NOx Reduction and Desorption Studies Under Electric Discharge Plasma Using a Simulated Gas Mixture:A Case Study on the Effect of Corona Electrodes

In this study, reduction and desorption of oxides of nitrogen （NOx） were conducted using an electrical discharge plasma technique. The study was carried out using a simulated gas mixture to explore the possibility of re-generation of used adsorbents by a nonthermal plasma desorption technique. Three different types of corona electrodes, namely, pipe, helical wire, and straight wire, were used for analyzing their effectiveness in NOx reduction/desorption. The pipe- type corona electrode exhibited a nitric oxide （NO） conversion of 50%, which is 1.5 times that of the straight-wire-type electrode at an energy density of 175 J/L. The helical-wire-type corona electrode exhibited a NOx desorption efficiency almost 4 times that of the pipe-type electrode, indicating the possibility that corona-generated species play a crucial role in desorption.

Study of Pulsed Plasma in a Crossed Flow Dielectric Barrier Discharge Reactor for Improvement of NO_x Removal in Raw Diesel Engine Exhaust

Improved performance of plasma in raw engine exhaust treatment is reported. A new type of reactor referred to as of cross-flow dielectric barrier discharge （DBD） was used, in which the gas flow is perpendicular to the corona electrode. In raw exhaust environment, the cross-flow （radial-flow） reactor exhibits a superior performance with regard to NOx removal when compared to that with axial flow of gas. Experiments were conducted at different flow rates ranging from 2 L/min to 25 L/min. The plasma assisted barrier discharge reactor has shown encouraging results in NOx removal at high flow rates.

Finite element modeling and analysis of powder mixed electric discharge machining process for temperature distribution and volume removal considering multiple craters

Powder mixed electric discharge machining(PMEDM)is one of the modern developments in electric discharge machining(EDM)process.In the present work,finite element modeling has been carried out considering randomly oriented multiple sparks during PMEDM.Transient thermal analysis is done to obtain temperature distribution,volume removal,and proportion of volume removed by melting and evaporation at different current,pulse on time and fraction of heat that enters to work piece.Gradually growing spark behavior and Gaussian distribution of heat source is used to simulate multiple craters.Temperature distribution along radial direction shows peak temperature at center of spark and thereafter a gradual decrease with increase in radial distance.Along depth direction temperature sharply decreases that forms wider craters with shallow depth in PMEDM.Peak temperature and volume removal increases with current more rapidly.Volume removal by melting is much higher than evaporation at lower current settings and with higher current almost equal amount of material is removed by melting and evaporation thus reducing the re-solidification of melted material.Current plays a significant role behind the contribution of material removal by evaporation followed by fraction of heat.Increase in pulse on duration increases the total volume of material removal however does not significantly increase the proportion of volume removal by vaporization.

Effect of electrical discharge in water on concentration of nitrate solution

In this work, the effect of electrical discharge on nitrate concentration is considered in aqueous solution. The atmospheric pressure plasma was produced by a high-voltage power supply at 27 k Hz using pin-to-pin configuration. Air, argon,and argon/methane mixture were used to study the working gas effect. UV-VIS spectroscopy and ion chromatography were used to analyze the effect of the electrical discharge on nitrate concentration in deionized water. Optical emission spectroscopy（OES） was applied to diagnose active species inside and on the surface of the deionized water solution. The results of the present work showed that the atmospheric pressure electric discharge with air increases nitrate concentration while it remains constant using argon and argon/methane electrical discharges. It was also revealed that in the presence of air, the electrical discharge reduces p H, acidifying the solution and increasing solution conductivity due to production of extra nitrate ions. On the other hand, argon electrical discharge increases p H and conductivity due to production of OHion in water.

Review on reactive species in water treatment using electrical discharge plasma:formation, measurement, mechanisms and mass transfer

In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the electrical discharge plasma are reviewed, and their possible roles in the degradation of contaminants are discussed. Measurement methods for the quantification of important reactive species and their advantages and shortcomings are presented. Approaches on how to enhance the diffusion of the reactive species in solution are examined. In addition, the formation of typical reactive species in different electrical discharge plasma is compared.

Statistical Description of Debris Particle Size Distribution in Electrical Discharge Machining

Gap debris as discharge product is closely related to machining process in electrical discharge machining（EDM）. A lot of recent researches have focused on the relationship among debris size, surfaces texture, remove rate, and machining stability. The study on statistical distribution of debris size contributes to the research, but it is still superficial currently. In order to obtain the distribution law of the debris particle size, laser particle size analyzer（LPSA） combined with scanning electron microscope（SEM） is used to analyze the EDM debris size. Firstly, the heating dried method is applied to obtain the debris particles. Secondly, the measuring range of LPSA is determined as 0.5–100 μm by SEM observation, and the frequency distribution histogram and the cumulative frequency distribution scattergram of debris size are obtained by using LPSA. Thirdly, according to the distribution characteristic of the frequency distribution histogram, the statistical distribution functions of lognormal, exponentially modified Gaussian（EMG）, Gamma and Weibull are chosen to achieve curve fitting of the histogram. At last, the distribute law of the debris size is obtained by fitting results. Experiments with different discharge parameters are carried out on an EDM machine designed by the authors themselves, and the machining conditions are tool electrode of red-copper material, workpiece of ANSI 1045 material and working fluid of de-ionized water. The experimental results indicate that the debris sizes of all experiment sample truly obey the Weibull distribution. The obtained distribution law is significantly important for all the models established based on the debris particle size.

Surface Modification Process by Electrical Discharge Machining with Ti Powder Green Compact Electrode

This paper describes a new method of surface modification by Electrical Discharge Machining (EDM). By using ordinary EDM machine tool and kerosene fluid, a hard ceramic layer can be created on the workpiece surface with Ti or other compressed powder electrode in a certain condition. This new revolutionary method is called Electrical Discharge Coating (EDC). The process of EDC begins with electrode wear during EDM,then a kind of hard carbide is created through the thermal and chemical reaction between the worn electrode material and the carbon particle decomposed from kerosene fluid under high temperature. The carbide is piled up on a workpiece quickly and becomes a hard layer of ceramic about 20 μm in several minutes. This paper studies the principle and process of EDC systemically by using Ti powder green compact electrode. In order to obtain a layer of compact ceramic film, it is very important to select proper electric pulse parameters, such as pulse width, pulse interval, peak current. Meantime, the electrode materials and its forming mode will effect the machining surface quality greatly. This paper presents a series of experiment results to study the EDC process by adopt different technology parameters. Experiments and analyses show that a compact TiC ceramic layer can be created on the surface of metal workpiece. The hardness of ceramic layer is more 3 times higher than the base body, and the hardness changes gradiently from surface to base body. The method will have a great future because many materials can be easily added to the electrode and then be coated on the workpiece surface. Gearing the parameters ceramic can be created with different thickness. The switch between deposition and removal process is carried out easily by changing the polarity, thus the gear to the thickness and shape of the composite ceramic layer is carried out easily. This kind of composite ceramic layer will be used to deal with the surface of the cutting tools or molds possibly, in order to lengthen their life. It also can be found wide application in the fields of surface repairing and strengthening of the ship or aircraft.

Micro Electrical Discharge Machining Deposition in Air for Fabrication of Micro Spiral Structures

Micro electrical discharge machining（EDM） deposition process is a new micro machining method for fabrication of metal micro structures. In this process, the high level of tool electrode wear is used to achieve the metal material deposition. Up to now, the studies of micro EDM deposition process focused mainly on the researches of deposition process, namely the effects of discharge parameters in deposition process on the deposition rate or deposition quality. The research of the formation of micro structures with different discharge energy density still lacks. With proper conditions and only by the z-axis feeding in vertical direction, a novel shape of micro spiral structure can be deposited, with 0.11 mm in wire diameter, 0.20 mm in outside diameter, and 3.78 mm in height. Then some new deposition strategies including angular deposition and against the gravity deposition were also successful. In order to find the forming mechanism of the spiral structures, the numerical simulation of the transient temperature distribution on the discharge point was conducted by using the finite-element method（FEM）. The results show that there are two major factors lead to the forming of the spiral structures. One is the different material removal form of tool electrode according with the discharge energy density, the other is the influenced degree of the movement of the removed material particles in the discharge gap. The more the energy density in single discharge is, the smaller the mass of the removed material particles is, and the easier the movements of which will be changed to form an order tendency. The fine texture characteristics of the deposited micro spiral structures were analyzed by the energy spectrum analysis and the metallographic analysis. It shows that the components of the deposited material are almost the same as those of the tool electrode. Moreover the deposited material has the brass metallic luster in the longitudinal profile and has compact bonding with the base material. This research is useful to understand the micro-process of micro EDM deposition better and helpful to increase the controllability of the new EDM method for fabrication of micro structures.

Experimental Research on Effects of Process Parameters on Servo Scanning 3D Micro Electrical Discharge Machining

Servo scanning 3D micro electrical discharge machining (3D SSMEDM) is a novel and effective method in fabricating complex 3D micro structures with high aspect ratio on conducting materials. In 3D SSMEDM process, the axial wear of tool electrode can be compensated automatically by servo-keeping discharge gap, instead of the traditional methods that depend on experiential models or intermittent compensation. However, the effects of process parameters on 3D SSMEDM have not been reported up until now. In this study, the emphasis is laid on the effects of pulse duration, peak current, machining polarity, track style, track overlap, and scanning velocity on the 3D SSMEDM performances of machining efficiency, processing status, and surface accuracy. A series of experiments were carried out by machining a micro-rectangle cavity (900 μm×600 μm) on doped silicon. The experimental results were obtained as follows. Peak current plays a main role in machining efficiency and surface accuracy. Pulse duration affects obviously the stability of discharge state. The material removal rate of cathode processing is about 3/5 of that of anode processing. Compared with direction-parallel path, contour-parallel path is better in counteracting the lateral wear of tool electrode end. Scanning velocity should be selected moderately to avoid electric arc and short. Track overlap should be slightly less than the radius of tool electrode. In addition, a typical 3D micro structure of eye shape was machined based on the optimized process parameters. These results are beneficial to improve machining stability, accuracy, and efficiency in 3D SSMEDM.

Degradation of Synthetic Dyeing Wastewater by Underwater Electrical Discharge Processes

Electrical discharge treatments of synthetic dyeing wastewater were carried out with two different systems： underwater pulsed electrical discharge （UPED） and underwater dielectric barrier discharge （UDBD）. Reactive Blue 4 （RB4） and Acid Red 4 （AR4） were used as model contaminants for the synthetic wastewater. The performance of the aforementioned systems was compared with respect to the chromaticity removal and the energy requirement. The results showed that the present electrical discharge systems were very effective for degradation of the dyes. The dependences of the dye degradation rate on treatment time, initial dye concentration, electrical energy, and the type of working gas including air, 02, and N2 were examined. The change in the initial dye concentration did not largely affect the degradation of either RB4 or AR4. The energy delivered to the UPED system was only partially utilized for generating reactive species capable of degrading the dyes, leading to higher energy requirement than the UDBD system. Among the working gases, the best performance was observed with O2. As the degradation proceeded, the concentration of total dissolved solids and the solution conductivity kept increasing while pH showed a decreasing trend, revealing that the dyes were effectively mineralized.

Improving energy utilization efficiency of electrical discharge milling in titanium alloys machining

Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.

CUTTING REGULARITY AND DISCHARGE CHARACTERISTICS BY USING COMPOSITE COOLING LIQUID IN WIRE CUT ELECTRICAL DISCHARGE MACHINE WITH HIGH WIRE TRAVELING SPEED

The analysis of cutting regularity is provided through using and comparing two typical cooling liquids. It is proved that cutting regularity is greatly affected by cooling liquid＇s washing ability. Discharge characteristics and theoretic analysis between two electrodes are also discussed based on discharge waveform. By using composite cooling liquid which has strong washing ability, the efficiency in the first stable cutting phase has reached more than 200 mm^2/min, and the roughness of the surface has reached Ra〈0.8 μm after the fourth cutting with more than 50 mm^2/min average cutting efficiency. It is pointed out that cutting situation of the wire cut electrical discharge machine with high wire traveling speed （HSWEDM） is better than the wire cut electrical discharge machine with low wire traveling speed （LSWEDM） in the condition of improving the cooling liquid washing ability. The machining indices of HSWEDM will be increased remarkably by using the composite cooling liquid.

Micro electrical discharge machining of small hole in TC4 alloy

Aiming at machining deeply small holes in TC4 alloy,a series of experiments were carried out on a self-developed multi-axis micro electrical discharge machining(micro-EDM)machine tool.To improve machining efficiency and decrease relative wear of electrode in machining deeply small hole in TC4 alloy,many factors in micro-EDM,such as polarity,electrical parameters and supplying ways of working fluid were studied.Experimental results show that positive polarity machining is far superior to negative polarity machining;it is more optimal when open-circuit voltage,pulse width and pulse interval are 130 V,5μs and 15μs respectively on the self developed multi-axis micro-EDM machine tool;when flushing method is applied in micro-EDM,the machining efficiency is higher and relative wear of electrode is smaller.

MICRO ELECTRICAL DISCHARGE MACHINING DEPOSITION IN AIR

A new deposition method is described using micro electrical discharge machining （EDM） to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition （EDD） are analyzed and the realized conditions are predicted. With an ordinary EDM shaping machine, brass as the electrode, high-speed steel as the workpiece, a lot of experiments are carried out on micro EDD systematically and thoroughly. The effects of major processing parameters, such as the discharge current, discharge duration, pulse interval and working medium, are obtained, As a result, a micro cylinder with 0.19 mm in diameter and 7.35 mm in height is deposited. By exchanging the polarities of the electrode and workpiece the micro cylinder can be removed selectively. So the reversible machining of deposition and removal is achieved, which breaks through the constraint of traditional EDM. Measurements show that the deposited material is compact and close to workpiece base, whose components depend on the tool electrode, material.

Surface modification and functionalization by electrical discharge coating:a comprehensive review

Hard coatings are extensively required in industry for protecting mechanical/structural parts that withstand extremely high temperature,stress,chemical corrosion,and other hostile environments.Electrical discharge coating(EDC)is an emerging surface modification technology to produce such hard coatings by using electrical discharges to coat a layer of material on workpiece surface to modify and enhance the surface characteristics or create new surface functions.This paper presents a comprehensive overview of EDC technologies for various materials,and summarises the types and key parameters of EDC processes as well as the characteristics of resulting coatings.It provides a systematic summary of the fundamentals and key features of the EDC processes,as well as its applications and future trends.

Scale Effects and a Method for Similarity Evaluation in Micro Electrical Discharge Machining

Electrical discharge machining（EDM） is a promising non-traditional micro machining technology that offers a vast array of applications in the manufacturing industry. However, scale effects occur when machining at the micro-scale, which can make it difficult to predict and optimize the machining performances of micro EDM. A new concept of ＂scale effects＂ in micro EDM is proposed, the scale effects can reveal the difference in machining performances between micro EDM and conventional macro EDM. Similarity theory is presented to evaluate the scale effects in micro EDM. Single factor experiments are conducted and the experimental results are analyzed by discussing the similarity difference and similarity precision. The results show that the output results of scale effects in micro EDM do not change linearly with discharge parameters. The values of similarity precision of machining time significantly increase when scaling-down the capacitance or open-circuit voltage. It is indicated that the lower the scale of the discharge parameter, the greater the deviation of non-geometrical similarity degree over geometrical similarity degree, which means that the micro EDM system with lower discharge energy experiences more scale effects. The largest similarity difference is 5.34 while the largest similarity precision can be as high as 114.03. It is suggested that the similarity precision is more effective in reflecting the scale effects and their fluctuation than similarity difference. Consequently, similarity theory is suitable for evaluating the scale effects in micro EDM. This proposed research offers engineering values for optimizing the machining parameters and improving the machining performances of micro EDM.

Modelling effect of magnetic field on material removal in dry electrical discharge machining

One of the reasons for increased material removal rate in magnetic field assisted dry electrical discharge machining （EDM） is confinement of plasma due to Lorentz forces. This paper presents a mathematical model to evaluate the effect of external magnetic field on crater depth and diameter in single- and multiple-discharge EDM process. The model incorporates three main effects of the magnetic field, which include plasma confinement, mean free path reduction and pulsating magnetic field effects. Upon the application of an external magnetic field, Lorentz forces that are developed across the plasma column confine the plasma column. Also, the magnetic field reduces the mean free path of electrons due to an increase in the plasma pressure and cycloidal path taken by the electrons between the electrodes. As the mean free path of electrons reduces, more ionization occurs in plasma column and eventually an increase in the current density at the inter-electrode gap occurs. The model results for crater depth and its diameter in single discharge dry EDM process show an error of 9%-10% over the respective experimental values.

Micro Electrical Discharge Machining(μEDM):Holes Drilling and Characterization of the Process Parameters

μEDM(micro-electrical discharge machining)is a process for machining conductive materials without mechanical contact;it is particularly suitable for machining hard materials.The principle consists in creating electrical discharges between a micro-tool and a workpiece,both of which are immersed in a dielectric.It is a complementary process to mechanical,laser,micro-machining techniques,and even to techniques derived from silicon microtechnology(RIE,DRIE,LIGA).However,the resolution ofμEDM is limited;it depends on several electrical and physical parameters.The goal of this paper is to characterize the holes obtained by drilling usingμEDM with different micro-tool diameters(Φ=250μm;Φ=80μm;Φ=40μm;Φ=20μm)for an experimental time of t=2 h.The results obtained let us conclude that a large diameter micro-tool(Φ=250μm)leads to removing a larger amount of material(43×10^(5)μm^(3))than small diameters:Φ=80μm;Φ=40μm;Φ=20μm where the removed volume is equal to 2.6×10^(5)μm^(3);105μm^(3);0.4×10^(5)μm^(3),respectively.The electrode-tool diameter influences the maximum depth of the holes;a diameter ofΦ=250μm generates a hole where the maximum depth is 170μm while small diameters:Φ=80μm;Φ=40μm;Φ=20μm provide holes with a depth of 82μm;51μm;50μm respectively.Through these experiments,we can also conclude that the lateral gap of the holes is almost constant.It is about 40μm whatever the diameter.

Electrical discharge and arc milling with automatic tracking of optimal flushing direction:A novel high-efficiency compound machining method

The arc milling method has the advantages of high machining efficiency and low cost and is independent of the strength and hardness of machined materials.However,frequent electrode back-offs and the risk of workpiece burning may occur if erosion products are not removed promptly.In this study,it was found that the flushing method of the working medium had a significant impact on the machining performance of arc milling.Based on this,a novel highefficiency compound machining method of electrical discharge and arc milling with automatic tracking of the optimal flushing direction was proposed.An automatic tracking optimizer for external working medium injection was designed to determine the optimal external flushing direction according to the feed direction.The influence of flushing methods,working mediums,and machining parameters on the machining efficiency,tool electrode wear rate,machining error,and surface integrity of titanium alloys were investigated.The results indicated that better machining performance and environmental friendliness were achieved using the compound flushing method of outer compressed air and inner deionized water.Additionally,the automatic tracking flushing method in the opposite direction of the feed direction showed superior results compared to other directions.The material removal rate with the opposite direction injection could be increased up to 1.62 times that of the same direction,and the relative electrode wear rate could be reduced by 14.76%.This novel method has broad application prospects for machining parts with difficult-to-cut materials in aerospace and military industries.