One-step synthesis of FeO(OH)nanoparticles by electric explosion of iron wire underwater

In this study,we investigated electric explosion of iron wire in distilled water with different energy input adjusted by charging voltage.The as-prepared samples were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM)and X-ray photoelectron spectroscopy(XPS),showing the presence of iron and multiple iron-based compounds oxides with contents influenced by the experimental conditions.In particular,pure FeO(OH)nanoparticles were obtained using electric explosion of iron wire with energy input of 1125 J at charging voltage of 15 kV.Analysis of discharge current and resistive voltage data indicate that the high energy input induced bystrong plasma discharge at high charging voltage is a key factor to form FeO(OH).This study presents a one-step method to synthesize FeO(OH)nanoparticles using electric explosion of iron wire.

Study on theoretical model for electrical explosion resistivity of Al/Ni reactive multilayer foil

Al/Ni reactive multilayer foil(RMF)possesses excellent comprehensive properties as a promising substitute for traditional Cu bridge.A theoretical resistivity model of Al/Ni RMF was developed to guide the optimization of EFIs.Al/Ni RMF with different bilayer thicknesses and bridge dimensions were prepared by MEMS technology and electrical explosion tests were carried out.According to physical and chemical reactions in bridge,the electrical explosion process was divided into 5 stages:heating of condensed bridge,vaporization and diffusion of Al layers,intermetallic combination reaction,intrinsic explosion,ionization of metal gases,which are obviously shown in measured voltage curve.Effects of interface and grain boundary scattering on the resistivity of film metal were considered.Focusing on variations of substance and state,the resistivity was developed as a function of temperature at each stage.Electrical explosion curves were calculated by this model at different bilayer thicknesses,bridge dimensions and capacitor voltages,which showed an excellent agreement with experimental ones.

A nanoparticle formation model considering layered motion based on an electrical explosion experiment with AI wires

To study the evolution of nanoparticles during Al wire electrical explosion,a nanoparticle formation model that considered layered motion was developed,and an experimental system was set up to carry out electrical explosion experiments using 0.1 mm and 0.2 mm Al wires.The characteristic parameters and evolution process during the formation of nanoparticles were calculated and analyzed.The results show that the maximum velocities of the innermost and outermost layers are about 1200 m·s-1and 1600 m·s-1,and the velocity of the middle layer is about 1400 m·s-1,respectively.Most of the nanoparticles are formed in the temperature range of2600 K-2500 K.The characteristic temperature for the formation of Al nanoparticles is~2520K,which is also the characteristic temperature of other parameters.The size distribution range of the formed nanoparticles is 18 to 110 nm,and most of them are around 22 nm.The variation of saturated vapor pressure determines the temperature distribution range of particle nucleation.There is a minimum critical diameter of particles(~25 nm);particles smaller than the critical diameter can grow into larger particles during surface growth.Particle motion has an effect on the surface growth and aggregation process of particles,and also on the distribution area of larger-diameter particles.The simulation results are in good agreement with the experiments.We provide a method to estimate the size and distribution of nanoparticles,which is of great significance to understand the formation process of particles during the evolution of wire electrical explosion.

Numerical simulation of the initial plasma formation and current transfer in single-wire electrical explosion in vacuum

In this paper, a computational model is constructed to investigate the phenomenon of the initial plasma formation and current transfer in the single-wire electrical explosion in a vacuum. The process of the single-wire electrical explosion is divided into four stages. Stage Ⅰ： the wire is in solid state. Stage Ⅱ： the melting stage. Stage Ⅲ： the wire melts completely and the initial plasma forms. Stage IV： the core and corona expand separately. The thermodynamic calculation is applied before the wire melts completely in stages Ⅰ and Ⅱ. In stage Ⅲ, a one-dimensional magnetohydrodynamics model comes into play until the instant when the voltage collapse occurs. The temperature, density, and velocity, which are derived from the magnetohydrodynamics calculation, are averaged over the distribution area. The averaged parameters are taken as the initial conditions for stage Ⅳ in which a simplified magnetohydrodynamics model is applied. A wide-range semi-empirical equation of state, which is established based on the Thomas-Fermi-Kirzhnits model, is constructed to describe the phase transition from solid state to plasma state. The initial plasma formation and the phenomenon of current transfer in the electrical explosion of aluminum wire are investigated using the computational model. Experiments of electrical explosion of aluminum wires are carried out to verify this model. Simulation results are also compared with experimental results of the electrical explosion of copper wire.

Nanopowder production by gas-embedded electrical explosion of wire

A small electrical explosion of wire （EEW） setup for nanopowder production is constructed. It consists of a low inductance capacitor bank of 2 μF–4 μF typically charged to 8 kV–30 kV, a triggered gas switch, and a production chamber housing the exploding wire load and ambient gas. With the EEW device, nanosize powders of titanium oxides, titanium nitrides, copper oxides, and zinc oxides are successfully synthesized. The average particle size of synthesized powders under different experimental conditions is in a range of 20nm–80nm. The pressure of ambient gas or wire vapor can strongly affect the average particle size. The lower the pressure, the smaller the particle size is. For wire material with relatively high resistivity, such as titanium, whose deposited energy Wd is often less than sublimation energy W s due to the flashover breakdown along the wire prematurely ending the Joule heating process, the synthesized particle size of titanium oxides or titanium nitrides increases with overheat coefficient k （k = W d /Ws ） increasing.

Second Discharge Characteristics of Aluminum Wire Electrical Explosion Under Various Argon Pressures

Electrical wire explosion is a promising method for the preparation of metal nanopowder, but the properties of metal nanopowder are affected by the second discharge process of electrical wire explosion. The second discharge characteristics of aluminum wire electrical ex- plosion under variant argon pressures were studied in a RLC discharge circuit. The results show that the curve of the second discharge voltages versus the pressure presents a U-shape. To clarify the roles of aluminum vapor and argon in the process of the second discharge, a spectrograph and a high speed framing camera were used to study the radiation spectrum and spatial distribution of the electrical explosion plasma. It is observed that argon participates in the second discharge process under low pressure. A discharge channel develops along the surface of the aluminum vapor. Under higher pressure, a second discharge takes place in the aluminum vapor and the discharge channel is inside the aluminum vapor.

Discharge and post-explosion behaviors of electrical explosion of conductors from a single wire to planar wire array

This work deals with an experimental study of a Cu planar wire array(PWA)in air and water under the stored energy 300-1200 J.A single Cu wire is adopted as a controlled trial.Four configurations of PWA and a wire with the same mass(cross-section area)but the different specific surface areas(15-223 cm^(2)g^(-1))are exploded.The transient process is analyzed using high-speed photography in combination with the results of optical emission and discharge.Discharge characteristics revealed that PWA always has a higher electric power peak,early but higher voltage peak,as well as faster vaporization and ionization process than the single-wire case.Two to three times stronger optical emission could be obtained when replacing the single-wire with PWA,indicating a higher energy-density state is reached.Phenomenologically,in both air and water,single-wire load tends to develop a transverse stratified structure,while PWA is dominated by the uneven energy deposition among wires.Finally,the synchronism and uniformity of the PWA explosion are discussed.

Influence of current injection ways on efficiency and size of powders in preparation of nano-powders with electrical explosion

Wire electrical explosion may result in the existence of micro-sized large particles in powders while current injection ways may influence the size and content of micro-sized large particles. Therefore, two kinds of electrical explosion devices with different electrodes by gas discharge were designed in this paper. The pole-board electrodes and the cone electrodes were used respectively for studying copper wire electrical explosion process. The current and voltage data were measured with the Rogowski coil and high voltage probe. The results show that the pulverizing process of electrical explosion is more efficient when the wire electrode current density injected into the cone electrodes is approximately twice as much as the pole-board electrodes. The content of micro-sized large particles is the least among the products of the electrical explosion, when the total deposition energy of the wire prior to vaporization stage is 2. 5 times larger than that of the theoretical value of the completed vaporization.

Design,preparation,and characterization of a novel ZnO/CuO/Al energetic diode with dual functionality:Logic and destruction

Self-destructing chips have promising applications for securing data.This paper proposes a new concept of energetic diodes for the first time,which can be used for self-destructive chips.A simple two-step electrochemical deposition method is used to prepare ZnO/CuO/Al energetic diode,in which N-type ZnO and P-type CuO are constricted to a PN junction.This paper comprehensively discusses the material properties,morphology,semiconductor characteristics,and exploding performances of the energetic diode.Experimental results show that the energetic diode has typical rectification with a turn-on voltage of about 1.78 V and a reverse leakage current of about 3×10^(-4)A.When a constant voltage of 70 V loads to the energetic diode in the forward direction for about 0.14 s or 55 V loads in the reverse direction for about 0.17 s,the loaded power can excite the energetic diode exploding and the current rises to about100 A.Due to the unique performance of the energetic diode,it has a double function of rectification and explosion.The energetic diode can be used as a logic element in the normal chip to complete the regular operation,and it can release energy to destroy the chip accurately.

Effect of the Circuit and Wire Parameters on Exploding an Al Wire in Water

The underwater electrical explosion of an aluminum wire is influenced by many factors, such as wire parameters, pulsed power energy, etc. In this paper, underwater electrical explosion of an aluminum wire was investigated with pulsed voltage in the time scale of a few microseconds. A self-integrated Rogowski coil and a voltage divider were used for the measurements of current and voltage at the wire load, respectively. The deposited energy before breakdown was calculated based on experimental waveforms of current and voltage by mathematical method. Effects of the applied voltage, circuit inductance and sion and energy deposition were analyzed by means parameters of Al wire on the electrical exploof experiments and calculation. The results show that the current rise rate has an important influence on explosion process, such as the energy deposition before breakdown, the electrical power as well as the various explosion stages. A higher current rise rate can be achieved by increasing applied voltage and decreasing circuit inductance. The inhomogeneity of the energy deposition will result in prematured breakdown as well as lowered energy deposition, making the explosion process of wire more complicated.

Determining the resistance of X-pinch plasma

The current and the voltage of an X-pinch were measured. The inductance of the X-pinch was assumed to be a constant and estimated by the calculation of the magnetic field based on the well-known Biot–Savart’s Law. The voltage of the inductance was calculated with L · di/dt and subtracted from the measured voltage of the X-pinch. Then, the resistance of the X-pinch was determined and the following results were obtained. At the start of the current flow the resistance of the exploding wires is several tens of Ohms, one order of magnitude, higher than the metallic resistance of the wires at room temperature, and then it falls quickly to about 1 , which reflects the physical processes occurring in the electrically exploding wires, i.e., a current transition from the highly resistive wire core to the highly conductive plasma. It was shown that the inductive contribution to the voltage of the X-pinch is less than the resistive contribution. For the wires we used, the wires’ material and diameter have no strong influence on the resistance of the X-pinch, which may be explained by the fact that the current flows through the plasma rather than through the metallic wire itself. As a result, the current is almost equally divided between two parallel X-pinches even though the diameter and material of the wires used for these two X-pinches are significantly different.