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Efficient Electromagnetic Wave Absorption and Thermal Infrared Stealth in PVTMS@MWCNT Nano‑Aerogel via Abundant Nano‑Sized Cavities and Attenuation Interfaces
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作者 Haoyu Ma Maryam Fashandi +5 位作者 Zeineb Ben Rejeb Xin Ming Yingjun Liu Pengjian Gong Guangxian Li Chul B.Park 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期370-383,共14页
Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT... Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT aerogel structure shows nano-pore size(30-40 nm),high specific surface area(559 m^(2)g^(−1)),high void fraction(91.7%)and enhanced mechanical property:(1)the nano-pore size is beneficial for efficiently blocking thermal conduction and thermal convection via Knudsen effect(beneficial for infrared(IR)stealth);(2)the heterogeneous interface was beneficial for IR reflection(beneficial for IR stealth)and MWCNT polarization loss(beneficial for electromagnetic wave(EMW)attenuation);(3)the high void fraction was beneficial for enhancing thermal insulation(beneficial for IR stealth)and EMW impedance match(beneficial for EMW attenuation).Guided by the above theoretical design strategy,PVTMS@MWCNT nano-aerogel shows superior EMW absorption property(cover all Ku-band)and thermal IR stealth property(ΔT reached 60.7℃).Followed by a facial combination of the above nano-aerogel with graphene film of high electrical conductivity,an extremely high electromagnetic interference shielding material(66.5 dB,2.06 mm thickness)with superior absorption performance of an average absorption-to-reflection(A/R)coefficient ratio of 25.4 and a low reflection bandwidth of 4.1 GHz(A/R ratio more than 10)was experimentally obtained in this work. 展开更多
关键词 Nano-pore size Heterogeneous interface electromagnetic wave absorption Thermal infrared stealth Nano-aerogel
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Nitrogen‑Doped Magnetic‑Dielectric‑Carbon Aerogel for High‑Efficiency Electromagnetic Wave Absorption
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作者 Shijie Wang Xue Zhang +5 位作者 Shuyan Hao Jing Qiao Zhou Wang Lili Wu Jiurong Liu Fenglong Wang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期313-327,共15页
Carbonbased aerogels derived from biomass chitosan are encountering a flourishing moment in electromagnetic protection on account of lightweight,controllable fabrication and versatility.Nevertheless,developing a facil... Carbonbased aerogels derived from biomass chitosan are encountering a flourishing moment in electromagnetic protection on account of lightweight,controllable fabrication and versatility.Nevertheless,developing a facile construction method of component design with carbon-based aerogels for high-efficiency electromagnetic wave absorption(EWA)materials with a broad effective absorption bandwidth(EAB)and strong absorption yet hits some snags.Herein,the nitrogen-doped magnetic-dielectric-carbon aerogel was obtained via ice template method followed by carbonization treatment,homogeneous and abundant nickel(Ni)and manganese oxide(MnO)particles in situ grew on the carbon aerogels.Thanks to the optimization of impedance matching of dielectric/magnetic components to carbon aerogels,the nitrogen-doped magnetic-dielectric-carbon aerogel(Ni/MnO-CA)suggests a praiseworthy EWA performance,with an ultra-wide EAB of 7.36 GHz and a minimum reflection loss(RLmin)of−64.09 dB,while achieving a specific reflection loss of−253.32 dB mm−1.Furthermore,the aerogel reveals excellent radar stealth,infrared stealth,and thermal management capabilities.Hence,the high-performance,easy fabricated and multifunctional nickel/manganese oxide/carbon aerogels have broad application aspects for electromagnetic protection,electronic devices and aerospace. 展开更多
关键词 electromagnetic wave absorption Wide bandwidth Dielectric-magnetic synergy MULTIFUNCTION
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Tracking Regulatory Mechanism of Trace Fe on Graphene Electromagnetic Wave Absorption
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作者 Kaili Zhang Yuhao Liu +5 位作者 Yanan Liu Yuefeng Yan Guansheng Ma Bo Zhong Renchao Che Xiaoxiao Huang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期79-96,共18页
Polarization and conductance losses are the fundamental dielectric attenuation mechanisms for graphene-based absorbers, but it is not fully understood in revealing the loss mechanism of affect graphene itself. For the... Polarization and conductance losses are the fundamental dielectric attenuation mechanisms for graphene-based absorbers, but it is not fully understood in revealing the loss mechanism of affect graphene itself. For the first time, the reduced graphene oxide(RGO) based absorbers are developed with regulatory absorption properties and the absorption mechanism of RGO is mainly originated from the carrier injection behavior of trace metal Fe nanosheets on graphene. Accordingly, the minimum reflection loss(RLmin) of Fe/RGO-2composite reaches-53.38 dB(2.45 mm), and the effective absorption bandwidth achieves 7.52 GHz(2.62 mm) with lower filling loading of 2 wt%. Using off-axis electron hologram testing combined with simulation calculation and carrier transport property experiments, we demonstrate here the carrier injection behavior from Fe to graphene at the interface and the induced charge accumulation and rearrangement, resulting in the increased interfacial and dipole polarization and the conductance loss. This work has confirmed that regulating the dielectric property of graphene itself by adding trace metals can not only ensure good impedance matching, but also fully exploit the dielectric loss ability of graphene at low filler content,which opens up an efficient way for designing lightweight absorbers and may be extended to other types materials. 展开更多
关键词 Reduced graphene oxide Fe nanosheets Dielectric loss electromagnetic wave absorption
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From VIB‑to VB‑Group Transition Metal Disulfides:Structure Engineering Modulation for Superior Electromagnetic Wave Absorption
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作者 Junye Cheng Yongheng Jin +10 位作者 Jinghan Zhao Qi Jing Bailong Gu Jialiang Wei Shenghui Yi Mingming Li Wanli Nie Qinghua Qin Deqing Zhang Guangping Zheng Renchao Che 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期218-257,共40页
The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various field... The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance. 展开更多
关键词 Transition metal disulfides electromagnetic wave absorption Impedance matching Structure engineering modulation
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Design principles in MOF-derived electromagnetic wave absorption materials:Review and perspective 被引量:3
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作者 Zhenguo Gao Kai Yang +4 位作者 Zehao Zhao Di Lan Qian Zhou Jiaoqiang Zhang Hongjing Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第3期405-427,共23页
At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielec... At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielectric and magnetic attenuations.However,the basic design principles in MOF-derived microwave absorption materials have not been summarized.This review is devoted to analyzing design principles in MOF-derived microwave absorption materials from the following perspectives:diverse monomers(ligands and ions of MOFs),topologies,chemical states,and physical properties.The derived essential information regarding the EM wave absorption mechanism and the structural-functional dependency is also comprehensively summarized.Finally,a clear insight into the challenges and perspectives of the industrial revolution upgrading in this promising field is proposed. 展开更多
关键词 metal-organic frameworks TOPOLOGIES chemical states physical properties electromagnetic wave absorption
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Hollow Gradient-Structured Iron-Anchored Carbon Nanospheres for Enhanced Electromagnetic Wave Absorption 被引量:2
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作者 Cao Wu Jing Wang +14 位作者 Xiaohang Zhang Lixing Kang Xun Cao Yongyi Zhang Yutao Niu Yingying Yu Huili Fu Zongjie Shen Kunjie Wu Zhenzhong Yong Jingyun Zou Bin Wang Zhou Chen Zhengpeng Yang Qingwen Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期144-160,共17页
In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which c... In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications. 展开更多
关键词 Gradient structures Carbon nanospheres electromagnetic wave absorption Impedance matching
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Composites of In/C hexagonal nanorods and graphene nanosheets for high-performance electromagnetic wave absorption
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作者 Rao Zhang Congpu Mu +4 位作者 Bochong Wang Jianyong Xiang Kun Zhai Tianyu Xue Fusheng Wen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第3期485-493,共9页
In recent years,electromagnetic wave(EMW)absorption has been extensively investigated for solving EMW radiation and pollution.The metal-organic frameworks(MOFs)have attracted attention due to their low density and uni... In recent years,electromagnetic wave(EMW)absorption has been extensively investigated for solving EMW radiation and pollution.The metal-organic frameworks(MOFs)have attracted attention due to their low density and unique structure,which can meet the requirements of strong reflection loss(RL)and wide absorption bandwidth of EMW absorption materials.In this manuscript,indium nanoparticles/porous carbon(In/C)nanorods composites were prepared via the pyrolysis of nanorods-like In-MOFs at a low temperature of450°C.Indium nanoparticles are evenly attached and embedded on porous carbon.Low electrical conductivity of In/C nanorods is unfavorable to EMW absorption performance,which is due to the low temperature carbonization.Thus,graphene(Gr)nanosheets with high electrical conductivity are introduced to adjust electromagnetic parameters of In/C nanorods for enhancing EMW absorption.The minimum RL of the In/C-Gr-4 composite is up to-43.7 dB with a thin thickness of 1.30 mm.In addition,when the thickness is further reduced to 1.14 mm,the minimum RL of-39.3 dB at 16.1 GHz and effective absorption bandwidth of 3.7 GHz(from 14.3 to 18.0 GHz)can be achieved.This work indicates that In/C-Gr composites show excellent EMW absorption performance. 展开更多
关键词 electromagnetic wave absorption metal-organic frameworks indium nanoparticles nanorod graphene PERMITTIVITY
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Flexible and Waterproof 2D/1D/0D Construction of MXene-Based Nanocomposites for Electromagnetic Wave Absorption,EMI Shielding,and Photothermal Conversion 被引量:10
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作者 Zhen Xiang Yuyang Shi +2 位作者 Xiaojie Zhu Lei Cai Wei Lu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第10期77-97,共21页
High-performance electromagnetic wave absorption and electromagnetic interference(EMI)shielding materials with multifunctional characters have attracted extensive scientific and technological interest,but they remain ... High-performance electromagnetic wave absorption and electromagnetic interference(EMI)shielding materials with multifunctional characters have attracted extensive scientific and technological interest,but they remain a huge challenge.Here,we reported an electrostatic assembly approach for fabricating 2D/1D/0D construction of Ti_(3)C_(2)Tx/carbon nanotubes/Co nanoparticles(Ti_(3)C_(2)Tx/CNTs/Co)nanocomposites with an excellent electromagnetic wave absorption,EMI shielding efficiency,flexibility,hydrophobicity,and photother-mal conversion performance.As expected,a strong reflection loss of-85.8 dB and an ultrathin thickness of 1.4 mm were achieved.Mean-while,the high EMI shielding efficiency reached 110.1 dB.The excel-lent electromagnetic wave absorption and shielding performances were originated from the charge carriers,electric/magnetic dipole polariza-tion,interfacial polarization,natural resonance,and multiple internal reflections.Moreover,a thin layer of polydimethylsiloxane rendered the hydrophilic hierarchical Ti_(3)C_(2)Tx/CNTs/Co hydrophobic,which can prevent the degradation/oxidation of the MXene in high humidity condition.Interestingly,the Ti_(3)C_(2)Tx/CNTs/Co film exhibited a remark-able photothermal conversion performance with high thermal cycle stability and tenability.Thus,the multifunctional Ti_(3)C_(2)Tx/CNTs/Co nanocomposites possessing a unique blend of outstanding electromagnetic wave absorption and EMI shielding,light-driven heating perfor-mance,and flexible water-resistant features were highly promising for the next-generation intelligent electromagnetic attenuation system. 展开更多
关键词 Ti_(3)C_(2)Tx CNTS Co Low-dimensional materials electromagnetic wave absorption EMI shielding MULTIFUNCTION
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Non‑Magnetic Bimetallic MOF‑Derived Porous Carbon‑Wrapped TiO2/ ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption 被引量:8
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作者 Jing Qiao Xue Zhang +7 位作者 Chang Liu Longfei Lyu Yunfei Yang Zhou Wang Lili Wu Wei Liu Fenglong Wang Jiurong Liu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第5期45-60,共16页
Modern communication technologies put forward higher requirements for electromagnetic wave(EMW)absorption materials.Metal-organic framework(MOF)derivatives have been widely concerned with its diverse advantages.To bre... Modern communication technologies put forward higher requirements for electromagnetic wave(EMW)absorption materials.Metal-organic framework(MOF)derivatives have been widely concerned with its diverse advantages.To break the mindset of magneticderivative design,and make up the shortage of monometallic non-magnetic derivatives,we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption.The porous carbon-wrapped TiO2/ZrTiO4 composites derived from PCN-415(TiZr-MOFs)are qualified with a minimum reflection loss of−67.8 dB(2.16 mm,13.0 GHz),and a maximum effective absorption bandwidth of 5.9 GHz(2.70 mm).Through in-depth discussions,the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed.Therefore,this work confirms the huge potentials of nonmagnetic bimetallic MOFs derivatives in EMW absorption applications. 展开更多
关键词 Bimetallic metal-organic framework PCN-415 MOF derivatives TiO2/ZrTiO4/C composites electromagnetic wave absorption
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One-Dimensional Magnetic FeCoNi Alloy Toward Low-Frequency Electromagnetic Wave Absorption 被引量:5
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作者 Bintong Yang Jiefeng Fang +7 位作者 Chunyang Xu Hui Cao Ruixuan Zhang Biao Zhao Mengqiu Huang Xiangyu Wang Hualiang Lv Renchao Che 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第10期260-272,共13页
Rational designing of one-dimensional(1D)magnetic alloy to facilitate electromagnetic(EM)wave attenuation capability in low-frequency(2-6 GHz)microwave absorption field is highly desired but remains a significant chal... Rational designing of one-dimensional(1D)magnetic alloy to facilitate electromagnetic(EM)wave attenuation capability in low-frequency(2-6 GHz)microwave absorption field is highly desired but remains a significant challenge.In this study,a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method.The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique,indicating the excellent magnetic loss ability under an external EM field.Then,the in-depth analysis shows that many factors,including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy,primarily contribute to the enhanced EM wave absorption performance.Therefore,the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm.Thus,this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers. 展开更多
关键词 Medium-entropy magnetic alloy ONE-DIMENSION Off-axis electronic holography technique Improved electrospinning Lower-frequency electromagnetic wave absorption
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Multifunctional SiC@SiO_(2) Nanofiber Aerogel with Ultrabroadband Electromagnetic Wave Absorption 被引量:5
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作者 Limeng Song Fan Zhang +7 位作者 Yongqiang Chen Li Guan Yanqiu Zhu Mao Chen Hailong Wang Budi Riza Putra Rui Zhang Bingbing Fan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第9期237-256,共20页
Traditional ceramic materials are generally brittle and not flexible with high production costs,which seriously hinders their practical applications.Multifunctional nanofiber ceramic aerogels are highly desirable for ... Traditional ceramic materials are generally brittle and not flexible with high production costs,which seriously hinders their practical applications.Multifunctional nanofiber ceramic aerogels are highly desirable for applications in extreme environments,however,the integration of multiple functions in their preparation is extremely challenging.To tackle these challenges,we fabricated a multifunctional SiC@SiO_(2) nanofiber aerogel(SiC@SiO_(2) NFA)with a threedimensional(3D)porous cross-linked structure through a simple chemical vapor deposition method and subsequent heat-treatment process.The as-prepared SiC@SiO_(2) NFA exhibits an ultralow density(~11 mg cm^(-3)),ultra-elastic,fatigue-resistant and refractory performance,high temperature thermal stability,thermal insulation properties,and significant strain-dependent piezoresistive sensing behavior.Furthermore,the SiC@SiO_(2) NFA shows a superior electromagnetic wave absorption performance with a minimum refection loss(RL_(min))value of-50.36 d B and a maximum effective absorption bandwidth(EAB_(max))of 8.6 GHz.The successful preparation of this multifunctional aerogel material provides a promising prospect for the design and fabrication of the cutting-edge ceramic materials. 展开更多
关键词 MULTIFUNCTIONAL SiC@SiO_(2)nanofiber aerogel Chemical vapor deposition electromagnetic wave absorption Ceramic materials
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Digital Light Processing 3D-Printed Ceramic Metamaterials for Electromagnetic Wave Absorption 被引量:4
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作者 Rui Zhou Yansong Wang +3 位作者 Ziyu Liu Yongqiang Pang Jianxin Chen Jie Kong 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第7期279-292,共14页
Combining 3D printing with precursor-derived ceramic for fabricating electromagnetic(EM) wave-absorbing metamaterials has attracted great attention. This study presents a novel ultraviolet-curable polysiloxane precurs... Combining 3D printing with precursor-derived ceramic for fabricating electromagnetic(EM) wave-absorbing metamaterials has attracted great attention. This study presents a novel ultraviolet-curable polysiloxane precursor for digital light processing(DLP) 3D printing to fabricate ceramic parts with complex geometry, no cracks and linear shrinkage. Guiding with the principles of impedance matching, attenuation, and effective-medium theory, we design a crosshelix-array metamaterial model based on the complex permittivity constant of precursor-derived ceramics. The corresponding ceramic metamaterials can be successfully prepared by DLP printing and subsequent pyrolysis process, achieving a low reflection coefficient and a wide effective absorption bandwidth in the X-band even under high temperature. This is a general method that can be extended to other bands, which can be realized by merely adjusting the unit structure of meta-materials. This strategy provides a novel and effective avenue to achieve “target-design-fabricating” ceramic metamaterials, and it exposes the downstream applications of highly efficient and broad EM wave-absorbing materials and structures with great potential applications. 展开更多
关键词 electromagnetic wave absorption METAMATERIAL Precursor-derived ceramics 3D printing
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Synthesis of carbon-coated cobalt ferrite core-shell structure composite:A method for enhancing electromagnetic wave absorption properties by adjusting impedance matching 被引量:1
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作者 Jing Gao Zhijun Ma +1 位作者 Fuli Liu Cunxin Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第7期206-217,共12页
Cobalt ferrite has problems such as poor impedance matching and high density,which results in unsatisfactory electromagnetic wave(EMW)absorption performance.In this study,the CoFe_(2)O_(4)@C core-shell structure compo... Cobalt ferrite has problems such as poor impedance matching and high density,which results in unsatisfactory electromagnetic wave(EMW)absorption performance.In this study,the CoFe_(2)O_(4)@C core-shell structure composite was synthesized by a two-step hydrothermal method.X-ray diffraction,transmission electron microscopy,Fourier transform infrared spectroscopy,thermogravimetric analysis,and vector network analysis et al.were used to test the structure and EMW absorption properties of CoFe_(2)O_(4)@C composite.The results show that the reflection loss(RL)of the CoFe_(2)O_(4)@C composite reaches the maximum value of25.66 dB at 13.92 GHz,and the effective absorbing band(EAB)is 4.59 GHz(11.20-15.79 GHz)when the carbon mass content is 6.01%.The RL and EAB of CoFe_(2)O_(4)@C composite are increased by 219.55%and 4.59 GHz respectively,and the density is decreased by 20.78%compared with the cobalt ferrite.Such enhanced EMW absorption properties of CoFe_(2)O_(4)@C composite are attributed to the attenuation caused by the strong natural resonance of the cobalt ferrite,moreover,the carbon coating layer adjusts the impedance matching of the composite,and the introduced dipole polarization and interface polarization can cause multiple Debye relaxation processes. 展开更多
关键词 Cobalt ferrite Core-shell structure composite electromagnetic wave absorption Impedance matching
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Metal–phenolic coordination crystals derived magnetic hollow carbon spheres for ultrahigh electromagnetic wave absorption
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作者 Hanxiao Xu Zizhuang He +2 位作者 Yiruo Wang Xiangru Ren Panbo Liu 《Nano Research》 SCIE EI CSCD 2024年第3期1616-1624,共9页
Owing to the tunable compositions and versatile functionality,the development of eco-friendly metal–phenolic coordination crystals derivatives is highly anticipated for electromagnetic wave absorption.In this study,t... Owing to the tunable compositions and versatile functionality,the development of eco-friendly metal–phenolic coordination crystals derivatives is highly anticipated for electromagnetic wave absorption.In this study,three kinds of magnetic hollow carbon spheres(HCSs)with macro-meso-microporous characteristics,including Fe/HCS,Co/HCS,and CoNi/HCS,are successfully fabricated via the co-operative hard template and self-assembling process,in which magnetic particles are encapsulated in carbon shell matrix after the pyrolysis of metal–polyphenol coordination crystals and further subsequent template removal.On the one hand,hierarchical macro-meso-micropores effectively balance the impedance gap between absorbers and air and introduce structural defects or distortion,leading to matched impedance and enhanced dipolar/defect polarization.On the other hand,wrapped magnetic particles provide uncountable hetero-interfaces and induce ferromagnetic resonance,resulting in strengthened interfacial polarization and additional magnetic loss.In particular,enhanced minimum reflection loss(RL,min)and broadband effective absorption bandwidth(EAB)are achieved with only 10 wt.%filler loading.Specifically,the RL,min and EAB values are-57.5 dB and 7.2 GHz for Fe/HCS,-50.0 dB and 5.8 GHz for Co/HCS,and-52.1 dB and 6.7 GHz for CoNi/HCS,respectively.Moreover,this work provides us a modular-assembly strategy to regulate the hollow cavity of absorbers and simultaneously manipulates the chemical components of absorbers to regulate electromagnetic wave absorption performance. 展开更多
关键词 hollow engineering hierarchical pores hetero-interfaces synergetic effect electromagnetic wave absorption
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Synthetic strategy of biomimetic sea urchin-like Co-NC@PANI modified MXene-based magnetic aerogels with enhanced electromagnetic wave absorption properties
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作者 Meng Yu Ying Huang +6 位作者 Xudong Liu Kaihang She Xiaoxiao Zhao Wanqing Fan Xiaofang Ma Junhui Zou Tiehu Li 《Nano Research》 SCIE EI CSCD 2024年第3期2025-2037,共13页
The rational and effective combination of multicomponent materials and ingenious microstructure design for efficient electromagnetic wave(EMW)absorption are still challenging.In this paper,MXene was used as the aeroge... The rational and effective combination of multicomponent materials and ingenious microstructure design for efficient electromagnetic wave(EMW)absorption are still challenging.In this paper,MXene was used as the aerogel matrix,modified with sea urchin-like magnetic Co/N-doped carbon@polyaniline(Co-NC@PANI),gelatin was introduced as the reinforcement phase of the aerogel backbone,and a microwave absorber with high efficiency and excellent performance was successfully prepared.The sea urchin-like Co-NC@PANI not only adjusted the impedance matching of the MXene but also introduced a magnetic loss mode into the composite.The multicomponent interfacial polarization,heterostructure,three-dimensional(3D)lightweight porous structure,and electromagnetic synergy strategy enabled the MXene-based aerogel modified by Co-NC@PANI(MCoP)to exhibit surprising EMW absorption properties.The maximum reflection loss(RL_(max))of the aerogel composite reached-62.4 dB,and the effective absorption bandwidth(EAB)reached 6.56 GHz when the loading was only 12%.In addition,through electromagnetic simulation experiments,the change in the electromagnetic field before and after EMW passed through the materials and the distribution of the volume loss density of EMW by the coaxial ring were observed.The coordinated electromagnetic balance strategy in the 3D network provides inspiration for the construction of materials and expands the research direction of lightweight and outstanding microwave absorbers. 展开更多
关键词 MXene sea urchin-like Co/N-doped carbon@polyaniline(Co-NC@PANI) aerogel electromagnetic synergy strategy electromagnetic wave absorption
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Facile fabrication of graphene/g-C_(3)N_(4) for electromagnetic wave absorption
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作者 Qiang Su Yunfei He +4 位作者 Dongdong Liu Daguang Li Long Xia Xiaoxiao Huang Bo Zhong 《Nano Research》 SCIE EI CSCD 2024年第3期1687-1698,共12页
With the development of the miniaturization of electronic equipment and lightweight weapon equipment,there are new requirements for electromagnetic wave absorption material(EMWAM).EMWAM has outstanding electromagnetic... With the development of the miniaturization of electronic equipment and lightweight weapon equipment,there are new requirements for electromagnetic wave absorption material(EMWAM).EMWAM has outstanding electromagnetic wave absorption properties and lightweight characteristics become an important direction of research.In this study,graphene/g-C_(3)N_(4)(GGCN)EMWAM was first synthesized in situ by simple heat treatment,in which the g-C_(3)N_(4) had a porous structure and dispersed on the surface of graphene.The impedance matching of the GGCN was well adjusted by decreasing the dielectric constant and attenuation constant due to the g-C_(3)N_(4) semiconductor property and the graphite-like structure.The EMW loss mechanism of GGCN was also analyzed by simulating GGCN’s electric field mode distribution and resistance loss power density.The analysis result shows that the distribution of g-C_(3)N_(4) among GGCN sheets can produce more polarization effects and relaxation effects by increasing the lamellar spacing.Furthermore,the polarization loss of GGCN could be increased successfully by porous g-C_(3)N_(4).Ultimately,the EMW absorption property of GGCN is optimized significantly,and GGCN exhibits excellent EMW absorption performance.When the thickness is 2 mm,the effective absorption bandwidth(EAB)can reach 4.6 GHz,and when the thickness is 4.5 mm,the minimum reflection loss(RLmin)at 4.56 GHz can reach-34.69 dB.Moreover,the practical application of EMWAM was studied by radar cross-section(RCS)simulation,showing that GGCN has a good application prospect. 展开更多
关键词 graphene/g-C_(3)N_(4) impedance matching simulation analysis dielectric loss excellent electromagnetic wave absorption
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Magnetic NiFe_(2)O_(4)@FeNi_(3)core-shell nanospheres derived from FeNi-LDH precursor anchoring on rGO nanosheets for enhanced electromagnetic wave absorption
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作者 Kunyao Cao Yuan Fang +5 位作者 Shuai Wang Yue Zhang Jiayue Wen Jun Chen Rui Zhao Weidong Xue 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第4期101-114,共14页
Graphene has been extensively utilized in the domain of electromagnetic wave(EMW)absorption ma-terials because of its excellent electrical conductivity.However,the inferior impedance matching per-formance and the sing... Graphene has been extensively utilized in the domain of electromagnetic wave(EMW)absorption ma-terials because of its excellent electrical conductivity.However,the inferior impedance matching per-formance and the single loss mechanism vastly restrict the application.Hence,it’s an effective strat-egy to solve these issues by introducing magnetic components.Notably,layer double hydroxide(LDH)is an appropriate template to obtain magnetic component materials.Considering that ferromagnetic met-als such as Fe,Co,Ni,and their corresponding metal oxides are usually treated as magnetic compo-nents which are promising candidates for EMW absorption materials.Therefore,in this work,a FeNi-layered double hydroxide-reduced graphene oxide(FeNi-LDH-rGO)aerogel was synthesized through a series of processes such as electrostatic self-assembly,hydrothermal,freeze-drying,and annealing.The magnetic NiFe_(2)O_(4)@FeNi_(3)core-shell nanospheres were obtained from FeNi-LDH precursor,anchoring on rGO nanosheets after the annealing treatment.Furthermore,the effects of different mass ratios of LDH to GO as well as different annealing temperatures of LDH-rGO aerogel on the EMW absorption prop-erty and impedance matching performance were explored.As a consequence,the fabricated ultralight 600LDH-rGO 2:1 aerogel shows a broad effective absorption bandwidth(EAB)of 7.04 GHz at a thickness of 2.3 mm with a low filling content of only 6 wt%and a low density of 4.4 mg/cm^(3).In conclusion,the synthetic LDH-rGO aerogels offer an effective strategy for preparing EMW absorption materials that own three-dimensional porous network structure and unique magnetic NiFe_(2)O_(4)@FeNi_(3)core-shell struc-ture nanospheres. 展开更多
关键词 Electrostatic self-assembly electromagnetic wave absorption LDH-rGO aerogel Layered double hydroxide Reduced graphene oxide NiFe_(2)O_(4)@FeNi_(3)core-shell structure
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Flower-like CuS/γ-Fe_(2)O_(3) van der Waals heterostructures with highefficient electromagnetic wave absorption
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作者 Na Lu Jingshen Xu +1 位作者 Mengwei Yuan Genban Sun 《Nano Research》 SCIE EI CSCD 2024年第4期3324-3333,共10页
The escalating electromagnetic(EM)pollution issues and the demand to elevate military stealth technology make it imperative to develop cost-effective and high-performance electromagnetic wave(EMW)absorbing materials.I... The escalating electromagnetic(EM)pollution issues and the demand to elevate military stealth technology make it imperative to develop cost-effective and high-performance electromagnetic wave(EMW)absorbing materials.In this paper,the flower-like CuS/γ-Fe_(2)O_(3) van der Waals(vdW)heterostructures have been synthesized via a facile two-step solvothermal approach.The flower-like CuS skeleton increases the attenuation path of EMW while reducing the material density.Different contents ofγ-Fe_(2)O_(3) nanoparticles anchor between the flower-like CuS nanosheets to constitute a heterogeneous structure,which enables dielectric and magnetic loss synergistically to optimize impedance matching and remarkably improve the EMW absorption performance.The minimum reflection loss(RLmin)is-49.36 dB with a thickness of only 1.6 mm and the effective absorption bandwidth(EAB)reaches 4.64 GHz(13.36–18 GHz).By adjusting the thickness of the absorber,the EAB can cover 96%of the GHz band.Notably,the superior absorption of-61.53 dB at middle frequency band can be obtained by adjusting the amount of Fe_(2)O_(3) addition.In this study,the adjustment of EM parameters and the optimization of impedance matching have been achieved by constructing a novel vdW heterogeneous structure,which provides fresh ideas and references for the design of high-performance EMW absorbing materials. 展开更多
关键词 flower-like CuS γ-Fe_(2)O_(3) van der Waals heterostructures impedance matching electromagnetic wave absorption
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Absorption properties and mechanism of lightweight and broadband electromagnetic wave-absorbing porous carbon by the swelling treatment
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作者 Jianghao Wen Di Lan +4 位作者 Yiqun Wang Lianggui Ren Ailing Feng Zirui Jia Guanglei Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1701-1712,共12页
Bioderived carbon materials have garnered considerable interest in the fields of microwave absorption and shielding due to their reproducibility and environmental friendliness.In this study,KOH was evenly distributed ... Bioderived carbon materials have garnered considerable interest in the fields of microwave absorption and shielding due to their reproducibility and environmental friendliness.In this study,KOH was evenly distributed on biomass Tremella using the swelling induction method,leading to the preparation of a three-dimensional network-structured hierarchical porous carbon(HPC)through carbonization.The achieved microwave absorption intensity is robust at-47.34 dB with a thin thickness of 2.1 mm.Notably,the widest effective absorption bandwidth,reaching 7.0 GHz(11–18 GHz),is attained at a matching thickness of 2.2 mm.The exceptional broadband and reflection loss performance are attributed to the 3D porous networks,interface effects,carbon network defects,and dipole relaxation.HPC has outstanding absorption characteristics due to its excellent impedance matching and high attenuation constant.The uniform pore structures considerably optimize the impedance-matching performance of the material,while the abundance of interfaces and defects enhances the dielectric loss,thereby improving the attenuation constant.Furthermore,the impact of carbonization temperature and swelling rate on microwave absorption performance was systematically investigated.This research presents a strategy for preparing absorbing materials using biomass-derived HPC,showcasing considerable potential in the field of electromagnetic wave absorption. 展开更多
关键词 BIOMASS hierarchical porous carbon dielectric loss electromagnetic wave absorption
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Biomimetic leaf structures for ultra-thin electromagnetic wave absorption
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作者 Shikun Hou Ying Wang +6 位作者 Feng Gao Fei Jin Benfeng Zhu Qiong Wu Hongliang Ge Zhihai Cao Hua Yang 《Nano Research》 SCIE EI CSCD 2024年第5期4507-4516,共10页
Ultra-thin electromagnetic wave(EMW)absorbers present challenging demands on EMW absorption performance.Drawing inspiration from heather leaf structures,this study introduces an innovative design strategy for EMW abso... Ultra-thin electromagnetic wave(EMW)absorbers present challenging demands on EMW absorption performance.Drawing inspiration from heather leaf structures,this study introduces an innovative design strategy for EMW absorbing material,proposing biomimetic leaf SnO_(2) structures(bio-SnO_(2))on carbon fabric(CF).By employing leaf-shaped SnS2 as precursors,biomimetic leaf SnO_(2) nanostructures are constructed on CF surface after a simple thermal treatment,resulting in bio-SnO_(2)@CF composite.Experimental results indicate that bio-SnO_(2)@CF exhibits an exceptional minimum reflection loss of-54.8 dB at an incredibly thin thickness of 1.2 mm.Radar cross section(RCS)simulations further validate the outstanding EMW attenuation ability of bio-SnO_(2)@CF,attaining a maximum RCS reduction value of 16.9 dBm^(2) at an incident wave angle ofθ=0°.This novel research showcases the biomimetic structural design strategy and its remarkable function in enhancing the EMW absorbing performance at ultra-thin absorber thickness. 展开更多
关键词 biomimetic leaf structures electromagnetic wave absorption ultra-thin thickness
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