Based on the energy transfer process from host to dopant in an organic electrophosphorescent (EP) device, the expression of energy transfer probability (η) between the host (TPD) and guest (Ir(ppy)3) EP sys...Based on the energy transfer process from host to dopant in an organic electrophosphorescent (EP) device, the expression of energy transfer probability (η) between the host (TPD) and guest (Ir(ppy)3) EP systems was proposed. The results show that: (1) The rate of the triplet energy transfer (KHG and KGH) increases exponentially with increasing donor-acceptor molecular distance (R), whereas decreases as the intermolecular distance (RHH) increases from 0.8 to 2.4 nm. Furthermore, KGH changes more quickly than KHG. (2) The energy transfer probability (η) increases as R reduces, and the RHH changes can be safely neglected for R〈0.9 nm. The situation changes for 0.9nm〈 R 〈 1.1nm, RHH (〈1nm) plays an essential role when η changes and increases with the latter. However, if R〉1.1nm, the transfer probability will be below zero. Here, the energy transfer principle may be less important, and the high electroluminescence (EL) quantum efficiency of phosphorescent system will be attributed to the direct electron-hole recombination in phosphorescent molecules. (3) The η will increase when the Forster radius (R0) increases or Gibb's energy decreases.展开更多
The synthesis and phosphorescence properties of two novel Ir(Ⅲ)complexes bearing tert-butyl substituents,bis(4-tert-butyl-2- phenylbenzothiozolato-N,C^(2′))iridium(Ⅲ)(acetylacetonate)[(tbt)_2Ir(acac)]and bis(4-tert...The synthesis and phosphorescence properties of two novel Ir(Ⅲ)complexes bearing tert-butyl substituents,bis(4-tert-butyl-2- phenylbenzothiozolato-N,C^(2′))iridium(Ⅲ)(acetylacetonate)[(tbt)_2Ir(acac)]and bis(4-tert-butyl-1-phenyl-1H-benzimidazolato- N,C^(2′))iridium(Ⅲ)(acetylacetonate)[(tpbi)_2Ir(acac)],are reported,their molecular structures are confirmed by^1H NMR,ESI-MS and elementary analysis.Photoluminescence(PL)studies revealed that they can emit strong green and orange phosphorescence in high quantum yields.Compared to their prototypes lacking of tert-butyl substituents,the two novel iridium(Ⅲ)complexes both have shorter lifetimes and improved or nearly similar PL quantum efficiencies,implying that the exciton quenching is inhibited effectively when molecular steric hindrance increases.The two chelates have great potential to be used as electrophosphorescent materials.展开更多
Three new cyclometalated iridium(m) complexes based on ligands of diphenylquinoline with fluorinated subsfituents were prepared, and characterized by elemental analysis (EA), ^1H NMR, and mass spectroscopy (MS)....Three new cyclometalated iridium(m) complexes based on ligands of diphenylquinoline with fluorinated subsfituents were prepared, and characterized by elemental analysis (EA), ^1H NMR, and mass spectroscopy (MS). The photophysical and electrophosphorescent properties of the complexes were briefly discussed.展开更多
A novel iridium-complex,(BPPBI) 2 Ir(2-TFDBC)[BPPBI=2-(biphenyl-4-yl)-1-phenyl-1H-benzo[d]imidazole,2-TFDBC=1-(9-ethyl-9H-carbazol-2-yl)-4,4,4-trifluorobutane-1,3-dione],was synthesized,and its structure and c...A novel iridium-complex,(BPPBI) 2 Ir(2-TFDBC)[BPPBI=2-(biphenyl-4-yl)-1-phenyl-1H-benzo[d]imidazole,2-TFDBC=1-(9-ethyl-9H-carbazol-2-yl)-4,4,4-trifluorobutane-1,3-dione],was synthesized,and its structure and component were confirmed by 1 H NMR and element analysis,respectively.UV-Vis absorption and photoluminescent(PL) spectra of(BPPBI) 2 Ir(2-TFDBC) in dichloromethane were investigated.The Ir-complex exhibited a long wavelength excitation of 470 nm,i.e.,low-energy excitation.So,it is a promising candidate for phosphorescent probe and PL material.(BPPBI) 2 Ir(2-TFDBC)-based electroluminescent devices,ITO/MoO 3(10 nm)/NPB(80 nm)/CBP:x(BPPBI) 2 Ir(2-TFDBC)(20 nm)/TPBi(45 nm)/LiF/Al,were fabricated,where x(%) was of 4% or 8% doping concentration(mass fraction);ITO=indium tin oxides;NBP=N,N'-bis-(1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)4,4'-diamine,CBP=4,4'-bis(N-carbazolyl)-1,1'-biphenyl,TPBi=1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene.The devices showed a red emission of 620 nm.The maximum current efficiency and brightness were 1.7 cd/A and 4063 cd/m 2 for a device of 8%(mass fraction) doping level,respectively.The moderate luminous efficiency was due to the inadequate energy transfer from the host material to the guest material.展开更多
This paper summarizes the mechanism and routes for excitation of triplet emitters in dopant emission based phosphorescent organic light-emitting diodes (PhOLEDs),providing a comprehensive overview of recent progress i...This paper summarizes the mechanism and routes for excitation of triplet emitters in dopant emission based phosphorescent organic light-emitting diodes (PhOLEDs),providing a comprehensive overview of recent progress in molecular hosts for triplet emitters in PhOLEDs.Particularly,based on the nature of different hosts,e.g.,hole transporting,electron transporting or bipolar materials,in which the dopant emitters can be hosted to generate phosphorescence,the respective device performances are summarized and compared.Highlights are given to the relationships among the molecular structure,thermal stability,triplet energy,carrier mobility,molecular orbital energy level and their corresponding device performances.展开更多
Iridium(Ⅲ) complexes are one of the most important electrophosphorescent dyes with tunable emissions in the range of visible and near infrared lights,high photoluminescence yields and short lifetimes for high-effic...Iridium(Ⅲ) complexes are one of the most important electrophosphorescent dyes with tunable emissions in the range of visible and near infrared lights,high photoluminescence yields and short lifetimes for high-efficiency organic light-emitting diodes(OLED) with 100% exciton harvesting.This review summarizes the recent development of electroluminescent Ir^(3+) complexes functionalized with host-featured carrier-transporting groups,with emphasis on correlations between functionalization,optoelectronic properties and device performance.According to the introducing approaches,the complexes were sorted with conjugated and aliphatic linkages,as well as the types of functional groups.The modification effect on physical properties and the state-of-the-art device performances were discussed.展开更多
The exploration of high-performance solution-processible host materials for blue and white electrophosphorescent devices is a key and fundamental challenge in the ongoing development of organic semiconductors.Herein,t...The exploration of high-performance solution-processible host materials for blue and white electrophosphorescent devices is a key and fundamental challenge in the ongoing development of organic semiconductors.Herein,two solution-processible resonance host materials with self-adaptive characteristics are delicately designed and constructed.Because of the dynamic tautomerization upon resonance variation,these smart hosts show self-adaptive and selectively enhanced charge carrier flux at high triplet energy levels.Conferred by the resonance molecules,solution-processed blue and white devices exhibit excellent maximum current efficiencies(CEs)of 29.8 and 57.3 cd A−1,and external quantum efficiencies(EQEs)up to 14.5%and 23.5%,respectively.Our works highlight the significant progress of the solution-processed phosphorescent organic light-emitting diodes(PhOLEDs)using resonance host molecules,potentially furnishing a leap forward in constructing advanced organic semiconductors for next-generation optoelectronic devices.展开更多
基金Project supported by the Excellent Youth Foundation of Hu'nan Province (Grant No 03JJY1008), and by the Science Foundation for Post-doctorate of China (Grant No 2004035083).
文摘Based on the energy transfer process from host to dopant in an organic electrophosphorescent (EP) device, the expression of energy transfer probability (η) between the host (TPD) and guest (Ir(ppy)3) EP systems was proposed. The results show that: (1) The rate of the triplet energy transfer (KHG and KGH) increases exponentially with increasing donor-acceptor molecular distance (R), whereas decreases as the intermolecular distance (RHH) increases from 0.8 to 2.4 nm. Furthermore, KGH changes more quickly than KHG. (2) The energy transfer probability (η) increases as R reduces, and the RHH changes can be safely neglected for R〈0.9 nm. The situation changes for 0.9nm〈 R 〈 1.1nm, RHH (〈1nm) plays an essential role when η changes and increases with the latter. However, if R〉1.1nm, the transfer probability will be below zero. Here, the energy transfer principle may be less important, and the high electroluminescence (EL) quantum efficiency of phosphorescent system will be attributed to the direct electron-hole recombination in phosphorescent molecules. (3) The η will increase when the Forster radius (R0) increases or Gibb's energy decreases.
文摘The synthesis and phosphorescence properties of two novel Ir(Ⅲ)complexes bearing tert-butyl substituents,bis(4-tert-butyl-2- phenylbenzothiozolato-N,C^(2′))iridium(Ⅲ)(acetylacetonate)[(tbt)_2Ir(acac)]and bis(4-tert-butyl-1-phenyl-1H-benzimidazolato- N,C^(2′))iridium(Ⅲ)(acetylacetonate)[(tpbi)_2Ir(acac)],are reported,their molecular structures are confirmed by^1H NMR,ESI-MS and elementary analysis.Photoluminescence(PL)studies revealed that they can emit strong green and orange phosphorescence in high quantum yields.Compared to their prototypes lacking of tert-butyl substituents,the two novel iridium(Ⅲ)complexes both have shorter lifetimes and improved or nearly similar PL quantum efficiencies,implying that the exciton quenching is inhibited effectively when molecular steric hindrance increases.The two chelates have great potential to be used as electrophosphorescent materials.
基金supported by the National Natural Science Foundation of China(No.20371036 and 20474047)the Program for New Century Excellent Talents in University,the Ministry of Education of Chinathe Hubei Province Science Fund for Distinguished Young Scholar(No.2003ABB008).
文摘Three new cyclometalated iridium(m) complexes based on ligands of diphenylquinoline with fluorinated subsfituents were prepared, and characterized by elemental analysis (EA), ^1H NMR, and mass spectroscopy (MS). The photophysical and electrophosphorescent properties of the complexes were briefly discussed.
基金Supported by the Natural Science Foundation of Guangdong Province,China(No.10152404801000017)
文摘A novel iridium-complex,(BPPBI) 2 Ir(2-TFDBC)[BPPBI=2-(biphenyl-4-yl)-1-phenyl-1H-benzo[d]imidazole,2-TFDBC=1-(9-ethyl-9H-carbazol-2-yl)-4,4,4-trifluorobutane-1,3-dione],was synthesized,and its structure and component were confirmed by 1 H NMR and element analysis,respectively.UV-Vis absorption and photoluminescent(PL) spectra of(BPPBI) 2 Ir(2-TFDBC) in dichloromethane were investigated.The Ir-complex exhibited a long wavelength excitation of 470 nm,i.e.,low-energy excitation.So,it is a promising candidate for phosphorescent probe and PL material.(BPPBI) 2 Ir(2-TFDBC)-based electroluminescent devices,ITO/MoO 3(10 nm)/NPB(80 nm)/CBP:x(BPPBI) 2 Ir(2-TFDBC)(20 nm)/TPBi(45 nm)/LiF/Al,were fabricated,where x(%) was of 4% or 8% doping concentration(mass fraction);ITO=indium tin oxides;NBP=N,N'-bis-(1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)4,4'-diamine,CBP=4,4'-bis(N-carbazolyl)-1,1'-biphenyl,TPBi=1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene.The devices showed a red emission of 620 nm.The maximum current efficiency and brightness were 1.7 cd/A and 4063 cd/m 2 for a device of 8%(mass fraction) doping level,respectively.The moderate luminous efficiency was due to the inadequate energy transfer from the host material to the guest material.
基金supported by the National Natural Science Foundation of China (20974046)funding from the Nanjing University of Posts and Telecommunications (207162)+2 种基金Natural Science Foundation of Jiangsu High Education (08KJB430011)New Century Excellent Talents funding from Ministry of Education in China (NCET-08-0697)National Basic Research Program of China (973 Program) (2009CB930600)
文摘This paper summarizes the mechanism and routes for excitation of triplet emitters in dopant emission based phosphorescent organic light-emitting diodes (PhOLEDs),providing a comprehensive overview of recent progress in molecular hosts for triplet emitters in PhOLEDs.Particularly,based on the nature of different hosts,e.g.,hole transporting,electron transporting or bipolar materials,in which the dopant emitters can be hosted to generate phosphorescence,the respective device performances are summarized and compared.Highlights are given to the relationships among the molecular structure,thermal stability,triplet energy,carrier mobility,molecular orbital energy level and their corresponding device performances.
基金financially supported by NSFC(Nos.51373050 and 61176020)New Century Excellent Talents Supporting Program of MOE(No.NCET-12-0706)+2 种基金Science and Technology Bureau of Heilongjiang Province(Nos.ZD201402 and JC2015002)Education Bureau of Heilongjiang Province(No.2014CJHB005)the Fok Ying-Tong Education Foundation for Young Teachers in the Higher Education Institutions of China(No.141012)
文摘Iridium(Ⅲ) complexes are one of the most important electrophosphorescent dyes with tunable emissions in the range of visible and near infrared lights,high photoluminescence yields and short lifetimes for high-efficiency organic light-emitting diodes(OLED) with 100% exciton harvesting.This review summarizes the recent development of electroluminescent Ir^(3+) complexes functionalized with host-featured carrier-transporting groups,with emphasis on correlations between functionalization,optoelectronic properties and device performance.According to the introducing approaches,the complexes were sorted with conjugated and aliphatic linkages,as well as the types of functional groups.The modification effect on physical properties and the state-of-the-art device performances were discussed.
基金This work was supported by the National Natural Science Foundation of China(21704042,21604039,61875090,51873159,91833306,21674049)the Six Talent Plan of Jiangsu Province(XCL-049)+4 种基金1311 Talents Program of Nanjing University of Posts and Telecommunications(Dingfeng)the Natural Science Fund for Colleges and Universities in Jiangsu Province(17KJB150017)China Postdoctoral Science Foundation Funded Project(2018M642284)the Nanjing University of Posts and Telecommunications Start-up Fund(NUPTSF)(NY219007,NY217140)the Science and Technology Innovation Project for Overseas Students in Nanjing.
文摘The exploration of high-performance solution-processible host materials for blue and white electrophosphorescent devices is a key and fundamental challenge in the ongoing development of organic semiconductors.Herein,two solution-processible resonance host materials with self-adaptive characteristics are delicately designed and constructed.Because of the dynamic tautomerization upon resonance variation,these smart hosts show self-adaptive and selectively enhanced charge carrier flux at high triplet energy levels.Conferred by the resonance molecules,solution-processed blue and white devices exhibit excellent maximum current efficiencies(CEs)of 29.8 and 57.3 cd A−1,and external quantum efficiencies(EQEs)up to 14.5%and 23.5%,respectively.Our works highlight the significant progress of the solution-processed phosphorescent organic light-emitting diodes(PhOLEDs)using resonance host molecules,potentially furnishing a leap forward in constructing advanced organic semiconductors for next-generation optoelectronic devices.