations can provide some insights into the elastic behaviors of adsorbed protein chains. 展开更多
关键词 elastic behavior Adsorbed protein-like chain Pruned-Enriched-Rosenbluth method Orientation-dependent monomer-monomer interactions model
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Draft effect on wave action with a semi-infinite elastic plate 被引量:4
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作者 TENG Bin GOU Ying +1 位作者 CHENG Liang LIU Shuxue 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2006年第6期116-127,共12页
A method for analyzing reflection and transmission of ocean waves from a semi-infinlte elastic plate with a draft is developed. The relation of energy conservation for plates with three different edge conditions ( fr... A method for analyzing reflection and transmission of ocean waves from a semi-infinlte elastic plate with a draft is developed. The relation of energy conservation for plates with three different edge conditions ( free, simply supported and built-in) is also derived. It is found that the present method satisfies the energy relation very well. The effects of draft on wave reflection and transmission coefficients as well as on the vertical vibration of the plates are examined through numerical tests. It is demonstrated that the zero draft assumption works well for low wave frequencies, but the effect of plate draft becomes significant for high wave frequencies. 展开更多
关键词 elastic plate DRAFT water waves interaction REFLECTION TRANSMISSION
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Soliton solution and interaction property for a coupled modified Korteweg-de Vries (mKdV) system 被引量:5
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作者 杨建荣 毛杰健 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第12期4337-4343,共7页
Hirota's bilinear direct method is applied to constructing soliton solutions to a special coupled modified Korteweg- de Vries (mKdV) system. Some physical properties such as the spatiotemporal evolution, waveform s... Hirota's bilinear direct method is applied to constructing soliton solutions to a special coupled modified Korteweg- de Vries (mKdV) system. Some physical properties such as the spatiotemporal evolution, waveform structure, interactive phenomena of solitons are discussed, especially in the two-soliton case. It is found that different interactive behaviours of solitary waves take place under different parameter conditions of overtaking collision in this system. It is verified that the elastic interaction phenomena exist in this (1+1)-dimensional integrable coupled model. 展开更多
关键词 coupled mKdV system Hirota's bilinear method soliton solution elastic interaction
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Augmented Virtual Stiffness Rendering of a Cable-driven SEA for Human-Robot Interaction 被引量:2
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作者 Ningbo Yu Wulin Zou +1 位作者 Wen Tan Zhuo Yang 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2017年第4期714-723,共10页
Human-robot interaction(HRI) is fundamental for human-centered robotics, and has been attracting intensive research for more than a decade. The series elastic actuator(SEA) provides inherent compliance, safety and fur... Human-robot interaction(HRI) is fundamental for human-centered robotics, and has been attracting intensive research for more than a decade. The series elastic actuator(SEA) provides inherent compliance, safety and further benefits for HRI, but the introduced elastic element also brings control difficulties. In this paper, we address the stiffness rendering problem for a cable-driven SEA system, to achieve either low stiffness for good transparency or high stiffness bigger than the physical spring constant, and to assess the rendering accuracy with quantified metrics. By taking a velocity-sourced model of the motor, a cascaded velocity-torque-impedance control structure is established. To achieve high fidelity torque control, the 2-DOF(degree of freedom) stabilizing control method together with a compensator has been used to handle the competing requirements on tracking performance, noise and disturbance rejection,and energy optimization in the cable-driven SEA system. The conventional passivity requirement for HRI usually leads to a conservative design of the impedance controller, and the rendered stiffness cannot go higher than the physical spring constant. By adding a phase-lead compensator into the impedance controller,the stiffness rendering capability was augmented with guaranteed relaxed passivity. Extensive simulations and experiments have been performed, and the virtual stiffness has been rendered in the extended range of 0.1 to 2.0 times of the physical spring constant with guaranteed relaxed passivity for physical humanrobot interaction below 5 Hz. Quantified metrics also verified good rendering accuracy. 展开更多
关键词 Cable actuation impedance control physical human-robot interaction relaxed passivity series elastic actuator stabilizing 2-DOF(degree of freedom) controllers
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Channel Stability Analysis by One-Way Fluid Structure Interaction: A Case Study in China 被引量:2
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作者 Xiaobin Zhu Xiaoling Wang +2 位作者 Minghui Liu Zhen Wang Xiaoxin Zhang 《Transactions of Tianjin University》 EI CAS 2017年第5期451-460,共10页
Channel engineering stability with underground goafs is a complex three-dimensional problem, especially when considering channel leakage, and is influenced by a number of processes, such as seepage, fluid structure in... Channel engineering stability with underground goafs is a complex three-dimensional problem, especially when considering channel leakage, and is influenced by a number of processes, such as seepage, fluid structure interaction (FSI), modeling, and selection of geological mechanical parameters. In this study, stability finite element analysis by one-way FSI was performed by establishing an integrated 3D engineering geological model. The extended Fourier amplitude sensitivity test was used to quantitatively assess the first-order and total sensitivities of the engineering model to critical geological mechanical parameters. Results illustrate that the channel engineering deformation is under a reasonable range and the elastic modulus is the highest total sensitivity parameter for the channel tilt and curvature at 0.7395 and 0.7525, respectively. Moreover, the most observable coupling effects for the curvature and horizontal strain are cohesion (0.1933) and density (0.7410), respectively. © 2017, Tianjin University and Springer-Verlag GmbH Germany. 展开更多
关键词 elastic moduli Fluid structure interaction GEOLOGY STABILITY
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Interaction of 14-3-3σ with KCMF1 suppresses the proliferation and colony formation of human colon cancer stem cells 被引量:4
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作者 Jian Zou Lin Mi +1 位作者 Xiao-Feng Yu Jie Dong 《World Journal of Gastroenterology》 SCIE CAS 2013年第24期3770-3780,共11页
AIM: To investigate the biological function of 14-3-3σ protein and to look for proteins that interact with 14-3-3σ protein in colon cancer stem cells. METHODS: Reverse transcription polymerase chain reaction was per... AIM: To investigate the biological function of 14-3-3σ protein and to look for proteins that interact with 14-3-3σ protein in colon cancer stem cells. METHODS: Reverse transcription polymerase chain reaction was performed to amplify the 14-3-3σ gene from the mRNA of colon cancer stem cells. The gene was then cloned into the pGEM-T vector. After being sequenced, the target gene 14-3-3σ was cut from the pGEM-T vector and cloned into the pGBKT7 yeast expression plasmid. Then, the bait plasmid pGBKT7-14-3-3σ was transformed into the yeast strain AH109. After the expression of the pGBKT7-14-3-3σ fusion protein in the AH109 yeast strain was accomplished, a yeast two-hybrid screening assay was performed by mating AH109 with Y187 that contained a HeLa cDNA library plasmid. The interaction between the 14-3-3σ protein and the proteins obtained from positive colonies was further confirmed by repeating the yeast two-hybridscreen. After extracting and sequencing the plasmids from the positive colonies, we performed a bioinformatics analysis. A coimmunoprecipitation assay was performed to confirm the interaction between 14-3-3σ and the proteins obtained from the positive colonies. Finally, we constructed 14-3-3σ and potassium channel modulatory factor 1 (KCMF1) siRNA expression plasmids and transfected them into colon cancer stem cells. RESULTS: The bait plasmid pGBKT7-14-3-3σ was constructed successfully, and the 14-3-3σ protein had no toxic or autonomous activation effect on the yeast. Nineteen true-positive colonies were selected and sequenced, and their full-length sequences were obtained. We searched for homologous DNA sequences for these sequences from GenBank. Among the positive colonies, four coding genes with known functions were obtained, including KCMF1 , quinone oxidore-ductase (NQO2 ), hydroxyisobutyrate dehydrogenase (HIBADH ) and 14-3-3σ . For the subsequent coimmu-noprecipitation assay, the plasmids PCDEF-Flag-14-3-3σ, PCDEF-Myc-KCMF1, PCDEF-Myc-NQO2 and PCDEF-Myc-HIBADH were successfully constructed, and the sequences were further confirmed by DNA sequencing. The Fugene 6 reagent was used to transfect the plasmids, and fluorescence-activated cell sorting analysis showed the transfection efficiency was 97.8% after 48 h. The HEK 293FT cells showed the stable expression of the PCDEF-Flag-14-3-3σ, PCDEF-Myc-KCMF1, PCDEF-Myc-NQO2 and PCDEF-Myc-HIBADH plasmids. After anti-Myc antibody immunoprecipitation with Myc-KCMF1, Myc-NQO2 and Myc-HIBADH from cell lysates, the presence of Flag-14-3-3σ protein in the immuno-precipitated complex was determined by western blot analysis. The knock-down expression of the 14-3-3σ and KCMF1 proteins significantly inhibited cell proliferation and colony formation of SW1116csc. CONCLUSION: Genes of the proteins that interactedwith 14-3-3σ were successfully screened from a HeLa cDNA library. KCMF1 and 14-3-3σ protein may affect the proliferation and colony formation of human colon cancer stem cells. 展开更多
关键词 14-3- protein interactING proteins YEAST TWO-HYBRID system COLON cancer stem cells
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Jet formation in shock-heavy gas bubble interaction 被引量:7
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作者 Zhi-Gang Zhai Ting Si +1 位作者 Li-Yong Zou Xi-Sheng Luo 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2013年第1期24-35,共12页
The influences of the acoustic impedance and shock strength on the jet formation in shock-heavy gas bubble interaction are numerically studied in this work. The process of a shock interacting with a krypton or a SF6 b... The influences of the acoustic impedance and shock strength on the jet formation in shock-heavy gas bubble interaction are numerically studied in this work. The process of a shock interacting with a krypton or a SF6 bubble is studied by the numerical method VAS2D. As a validation, the experiments of a SF6 bubble accelerated by a planar shock were performed. The results indicate that, due to the mismatch of acoustic impedance, the way of jet formation in heavy gas bubble with different species is diversified under the same initial condition. With respect to the same bubble, the manner of jet formation is also distinctly different under different shock strengths. The disparities of the acoustic impedance result in different effects of shock focusing in the bubble, and different behaviors of shock wave inside and outside the bubble. The analyses of the wave pattern and the pressure variation indicate that the jet formation is closely associated with the pressure perturbation. Moreover, the analy- sis of the vorticity deposition, and comparisons of circulation and baroclinic torque show that the baroclinic vorticity also contributes to the jet formation. It is concluded that the pres- sure perturbation and baroclinic vorticity deposition are the two dominant factors for the jet formation in shock-heavy gas bubble interaction. 展开更多
关键词 Shock-bubble interaction - Heavy gas bubble Acoustic impedance JET
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Particles Composition and Interactions Using the Nuon Model
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作者 René Brun 《Journal of Modern Physics》 CAS 2023年第5期623-665,共43页
The Standard Model in Particle Physics has been able to make many predictions confirmed later with a flow of experimental results. With the discovery of the Higgs boson at the LHC, one is full of admiration for the pe... The Standard Model in Particle Physics has been able to make many predictions confirmed later with a flow of experimental results. With the discovery of the Higgs boson at the LHC, one is full of admiration for the people contributing to this model fifty years ago and its predictions that have been confirmed gradually. The original particle quark constituent model has evolved with the deep inelastic experiments to a quark and gluons system, then to a more general system with virtual quarks. This work is the result of observations while working at CERN in Geneva with many different experiments at the ISR, SPS, LEP, LHC colliders. A new model based on nuons is introduced, that allows accurate evaluations of the particle masses (mesons and baryons) and magnetic moment, computes very accurately the kinematics distributions for particles and jets observed in the p-p collisions at the LHC (elastic and inelastic) and at lower energy machines. This new model looks at a first glance in contradiction with the quark model because it can build the elementary particles with nuons only, i.e. electrons and neutrinos. However, all the existing physics involved in electron, positron and neutrino interactions may be used to explain interactions between composite particles such as protons or heavy ions. 展开更多
关键词 Standard Model Particle Masses Particles interactions elastic Scattering Deep Inelastic Jets Charge Density
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A cation-dipole-reinforced elastic polymer electrolyte enabling long-cycling quasi-solid-state lithium metal batteries 被引量:1
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作者 Zhuyi Wang Yiming Wang +3 位作者 Pan Zhai Preeyaporn Poldorn Siriporn Jungsuttiwong Shuai Yuan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第12期340-348,I0009,共10页
The application of ionic liquids(IL)in polymer electrolytes represents a safer alternative to the currently used organic solvents in lithium batteries due to their nonflammability and thermal stability.However,as a pl... The application of ionic liquids(IL)in polymer electrolytes represents a safer alternative to the currently used organic solvents in lithium batteries due to their nonflammability and thermal stability.However,as a plasticizer,it is generally agreed that the introduction of ionic liquid usually leads to a trade-off between ion transport and mechanical properties of polymer electrolyte.Here we report the synthesis of an IL-embedded polymer electrolyte with both high ionic conductivity(2.77×10^(-4)S cm^(-1)at room temperature)and excellent mechanical properties(high tensile strength up to 11.4 MPa and excellent stretchability of 387%elongation at break)achieved by strong ion–dipole interactions between polymer electrolyte components,which was unveiled by the DFT calculation.Moreover,this polymer electrolyte also exhibits nonflammability,good thermal stability and the ability to recover reversibly from applied stress,i.e.,excellent elasticity.This highly viscoelastic polymer electrolyte enables tight interfacial contact and good adaptability with electrodes for stable lithium stripping/plating for 2000 h under a current density of 0.1 mA cm^(-2).By coupling with this polymer electrolyte,the LiFePO_(4)/Li cells exhibit outstanding cycling stability at room temperature as well as the reliability under extreme environmental temperature or being abused. 展开更多
关键词 elastic polymer electrolyte Ion-dipole interactions High tensile strength Quasi-solid-state lithium battery Long cycling
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Dinuclear Silver(Ⅰ) Complex Based on 1-Picolyl-3-propylbenzimidazolium Salt: Crystal Structure and Weak Interactions 被引量:3
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作者 肖姗 葛树生 +1 位作者 王修光 柳清湘 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第2期167-172,共6页
1-Picolyl-3-propylbenzimidazolium bromide (LBr) was prepared from benzimida- zole by alkylation with 2-chloromethyl-pyridine in the presence of NaH, followed by quaternization with 1-bromopropane. Ligand LBr was tre... 1-Picolyl-3-propylbenzimidazolium bromide (LBr) was prepared from benzimida- zole by alkylation with 2-chloromethyl-pyridine in the presence of NaH, followed by quaternization with 1-bromopropane. Ligand LBr was treated with AgBr in CH2Cl2 to afford a dinuclear silver(I) complex L2Ag2Br4 (1). In complex 1, a 2-D supramolecular layer is formed through two types of π-π stacking interactions. Fluorescent emission spectra of ligand LBr and complex 1 are described. 展开更多
关键词 silver complex π-π interactions
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An analytical solution for the elastic fields near spheroidal nano-inclusions 被引量:4
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作者 Z. Y. Ou G. F. Wang T. J. Wang Department of Engineering Mechanics,MOE Key Laboratory for Strength and Vibration,Xi’an Jiaotong University, Xi’an 710049, China 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2009年第6期821-830,共10页
When the size of an inclusion shrinks to nanometers, interface energy plays an important role in the deformation around it. In the present paper, we consider the effect of interface energy on the elastic fields near a... When the size of an inclusion shrinks to nanometers, interface energy plays an important role in the deformation around it. In the present paper, we consider the effect of interface energy on the elastic fields near a spheroidal nanoinclusion embedded in an elastic medium on the basis of surface elasticity theory. Using Boussinesq-Sadowsky potential function method, we obtain the deformation field near the inclusion subjected to a uniformly uniaxial loading at infinity. The results show that the elastic fields near the nano-inclusion depend strongly on the interface properties, the size and shape of inclusion. These new characteristics may be helpful to understand various relevant mechanical performances of nanosized inhomogeneities. 展开更多
关键词 Interface energy .elastic fields .Inhomogeneity - Nanometer
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Highly enhanced visible-light photocatalytic hydrogen evolution on g-C_3N_4 decorated with vopc through π-π interaction 被引量:2
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作者 Yanan Liu Liubo Ma +4 位作者 Congcong Shen Xin Wang Xiao Zhou Zhiwei Zhao Anwu Xu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第2期168-176,共9页
Photocatalytic H2 evolution reactions on pristine graphitic carbon nitrides(g-C3N4),as a promising approach for converting solar energy to fuel,are attractive for tackling global energy concerns but still suffer from ... Photocatalytic H2 evolution reactions on pristine graphitic carbon nitrides(g-C3N4),as a promising approach for converting solar energy to fuel,are attractive for tackling global energy concerns but still suffer from low efficiencies.In this article,we report a tractable approach to modifying g-C3N4 with vanadyl phthalocyanine(VOPc/CN)for efficient visible-light-driven hydrogen production.A non-covalent VOPc/CN hybrid photocatalyst formed viaπ-πstacking interactions between the two components,as confirmed by analysis of UV-vis absorption spectra.The VOPc/CN hybrid photocatalyst shows excellent visible-light-driven photocatalytic performance and good stability.Under optimal conditions,the corresponding H2 evolution rate is nearly 6 times higher than that of pure g-C3N4.The role of VOPc in promoting hydrogen evolution activity was to extend the visible light absorption range and prevent the recombination of photoexcited electron-hole pairs effectively.It is expected that this facile modification method could be a new inspiration for the rational design and exploration of g-C3N4-based hybrid systems with strong light absorption and high-efficiency carrier separation. 展开更多
关键词 VOPc/g-C3N4 π-πinteraction Visible light photocatalysis Hydrogen evolution Charge separation efficiency
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An Observational Study of the 30-50 Day Atmospheric Oscillations Part II: Temporal Evolution and Hemispheric Interaction across the Equator 被引量:3
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作者 李崇银 周亚萍 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 1991年第4期399-406,共8页
In this part, the temporal evolution and interaction across the equator of 30-50 day oscillation in the atmosphere are investigated further. The annual variation of 30-50 day oscillation is quite obvious in the mid-hi... In this part, the temporal evolution and interaction across the equator of 30-50 day oscillation in the atmosphere are investigated further. The annual variation of 30-50 day oscillation is quite obvious in the mid-high latitudes. In the tropical atmosphere, the obvious interannual variation is an important property for temporal evolution of 30-50 day oscillation. The low-frequency wavetrain across the equator over the central Pacific and central Atlantic area, the movement of the long-lived low-frequency system across the equator and the meridional wind component across the equator will obviously show the interaction of 30-50 day oscillation in the atmosphere across the equator. 展开更多
关键词 EI over An Observational Study of the 30-50 Day Atmospheric Oscillations Part II Temporal Evolution and Hemispheric interaction across the Equator Nino
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A Silver Complex of 6,7-Dicyanodipyridoquinoxaline:π-Stacking Interactions and Luminescence 被引量:1
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作者 陈慧芬 李艳 +3 位作者 王明盛 吴阿清 郭国聪 黄锦顺 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第11期1398-1403,共6页
The reaction of 6,7-dicyanodipyridoquinoxaline (DICNQ) with AgNO3 in a 1:1 molar ratio by solution method gave a new complex [Ag(DICNQ)2]NO3 1. Single-crystal X-ray diffraction analysis reveals that the complex c... The reaction of 6,7-dicyanodipyridoquinoxaline (DICNQ) with AgNO3 in a 1:1 molar ratio by solution method gave a new complex [Ag(DICNQ)2]NO3 1. Single-crystal X-ray diffraction analysis reveals that the complex crystallizes in the space group Ibca of orthorhombic system with eight formula units in a cell. Crystal data for 1: a = 15.7055(17), b = 18.411(2), c = 20.680(2)A, V = 5979.7(11)A3, Z = 8, C32Hl2AgN13O3, Mr = 734.42, Dc = 1.632 g/cm3, μ= 0.734 mm-1, F(000) = 2928, S = 1.023 and T= 293(2) K. The final R = 0.0659 and wR = 0.1927 for 2118 observed reflections with I 〉 2σ(I), and R = 0.0801 and wR = 0.2196 for all data. The complex builds up a packing structure by π-π stacking interactions and shows a luminescent feature. 展开更多
关键词 silver complex crystal structure π-πstacking interactions LUMINESCENCE
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