The electron g-factor relates the magnetic moment to the spin angular momentum. It was originally theoretically calculated to have a value of exactly 2. Experiments yielded a value of 2 plus a very small fraction, ref...The electron g-factor relates the magnetic moment to the spin angular momentum. It was originally theoretically calculated to have a value of exactly 2. Experiments yielded a value of 2 plus a very small fraction, referred to as the g-factor anomaly. This anomaly has been calculated theoretically as a power series of the fine structure constant. This document shows that the anomaly is the result of the electron charge thickness. If the thickness were to be zero, g = 2 exactly, and there would be no anomaly. As the thickness increases, the anomaly increases. An equation relating the g-factor and the surface charge thickness is presented. The thickness is calculated to be 0.23% of the electron radius. The cause of the anomaly is very clear, but why is the charge thickness greater than zero? Using the model of the interior structure of the electron previously proposed by the author, it is shown that the non-zero thickness, and thus the g-factor anomaly, are due to the proposed positive charge at the electron center and compressibility of the electron material. The author’s previous publication proposes a theory for splitting the electron into three equal charges when subjected to a strong external magnetic field. That theory is revised in this document, and the result is an error reduced to 0.4% in the polar angle where the splits occur and a reduced magnetic field required to cause the splits.展开更多
The novel linear, circular, hooped, and helical molecules based on oligo[8]thio- phene were theoretically studied for the applications of charge transfer devices. To investigate the influence of topology for oligo[8]t...The novel linear, circular, hooped, and helical molecules based on oligo[8]thio- phene were theoretically studied for the applications of charge transfer devices. To investigate the influence of topology for oligo[8]thiophene derivatives, the geometry structures, frontier molecular orbital (FMO) energies, charge transport properties, and stability property were predicted by density functional theory methods. The calculated results reported herein show that the oligo[8]thiophene derivative with linear structure has smaller energy gap, and fused oligo[8]thiophene derivative with circular structure has the smallest reorganization energy among the designed molecules. We have also studied the stability properties of the designed molecules, and oligo[8]thiophene derivatives are more stable tharJ the fused oligo[8]thiophene derivatives.展开更多
The modulation of electrical properties of MoS_2 has attracted extensive research interest because of its potential applications in electronic and optoelectronic devices.Herein,interfacial charge transfer induced elec...The modulation of electrical properties of MoS_2 has attracted extensive research interest because of its potential applications in electronic and optoelectronic devices.Herein,interfacial charge transfer induced electronic property tuning of MoS_2 are investigated by in situ ultraviolet photoelectron spectroscopy and x-ray photoelectron spectroscopy measurements.A downward band-bending of MoS_2-related electronic states along with the decreasing work function,which are induced by the electron transfer from Cs overlayers to MoS_2,is observed after the functionalization of MoS_2 with Cs,leading to n-type doping.Meanwhile,when MoS_2 is modified with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane(F_4-TCNQ),an upward band-bending of MoS_2-related electronic states along with the increasing work function is observed at the interfaces.This is attributed to the electron depletion within MoS_2 due to the strong electron withdrawing property of F_4-TCNQ,indicating p-type doping of MoS_2.Our findings reveal that surface transfer doping is an effective approach for electronic property tuning of MoS_2 and paves the way to optimize its performance in electronic and optoelectronic devices.展开更多
A model for the internal structure of the electron using classical physics equations has been previously published by the author. The model employs both positive and negative charges and positive and negative masses. ...A model for the internal structure of the electron using classical physics equations has been previously published by the author. The model employs both positive and negative charges and positive and negative masses. The internal attributes of the electron structure were calculated for both ring and spherical shapes. Further examination of the model reveals an instability for the ring shape. The spherical shape appears to be stable, but relies on tensile or compressive forces of the electron material for stability. The model is modified in this document to eliminate the dependency on material forces. Uniform stability is provided solely by balancing electrical and centrifugal forces. This stability is achieved by slightly elongating the sphere along the spin axis to create a prolate ellipsoid. The semi-major axis of the ellipsoid is the spin axis of the electron, and is calculated to be 1.20% longer than the semi-minor axis, which is the radius of the equator. Although the shape deviates slightly from a perfect sphere, the electric dipole moment is zero. In the author’s previously published document, the attributes of the internal components of the electron, such as charge and mass, were calculated and expressed as ratios to the classically measured values for the composite electron. It is interesting to note that all of these ratios are nearly the same as the inverse of the Fine Structure Constant, with differences of less than 15%. The electron model assumed that the outer surface charge was fixed and uniform. By allowing the charge to be mobile and the shape to have a particular ellipticity, it is shown that the calculated charge and mass ratios for the model can be exactly equal to the Fine Structure Constant and the Constant plus one. The electron radius predicted by the model is 15% greater than the Classical Electron Radius.展开更多
Our calculations are based on the modeling technique and simulation Ab-Initio that appeals to the Density Functional Theory (DFT) relying on the Full-Potential Linearized Augmented Plane Waves (FP-LAPW) method that re...Our calculations are based on the modeling technique and simulation Ab-Initio that appeals to the Density Functional Theory (DFT) relying on the Full-Potential Linearized Augmented Plane Waves (FP-LAPW) method that requires a calculation process using approximations such as Local Density (LDA) and Generalized Gradient (GGA) developed in the modelling software of nanostructures WIEN2k. The optimal structure of the binary semiconductor ZnSe crystallizing in the complex phase of Zinc Blende (B3) was determined by studying the variation of energy depending on the volume of the elementary cell. Then the electronic properties of the optimized state were analyzed such as the gap energy, the total density of states (TDOS), the partial density of states (PDOS) and the repartition of the electronic charge density. The obtained results were successful compared with other theoretical and experimental values reported in literature.展开更多
Using our recently published electron’s charge electromagnetic flux manifold fiber model of the electron, described by analytical method and numerical simulations, we show how the fine structure constant is embedded ...Using our recently published electron’s charge electromagnetic flux manifold fiber model of the electron, described by analytical method and numerical simulations, we show how the fine structure constant is embedded as a geometrical proportionality constant in three dimensional space of its charge manifold and how this dictates the first QED term one-loop contribution of its anomalous magnetic moment making for the first time a connection of its intrinsic characteristics with physical geometrical dimensions and therefore demonstrating that the physical electron charge cannot be dimensionless. We show that the fine structure constant (FSC) α, and anomalous magnetic moment α<sub>μ</sub> of the electron is related to the sphericity of its charge distribution which is not perfectly spherical and thus has a shape, and therefore its self-confined charge possesses measurable physical dimensions. We also explain why these are not yet able to be measured by past and current experiments and how possible we could succeed.展开更多
In previous publications, the author has proposed a model of the electron’s internal structure, wherein a positively-charged negative mass outer shell and a negatively-charged positive mass central core are proposed ...In previous publications, the author has proposed a model of the electron’s internal structure, wherein a positively-charged negative mass outer shell and a negatively-charged positive mass central core are proposed to resolve the electron’s charge and mass inconsistencies. That model is modified in this document by assuming the electron’s radius is exactly equal to the classical electron radius. The attributes of the internal components of the electron’s structure have been recalculated accordingly. The shape of the electron is also predicted, and found to be slightly aspherical on the order of an oblate ellipsoid. This shape is attributed to centrifugal force and compliant outer shell material. It is interesting to note that all of the electron’s attributes, both external and internal, with the exception of mass and angular moment, are functions of the fine structure constant a, and can be calculated from just three additional constants: electron mass, Planck’s constant, and speed of light. In particular, the ratios of the outer shell charge and mass to the electron charge and mass, respectively, are 3/2a. The ratios of the central core charge and mass to the electron charge and mass, respectively, are 1-(3/2a). Attributes of the electron are compared with those of the muon. Charge and spin angular momentum are the same, while mass, magnetic moment, and radius appear to be related by the fine structure constant. The mass of the electron outer shell is nearly equal to the mass of the muon. The muon internal structure can be modeled exactly the same as for the electron, with exactly the same attribute relationships.展开更多
The author’s earlier papers proposed a model of the electron’s internal structure comprised of both positive and negative masses and charges. Their relation to the fine structure constant a was calculated in the aut...The author’s earlier papers proposed a model of the electron’s internal structure comprised of both positive and negative masses and charges. Their relation to the fine structure constant a was calculated in the author’s previous paper. In this paper, more details of the model of the electron’s internal structure, in particular the thicknesses of its outer shell mass and charge, are calculated. Magnetostriction of the electron’s surface is generated by the electron’s spinning surface charge. It is calculated that this magnetostriction holds the electron together, counterbalancing the outward electrical and centrifugal forces. The results of these calculations enable the prediction that a sufficiently strong external magnetic field can split the electron into three equal pieces. The field strength would have to be on the order of at least 8% of the strength at the center of the electron. A model for the origin and creation of an electron from a gamma ray wave is proposed. Evidence is presented that, for certain transitions, mass might be quantized and that the quantum of mass would be 1/2a times the electron mass.展开更多
This work is devoted to the experimental determination of the electrostatic properties of the molecular 4-methyl-7-(salicylidene amino) coumarin(C17H13NC3) using high resolution x-ray diffraction data. The experim...This work is devoted to the experimental determination of the electrostatic properties of the molecular 4-methyl-7-(salicylidene amino) coumarin(C17H13NC3) using high resolution x-ray diffraction data. The experimental results are compared with those obtained theoretically from calculation type ab initio. The experimental investigation is carried out using the molecular electron charge density distribution based on the multipolar model of Hansen and Coppens. However the theoretical calculations are conducted by using the molecular orbital B3 LYP method and the Hartree-Fock(HF) approximation with the basis set 6-31G(d,p) implemented in the Gaussian program. In addition to the structural analysis,the thermal agitation is also analyzed in terms of rigid blocks to ensure a better precision of the results. Subsequently, the electrostatic atomic and molecular properties such as the net charges, the molecular dipolar moment to highlight the nature of charge transfer existing within the molecule studied are derived. Moreover, the obtained electrostatic potential enables the localization of the electropositive and the electronegative parts of the investigated molecule. The present work reports in detail the obtained electrostatic properties of this biologically important molecule.展开更多
Pseudo-spark switch(PSS) is one of the most widely used discharge switches for pulse power technology.It has many special characteristics such as reliability in a wide voltage range,small delay time,as well as small...Pseudo-spark switch(PSS) is one of the most widely used discharge switches for pulse power technology.It has many special characteristics such as reliability in a wide voltage range,small delay time,as well as small delay jitter.In this paper,the measuring method for the initial plasma of ZnO surface flashover triggering device of PSS is studied and the results of the measurement show that the electron emission charge is mainly influenced by trigger voltage,gas pressure and DC bias voltage.When the bias voltage increases from 2 kV to 6 kV with the gap distancc fixed at 3 mm,the electron emission charge changes from 2 μC to about 6μC.When the gap distance changes from 3 mm to 5 mm with the bias voltage fixed at 2 kV,the electron emission charge increases from 1.5 μC to 2.5μC.When the gap distance is 4 mm,the hold-off voltage of PSS is 45 kV at gas pressure of 2 Pa,the minimum operating voltage is less than 1 kV.So,the operating scope is from 2.22%to 99%of its self-breakdown voltage.The discharging delay time decreases from 450 ns to 150 ns when the trigger pulse voltage is 1 kV and the discharging voltage is changed from 1 kV to 12 kV.When the trigger pulse voltage is 6 kV,the discharging delay time is less than 100 ns and changes from 100 ns to 50 ns,and the delay jitters are less than30 ns.展开更多
Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method, followed by thermal annealing to form the Si nanocrystals(Si-NCs) embedded in Si Nx floating gate MOS structures. The c...Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method, followed by thermal annealing to form the Si nanocrystals(Si-NCs) embedded in Si Nx floating gate MOS structures. The capacitance–voltage(C–V), current–voltage(I–V), and admittance–voltage(G–V) measurements are used to investigate the charging characteristics. It is found that the maximum flat band voltage shift(△VFB) due to full charged holes(~ 6.2 V) is much larger than that due to full charged electrons(~ 1 V). The charging displacement current peaks of electrons and holes can be also observed by the I–V measurements, respectively. From the G–V measurements we find that the hole injection is influenced by the oxide hole traps which are located near the Si O2/Si-substrate interface. Combining the results of C–V and G–V measurements, we find that the hole charging of the Si-NCs occurs via a two-step tunneling mechanism. The evolution of G–V peak originated from oxide traps exhibits the process of hole injection into these defects and transferring to the Si-NCs.展开更多
A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminesce...A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminescent materials for organic light-emitting diodes(OLEDs). The frontier molecular orbitals(FMOs) analysis has turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer(ICT). The calculated results show that the optical and electronic properties of star-shaped molecules are affected by the substituent groups in N-position of 1,8-naphthalimide ring. Our results suggest that star-shaped molecules with n-butyl(1),benzene(2),thiophene(3),thiophene S?,S?-dioxide(4),benzo[c][1,2,5]thiadiazole(5),and 2,7a-dihydrobenzo[d]thiazole(6) fragments are expected to be promising candidates for luminescent and electron transport materials for OLEDs. This study should be helpful in further theoretical investigations on such kind of systems and also to the experimental study for charge transport and/or luminescent materials for OLEDs.展开更多
Previous models of the free electron using classical physics equations have predicted attributes that are inconsistent with the experimentally observed attributes. For example, the magnetic moment has been calculated ...Previous models of the free electron using classical physics equations have predicted attributes that are inconsistent with the experimentally observed attributes. For example, the magnetic moment has been calculated for the observed spinning electric charge. For the calculated moment to equal the observed moment, the electron would either have to spin at two hundred times the speed of light or have a charge radius two hundred times greater than the classical radius. A similar inconsistency results when the mass derived from the spin angular momentum is compared with the observed mass. A classical model is herein proposed which eliminates the magnetic moment inconsistency and also predicts the radius of the electron. The novel feature of the model is the replacement of a single charge with two opposite charges, one on the outer surface of the electron and the other at the center.展开更多
In a previous publication, the author discussed the electron mass and charge inconsistencies resulting from classical models. A model was proposed using classical equations and two opposite charges to resolve the char...In a previous publication, the author discussed the electron mass and charge inconsistencies resulting from classical models. A model was proposed using classical equations and two opposite charges to resolve the charge inconsistency. The model proposed in that article is modified herein using classical equations to define a model that also resolves the mass inconsistency. The positive mass of the outer shell of the electron core is replaced with a negative mass. The small negatively-charged core at the center still has positive mass.展开更多
The dust acoustic(DA) shock wave with dust charge fluctuations, non-Maxwellian ions, and non-isothermal electrons is studied theoretically. The perturbation technique is employed to derive the lower order three-dime...The dust acoustic(DA) shock wave with dust charge fluctuations, non-Maxwellian ions, and non-isothermal electrons is studied theoretically. The perturbation technique is employed to derive the lower order three-dimensional(3D) Burgers equation, and shock wave solution is explored by the tan-hyperbolic method. The effects of flat trapped and trapped electron distributions in the presence of Maxwellian and non-Maxwellian ions on characteristics shock waves are observed. The temperature ratio of non-Maxwellian ion temperature and non-isothermal electron temperature is found to play an important role in forming the shock-like structure.展开更多
Single electron transistors(SETs) are known to be extremely sensitive electrometers owing to their high charge sensitivity. In this work, we report the design, fabrication, and characterization of a silicon-on-insul...Single electron transistors(SETs) are known to be extremely sensitive electrometers owing to their high charge sensitivity. In this work, we report the design, fabrication, and characterization of a silicon-on-insulatorbased SET scanning probe. The fabricated SET is located about 10 m away from the probe tip. The SET with a quantum dot of about 70 nm in diameter exhibits an obvious Coulomb blockade effect measured at 4.1 K. The Coulomb blockade energy is about 18 me V, and the charge sensitivity is in the order of 10^-(5)–10(^-3)e/Hz^(1/2). This SET scanning probe can be used to map charge distribution and sense dynamic charge fluctuation in nanodevices or circuits under test, realizing high sensitivity and high spatial resolution charge detection.展开更多
Cyanocobalamin (CNCbl) is a paradigm system for the study of excited electronic states and biological cofactors including the B12 vitamers, The photophysics of CNCbl has been thoroughly investigated using both ultra...Cyanocobalamin (CNCbl) is a paradigm system for the study of excited electronic states and biological cofactors including the B12 vitamers, The photophysics of CNCbl has been thoroughly investigated using both ultrafast spectroscopy and time dependent density functional theory (TD-DFT). Here we review the spectroscopic and theoretical investigations of CNCbl with emphasis on the nature of S1, the lowest excited electronic state, and extend the spectroscopic measurements to include the ultraviolet region of the spectrum. Ultrafast transient absorption measurements in the visible αβ band region and in the mid- infrared led to assignment of the S1 state to a ligand-to-metal charge transfer (LMCT) with lengthened axial bonds and a ~3 kcal/mol harrier for internal conversion to the ground state. The present measurements encompassing the y band region of the spectrum provide further support for the assignment of the S1 state. The experiments are in good agreement with the results of TD-DFT calculations which confirm the expected lengthening of the axial bonds in S1 and account for the observed barrier for internal conversion back to the ground state,展开更多
We show by a statistical analysis of high-resolution scanning tunneling microscopy (STM) exper- iments, that the interpretation of the density of electron charge as a statistical quantity leads to a conflict with th...We show by a statistical analysis of high-resolution scanning tunneling microscopy (STM) exper- iments, that the interpretation of the density of electron charge as a statistical quantity leads to a conflict with the Heisenberg uncertainty principle. Given the precision in these experiments we find that the uncertainty principle would be violated by close to two orders of magnitude, if this interpretation were correct. We are thus forced to conclude that the density of electron charge is a physically real, i.e., in principle precisely measurable quantity.展开更多
A unique facility for laser plasma physics and advanced accelerator research has recently been built at Tsinghua University. This system is based on a Tsinghua Thomson scattering X-ray source (TTX), which combines a...A unique facility for laser plasma physics and advanced accelerator research has recently been built at Tsinghua University. This system is based on a Tsinghua Thomson scattering X-ray source (TTX), which combines an ultrafast TW laser with a synchronized 45 MeV high brightness linac. In our recent laser wakefield acceleration experiments, we have obtained 10-40 MeV high quality monoenergetic electron beams by running the laser at 5 TW peak power. Under certain conditions a very low relative energy spread of a few percent can be achieved. Absolute charge calibration for three different scintillating screens has also been performed using the linac system.展开更多
In the present investigation,a new composite nanostructured photoanodes were prepared using TiO_2 nanotubes(TNTs) with TiO_2 nanoparticles(TNPs).TNPs were synthesized by sol-gel method,and TNTs were prepared throu...In the present investigation,a new composite nanostructured photoanodes were prepared using TiO_2 nanotubes(TNTs) with TiO_2 nanoparticles(TNPs).TNPs were synthesized by sol-gel method,and TNTs were prepared through alkali hydrothermal method.Dye-sensitized solar cells(DSSCs) were fabricated with different photoanodes comprising of various ratios of TNTs + TNPs,synthetic indigo dye as photosensitizer,PMII(l-propyl-3-methylimidazolium iodide) as ionic liquid electrolyte and cobalt sulfide as counter electrode.The structures and morphologies of TNPs and TNTs were analyzed through X-ray diffractometer,transmission electron microscope and scanning electron microscopes.The results of the investigation showed that the DSSC-4 made with composite photoanode structure(TNTs/TNPs)(90% of TNPs + 10% of TNTs) had improved photocurrent efficiency(2.11%) than pure TNPs(1.00%) and TNT film(0.78%).Electrochemical impedance spectra revealed that the composite TNTs/TNPs film-based DSSCs possessed the lowest charge-transfer resistances and longest electron lifetime.Hence,it could be concluded that the composite TNTs/TNPs photoanode facilitates the charge transport rate and enhances the efficiencies of DSSCs.展开更多
文摘The electron g-factor relates the magnetic moment to the spin angular momentum. It was originally theoretically calculated to have a value of exactly 2. Experiments yielded a value of 2 plus a very small fraction, referred to as the g-factor anomaly. This anomaly has been calculated theoretically as a power series of the fine structure constant. This document shows that the anomaly is the result of the electron charge thickness. If the thickness were to be zero, g = 2 exactly, and there would be no anomaly. As the thickness increases, the anomaly increases. An equation relating the g-factor and the surface charge thickness is presented. The thickness is calculated to be 0.23% of the electron radius. The cause of the anomaly is very clear, but why is the charge thickness greater than zero? Using the model of the interior structure of the electron previously proposed by the author, it is shown that the non-zero thickness, and thus the g-factor anomaly, are due to the proposed positive charge at the electron center and compressibility of the electron material. The author’s previous publication proposes a theory for splitting the electron into three equal charges when subjected to a strong external magnetic field. That theory is revised in this document, and the result is an error reduced to 0.4% in the polar angle where the splits occur and a reduced magnetic field required to cause the splits.
基金Supported by the National Natural Science Foundation of China(No.21302062)the Science Foundation for Young Teachers of Jilin Agricultural University(No.201219)
文摘The novel linear, circular, hooped, and helical molecules based on oligo[8]thio- phene were theoretically studied for the applications of charge transfer devices. To investigate the influence of topology for oligo[8]thiophene derivatives, the geometry structures, frontier molecular orbital (FMO) energies, charge transport properties, and stability property were predicted by density functional theory methods. The calculated results reported herein show that the oligo[8]thiophene derivative with linear structure has smaller energy gap, and fused oligo[8]thiophene derivative with circular structure has the smallest reorganization energy among the designed molecules. We have also studied the stability properties of the designed molecules, and oligo[8]thiophene derivatives are more stable tharJ the fused oligo[8]thiophene derivatives.
基金Supported by the National Natural Science Foundation of China (Grant No.22002031)the Natural Science Foundation of Zhejiang Province (Grant No.LY18F010019)the Innovation Project in Hangzhou for Returned Scholar。
文摘The modulation of electrical properties of MoS_2 has attracted extensive research interest because of its potential applications in electronic and optoelectronic devices.Herein,interfacial charge transfer induced electronic property tuning of MoS_2 are investigated by in situ ultraviolet photoelectron spectroscopy and x-ray photoelectron spectroscopy measurements.A downward band-bending of MoS_2-related electronic states along with the decreasing work function,which are induced by the electron transfer from Cs overlayers to MoS_2,is observed after the functionalization of MoS_2 with Cs,leading to n-type doping.Meanwhile,when MoS_2 is modified with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane(F_4-TCNQ),an upward band-bending of MoS_2-related electronic states along with the increasing work function is observed at the interfaces.This is attributed to the electron depletion within MoS_2 due to the strong electron withdrawing property of F_4-TCNQ,indicating p-type doping of MoS_2.Our findings reveal that surface transfer doping is an effective approach for electronic property tuning of MoS_2 and paves the way to optimize its performance in electronic and optoelectronic devices.
文摘A model for the internal structure of the electron using classical physics equations has been previously published by the author. The model employs both positive and negative charges and positive and negative masses. The internal attributes of the electron structure were calculated for both ring and spherical shapes. Further examination of the model reveals an instability for the ring shape. The spherical shape appears to be stable, but relies on tensile or compressive forces of the electron material for stability. The model is modified in this document to eliminate the dependency on material forces. Uniform stability is provided solely by balancing electrical and centrifugal forces. This stability is achieved by slightly elongating the sphere along the spin axis to create a prolate ellipsoid. The semi-major axis of the ellipsoid is the spin axis of the electron, and is calculated to be 1.20% longer than the semi-minor axis, which is the radius of the equator. Although the shape deviates slightly from a perfect sphere, the electric dipole moment is zero. In the author’s previously published document, the attributes of the internal components of the electron, such as charge and mass, were calculated and expressed as ratios to the classically measured values for the composite electron. It is interesting to note that all of these ratios are nearly the same as the inverse of the Fine Structure Constant, with differences of less than 15%. The electron model assumed that the outer surface charge was fixed and uniform. By allowing the charge to be mobile and the shape to have a particular ellipticity, it is shown that the calculated charge and mass ratios for the model can be exactly equal to the Fine Structure Constant and the Constant plus one. The electron radius predicted by the model is 15% greater than the Classical Electron Radius.
文摘Our calculations are based on the modeling technique and simulation Ab-Initio that appeals to the Density Functional Theory (DFT) relying on the Full-Potential Linearized Augmented Plane Waves (FP-LAPW) method that requires a calculation process using approximations such as Local Density (LDA) and Generalized Gradient (GGA) developed in the modelling software of nanostructures WIEN2k. The optimal structure of the binary semiconductor ZnSe crystallizing in the complex phase of Zinc Blende (B3) was determined by studying the variation of energy depending on the volume of the elementary cell. Then the electronic properties of the optimized state were analyzed such as the gap energy, the total density of states (TDOS), the partial density of states (PDOS) and the repartition of the electronic charge density. The obtained results were successful compared with other theoretical and experimental values reported in literature.
文摘Using our recently published electron’s charge electromagnetic flux manifold fiber model of the electron, described by analytical method and numerical simulations, we show how the fine structure constant is embedded as a geometrical proportionality constant in three dimensional space of its charge manifold and how this dictates the first QED term one-loop contribution of its anomalous magnetic moment making for the first time a connection of its intrinsic characteristics with physical geometrical dimensions and therefore demonstrating that the physical electron charge cannot be dimensionless. We show that the fine structure constant (FSC) α, and anomalous magnetic moment α<sub>μ</sub> of the electron is related to the sphericity of its charge distribution which is not perfectly spherical and thus has a shape, and therefore its self-confined charge possesses measurable physical dimensions. We also explain why these are not yet able to be measured by past and current experiments and how possible we could succeed.
文摘In previous publications, the author has proposed a model of the electron’s internal structure, wherein a positively-charged negative mass outer shell and a negatively-charged positive mass central core are proposed to resolve the electron’s charge and mass inconsistencies. That model is modified in this document by assuming the electron’s radius is exactly equal to the classical electron radius. The attributes of the internal components of the electron’s structure have been recalculated accordingly. The shape of the electron is also predicted, and found to be slightly aspherical on the order of an oblate ellipsoid. This shape is attributed to centrifugal force and compliant outer shell material. It is interesting to note that all of the electron’s attributes, both external and internal, with the exception of mass and angular moment, are functions of the fine structure constant a, and can be calculated from just three additional constants: electron mass, Planck’s constant, and speed of light. In particular, the ratios of the outer shell charge and mass to the electron charge and mass, respectively, are 3/2a. The ratios of the central core charge and mass to the electron charge and mass, respectively, are 1-(3/2a). Attributes of the electron are compared with those of the muon. Charge and spin angular momentum are the same, while mass, magnetic moment, and radius appear to be related by the fine structure constant. The mass of the electron outer shell is nearly equal to the mass of the muon. The muon internal structure can be modeled exactly the same as for the electron, with exactly the same attribute relationships.
文摘The author’s earlier papers proposed a model of the electron’s internal structure comprised of both positive and negative masses and charges. Their relation to the fine structure constant a was calculated in the author’s previous paper. In this paper, more details of the model of the electron’s internal structure, in particular the thicknesses of its outer shell mass and charge, are calculated. Magnetostriction of the electron’s surface is generated by the electron’s spinning surface charge. It is calculated that this magnetostriction holds the electron together, counterbalancing the outward electrical and centrifugal forces. The results of these calculations enable the prediction that a sufficiently strong external magnetic field can split the electron into three equal pieces. The field strength would have to be on the order of at least 8% of the strength at the center of the electron. A model for the origin and creation of an electron from a gamma ray wave is proposed. Evidence is presented that, for certain transitions, mass might be quantized and that the quantum of mass would be 1/2a times the electron mass.
文摘This work is devoted to the experimental determination of the electrostatic properties of the molecular 4-methyl-7-(salicylidene amino) coumarin(C17H13NC3) using high resolution x-ray diffraction data. The experimental results are compared with those obtained theoretically from calculation type ab initio. The experimental investigation is carried out using the molecular electron charge density distribution based on the multipolar model of Hansen and Coppens. However the theoretical calculations are conducted by using the molecular orbital B3 LYP method and the Hartree-Fock(HF) approximation with the basis set 6-31G(d,p) implemented in the Gaussian program. In addition to the structural analysis,the thermal agitation is also analyzed in terms of rigid blocks to ensure a better precision of the results. Subsequently, the electrostatic atomic and molecular properties such as the net charges, the molecular dipolar moment to highlight the nature of charge transfer existing within the molecule studied are derived. Moreover, the obtained electrostatic potential enables the localization of the electropositive and the electronegative parts of the investigated molecule. The present work reports in detail the obtained electrostatic properties of this biologically important molecule.
基金supported by National Natural Science Foundation of China(No.51177131)the New Century Talent Foundation of Ministry of Education of China(NCET-08-0438)
文摘Pseudo-spark switch(PSS) is one of the most widely used discharge switches for pulse power technology.It has many special characteristics such as reliability in a wide voltage range,small delay time,as well as small delay jitter.In this paper,the measuring method for the initial plasma of ZnO surface flashover triggering device of PSS is studied and the results of the measurement show that the electron emission charge is mainly influenced by trigger voltage,gas pressure and DC bias voltage.When the bias voltage increases from 2 kV to 6 kV with the gap distancc fixed at 3 mm,the electron emission charge changes from 2 μC to about 6μC.When the gap distance changes from 3 mm to 5 mm with the bias voltage fixed at 2 kV,the electron emission charge increases from 1.5 μC to 2.5μC.When the gap distance is 4 mm,the hold-off voltage of PSS is 45 kV at gas pressure of 2 Pa,the minimum operating voltage is less than 1 kV.So,the operating scope is from 2.22%to 99%of its self-breakdown voltage.The discharging delay time decreases from 450 ns to 150 ns when the trigger pulse voltage is 1 kV and the discharging voltage is changed from 1 kV to 12 kV.When the trigger pulse voltage is 6 kV,the discharging delay time is less than 100 ns and changes from 100 ns to 50 ns,and the delay jitters are less than30 ns.
基金Project supported by the National Basic Research Program of China(Grant No.2010CB934402)the National Natural Science Foundation of China(Grant No.11374153)
文摘Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method, followed by thermal annealing to form the Si nanocrystals(Si-NCs) embedded in Si Nx floating gate MOS structures. The capacitance–voltage(C–V), current–voltage(I–V), and admittance–voltage(G–V) measurements are used to investigate the charging characteristics. It is found that the maximum flat band voltage shift(△VFB) due to full charged holes(~ 6.2 V) is much larger than that due to full charged electrons(~ 1 V). The charging displacement current peaks of electrons and holes can be also observed by the I–V measurements, respectively. From the G–V measurements we find that the hole injection is influenced by the oxide hole traps which are located near the Si O2/Si-substrate interface. Combining the results of C–V and G–V measurements, we find that the hole charging of the Si-NCs occurs via a two-step tunneling mechanism. The evolution of G–V peak originated from oxide traps exhibits the process of hole injection into these defects and transferring to the Si-NCs.
基金Support by the National Natural Science Foundation of China(No.21563002)the Natural Science Foundation of Inner Mongolia Autonomous Region(No.2015MS0201)the Research Program of Sciences at Universities of Inner Mongolia Autonomous Region(No.NJZZ235)
文摘A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminescent materials for organic light-emitting diodes(OLEDs). The frontier molecular orbitals(FMOs) analysis has turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer(ICT). The calculated results show that the optical and electronic properties of star-shaped molecules are affected by the substituent groups in N-position of 1,8-naphthalimide ring. Our results suggest that star-shaped molecules with n-butyl(1),benzene(2),thiophene(3),thiophene S?,S?-dioxide(4),benzo[c][1,2,5]thiadiazole(5),and 2,7a-dihydrobenzo[d]thiazole(6) fragments are expected to be promising candidates for luminescent and electron transport materials for OLEDs. This study should be helpful in further theoretical investigations on such kind of systems and also to the experimental study for charge transport and/or luminescent materials for OLEDs.
文摘Previous models of the free electron using classical physics equations have predicted attributes that are inconsistent with the experimentally observed attributes. For example, the magnetic moment has been calculated for the observed spinning electric charge. For the calculated moment to equal the observed moment, the electron would either have to spin at two hundred times the speed of light or have a charge radius two hundred times greater than the classical radius. A similar inconsistency results when the mass derived from the spin angular momentum is compared with the observed mass. A classical model is herein proposed which eliminates the magnetic moment inconsistency and also predicts the radius of the electron. The novel feature of the model is the replacement of a single charge with two opposite charges, one on the outer surface of the electron and the other at the center.
文摘In a previous publication, the author discussed the electron mass and charge inconsistencies resulting from classical models. A model was proposed using classical equations and two opposite charges to resolve the charge inconsistency. The model proposed in that article is modified herein using classical equations to define a model that also resolves the mass inconsistency. The positive mass of the outer shell of the electron core is replaced with a negative mass. The small negatively-charged core at the center still has positive mass.
文摘The dust acoustic(DA) shock wave with dust charge fluctuations, non-Maxwellian ions, and non-isothermal electrons is studied theoretically. The perturbation technique is employed to derive the lower order three-dimensional(3D) Burgers equation, and shock wave solution is explored by the tan-hyperbolic method. The effects of flat trapped and trapped electron distributions in the presence of Maxwellian and non-Maxwellian ions on characteristics shock waves are observed. The temperature ratio of non-Maxwellian ion temperature and non-isothermal electron temperature is found to play an important role in forming the shock-like structure.
基金Project supported by the Instrument Developing Project of the Chinese Academy of Sciences(No.YZ201152)the National Natural Science Foundation of China(No.11403084)+1 种基金the Fundamental Research Funds for Central Universities(Nos.JUSRP51510,JUDCF12032)the Graduate Student Innovation Program for Universities of Jiangsu Province(No.CXLX12_0724)
文摘Single electron transistors(SETs) are known to be extremely sensitive electrometers owing to their high charge sensitivity. In this work, we report the design, fabrication, and characterization of a silicon-on-insulatorbased SET scanning probe. The fabricated SET is located about 10 m away from the probe tip. The SET with a quantum dot of about 70 nm in diameter exhibits an obvious Coulomb blockade effect measured at 4.1 K. The Coulomb blockade energy is about 18 me V, and the charge sensitivity is in the order of 10^-(5)–10(^-3)e/Hz^(1/2). This SET scanning probe can be used to map charge distribution and sense dynamic charge fluctuation in nanodevices or circuits under test, realizing high sensitivity and high spatial resolution charge detection.
文摘Cyanocobalamin (CNCbl) is a paradigm system for the study of excited electronic states and biological cofactors including the B12 vitamers, The photophysics of CNCbl has been thoroughly investigated using both ultrafast spectroscopy and time dependent density functional theory (TD-DFT). Here we review the spectroscopic and theoretical investigations of CNCbl with emphasis on the nature of S1, the lowest excited electronic state, and extend the spectroscopic measurements to include the ultraviolet region of the spectrum. Ultrafast transient absorption measurements in the visible αβ band region and in the mid- infrared led to assignment of the S1 state to a ligand-to-metal charge transfer (LMCT) with lengthened axial bonds and a ~3 kcal/mol harrier for internal conversion to the ground state. The present measurements encompassing the y band region of the spectrum provide further support for the assignment of the S1 state. The experiments are in good agreement with the results of TD-DFT calculations which confirm the expected lengthening of the axial bonds in S1 and account for the observed barrier for internal conversion back to the ground state,
文摘We show by a statistical analysis of high-resolution scanning tunneling microscopy (STM) exper- iments, that the interpretation of the density of electron charge as a statistical quantity leads to a conflict with the Heisenberg uncertainty principle. Given the precision in these experiments we find that the uncertainty principle would be violated by close to two orders of magnitude, if this interpretation were correct. We are thus forced to conclude that the density of electron charge is a physically real, i.e., in principle precisely measurable quantity.
基金Supported by NSFC(11375006,11005063,11175102)Tsinghua University Initiative Scientific Research Program+1 种基金the Thousand Young Talents ProgramBeijing Higher Education Young Elite Teacher Project
文摘A unique facility for laser plasma physics and advanced accelerator research has recently been built at Tsinghua University. This system is based on a Tsinghua Thomson scattering X-ray source (TTX), which combines an ultrafast TW laser with a synchronized 45 MeV high brightness linac. In our recent laser wakefield acceleration experiments, we have obtained 10-40 MeV high quality monoenergetic electron beams by running the laser at 5 TW peak power. Under certain conditions a very low relative energy spread of a few percent can be achieved. Absolute charge calibration for three different scintillating screens has also been performed using the linac system.
文摘In the present investigation,a new composite nanostructured photoanodes were prepared using TiO_2 nanotubes(TNTs) with TiO_2 nanoparticles(TNPs).TNPs were synthesized by sol-gel method,and TNTs were prepared through alkali hydrothermal method.Dye-sensitized solar cells(DSSCs) were fabricated with different photoanodes comprising of various ratios of TNTs + TNPs,synthetic indigo dye as photosensitizer,PMII(l-propyl-3-methylimidazolium iodide) as ionic liquid electrolyte and cobalt sulfide as counter electrode.The structures and morphologies of TNPs and TNTs were analyzed through X-ray diffractometer,transmission electron microscope and scanning electron microscopes.The results of the investigation showed that the DSSC-4 made with composite photoanode structure(TNTs/TNPs)(90% of TNPs + 10% of TNTs) had improved photocurrent efficiency(2.11%) than pure TNPs(1.00%) and TNT film(0.78%).Electrochemical impedance spectra revealed that the composite TNTs/TNPs film-based DSSCs possessed the lowest charge-transfer resistances and longest electron lifetime.Hence,it could be concluded that the composite TNTs/TNPs photoanode facilitates the charge transport rate and enhances the efficiencies of DSSCs.