A well-known hazardous metal and top contaminant in wastewater is hexavalent chromium. The two forms of most commonly found chromium are chromate ( CrO 4 2− ) and dichromate ( Cr 2 O 7 2− ). Leather tanning, cooling t...A well-known hazardous metal and top contaminant in wastewater is hexavalent chromium. The two forms of most commonly found chromium are chromate ( CrO 4 2− ) and dichromate ( Cr 2 O 7 2− ). Leather tanning, cooling tower blow-down, plating, electroplating, rinse water sources, anodizing baths etc. are the main sources of Cr (VI) contamination. The Cr (VI) is not only non-biodegradable in the environment but also carcinogenic to living population. It is still difficult to treat Cr contaminated waste water effectively, safely, eco-friendly, and economically. As a result, many techniques have been used to treat Cr (VI)-polluted wastewater, including adsorption, chemical precipitation, coagulation, ion-exchange, and filtration. Among these practices, the most practical method is adsorption for the removal of Cr (VI) from aqueous solutions, which has gained widespread acceptance due to the ease of use and affordability of the equipment and adsorbent. It has been revealed that Fe-based adsorbents’ oxides and hydroxides have high adsorptive potential to lower Cr (VI) content below the advised threshold. Fe-based adsorbents were also discovered to be relatively cheap and toxic-free in Cr (VI) treatment. Fe-based adsorbents are commonly utilized in industry. It has been discovered that nanoparticles of Fe-, Ti-, and Cu-based adsorbents have a better capacity to remove Cr (VI). Cr (VI) was effectively removed from contaminated water using mixed element-based adsorbents (Fe-Mn, Fe-Ti, Fe-Cu, Fe-Zr, Fe-Cu-Y, Fe-Mg, etc.). Initial findings suggest that Cr (VI) removal from wastewater may be accomplished by using magnesium ferrite nanomaterials as an efficient adsorbent.展开更多
Traditional multi-band frequency selective surface （FSS） approaches are hard to achieve a perfect resonance response in a wide band due to the limit of the onset grating lobe frequency determined by the array. To so...Traditional multi-band frequency selective surface （FSS） approaches are hard to achieve a perfect resonance response in a wide band due to the limit of the onset grating lobe frequency determined by the array. To solve this problem, an approach of combining elements in different period to build a hybrid array is presented. The results of series of numerical simulation show that multi-periodicity combined element FSS, which are designed using this approach, usually have much weaker grating lobes than the traditional FSS. Furthermore, their frequency response can be well predicted through the properties of their member element FSS. A prediction method for estimating the degree of expected grating lobe energy loss in designing multi-band FSS using this approach is provided.展开更多
The prediction of the mechanical and electric properties of piezoelectric fibre composites has become an active research area in recent years. By means of introducing a boundary layer problem, some new kinds of two-sc...The prediction of the mechanical and electric properties of piezoelectric fibre composites has become an active research area in recent years. By means of introducing a boundary layer problem, some new kinds of two-scale finite element methods for solutions to the electric potential and the displacement for composite material in periodic struc- ture under the coupled piezoelectricity are derived. The coupled two-scale relation of the electric potential and the displacement is set up, and some finite element approximate estimates and numerical examples which show the effectiveness of the method are presented.展开更多
The previous methods of figuring the numbers of chemical elements is summed up in this paper. Based on that, another two creative calculative methods are introduced as well.
The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed ...The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed according to the degree of affinity of organic groups to the trace elements. The results show that there is a possibility that trace elements, especially LREE, were bound to peripheral organic functional groups of middle rank coal macromolecule. The most possible functional group that binds trace element is the hydroxyl, and to the less degree, the asymmetric -CH3 and 〉CH2 stretching, -CH3 stretching, etc. The degree of affinity of trace elements to different functional groups varies. The tendency obeys the natural structural changing law of trace elements-- the periodic law. The deviation of some trace elements from this regular trend is attributed to the deviation of intrinsic ＂confusion degree＂ （conventional molar entropy） of the matter system of coal basin, which is affected by the inner and outer factors during the evolution.展开更多
Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PG...Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PGE concentration reaches more than 800×10 -6. Sea floor hydrothermal fluid eruption was suggested to have been the main origin of the ore-forming materials. The whole process from the sedimentation to the redistribution of the ore-forming elements occurred on the conditions of intermediate to weak alkaline, weak reduction to weak oxidation. The temperature for the sedimentation and redistribution of the ore-forming elements was lower than 210 ℃. At such a low temperature, inert elements such as PGE, Au and Ag could quite easily be remobilized.展开更多
How do elements originate, how atoms are formed, and what are the laws? According to the unified logic of “Tong Yi Lun Thought”, combined with the elements’ attributes and the atomic composition that have been disc...How do elements originate, how atoms are formed, and what are the laws? According to the unified logic of “Tong Yi Lun Thought”, combined with the elements’ attributes and the atomic composition that have been discovered now, after determining that the mechanism of increasing yang in the atomic system is the increase of proton number, the Bian Zheng relationship among proton, neutron and electron determines that there are only 128 kinds of elements in the atomic system. At the same time, element atoms have corresponding logical relations when they are generated.展开更多
Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solutio...Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solution if the macrostructure is large enough to comprise an infinite number of unit cells. In this paper, a novel implementation algorithm of asymptotic homogenization (NIAH) is developed to calculate the effective CTE of periodic composite materials. Compared with the previous implementation of AH, there are two obvious advantages. One is its implementation as simple as representative volume element (RVE). The new algorithm can be executed easily using commercial finite element analysis (FEA) software as a black box. The detailed process of the new implementation of AH has been provided. The other is that NIAH can simultaneously use more than one element type to discretize a unit cell, which can save much computational cost in predicting the CTE of a complex structure. Several examples are carried out to demonstrate the effectiveness of the new implementation. This work is expected to greatly promote the widespread use of AH in predicting the CTE of periodic composite materials.展开更多
An analytical theory for calculating perturbations of the orbital elements of a satellite due to J2 to accuracy up to fourth power in eccentricity is developed. It is observed that there is significant improvement in ...An analytical theory for calculating perturbations of the orbital elements of a satellite due to J2 to accuracy up to fourth power in eccentricity is developed. It is observed that there is significant improvement in all the orbital elements with the present theory over second-order theory. The theory is used for computing the mean orbital elements, which are found to be more accurate than provided by Bhatnagar and taqvi’s theory (up to second power in eccentricity). Mean elements have a large number of practical applications.展开更多
Rotationally periodic symmetry is exploited in 2-D elastostatic calculation using the BEM.It is proved that the coefficient matrices of the global boundary element equations for the rotationally periodic system are bl...Rotationally periodic symmetry is exploited in 2-D elastostatic calculation using the BEM.It is proved that the coefficient matrices of the global boundary element equations for the rotationally periodic system are block-circulant so long as a kind of symmetry-adapted reference coordinate system is adopted. Furthermore,an efficient algorithm,which partitions the original problem of solving the boundary element equations into a series of subproblems,is proposed.The method permits arbitrary load distribution for stress analysis problems.展开更多
In this paper we simulate the repeated occurrence of strong earthquakes along a strike-slip fault by using a finite element model. The fault valve mechanism is included in the model in order to take into account the e...In this paper we simulate the repeated occurrence of strong earthquakes along a strike-slip fault by using a finite element model. The fault valve mechanism is included in the model in order to take into account the effeCt of POre fluid pressure variation. Five parameters are used to characterize the rheology of the fault, POre pressure variation, and fracture criteria. By Systematically varying these parameters and calculating a large number of models we carried out a preliminary investigation on the alternatively quiet and active periods of seismicity and their relation to model Parameters and loading conditions. Under the action of a constant-rate boundary movement, in the case of intermediate stress and pore pressure, the models display a regular quiescence-activity phenomenon with a cycle length of 1/3-1 of the recurrence pened. When the model is under high stress or high pore pressure, this phenomenon becomes irregular or inexplicit. When the model is subject to periedic boundary forces and the amplitude of force variation is not too small, it results in an alternatively quiet and active seismicity Pattern with the same Period Of the force variation.展开更多
Thirty one trace elements were determined in the petroleum and its fractions of 250℃ - 350℃, 350℃ - 450℃ and up 450℃ by inductively coupled plasma optical emission spectrometry. Such analyses are important for te...Thirty one trace elements were determined in the petroleum and its fractions of 250℃ - 350℃, 350℃ - 450℃ and up 450℃ by inductively coupled plasma optical emission spectrometry. Such analyses are important for technical diagnostics as well as specific sample characteristics. The sample preparation together with an efficient sample introduction allowed a fast quantification of the analytes using calibration curves prepared with analyte organic standards. Trace element occurrences, forms, distributions are examined as well as their implications in terms of reservoir geochemistry, oil refining and environment.展开更多
文摘A well-known hazardous metal and top contaminant in wastewater is hexavalent chromium. The two forms of most commonly found chromium are chromate ( CrO 4 2− ) and dichromate ( Cr 2 O 7 2− ). Leather tanning, cooling tower blow-down, plating, electroplating, rinse water sources, anodizing baths etc. are the main sources of Cr (VI) contamination. The Cr (VI) is not only non-biodegradable in the environment but also carcinogenic to living population. It is still difficult to treat Cr contaminated waste water effectively, safely, eco-friendly, and economically. As a result, many techniques have been used to treat Cr (VI)-polluted wastewater, including adsorption, chemical precipitation, coagulation, ion-exchange, and filtration. Among these practices, the most practical method is adsorption for the removal of Cr (VI) from aqueous solutions, which has gained widespread acceptance due to the ease of use and affordability of the equipment and adsorbent. It has been revealed that Fe-based adsorbents’ oxides and hydroxides have high adsorptive potential to lower Cr (VI) content below the advised threshold. Fe-based adsorbents were also discovered to be relatively cheap and toxic-free in Cr (VI) treatment. Fe-based adsorbents are commonly utilized in industry. It has been discovered that nanoparticles of Fe-, Ti-, and Cu-based adsorbents have a better capacity to remove Cr (VI). Cr (VI) was effectively removed from contaminated water using mixed element-based adsorbents (Fe-Mn, Fe-Ti, Fe-Cu, Fe-Zr, Fe-Cu-Y, Fe-Mg, etc.). Initial findings suggest that Cr (VI) removal from wastewater may be accomplished by using magnesium ferrite nanomaterials as an efficient adsorbent.
基金supported by the National Natural Science Foundation of China(90305026).
文摘Traditional multi-band frequency selective surface （FSS） approaches are hard to achieve a perfect resonance response in a wide band due to the limit of the onset grating lobe frequency determined by the array. To solve this problem, an approach of combining elements in different period to build a hybrid array is presented. The results of series of numerical simulation show that multi-periodicity combined element FSS, which are designed using this approach, usually have much weaker grating lobes than the traditional FSS. Furthermore, their frequency response can be well predicted through the properties of their member element FSS. A prediction method for estimating the degree of expected grating lobe energy loss in designing multi-band FSS using this approach is provided.
基金supported by the National Natural Science Foundation of China(Nos.10801042 and 11171257)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20104410120001)
文摘The prediction of the mechanical and electric properties of piezoelectric fibre composites has become an active research area in recent years. By means of introducing a boundary layer problem, some new kinds of two-scale finite element methods for solutions to the electric potential and the displacement for composite material in periodic struc- ture under the coupled piezoelectricity are derived. The coupled two-scale relation of the electric potential and the displacement is set up, and some finite element approximate estimates and numerical examples which show the effectiveness of the method are presented.
基金This work is supported by the National Science Foundation of China （No. 20471001 and 20671001）, the Important Project of Anhui Provincial Education Department （No. ZD2007004-1）, the Specific Project for Talents of Science and Technology of Universities of Anhui Province （No. 2005hbz03） and the Key Laboratory of Environment-friendly Polymer Materials of Anhui Province.
文摘The previous methods of figuring the numbers of chemical elements is summed up in this paper. Based on that, another two creative calculative methods are introduced as well.
基金supported by the National Science Foundation of China(Nos.41172143 and 40872101)Developmental Plan of Basic Research on Natural Science of Shanxi Province(20012JM5005)Science Research Plan of Shanxi education department(12JK0483)
文摘The relationship between trace elements in coal and organic functional groups of coal, also some of aromatic structure, was investigated by using curve fitting of infrared spectra. Cluster analysis was also performed according to the degree of affinity of organic groups to the trace elements. The results show that there is a possibility that trace elements, especially LREE, were bound to peripheral organic functional groups of middle rank coal macromolecule. The most possible functional group that binds trace element is the hydroxyl, and to the less degree, the asymmetric -CH3 and 〉CH2 stretching, -CH3 stretching, etc. The degree of affinity of trace elements to different functional groups varies. The tendency obeys the natural structural changing law of trace elements-- the periodic law. The deviation of some trace elements from this regular trend is attributed to the deviation of intrinsic ＂confusion degree＂ （conventional molar entropy） of the matter system of coal basin, which is affected by the inner and outer factors during the evolution.
文摘Some extraditional types—black rock series types of platinum group element (PGE), gold and silver mineralization occurrences were found in the Lower Cambrian in Guizhou and Hunan provinces of southwest China where PGE concentration reaches more than 800×10 -6. Sea floor hydrothermal fluid eruption was suggested to have been the main origin of the ore-forming materials. The whole process from the sedimentation to the redistribution of the ore-forming elements occurred on the conditions of intermediate to weak alkaline, weak reduction to weak oxidation. The temperature for the sedimentation and redistribution of the ore-forming elements was lower than 210 ℃. At such a low temperature, inert elements such as PGE, Au and Ag could quite easily be remobilized.
文摘How do elements originate, how atoms are formed, and what are the laws? According to the unified logic of “Tong Yi Lun Thought”, combined with the elements’ attributes and the atomic composition that have been discovered now, after determining that the mechanism of increasing yang in the atomic system is the increase of proton number, the Bian Zheng relationship among proton, neutron and electron determines that there are only 128 kinds of elements in the atomic system. At the same time, element atoms have corresponding logical relations when they are generated.
基金supported by the National Natural Science Foundation of China (Grants 11332004, 11572071)the Program for Changjiang Scholars and Innovative Research Team in Dalian University of Technology (PCSIRT)+2 种基金111 Project (Grant B14013)the CATIC Industrial Production Projects (Grant CXY2013DLLG32)the Fundamental Research Funds for the Central Universities (Grant DUT15ZD101)
文摘Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solution if the macrostructure is large enough to comprise an infinite number of unit cells. In this paper, a novel implementation algorithm of asymptotic homogenization (NIAH) is developed to calculate the effective CTE of periodic composite materials. Compared with the previous implementation of AH, there are two obvious advantages. One is its implementation as simple as representative volume element (RVE). The new algorithm can be executed easily using commercial finite element analysis (FEA) software as a black box. The detailed process of the new implementation of AH has been provided. The other is that NIAH can simultaneously use more than one element type to discretize a unit cell, which can save much computational cost in predicting the CTE of a complex structure. Several examples are carried out to demonstrate the effectiveness of the new implementation. This work is expected to greatly promote the widespread use of AH in predicting the CTE of periodic composite materials.
文摘An analytical theory for calculating perturbations of the orbital elements of a satellite due to J2 to accuracy up to fourth power in eccentricity is developed. It is observed that there is significant improvement in all the orbital elements with the present theory over second-order theory. The theory is used for computing the mean orbital elements, which are found to be more accurate than provided by Bhatnagar and taqvi’s theory (up to second power in eccentricity). Mean elements have a large number of practical applications.
文摘Rotationally periodic symmetry is exploited in 2-D elastostatic calculation using the BEM.It is proved that the coefficient matrices of the global boundary element equations for the rotationally periodic system are block-circulant so long as a kind of symmetry-adapted reference coordinate system is adopted. Furthermore,an efficient algorithm,which partitions the original problem of solving the boundary element equations into a series of subproblems,is proposed.The method permits arbitrary load distribution for stress analysis problems.
文摘In this paper we simulate the repeated occurrence of strong earthquakes along a strike-slip fault by using a finite element model. The fault valve mechanism is included in the model in order to take into account the effeCt of POre fluid pressure variation. Five parameters are used to characterize the rheology of the fault, POre pressure variation, and fracture criteria. By Systematically varying these parameters and calculating a large number of models we carried out a preliminary investigation on the alternatively quiet and active periods of seismicity and their relation to model Parameters and loading conditions. Under the action of a constant-rate boundary movement, in the case of intermediate stress and pore pressure, the models display a regular quiescence-activity phenomenon with a cycle length of 1/3-1 of the recurrence pened. When the model is under high stress or high pore pressure, this phenomenon becomes irregular or inexplicit. When the model is subject to periedic boundary forces and the amplitude of force variation is not too small, it results in an alternatively quiet and active seismicity Pattern with the same Period Of the force variation.
文摘Thirty one trace elements were determined in the petroleum and its fractions of 250℃ - 350℃, 350℃ - 450℃ and up 450℃ by inductively coupled plasma optical emission spectrometry. Such analyses are important for technical diagnostics as well as specific sample characteristics. The sample preparation together with an efficient sample introduction allowed a fast quantification of the analytes using calibration curves prepared with analyte organic standards. Trace element occurrences, forms, distributions are examined as well as their implications in terms of reservoir geochemistry, oil refining and environment.
