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Application of Electrical Capacitance Tomography to the Concentration Measurement in a Cyclone Dipleg 被引量:5
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作者 孙猛 刘石 +1 位作者 李志宏 雷兢 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2008年第4期635-639,共5页
Accurate solid concentration measurement plays a key role in the process industry. Measurements analyzed offline can be used to estimate process efficiencies, to identify problems in a flow, and to validate computatio... Accurate solid concentration measurement plays a key role in the process industry. Measurements analyzed offline can be used to estimate process efficiencies, to identify problems in a flow, and to validate computational models. Online measurements can be used for active control. Electrical capacitance tomography (ECT) is a unique measuring technique with great potential in multiphase flow measurement. Experimental studies are carried out on a solid concentration measurement in a cyclone separator dipleg, using ECT. In this experiment eight electrodes are selected for the ECT sensor that is placed on the straight tube of the dipleg. The fluctuating characteristics according to the screw feeder and the effect of the airflow rate from the top of the cyclone are analyzed. The feasibility andreliability of the method are verified by the experimental results. 展开更多
关键词 electrical capacitance tomography concentration measurement cyclone separator dipleg gas-solid two-phase flow
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Void Fraction Measurement in Oil-Gas Transportation Pipeline Using an Improved Electrical Capacitance Tomography System 被引量:5
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作者 牛刚 贾志海 王经 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第4期476-481,共6页
To measure the void fraction online in oil-gas pipeline, an improved electrical capacitance tomography (ECT) system has been designed. The capacitance sensor with new structure has twelve internal electrodes and overc... To measure the void fraction online in oil-gas pipeline, an improved electrical capacitance tomography (ECT) system has been designed. The capacitance sensor with new structure has twelve internal electrodes and overcomes the influence of the pipe wall. The data collection system is improved by using high performance IC (integrated circuit). Static tests of bubble flow, stratified flow and annular flow regime are carried out. Measurements are taken on bubble flow, stratified flow and slug flow. Results show that the new ECT system performs well on void fraction measurement of bubble flow and stratified flow, but the error of measurement for slug flow is more than 10%. 展开更多
关键词 electrical capacitance tomography void fraction MEASUREMENT oil-gas transportation
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Reconstruction of electrical capacitance tomography images based on fast linearized alternating direction method of multipliers for two-phase flow system 被引量:4
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作者 Chongkun Xia Chengli Su +1 位作者 Jiangtao Cao Ping Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第5期597-605,共9页
Electrical capacitance tomography(ECT)has been applied to two-phase flow measurement in recent years.Image reconstruction algorithms play an important role in the successful applications of ECT.To solve the ill-posed ... Electrical capacitance tomography(ECT)has been applied to two-phase flow measurement in recent years.Image reconstruction algorithms play an important role in the successful applications of ECT.To solve the ill-posed and nonlinear inverse problem of ECT image reconstruction,a new ECT image reconstruction method based on fast linearized alternating direction method of multipliers(FLADMM)is proposed in this paper.On the basis of theoretical analysis of compressed sensing(CS),the data acquisition of ECT is regarded as a linear measurement process of permittivity distribution signal of pipe section.A new measurement matrix is designed and L1 regularization method is used to convert ECT inverse problem to a convex relaxation problem which contains prior knowledge.A new fast alternating direction method of multipliers which contained linearized idea is employed to minimize the objective function.Simulation data and experimental results indicate that compared with other methods,the quality and speed of reconstructed images are markedly improved.Also,the dynamic experimental results indicate that the proposed algorithm can ful fill the real-time requirement of ECT systems in the application. 展开更多
关键词 electrical capacitance tomography Image reconstruction Compressed sensing Alternating direction method of multipliers Two-phase flow
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Voidage measurement based on genetic algorithm and electrical capacitance tomography 被引量:1
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作者 王微微 王保良 +1 位作者 黄志尧 李海青 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第12期1441-1445,共5页
A new voidage measurement method based on electrical capacitance tomography (ECT) technique, Genetic Algo- rithm (GA) and Partial Least Square (PLS) method was proposed. The voidage measurement model, linear capacitan... A new voidage measurement method based on electrical capacitance tomography (ECT) technique, Genetic Algo- rithm (GA) and Partial Least Square (PLS) method was proposed. The voidage measurement model, linear capacitance combi- nation, was developed to measure on-line voidage. GA and PLS method were used to determine the coefficients of the voidage measurement model. GA was used to explore the optimal capacitance combination which gave significant contribution to the voidage measurement. PLS method was applied to determine the weight coefficient of the contribution of each capacitance to the voidage measurement. Flow pattern identification result was introduced to improve the voidage measurement accuracy. Experi- mental results showed that the proposed voidage measurement method is effective and that the measurement accuracy is satis- factory. 展开更多
关键词 VOIDAGE Two-phase flow Genetic Algorithm (GA) electrical capacitance tomography (ECT)
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Dynamic Visualization Approach of the Multiphase Flow Using Electrical Capacitance Tomography 被引量:1
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作者 王泽璞 陈琪 +2 位作者 王雪瑶 李志宏 韩振兴 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第2期380-388,共9页
Identifying the flow patterns is vital for understanding the complicated physical mechanisms in multiphase flows.For this purpose,electrical capacitance tomography(ECT) technique is considered as a promising visualiza... Identifying the flow patterns is vital for understanding the complicated physical mechanisms in multiphase flows.For this purpose,electrical capacitance tomography(ECT) technique is considered as a promising visualization method for the flow pattern identification,in which image reconstruction algorithms play an important role.In this paper,a generalized dynamic reconstruction model,which integrates ECT measurement information and physical evolution information of the objects of interest,was presented.A generalized objective functional that simultaneously considers the spatial constraints,temporal constraints and dynamic evolution information of the objects of interest was proposed.Numerical simulations and experiments were implemented to evaluate the feasibility and efficiency of the proposed algorithm.For the cases considered in this paper,the proposed algorithm can well reconstruct the flow patterns,and the quality of the reconstructed images is improved,which indicates that the proposed algorithm is competent to reconstruct the flow patterns in the visualization of multiphase flows. 展开更多
关键词 electrical capacitance tomography VISUALIZATION flow pattern identification dynamic reconstruction algorithm
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Damage Detection for CFRP Based on Planar Electrical Capacitance Tomography 被引量:1
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作者 Wenru Fan Chi Wang 《Structural Durability & Health Monitoring》 EI 2020年第4期303-314,共12页
Due to the widespread use of carbon fiber reinforced polymer/plastic(CFRP),the nondestructive structural health monitoring for CFRP is playing an increasingly essential role.As a nonrad iative,noninvasive and nondestr... Due to the widespread use of carbon fiber reinforced polymer/plastic(CFRP),the nondestructive structural health monitoring for CFRP is playing an increasingly essential role.As a nonrad iative,noninvasive and nondestructive detection technique,planar electrical capacitance tomography(PECT)electrodes array is employed in this paper to reconstruct the damage image according to the calculated dielectric constant changes.The shape and duty ratio of PECT electro-des are optimized according to the relations between sensitivity distribution and the dielectric constant of different anisotropic degrees.The sensitivity matrix of optimized PECT sensor is more uniform as the result shows,because the sensitiv-ity of insensitivity area can be increased by adding rotation of optimized electro-des.The reconstructed image qualities due to different PECT arrays and different damage locations are investigated at last.The simulation results indicate that:PECT can be used to detect the surface damage of CFRP;the sensitivity matrix of PECT for CFRP is highly relevant with the degree of anisotropic dielectric con-stant;the rotatable PECT sensor with rotation has better performance in unifor-mity of sensitivity;for different damage locations,the rotatable sensor with rotation has better image quality in most cases. 展开更多
关键词 Planar electrical capacitance tomography(PECT) carbon fiber reinforced polymer/plastic(CFRP) damage detection image reconstruction
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Visualization detection of slurry transportation pipeline based on electrical capacitance tomography in mining filling
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作者 QIN Xue-bin SHEN Yu-tong +4 位作者 LI Ming-qiao LIU Lang YANG Pei-jiao HU Jia-chen JI Chen-chen 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第11期3757-3766,共10页
In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance... In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance tomography(ECT)is a technique for visualizing two-phase flow in a pipe or closed container.In this paper,a visual detection method was proposed by image reconstruction of core,laminar,bubble and annular flow based on ECT technology,which reflects distribution of slurry in deep filling pipeline and measures the degree of blockage.There is an error between the measured and the real two-phase flow distribution due to two factors,which are immature image reconstruction algorithm of ECT and difference of flow patterns leading to degrees of error.In this paper,convolutional neural networks(CNN)is used to recognize flow patterns,and then the optimal image is calculated by the improved particle swarm optimization(PSO)algorithm with weights using simulated annealing strategy,and the fitness function is improved based on the results of the shallow neural network.Finally,the reconstructed binary image is further processed to obtain the position,size and direction of the blocked pipe.The realization of this method provides technical support for pipeline detection technology. 展开更多
关键词 image reconstruction electrical capacitance tomography convolutional neural networks blocked pipe
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Visualization Detection of Solid-Liquid Two-Phase Flow in Filling Pipeline by Electrical Capacitance Tomography Technology
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作者 Ningbo Jing Mingqiao Li +3 位作者 Lang Liu Yutong Shen Peijiao Yang Xuebin Qin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2022年第4期465-476,共12页
During mine filling,the caking in the pipeline and the waste rock in the filling slurry may cause serious safety accidents such as pipe blocking or explosion.Therefore,the visualization of the innermine filling of the... During mine filling,the caking in the pipeline and the waste rock in the filling slurry may cause serious safety accidents such as pipe blocking or explosion.Therefore,the visualization of the innermine filling of the solid-liquid two-phase flow in the pipeline is important.This paper proposes a method based on capacitance tomography for the visualization of the solid-liquid distribution on the section of a filling pipe.A feedback network is used for electrical capacitance tomography reconstruction.This reconstruction method uses radial basis function neural network fitting to determine the relationship between the capacitance vector and medium distribution error.In the reconstruction process,the error in the linear back projection is removed;thus,the reconstruction problem becomes an accurate linear problem.The simulation results showthat the reconstruction accuracy of this algorithm is better than that of many traditional algorithms;furthermore,the reconstructed image artifacts are fewer,and the phase distribution boundary is clearer.This method can help determine the location and size of the caking and waste rock in the cross section of the pipeline more accurately and has great application prospects in the visualization of filling pipelines in mines. 展开更多
关键词 electrical capacitance tomography mine backfilling visualization detection image reconstruction radial basis function neural network
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Electrical capacitance volume tomography for measurement soil water infiltration in vessel experiments
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作者 Muhammad Mukhlisin Marlin Ramadhan Baidillah Mohd Raihan Taha 《Journal of Central South University》 SCIE EI CAS 2014年第1期358-364,共7页
Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is ... Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is first application of the method to visualization of water flow in soil.We describe the principles behind the method,and then demonstrate its use with a simple laboratory infiltration experiment.32 ECVT sensors were installed on the sides of an empty PVC column.Water was poured into the column at a constant rate,and ECVT data were collected every second.The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second.Data were analyzed to give bulk average water contents,which proved consistent with the water supply rates.Data were also analyzed to give 3D images(216 voxels) allowing visualization of the water distribution during the experiments.Result of this work shows that water infiltration into the soil,wall flow,progress of the unstable wetting front and the final water distribution are clearly visible. 展开更多
关键词 soil water infiltration electrical capacitance volume tomography real time imaging
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A Multiresolution Reconstructive Algorithm Based on Network Theory for Electrical Capacitance Tomography
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作者 Ma Ning Gong Xiaohong +1 位作者 Su Xiangfang Wang Yanping 《Wuhan University Journal of Natural Sciences》 CAS 1998年第1期56-60,共5页
Electrical capacitance tomography technique reconstructs dielectric constant distribution in an object by measuring the capacitances between the eletrode pairs which are mounted around this object. Because of the limi... Electrical capacitance tomography technique reconstructs dielectric constant distribution in an object by measuring the capacitances between the eletrode pairs which are mounted around this object. Because of the limitation of measurement condition, the measured data are imcomplet. This paper describes a multiresolution reconstructive algorithm which is based on network theory for electrical capacitance tomography technique. The dielectric constant distribution of flow of two components in a pipeline is reconstructed. The algorithm is as follows: Firstly, construct a rough, first level system model, and assume the dielectric constant distribution of the region to be reconstructed. After iteration, the dielectic constant of each unit can be reconstructed. Secondly, construct a finer, second level the system model and determine the initial dielectric constant of each unit in the region to be reconstructed according to related information between two levels. After iteration, the image of the pipeline's cross section can be reconstructed. The results of simulated experiments about different kinds of medium distributions show that this algorithm is effective and can converge. 展开更多
关键词 multiresolution reconstructive algorithm electrical capacitance tomography NETWORK
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Modeling and Implementation of AC Electrical Capacitance Tomography
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作者 K. Manikandan S. Sathiyamoorthy 《Circuits and Systems》 2016年第11期3818-3830,共14页
Electrical Capacitance Tomography (ECT) determines the dielectric permittivity of the interior object depending on the measurements of exterior capacitance. Generally, the electrodes are placed outside the PVC cylinde... Electrical Capacitance Tomography (ECT) determines the dielectric permittivity of the interior object depending on the measurements of exterior capacitance. Generally, the electrodes are placed outside the PVC cylinder where the medium to be imaged is present;but in ECT using inter-electrode capacitance measurements can be achieved by placing inside of the dielectric medium. In the proposed ECT system, the ECT sensor is modeled using ANSYS software and the model is implemented in real ECT system. For each step of measurement, a stable AC signal is applied to a pair of electrodes that form a capacitor. The novel system is to measure the capacitance range variation in picofarad and the corresponding voltage ranges from 1 volt to 4 volts. The switching speed of all combinational electrodes is implemented using embedded system to achieve higher speed performance of AC ECT system which eliminates the drift and stray capacitance error. This is yielding the original image of unknown multiphase medium inside the electrodes using Lab VIEW. This paper investigates several advantages such as improved overall system performance;simple structure, avoids stray capacitance effect, reduces the drift problem and achieves high signal to noise ratio. 展开更多
关键词 electrical capacitance Tomography ANSYS Lab VIEW Embedded System AC Signal
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Flame Imaging in Meso-scale Porous Media Burner Using Electrical Capacitance Tomography 被引量:5
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作者 陈琪 刘石 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第2期329-336,共8页
This study was conducted to investigate the characteristics of meso-scale combustion.The technique of electrical capacitance tomography(ECT) was used to locate flame position and monitor the effect corresponding to va... This study was conducted to investigate the characteristics of meso-scale combustion.The technique of electrical capacitance tomography(ECT) was used to locate flame position and monitor the effect corresponding to varied air/fuel ratio in a meso-scale combustor.Combustion phenomena including igniting,quenching and unsteady combustion have been visualized using ECT.The method of metallization protecting ECT sensor from high temperature damage and the novel calibration method adapted to ECT monitoring of unknown permittivity flame have been shown to be successful.At the same time,electrical nature of combustion and dielectric characteristics of hy-drocarbon flame were studied.The relationship between flame permittivity and state parameters of combustion gas was demonstrated preliminarily. 展开更多
关键词 electr:ical capacitance tomography meso-scale burner COMBUSTION flame permittivity
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Image Reconstruction Using a Genetic Algorithm for Electrical Capacitance Tomography 被引量:5
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作者 牟昌华 彭黎辉 +1 位作者 姚丹亚 萧德云 《Tsinghua Science and Technology》 SCIE EI CAS 2005年第5期587-592,共6页
Electrical capacitance tomography (ECT) has been used for more than a decade for imaging dielectric processes. However, because of its ill-posedness and non-linearity, ECT image reconstruction has always been a chal... Electrical capacitance tomography (ECT) has been used for more than a decade for imaging dielectric processes. However, because of its ill-posedness and non-linearity, ECT image reconstruction has always been a challenge. A new genetic algorithm (GA) developed for ECT image reconstruction uses initial results from a linear back-projection, which is widely used for ECT image reconstruction to optimize the threshold and the maximum and minimum gray values for the image. The procedure avoids optimizing the gray values pixel by pixel and significantly reduces the search space dimension. Both simulations and static experimental results show that the method is efficient and capable of reconstructing high quality images. Evaluation criteria show that the GA-based method has smaller image error and greater correlation coefficients. In addition, the GA-based method converges quickly with a small number of iterations. 展开更多
关键词 electrical capacitance tomography image reconstruction genetic algorithm
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Electrical Capacitance Tomography Measurement of Flow Patterns and Film Thickness in a Thermosyphon 被引量:4
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作者 JingtaoLI QiCHEN +1 位作者 XiangyuanDONG ShiLIU 《Journal of Thermal Science》 SCIE EI CAS CSCD 2005年第1期81-86,共6页
An experimental study was performed to evaluate the suitability of using an electrical capacitance tomography (ECT) system to visualize the flow patterns, and to measure the film thickness of the annular flow in a two... An experimental study was performed to evaluate the suitability of using an electrical capacitance tomography (ECT) system to visualize the flow patterns, and to measure the film thickness of the annular flow in a two-phase closed thermosyphon (TPCT). The performance of the ECT system was examined over a range of flow conditions.The experimental data were compared with the visual observations and existing correlations. Results indicated that the ECT system, with the linear back projection (LBP) algorithm, could be used to give an on-line qualitative image of the flow patterns. The Landweber iteration algorithm with optimal step length was implemented off-line to reconstruct high-resolution images. Then, the images were analyzed to obtain the film thickness of the annular flow. The experimental data compared well with the Nusselt's equation in low vapor velocity range, but showed an increasing deficiency with the increase of vapor velocity. 展开更多
关键词 THERMOSYPHON electrical capacitance tomography film thickness flow pattern.
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Investigation of gas-solids flow hydrodynamics in a cold model of a dual fluidised bed gasifier using electrical capacitance tomography sensors 被引量:4
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作者 Zhan Luo Yonglei Lin +2 位作者 Qiuya Tu Wuqiang Yang Haigang Wang 《Particuology》 SCIE EI CAS CSCD 2020年第4期193-204,共12页
The flow characteristics of a dual fluidised bed gasifier(DFBG)are more complex than those of a single fluidised bed gasifier.For stable operation and appropriate control,a cold DFBG test facility with both an upper a... The flow characteristics of a dual fluidised bed gasifier(DFBG)are more complex than those of a single fluidised bed gasifier.For stable operation and appropriate control,a cold DFBG test facility with both an upper and a lower U-valve was built,and electrical capacitance tomography(ECT)sensors were installed with pressure transducers to investigate the effects of operating conditions on gas-solids flow hydrodynamics.The operating parameters included gas velocities in the riser and in the bubbling fluidised bed,aeration velocity in the lower U-valve,bed material inventory,and particle size.This is the first time that ECT was applied in different flow zones of a dual fluidised bed gasifier system.The experimental results indicated that ECT in the recycle chamber could monitor the performance of the lower U-valve under different operating conditions for early detection of gas shortcut from the riser to the bubbling bed.Three main flow regimes in the riser and the differences between the reactors were identified by two sets of ECT sensors with pressure transducers.Finally,the effects of the operating conditions on the pressure drop in different parts of the DFBG was investigated. 展开更多
关键词 Dual fluidised bed gasifier HYDRODYNAMICS electrical capacitance tomography Flow regime identification
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Measurement of Ice Movement in Water Using Electrical Capacitance Tomography 被引量:2
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作者 JIANG Fan LIU Shi +1 位作者 LIU Jing WANG Xueyao 《Journal of Thermal Science》 SCIE EI CAS CSCD 2009年第1期8-12,共5页
The permafrost with the highest altitude and largest area in the mid and low latitude is located in the Qinghad-Tibet Plateau. As most frozen soils contain ice particles which are very sensitive to temperature and oth... The permafrost with the highest altitude and largest area in the mid and low latitude is located in the Qinghad-Tibet Plateau. As most frozen soils contain ice particles which are very sensitive to temperature and other external parameters, thus influencing the stability of the embankment in permafrost regions, it is very important to develop techniques to prevent damages to railway embankments due to thaw settlement. In this paper, the electrical capacitance sensors are designed to study the freezing front movement in a vessel and ice movement in water, which is the first step to apply the ECT system to the study of frozen soil. Two sensor arrangements are put into use. First, the traditional closed electrode sensors are put into use. In this arrangement, the electrodes are attached to the outside of the pipe or vessel, and the cross-sectional distribution of ice and water could be reconstructed from the capacitances measured. Also, the ice moving track at the cross section could be reflected thoroughly.Since the traditional closed electrode sensors can not meet the needs of measuring the ice freezing front move- ment, a new electrode sensors structure, that is, the unclosed electrode sensors are designed to satisfy the specific test of frozen soil. In this arrangement, several pairs of electrodes are arranged along the height of the vessel. A sudden decrease in the measured capacitance is observed when the freezing front advances past the electrodes.Therefore, according to the capacitance variation, the ice movement can be reflected. In summary, electrical capacitance tomography has the advantages of being non-intrusive. With different electrode sensor arrangement, ice movement and ice freezing front can be obtained. The electrical capacitance sensor system can be applied to investigate the complicated phenomena in frozen soil. 展开更多
关键词 electrical capacitance Tomography Ice-Water Interface Two-Phase Flows Frozen Soil
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An Advanced Algorithm of Electrical Capacitance Tomography
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作者 Yan Jie Guo Hongxing Bao Zongti 《Wuhan University Journal of Natural Sciences》 CAS 1999年第1期79-83,共5页
We describe a new two phase flow electrical capacitance tomography algorithm of image reconstruction which is based on 12 electrode capacitance transducers. According to the result of computer simulation, this algor... We describe a new two phase flow electrical capacitance tomography algorithm of image reconstruction which is based on 12 electrode capacitance transducers. According to the result of computer simulation, this algorithm is able to greatly increase the imaging fidelity without decreasing the imaging velocity. 展开更多
关键词 electrical capacitance tomography sensitivity distribution FEM
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Electrical Capacitance and Resistance Assessing Tree Vigor
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作者 QU Zhiwei WANG Xiangfeng LIANG Jun 《Chinese Forestry Science and Technology》 2005年第4期37-42,共6页
The paper summarizes the research progresses of electrical capacitance and electrical resistance assessing tree vigor and points out the development direction of the study. Researches show that electrical capacitance ... The paper summarizes the research progresses of electrical capacitance and electrical resistance assessing tree vigor and points out the development direction of the study. Researches show that electrical capacitance is related to the indexes of periodic growth rate of trees, foliar biomass and diameter of breast height, while electrical resistance has inverse relationships with the above indexes. Eiectrical capacitance and electrical resistance change when trees suffer environmental stress, insect pests or diseases. Especially, changes of electrical resistance are observed before symptom expression of some tree diseases, which can help to establish a certain disease potential hazard rating system. Mechanisms of electrical capacitance and resistance assessing tree vigor, especially in molecule level, still need to be studied and the application criteria of electrical resistance and capacitance need to be established. 展开更多
关键词 electrical resistance electrical capacitance tree vigor
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Structure-guided Capacitance Relationships in Oxidized Graphene Porous Materials Based Supercapacitors
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作者 Srinivas Gadipelli Hanieh Akbari +4 位作者 Juntao Li Christopher A.Howard Hong Zhang Paul R.Shearing Dan J.L.Brett 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第4期58-69,共12页
Supercapacitors formed from porous carbon and graphene-oxide(GO)materials are usually dominated by either electric double-layer capacitance,pseudo-capacitance,or both.Due to these combined features,reduced GO material... Supercapacitors formed from porous carbon and graphene-oxide(GO)materials are usually dominated by either electric double-layer capacitance,pseudo-capacitance,or both.Due to these combined features,reduced GO materials have been shown to offer superior capacitance over typical nanoporous carbon materials;however,there is a significant variation in reported values,ranging between 25 and 350 F g^(−1).This undermines the structure(e.g.,oxygen functionality and/or surface area)-performance relationships for optimization of cost and scalable factors.This work demonstrates important structure-controlled charge storage relationships.For this,a series of exfoliated graphene(EG)derivatives are produced via thermal-shock exfoliation of GO precursors and following controlled graphitization of EG(GEG)generates materials with varied amounts of porosity,redox-active oxygen groups and graphitic components.Experimental results show significantly varied capacitance values between 30 and 250 F g^(−1)at 1.0 A g^(−1)in GEG structures;this suggests that for a given specific surface area the redox-active and hydrophilic oxygen content can boost the capacitance to 250–300%higher compared to typical mesoporous carbon materials.GEGs with identical oxygen functionality show a surface area governed capacitance.This allows to establish direct structure-performance relationships between 1)redox-active oxygen functional concentration and capacitance and 2)surface area and capacitance. 展开更多
关键词 electric double-layer capacitance graphene-oxide PSEUDOcapacitance structure-performance relationships SUPERCAPACITORS
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Influence of polyethylene glycol on pore structure and electric double-layer capacitance of carbon xerogel
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作者 侯朝辉 李新海 +2 位作者 何则强 刘恩辉 邓凌峰 《Journal of Central South University of Technology》 2004年第3期255-260,共6页
Mesoporous polyethylene glycol-resorcinol and formaldehyde(PEG-RF) carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable p... Mesoporous polyethylene glycol-resorcinol and formaldehyde(PEG-RF) carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m(PEG)/m(RF) and the (relative) molecular mass of PEG on the pore structure and electric double layer capacitance(EDLC) performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach (755 m2/g) and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels. 展开更多
关键词 polymer blend method polyethylene glycol carbon xerogel electric double-layer capacitance
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