Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions,Mn^(4+)ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices...Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions,Mn^(4+)ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode(W-LED),plant cultivation LED,and temperature thermometer.Up to now,Mn^(4+)has been widely introduced into the lattices of various inorganic hosts for brightly redemitting phosphors.However,how to correlate the structure-activity relationship between host framework,luminescence property,and photoelectric device is urgently demanded.In this review,we thoroughly summarize the recent advances of Mn^(4+)doped phosphors.Meanwhile,several strategies like co-doping and defect passivation for improving Mn^(4+)emission are also discussed.Most importantly,the relationship between the protocols for tailoring the structures of Mn^(4+)doped phosphors,increased luminescence performance,and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated.Finally,the challenges and perspectives of Mn^(4+)doped phosphors for practical applications are anticipated.We cordially anticipate that this review can deliver a deep comprehension of not only Mn^(4+)luminescence mechanism but also the crystal structure tailoring strategy of phosphors,so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.展开更多
Aqueous battery-supercapacitor hybrid devices(BSHs)are of great importance to enrich electrochemical energy storage systems with both high energy and power densities.However,further improvement of BSHs in aqueous elec...Aqueous battery-supercapacitor hybrid devices(BSHs)are of great importance to enrich electrochemical energy storage systems with both high energy and power densities.However,further improvement of BSHs in aqueous electrolytes is greatly hampered by operating voltage and capacity limits.Different from the conventional intercalation/de-intercalation mechanism,Bi_(2)O_(3) implements charge storage by a reversible phase conversion mechanism.Herein,taking Bi_(2)O_(3) electrode with wide potential window(from-1.2 to 1 V vs.saturated calomel electrode)and high capacity as battery-type anode,we propose that the overall performance of aqueous BSHs can be greatly upgraded under neutral condition.By paring with stable layer-structuredδ-MnO_(2) cathode,a sodium-ion Bi_(2)O_(3)//MnO_(2) BSH with an ultrahigh voltage of 2.4 V in neutral sodium sulfate electrolyte is developed for the first time.This hybrid device exhibits high capacity(~215 C g^(-1) at 1 mA cm^(-2)),relatively long lifespan(~77.2%capacity retention after 1500 cycles),remarkable energy density(71.7 Wh kg^(-1)@400.5 W kg^(-1))and power density(3204.3 W kg^(-1)@18.8 Wh kg^(-1)).Electrochemical measurements combining a set of spectroscopic techniques reveal the reversible phase conversion between bismuth oxide and metallic bismuth(Bi_(2)O_(3)?Bi0)through Bi^(2+) transition phase in neutral sodium sulfate solution,which can deliver multielectron transfer up to 6,leading to the high-energy BSHs.Our work sheds light on the feasibility of using Bi_(2)O_(3) electrode under neutral condition to address the issue of narrow voltage and low capacity for aqueous BSHs.展开更多
Using carbon felt,polytetrafluoroethylene latex and powder catalyst to assembly a light energy conversion device,the photocatalytic activity of catalyst 2.0%WO3-TiO2(2%WO3 compounding TiO2) with oxygen vacancies was s...Using carbon felt,polytetrafluoroethylene latex and powder catalyst to assembly a light energy conversion device,the photocatalytic activity of catalyst 2.0%WO3-TiO2(2%WO3 compounding TiO2) with oxygen vacancies was studied through the water splitting for O2 evolution,using a high pressure mercury lamp as the light source and Fe 3+ as the electron acceptor in two different devices:an ordinary photolysis device with catalyst powder suspending through a magnetic stirrer and a self-assembly light energy conversion device.The results show that after 12 h irradiation,the photocatalytic activity of 2.0%WO3-TiO2 with oxygen vacancies in the self-assembly light energy conversion device is higher than that of the ordinary photolysis device,and the amount of oxygen evolution is about 12 and 9 mmol/L respectively in these two devices.After 12 h,the rates of O2 evolution are slow in each device and the photocatalyst almost loses the photoactivity in the ordinary photolysis device.So,compared with the ordinary photocatalytic device,the rate of oxygen evolution and the life time of the catalyst are improved in the self-assembly light energy conversion device.展开更多
Advanced electromagnetic devices,as the pillars of the intelligent age,are setting off a grand transformation,redefining the structure of society to present pluralism and diversity.However,the bombardment of electroma...Advanced electromagnetic devices,as the pillars of the intelligent age,are setting off a grand transformation,redefining the structure of society to present pluralism and diversity.However,the bombardment of electromagnetic radiation on society is also increasingly serious along with the growing popularity of"Big Data".Herein,drawing wisdom and inspiration from nature,an eco-mimetic nanoarchitecture is constructed for the first time,highly integrating the advantages of multiple components and structures to exhibit excellent electromagnetic response.Its electromagnetic properties and internal energy conversion can be flexibly regulated by tailoring microstructure with oxidative molecular layer deposition(oMLD),providing a new cognition to frequency-selective microwave absorption.The optimal reflection loss reaches≈−58 dB,and the absorption frequency can be shifted from high frequency to low frequency by increasing the number of oMLD cycles.Meanwhile,a novel electromagnetic absorption surface is designed to enable ultra-wideband absorption,covering almost the entire K and Ka bands.More importantly,an ingenious self-powered device is constructed using the eco-mimetic nanoarchitecture,which can convert electromagnetic radiation into electric energy for recycling.This work offers a new insight into electromagnetic protection and waste energy recycling,presenting a broad application prospect in radar stealth,information communication,aerospace engineering,etc.展开更多
Graphene and related two-dimensional materials have attracted great research interests due to prominently optical and electrical properties and flexibility in integration with versatile photonic structures.Here,we rep...Graphene and related two-dimensional materials have attracted great research interests due to prominently optical and electrical properties and flexibility in integration with versatile photonic structures.Here,we report an in-fiber photoelec-tric device by wrapping a few-layer graphene and bonding a pair of electrodes onto a tilted fiber Bragg grating(TFBG)for photoelectric and electric-induced thermo-optic conversions.The transmitted spectrum from this device consists of a dense comb of narrowband resonances that provides an observable window to sense the photocurrent and the electrical injection in the graphene layer.The device has a wavelength-sensitive photoresponse with responsivity up to 11.4 A/W,allowing the spectrum analysis by real-time monitoring of photocurrent evolution.Based on the thermal-optic effect of electrical injection,the graphene layer is energized to produce a global red-shift of the transmission spectrum of the TF-BG,with a high sensitivity approaching 2.167×10^(4)nm/A^(2).The in-fiber photoelectric device,therefore as a powerful tool,could be widely available as off-the-shelf product for photodetection,spectrometer and current sensor.展开更多
In this work,we design a twisting metamaterial for longitudinal-torsional(L-T)mode conversion in pipes through exploring the theory of perfect transmodal FabryPerot interference(TFPI).Assuming that the axial and radia...In this work,we design a twisting metamaterial for longitudinal-torsional(L-T)mode conversion in pipes through exploring the theory of perfect transmodal FabryPerot interference(TFPI).Assuming that the axial and radial motions in pipes can be decoupled,we find that the metamaterial can be designed in a rectangular coordinate system,which is much more convenient than that in a cylindrical system.Numerical calculation with detailed microstructures shows that an efficient L-T mode conversion can be obtained in pipes with different radii.In addition,we fabricate mode-converting microstructures on an aluminum pipe and conduct ultrasonic experiments,and the results are in good agreement with the numerical calculations.We expect that the proposed LT mode-converting metamaterial and its design methodology can be applied in various ultrasonic devices.展开更多
An oscillating buoy wave power device (OD) is a device extracting wave power by an oscillating buoy. Being excited by waves, the buoy heaves up and down to convert wave energy into electricity by means of a mechanical...An oscillating buoy wave power device (OD) is a device extracting wave power by an oscillating buoy. Being excited by waves, the buoy heaves up and down to convert wave energy into electricity by means of a mechanical or hydraulic device. Compared with an Oscillating Water Column (OWC) wave power device, the OD has the same capture width ratio as the OWC does, but much higher secondary conversion efficiency. Moreover, the chamber of the OWC, which is the most expensive and difficult part to be built, is not necessary for the OD, so it is easier to construct an OD. In this paper, a numerical calculation is conducted for an optimal design of the OD firstly, then a model of the device is built and, a model test is carried out in a wave tank. The results show that the total efficiency of the OD is much higher than that of the OWC and that the OD is a promising wave power device.展开更多
The emerging of commercial high-voltage gallium nitride(GaN) power devices provides extraordinary switching performance over silicone devices, which enables high-voltage power conversion switching at megahertz range.S...The emerging of commercial high-voltage gallium nitride(GaN) power devices provides extraordinary switching performance over silicone devices, which enables high-voltage power conversion switching at megahertz range.Such outstanding features also pose strong challenges for device packaging design since the package parasitics can significantly influence the device switching characteristics, and thus can shadow the advantages brought by GaN devices. Designers have been dealing with these challenges brought by high du/dt and high-frequency switching operation even since the silicon(Si) era when fast switching Si MOSFET is first developed and came up with lots of inspiring advanced power module packaging structures to mitigate the problems.This paper presents a review of advanced power module packaging and integration structures that are suitable for high frequency power conversion.The review covers the heritage from the high frequency Si MOSFET packaging to the state-of-the-art for GaN devices.展开更多
Inspired by recent discoveries of the quasi-Josephson effect in shunted nanowire devices,we propose a superconducting nanowire interference device in this study,which is a combination of parallel ultrathin superconduc...Inspired by recent discoveries of the quasi-Josephson effect in shunted nanowire devices,we propose a superconducting nanowire interference device in this study,which is a combination of parallel ultrathin superconducting nanowires and a shunt resistor.A simple model based on the switching effect of nanowires and fluxoid quantization effect is developed to describe the behavior of the device.The current-voltage characteristic and flux-to-voltage conversion curves are simulated and discussed to verify the feasibility.Appropriate parameters of the shunt resistor and inductor are deduced for fabricating the devices.展开更多
After a criticism on today’s model for electrical noise in resistors, we pass to use a Quantum-compliant model based on the discreteness of electrical charge in a complex Admittance. From this new model we show that ...After a criticism on today’s model for electrical noise in resistors, we pass to use a Quantum-compliant model based on the discreteness of electrical charge in a complex Admittance. From this new model we show that carrier drift viewed as charged particle motion in response to an electric field is unlike to occur in bulk regions of Solid-State devices where carriers react as dipoles against this field. The absence of the shot noise that charges drifting in resistors should produce and the evolution of the Phase Noise with the active power existing in the resonators of L-C oscillators, are two effects added in proof for this conduction model without carrier drift where the resistance of any two-terminal device becomes discrete and has a minimum value per carrier that is the Quantum Hall resistance Rk=h/q2展开更多
The cascadability of uniform fibre Bragg grating for 40 Gbit/s return to zero on-off keying to non-return to zero on-off keying format conversion has been shown using OptSim simulation program. The main idea of this a...The cascadability of uniform fibre Bragg grating for 40 Gbit/s return to zero on-off keying to non-return to zero on-off keying format conversion has been shown using OptSim simulation program. The main idea of this approach is use of specially designed uniform fibre Bragg grating with appropriate transfer function for shaping of 40 Gbit/s return to zero on-off keying optical spectrum. Error free performance is achieved after four cascades of uniform fibre Bragg grating with different reflectivity values.展开更多
基金financially supported by the National Natural Science Foundation of China(52072101,51972088,U20A20122 and U1663225)the Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52)of the Chinese Ministry of Education+2 种基金the Program of Introducing Talents of Discipline to Universities-Plan 111(Grant No.B20002)from the Ministry of Science and Technology and the Ministry of Education of ChinaHubei Provincial Department of Education for the“Chutian Scholar”programsupported by the European Commission Interreg V FranceWallonie-Vlaanderen project“Depollut Air”。
文摘Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions,Mn^(4+)ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode(W-LED),plant cultivation LED,and temperature thermometer.Up to now,Mn^(4+)has been widely introduced into the lattices of various inorganic hosts for brightly redemitting phosphors.However,how to correlate the structure-activity relationship between host framework,luminescence property,and photoelectric device is urgently demanded.In this review,we thoroughly summarize the recent advances of Mn^(4+)doped phosphors.Meanwhile,several strategies like co-doping and defect passivation for improving Mn^(4+)emission are also discussed.Most importantly,the relationship between the protocols for tailoring the structures of Mn^(4+)doped phosphors,increased luminescence performance,and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated.Finally,the challenges and perspectives of Mn^(4+)doped phosphors for practical applications are anticipated.We cordially anticipate that this review can deliver a deep comprehension of not only Mn^(4+)luminescence mechanism but also the crystal structure tailoring strategy of phosphors,so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.
基金supported by the National Natural Science Foundation of China (21872105, 22072107)the Science & Technology Commission of Shanghai Municipality (19DZ2271500)。
文摘Aqueous battery-supercapacitor hybrid devices(BSHs)are of great importance to enrich electrochemical energy storage systems with both high energy and power densities.However,further improvement of BSHs in aqueous electrolytes is greatly hampered by operating voltage and capacity limits.Different from the conventional intercalation/de-intercalation mechanism,Bi_(2)O_(3) implements charge storage by a reversible phase conversion mechanism.Herein,taking Bi_(2)O_(3) electrode with wide potential window(from-1.2 to 1 V vs.saturated calomel electrode)and high capacity as battery-type anode,we propose that the overall performance of aqueous BSHs can be greatly upgraded under neutral condition.By paring with stable layer-structuredδ-MnO_(2) cathode,a sodium-ion Bi_(2)O_(3)//MnO_(2) BSH with an ultrahigh voltage of 2.4 V in neutral sodium sulfate electrolyte is developed for the first time.This hybrid device exhibits high capacity(~215 C g^(-1) at 1 mA cm^(-2)),relatively long lifespan(~77.2%capacity retention after 1500 cycles),remarkable energy density(71.7 Wh kg^(-1)@400.5 W kg^(-1))and power density(3204.3 W kg^(-1)@18.8 Wh kg^(-1)).Electrochemical measurements combining a set of spectroscopic techniques reveal the reversible phase conversion between bismuth oxide and metallic bismuth(Bi_(2)O_(3)?Bi0)through Bi^(2+) transition phase in neutral sodium sulfate solution,which can deliver multielectron transfer up to 6,leading to the high-energy BSHs.Our work sheds light on the feasibility of using Bi_(2)O_(3) electrode under neutral condition to address the issue of narrow voltage and low capacity for aqueous BSHs.
基金Project(2010CL04) supported by the Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, ChinaProject(K-081025) supported by State Key Laboratory Breeding Base of Photocatalysis,Fuzhou University,China
文摘Using carbon felt,polytetrafluoroethylene latex and powder catalyst to assembly a light energy conversion device,the photocatalytic activity of catalyst 2.0%WO3-TiO2(2%WO3 compounding TiO2) with oxygen vacancies was studied through the water splitting for O2 evolution,using a high pressure mercury lamp as the light source and Fe 3+ as the electron acceptor in two different devices:an ordinary photolysis device with catalyst powder suspending through a magnetic stirrer and a self-assembly light energy conversion device.The results show that after 12 h irradiation,the photocatalytic activity of 2.0%WO3-TiO2 with oxygen vacancies in the self-assembly light energy conversion device is higher than that of the ordinary photolysis device,and the amount of oxygen evolution is about 12 and 9 mmol/L respectively in these two devices.After 12 h,the rates of O2 evolution are slow in each device and the photocatalyst almost loses the photoactivity in the ordinary photolysis device.So,compared with the ordinary photocatalytic device,the rate of oxygen evolution and the life time of the catalyst are improved in the self-assembly light energy conversion device.
基金supported by National Natural Science Foundation of China(No.52177014,52273257,51977009,11774027,51372282,and 51132002).
文摘Advanced electromagnetic devices,as the pillars of the intelligent age,are setting off a grand transformation,redefining the structure of society to present pluralism and diversity.However,the bombardment of electromagnetic radiation on society is also increasingly serious along with the growing popularity of"Big Data".Herein,drawing wisdom and inspiration from nature,an eco-mimetic nanoarchitecture is constructed for the first time,highly integrating the advantages of multiple components and structures to exhibit excellent electromagnetic response.Its electromagnetic properties and internal energy conversion can be flexibly regulated by tailoring microstructure with oxidative molecular layer deposition(oMLD),providing a new cognition to frequency-selective microwave absorption.The optimal reflection loss reaches≈−58 dB,and the absorption frequency can be shifted from high frequency to low frequency by increasing the number of oMLD cycles.Meanwhile,a novel electromagnetic absorption surface is designed to enable ultra-wideband absorption,covering almost the entire K and Ka bands.More importantly,an ingenious self-powered device is constructed using the eco-mimetic nanoarchitecture,which can convert electromagnetic radiation into electric energy for recycling.This work offers a new insight into electromagnetic protection and waste energy recycling,presenting a broad application prospect in radar stealth,information communication,aerospace engineering,etc.
基金We are grateful for financial supports from National Natural Science Foundation of China(Grant No.61975166)Key Research and Development Program(Grant No.2022YFA1404800).
文摘Graphene and related two-dimensional materials have attracted great research interests due to prominently optical and electrical properties and flexibility in integration with versatile photonic structures.Here,we report an in-fiber photoelec-tric device by wrapping a few-layer graphene and bonding a pair of electrodes onto a tilted fiber Bragg grating(TFBG)for photoelectric and electric-induced thermo-optic conversions.The transmitted spectrum from this device consists of a dense comb of narrowband resonances that provides an observable window to sense the photocurrent and the electrical injection in the graphene layer.The device has a wavelength-sensitive photoresponse with responsivity up to 11.4 A/W,allowing the spectrum analysis by real-time monitoring of photocurrent evolution.Based on the thermal-optic effect of electrical injection,the graphene layer is energized to produce a global red-shift of the transmission spectrum of the TF-BG,with a high sensitivity approaching 2.167×10^(4)nm/A^(2).The in-fiber photoelectric device,therefore as a powerful tool,could be widely available as off-the-shelf product for photodetection,spectrometer and current sensor.
基金Project supported by the National Natural Science Foundation of China(Nos.U2033208,52192633)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2021JQ-006)+1 种基金the China Postdoctoral Science Foundation(No.2020TQ0241)the Innovative Scientific Program of China Nuclear Power Engineering Co.,Ltd。
文摘In this work,we design a twisting metamaterial for longitudinal-torsional(L-T)mode conversion in pipes through exploring the theory of perfect transmodal FabryPerot interference(TFPI).Assuming that the axial and radial motions in pipes can be decoupled,we find that the metamaterial can be designed in a rectangular coordinate system,which is much more convenient than that in a cylindrical system.Numerical calculation with detailed microstructures shows that an efficient L-T mode conversion can be obtained in pipes with different radii.In addition,we fabricate mode-converting microstructures on an aluminum pipe and conduct ultrasonic experiments,and the results are in good agreement with the numerical calculations.We expect that the proposed LT mode-converting metamaterial and its design methodology can be applied in various ultrasonic devices.
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.59979025),the High Tech Research and Development(863)Program(Grant No.2001AA516010)and the Science&Technology Program of Guangdong(C32004)
文摘An oscillating buoy wave power device (OD) is a device extracting wave power by an oscillating buoy. Being excited by waves, the buoy heaves up and down to convert wave energy into electricity by means of a mechanical or hydraulic device. Compared with an Oscillating Water Column (OWC) wave power device, the OD has the same capture width ratio as the OWC does, but much higher secondary conversion efficiency. Moreover, the chamber of the OWC, which is the most expensive and difficult part to be built, is not necessary for the OD, so it is easier to construct an OD. In this paper, a numerical calculation is conducted for an optimal design of the OD firstly, then a model of the device is built and, a model test is carried out in a wave tank. The results show that the total efficiency of the OD is much higher than that of the OWC and that the OD is a promising wave power device.
文摘The emerging of commercial high-voltage gallium nitride(GaN) power devices provides extraordinary switching performance over silicone devices, which enables high-voltage power conversion switching at megahertz range.Such outstanding features also pose strong challenges for device packaging design since the package parasitics can significantly influence the device switching characteristics, and thus can shadow the advantages brought by GaN devices. Designers have been dealing with these challenges brought by high du/dt and high-frequency switching operation even since the silicon(Si) era when fast switching Si MOSFET is first developed and came up with lots of inspiring advanced power module packaging structures to mitigate the problems.This paper presents a review of advanced power module packaging and integration structures that are suitable for high frequency power conversion.The review covers the heritage from the high frequency Si MOSFET packaging to the state-of-the-art for GaN devices.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0304000)the National Natural Science Foundation of China(Grant Nos.61671438 and 61827823)+1 种基金the Science and Technology Commission of Shanghai Municipality,China(Grant No.18511110200)the Program of Shanghai Academic/Technology Research Leader,China(Grant No.18XD1404600).
文摘Inspired by recent discoveries of the quasi-Josephson effect in shunted nanowire devices,we propose a superconducting nanowire interference device in this study,which is a combination of parallel ultrathin superconducting nanowires and a shunt resistor.A simple model based on the switching effect of nanowires and fluxoid quantization effect is developed to describe the behavior of the device.The current-voltage characteristic and flux-to-voltage conversion curves are simulated and discussed to verify the feasibility.Appropriate parameters of the shunt resistor and inductor are deduced for fabricating the devices.
文摘After a criticism on today’s model for electrical noise in resistors, we pass to use a Quantum-compliant model based on the discreteness of electrical charge in a complex Admittance. From this new model we show that carrier drift viewed as charged particle motion in response to an electric field is unlike to occur in bulk regions of Solid-State devices where carriers react as dipoles against this field. The absence of the shot noise that charges drifting in resistors should produce and the evolution of the Phase Noise with the active power existing in the resonators of L-C oscillators, are two effects added in proof for this conduction model without carrier drift where the resistance of any two-terminal device becomes discrete and has a minimum value per carrier that is the Quantum Hall resistance Rk=h/q2
文摘The cascadability of uniform fibre Bragg grating for 40 Gbit/s return to zero on-off keying to non-return to zero on-off keying format conversion has been shown using OptSim simulation program. The main idea of this approach is use of specially designed uniform fibre Bragg grating with appropriate transfer function for shaping of 40 Gbit/s return to zero on-off keying optical spectrum. Error free performance is achieved after four cascades of uniform fibre Bragg grating with different reflectivity values.