Epitaxial BaTiO3 films with embedded metallic Ni nanocrystal （Ni-BaTiO3） were successfully fabricated on SrTiO3 （001） single-crystalline substrate through the laser molecular beam epitaxial （L-MBE） technique.Hig...Epitaxial BaTiO3 films with embedded metallic Ni nanocrystal （Ni-BaTiO3） were successfully fabricated on SrTiO3 （001） single-crystalline substrate through the laser molecular beam epitaxial （L-MBE） technique.High resolution transmission electron microscopy （HRTEM） and electron energy loss spectrum （EELS） with Kramers-Kronig analysis methods were employed to characterize the microstructures,elementary distribution and the electron structure of these films.HRTEM results suggested that the structure of BaTiO3 was tetragonal with lattice parameters of a=0.399 nm and c=0.403 nm.Energy dispersive X-Ray spectroscopy （EDX） confirmed metallic Ni nanocrystal embedded successfully in BaTiO3 epitaxial films.The Ni-BaTiO3 composite films were compound of the epitaxial BaTiO3 （110） layers alternating with Ni NCs array （111） layers.Furthermore,the existence of the misfit dislocations induced by the embedding of Ni nanoparticles was also clearly demonstrated by the HRTEM images.The Ni L2,3 edges of EELS revealed that Ni NCs in their metallic state were embedded uniformly in the BaTiO3 matrix.A chemical shift of about 7 eV regarding L3 edges in the Ni EELS was also observed.The optical band gap of BaTiO3 in these films was about 3.84 eV,higher than 3.55 eV for pure BaTiO3 films at room temperature.展开更多
This paper determined the lethal concentration （LC） and hemi-inhibition concentration （HIC） of inorganic element Cu2+, Zn2+,Se4+,Cd2 to the unicellular alga Platymonas helgolandica var. tsingtaoensis （cell densit...This paper determined the lethal concentration （LC） and hemi-inhibition concentration （HIC） of inorganic element Cu2+, Zn2+,Se4+,Cd2 to the unicellular alga Platymonas helgolandica var. tsingtaoensis （cell density were 3.4× 10’cell/ ml ）, Phaeodaetylum iTnutum （cell density is 2. 7 × 106 cell/ml） Dicrateria zhan jiangensis Hu （cell density were 5. 6 × 106 cell/ml）, Paviova luther（cell density is 2. 7 × 106 cell/ml）. The culture condition: temperature was 25±2℃, pH 7. 9± 0. 1, salinity 31±1.0,natural sunlight for 5 days. The different species unicellular alga with different absorbability to these inorganic elements were analyzed by Scanning Electron Microscopy X-ray Energy Spectrum. This is the international cooperation program with Department of Biology, University of San Francisco, USA.展开更多
基金Funded by National High Technology Research and Development Program of China (863 Program)
文摘Epitaxial BaTiO3 films with embedded metallic Ni nanocrystal （Ni-BaTiO3） were successfully fabricated on SrTiO3 （001） single-crystalline substrate through the laser molecular beam epitaxial （L-MBE） technique.High resolution transmission electron microscopy （HRTEM） and electron energy loss spectrum （EELS） with Kramers-Kronig analysis methods were employed to characterize the microstructures,elementary distribution and the electron structure of these films.HRTEM results suggested that the structure of BaTiO3 was tetragonal with lattice parameters of a=0.399 nm and c=0.403 nm.Energy dispersive X-Ray spectroscopy （EDX） confirmed metallic Ni nanocrystal embedded successfully in BaTiO3 epitaxial films.The Ni-BaTiO3 composite films were compound of the epitaxial BaTiO3 （110） layers alternating with Ni NCs array （111） layers.Furthermore,the existence of the misfit dislocations induced by the embedding of Ni nanoparticles was also clearly demonstrated by the HRTEM images.The Ni L2,3 edges of EELS revealed that Ni NCs in their metallic state were embedded uniformly in the BaTiO3 matrix.A chemical shift of about 7 eV regarding L3 edges in the Ni EELS was also observed.The optical band gap of BaTiO3 in these films was about 3.84 eV,higher than 3.55 eV for pure BaTiO3 films at room temperature.
文摘This paper determined the lethal concentration （LC） and hemi-inhibition concentration （HIC） of inorganic element Cu2+, Zn2+,Se4+,Cd2 to the unicellular alga Platymonas helgolandica var. tsingtaoensis （cell density were 3.4× 10’cell/ ml ）, Phaeodaetylum iTnutum （cell density is 2. 7 × 106 cell/ml） Dicrateria zhan jiangensis Hu （cell density were 5. 6 × 106 cell/ml）, Paviova luther（cell density is 2. 7 × 106 cell/ml）. The culture condition: temperature was 25±2℃, pH 7. 9± 0. 1, salinity 31±1.0,natural sunlight for 5 days. The different species unicellular alga with different absorbability to these inorganic elements were analyzed by Scanning Electron Microscopy X-ray Energy Spectrum. This is the international cooperation program with Department of Biology, University of San Francisco, USA.
