Since the launch of the economic reform and opening to the outside world, China has seen rapid growth in its export of mechanical and electrical products, with its export
A new deposition method is described using micro electrical discharge machining (EDM) to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition (EDD) are...A new deposition method is described using micro electrical discharge machining (EDM) to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition (EDD) are analyzed and the realized conditions are predicted. With an ordinary EDM shaping machine, brass as the electrode, high-speed steel as the workpiece, a lot of experiments are carried out on micro EDD systematically and thoroughly. The effects of major processing parameters, such as the discharge current, discharge duration, pulse interval and working medium, are obtained, As a result, a micro cylinder with 0.19 mm in diameter and 7.35 mm in height is deposited. By exchanging the polarities of the electrode and workpiece the micro cylinder can be removed selectively. So the reversible machining of deposition and removal is achieved, which breaks through the constraint of traditional EDM. Measurements show that the deposited material is compact and close to workpiece base, whose components depend on the tool electrode, material.展开更多
Electric Pulse Processing(EPP)treatment was innovatively introduced to optimize the strength and ductility of the CSAMed Cu deposits.The results show that EPP is an efficient and fast post-treatment to improve the str...Electric Pulse Processing(EPP)treatment was innovatively introduced to optimize the strength and ductility of the CSAMed Cu deposits.The results show that EPP is an efficient and fast post-treatment to improve the strength and ductility(within tens of seconds).The larger the pulse current and number of pulses,the better the mechanical properties.Interestingly,this research found that when the heat input determined by pulse current and number of pulses exceeds a certain threshold(pulse current intensity is 2000 A,number of pulses is 10),increasing the number of repeat time could also effectively improve the mechanical properties.A tensile strength of 210 MPa and a ductility of 14.0%could be obtained with reasonable EPP parameters(pulse current intensity is 2000 A,number of pulses is 10,and repeat number is 2),which is similar to those of conventional annealing(e.g.,tensile strength is 272 MPa,elongation is 28.3%).The microstructure evolution analysis shows that EPP can effectively improve the bonding quality between the deposited particles by recrystallization,promote grain growth and the formation of twins,which is the main reason for the improvement of mechanical properties.展开更多
A novel hydrothermal process was developed to extract zinc from pure zinc ferrite(ZnFe2O4) nanopowder and zinc-containing electric arc furnace(EAF) dust using hexahydrated ferric chloride(FeCl3-6H2O) as a decomp...A novel hydrothermal process was developed to extract zinc from pure zinc ferrite(ZnFe2O4) nanopowder and zinc-containing electric arc furnace(EAF) dust using hexahydrated ferric chloride(FeCl3-6H2O) as a decomposing agent.The effects of solid FeCl3-6H2O to ZnFe2O4 ratio by mass(RF/Z),hydrothermal reaction temperature,and time on zinc extraction were systematically investigated.In the results,when the hydrothermal reaction is conducted at 150℃ for 2 h with RF/Z of 15:20,the efficiency of zinc extraction from ZnFe2O4 reaches97.2%,and the concentration of ferric ions(Fe^3+) in the leaching solution is nearly zero,indicating a high selectivity for zinc.In addition,the zinc extraction efficiency from the EAF dust reaches 94.5%in the case of the hydrothermal reaction performed at 200℃ for 10 h with the solid FeCl3-6H2O to EAF dust ratio by mass(RF/EAF dust) of 15:10.Zinc and iron separation is achieved by adjusting the pH value of the leaching solution according to the different precipitation pH values of metal hydroxides.展开更多
Ce-substituted lithium ferrite, Li0.5CexFe2.5-x04 (x = 0, 0.05 and 0.1 ) compositions were synthesized from metal nitrates and citric acid by the solution combustion process by keeping the oxidizer to fuel ratio at ...Ce-substituted lithium ferrite, Li0.5CexFe2.5-x04 (x = 0, 0.05 and 0.1 ) compositions were synthesized from metal nitrates and citric acid by the solution combustion process by keeping the oxidizer to fuel ratio at unity. The thermal decomposition process was investigated by thermogravimetry-differential thermal analysis, which showed a stable phase formation above 600 ℃. The phase composition and molecular bonding of Li0.5CexFe2.5_x04 were characterized by X-ray powder diffraction analysis and Fourier transform infrared spectroscopy, respectively. An extensive study of electrical relaxation process has been represented with impedance and modulus as a function of frequency at different temperatures. The activation energy obtained from both the formalisms was found to be equal within the error. The dc conductivity and hopping frequency were thermally activated and their activation energies were found to be in the range of 0.69-0.64 eV for x = 0.05. The scaling of modulus and impedance were used to understand the electrical relaxation behaviour of the compositions and they suggest the time temperature superposition principle.展开更多
The effect of solar wind(SW) on the North Atlantic sea surface temperature(SST) in boreal winter is examined through an analysis of observational data during 1964-2013.The North Atlantic SSTs show a pronounced mer...The effect of solar wind(SW) on the North Atlantic sea surface temperature(SST) in boreal winter is examined through an analysis of observational data during 1964-2013.The North Atlantic SSTs show a pronounced meridional tripolar pattern in response to solar wind speed(SWS) variations.This pattern is broadly similar to the leading empirical orthogonal function(EOF) mode of interannual variations in the wintertime SSTs over North Atlantic.The time series of this leading EOF mode of SST shows a significant interannual period,which is the same as that of wintertime SWS.This response also appears as a compact north-south seesaw of sea level pressure and a vertical tripolar structure of zonal wind,which simultaneously resembles the North Atlantic Oscillation(NAO) in the overlying atmosphere.As compared with the typical low SWS winters,during the typical high SWS winters,the stratospheric polar night jet(PNJ) is evidently enhanced and extends from the stratosphere to the troposphere,even down to the North Atlantic Ocean surface.Notably,the North Atlantic Ocean is an exclusive region in which the SW signal spreads downward from the stratosphere to the troposphere.Thus,it seems that the SW is a possible factor for this North Atlantic SST tripolar mode.The dynamical process of stratosphere-troposphere coupling,together with the global atmospheric electric circuit-cloud microphysical process,probably accounts for the particular downward propagation of the SW signal.展开更多
文摘Since the launch of the economic reform and opening to the outside world, China has seen rapid growth in its export of mechanical and electrical products, with its export
基金This project is supported by National Natural Science Foundation of China (No.50275038).
文摘A new deposition method is described using micro electrical discharge machining (EDM) to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition (EDD) are analyzed and the realized conditions are predicted. With an ordinary EDM shaping machine, brass as the electrode, high-speed steel as the workpiece, a lot of experiments are carried out on micro EDD systematically and thoroughly. The effects of major processing parameters, such as the discharge current, discharge duration, pulse interval and working medium, are obtained, As a result, a micro cylinder with 0.19 mm in diameter and 7.35 mm in height is deposited. By exchanging the polarities of the electrode and workpiece the micro cylinder can be removed selectively. So the reversible machining of deposition and removal is achieved, which breaks through the constraint of traditional EDM. Measurements show that the deposited material is compact and close to workpiece base, whose components depend on the tool electrode, material.
基金This work was supported by the National Natural Science Foundation of China(Nos.52061135101,52071265)the Project of the State Key Laboratory of Solidification Processing(Northwestern Polytechnical University,China)(No.2021-TZ-01).
文摘Electric Pulse Processing(EPP)treatment was innovatively introduced to optimize the strength and ductility of the CSAMed Cu deposits.The results show that EPP is an efficient and fast post-treatment to improve the strength and ductility(within tens of seconds).The larger the pulse current and number of pulses,the better the mechanical properties.Interestingly,this research found that when the heat input determined by pulse current and number of pulses exceeds a certain threshold(pulse current intensity is 2000 A,number of pulses is 10),increasing the number of repeat time could also effectively improve the mechanical properties.A tensile strength of 210 MPa and a ductility of 14.0%could be obtained with reasonable EPP parameters(pulse current intensity is 2000 A,number of pulses is 10,and repeat number is 2),which is similar to those of conventional annealing(e.g.,tensile strength is 272 MPa,elongation is 28.3%).The microstructure evolution analysis shows that EPP can effectively improve the bonding quality between the deposited particles by recrystallization,promote grain growth and the formation of twins,which is the main reason for the improvement of mechanical properties.
基金supported by the National Basic Research Priorities Program of China (Nos. 2014CB643401 and 2013AA032003)the National Natural Science Foundation of China (No.51372019)
文摘A novel hydrothermal process was developed to extract zinc from pure zinc ferrite(ZnFe2O4) nanopowder and zinc-containing electric arc furnace(EAF) dust using hexahydrated ferric chloride(FeCl3-6H2O) as a decomposing agent.The effects of solid FeCl3-6H2O to ZnFe2O4 ratio by mass(RF/Z),hydrothermal reaction temperature,and time on zinc extraction were systematically investigated.In the results,when the hydrothermal reaction is conducted at 150℃ for 2 h with RF/Z of 15:20,the efficiency of zinc extraction from ZnFe2O4 reaches97.2%,and the concentration of ferric ions(Fe^3+) in the leaching solution is nearly zero,indicating a high selectivity for zinc.In addition,the zinc extraction efficiency from the EAF dust reaches 94.5%in the case of the hydrothermal reaction performed at 200℃ for 10 h with the solid FeCl3-6H2O to EAF dust ratio by mass(RF/EAF dust) of 15:10.Zinc and iron separation is achieved by adjusting the pH value of the leaching solution according to the different precipitation pH values of metal hydroxides.
基金Financial support from the UGC-SAP F.530/15/DRS/2009
文摘Ce-substituted lithium ferrite, Li0.5CexFe2.5-x04 (x = 0, 0.05 and 0.1 ) compositions were synthesized from metal nitrates and citric acid by the solution combustion process by keeping the oxidizer to fuel ratio at unity. The thermal decomposition process was investigated by thermogravimetry-differential thermal analysis, which showed a stable phase formation above 600 ℃. The phase composition and molecular bonding of Li0.5CexFe2.5_x04 were characterized by X-ray powder diffraction analysis and Fourier transform infrared spectroscopy, respectively. An extensive study of electrical relaxation process has been represented with impedance and modulus as a function of frequency at different temperatures. The activation energy obtained from both the formalisms was found to be equal within the error. The dc conductivity and hopping frequency were thermally activated and their activation energies were found to be in the range of 0.69-0.64 eV for x = 0.05. The scaling of modulus and impedance were used to understand the electrical relaxation behaviour of the compositions and they suggest the time temperature superposition principle.
基金Supported by the National(Key)Basic Research and Development(973)Program of China(2012CB957804)National Natural Science Foundation of China(41490642 and 41375069)
文摘The effect of solar wind(SW) on the North Atlantic sea surface temperature(SST) in boreal winter is examined through an analysis of observational data during 1964-2013.The North Atlantic SSTs show a pronounced meridional tripolar pattern in response to solar wind speed(SWS) variations.This pattern is broadly similar to the leading empirical orthogonal function(EOF) mode of interannual variations in the wintertime SSTs over North Atlantic.The time series of this leading EOF mode of SST shows a significant interannual period,which is the same as that of wintertime SWS.This response also appears as a compact north-south seesaw of sea level pressure and a vertical tripolar structure of zonal wind,which simultaneously resembles the North Atlantic Oscillation(NAO) in the overlying atmosphere.As compared with the typical low SWS winters,during the typical high SWS winters,the stratospheric polar night jet(PNJ) is evidently enhanced and extends from the stratosphere to the troposphere,even down to the North Atlantic Ocean surface.Notably,the North Atlantic Ocean is an exclusive region in which the SW signal spreads downward from the stratosphere to the troposphere.Thus,it seems that the SW is a possible factor for this North Atlantic SST tripolar mode.The dynamical process of stratosphere-troposphere coupling,together with the global atmospheric electric circuit-cloud microphysical process,probably accounts for the particular downward propagation of the SW signal.