Co_(3)O_(4)as an efficient passive NO_(x) adsorber for emission control during cold-start of diesel engines

The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from vehicles.These nanoparticles boast a substantial quantity of active chemisorbed oxygen and lattice oxygen,which exhibited a NO_(x) uptake capacity commensurate with Pd/SSZ-13 at 100℃.The primary NO_(x) release temperature falls within a temperature range of 200-350℃,making it perfectly suitable for diesel engines.The characterization results demonstrate that chemisorbed oxygen facilitate nitro/nitrites intermediates formation,contributing to the NO_(x) storage at 100℃,while the nitrites begin to decompose within the 150-200℃range.Fortunately,lattice oxygen likely becomes involved in the activation of nitrites into more stable nitrate within this particular temperature range.The concurrent processes of nitrites decomposition and its conversion to nitrates results in a minimal NO_(x) release between the temperatures of 150-200℃.The nitrate formed via lattice oxygen mainly induces the NO_(x) to be released as NO_(2) within a temperature range of 200-350℃,which is advantageous in enhancing the NO_(x) activity of downstream NH_(3)-SCR catalysts,by boosting the fast SCR reaction pathway.Thanks to its low cost,considerable NO_(x) absorption capacity,and optimal release temperature,Co_(3)O_(4)demonstrates potential as an effective material for passive NO_(x) adsorber applications.

China's Total Emission Control Policy:a Critical Review

As part of a comprehensive environmental management system, many countries establish emission control targets for mass emissions of a pollutant. Such targets are often the key objective of an environmental policy, such as an emission trading program. In China, however, it is more than just an objective of one particular policy; it has become a concept that has influenced many national environmental policies and activities. The objective of this article is to review the implementation of the total emission control policy in the past 10 years and explore emerging issues in its implementation. The article has three sections: a summary of the implementation experience, issues with the design and implementation of the policy, and policy recommendations.

Changes in PM2.5 sensitivity to NOx and NH3 emissions due to a large decrease in SO2 emissions from 2013 to 2018

The authors evaluated and compared the behavior of PM2.5 with respect to NOx and NH3 emission changes in high(the year 2013)and low(the year 2018)SO2 emission cases.Two groups of simulations were conducted based on anthropogenic emissions from China in 2013 and 2018,respectively.In each group of simulations,a respective 25%reduction in NOx and NH3 emissions were assumed.A sensitivity factor(β)was defined as the relative change in PM2.5 concentration due to 1%change in NOx or NH3 emissions.In the high SO2 emissions case,PM2.5 was more sensitive to NH3(0.31)emissions change than NOx(0.21).Due to the significant decrease in SO2 emissions from the high to low SO2 emissions case,the sensitivity of PM2.5 to NOx increased to 0.33,while its sensitivity to NH3 decreased to 0.22.The result implies that now and in the future,PM2.5 is/will be less sensitive to NH3 emissions change,while NOx emissions control is more effective in reducing the surface PM2.5 concentration.Seasonally,in the low SO2 emissions case,the sensitivities of PM2.5 to NOx and NH3 in winter were higher than those in summer,indicating that to dealwith severewinter hazemore attention should be paid to the emissions control of inorganic PM2.5 precursors,especially NOx.

Novel Oxygen Storage Components Promoted Palladium Catalysts for Emission Control in Natural Gas Powered Engines

A three-way catalyst comprised novel oxygen storage components for emission control in natural gas powered engines was prepared. The addition of novel oxygen storage components to the Pd/γ-Al2O3 catalysts resulted in improved activities of the fresh and aged catalyst by lowering the light-off temperature for methane in natural gas engines exhaust.

What is going up in smoke?——A study of emissions in the wood industry

The requirements that a business needs to consider when building a wood panels manufacturing plant are much the same as they have been for decades, but today there is also the need for multiple environmental studies and permits. These are costly and time consuming additional expenses that often are the longest lead-time items on any project. Most industrialized countries have legislation in place to limit and control the negative impact that emission of pollutants may have on the environment. This paper discusses what is actually happening inside wood drying plants, and the prerequisite conditions for genesis of pyrolytic products relative to the operational parameters, such as choice of input raw materials, driers design and operational regime, choice of fuels for the heat generation and how these factors influence production of stack emission. The characterization of emission condensate by analytical methods is described, and survey of emission control system in use worldwide is described, and means of investigating what may be the optimum design for the control of emission is discussed. Alternate uses of utilizing the condensate, other than burning, are presented for consideration.

Eureka Webair： Web-Based Air Quality Management, Real-Time Forecasting and Emission Control Optimization

For the assessment and management of regional to local air quality, an integrated environmental management information system was built within the multi national Eureka project 3266 Webair, http：//www.ess.co.at/WEBAIR. The system combines data bases and GIS and a range of coupled models and analytical tools that address a range of typical management problems and cover several levels of nesting from regional to city level and street canyons. The main functions are to support regulatory tasks, compliance monitoring, operational forecasting and reporting, impact assessment EIA （environmental impact assessment）, SEA （strategic environmental assessment） and public information within one consistent framework. A major objective is the improvement of air quality through emission control. The integrated model system together with its shared data bases provides a reliable, consistent basis for the non-linear techno-economic and multi-criteria optimization of emission control strategies （including greenhouse gases and energy efficiency）. A real-time expert system drives, supports and monitors the autonomous and interactive operations, and provides embedded QA/QC （quality assurance/quality control） functions for reliable operations and ease of use.

Study on the Environmental Quality Guarantee Ratio on the Basis of Total Air Pollutant Emission Amount Control

The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollutant emission is permitted under the total air pollutant emission amount control (TAPEAC) on the basis of A-value method. So the concept of the environmental quality guarantee ratio (EQGR) for TAPEAC is advanced in this paper and its quantitative formula is figured out for both hourly and daily EQGR. It is concluded that the EQGR is related with the yearly arrangement of A-value besides the pollutant type. According to the meteorological data in a lower area along Yangtze River in 2000, the yearly A-value trend is analyzed. Based on the data, the hourly EQGR of SO 2 and NO 2 is respectively 97.4% and 90.2%, and daily EQGR respectively 90.2% and 79.5%.

Experimental Research on SOx from Ship Emissions by Lye Absorption

To protect environment, and to comply with the IMO＇s （International Maritime Organization） newest regulations about ship＇s SOx emission. This thesis illustrates a closed recycling absorb system based on NaOH solution recycling particularly for SOx onboard. The goal is to use NaOH solution to absorb SOx, and reduce the damage the ships made towards environment. The thesis analyzes the main features that could influence the absorption of SOx on board, and the precipitations during the experiment. To reveal that NaOH solution is very highly effective and economic in absorption of SOx on ships by this experiment, and to set a theoretical basic fundamental for future application of alkali solution recycling absorption system for SOx.

COMPOSITIVE EMISSION CONTROL SYSTEM OF GASOLINE VEHICLE

The working principle of a kind of compositive emission control system is inquired into, which includes exhaust heater, secondary air supplement, exhaust gas recirculation （EGR）, thermal reactor and catalytic converter, etc. The purification effect of CO, HC and NOx emission of the gasoline spark ignite （S.I.） engine is studied. The entire vehicle driving cycle tests based on the national emission standard and a series of the gasoline engine-testing bench tests including full load characteristic experiment, load characteristic experiment and idle speed experiment are done. The results show that the system has a very good emission control effect to CO, HC and NOx of gasoline engine. The construction of the system is very simple and can be mounted on the exhaust pipe conveniently without any alteration of the vehicle-use gasoline engine.

Sulfur Dioxide Emission Control,Blockade and Drainage

This paper presents the present status of sulfur dioxide emission from thermal plants in China, tells the main problems existing in its emission control and finally gives out suggestions to the problems, that is, to constitute complete standards and regulations and enhancesupervision accordingly.

The Future of Quasi Emission Control Enterprises in a Low-Carbon Economy

At 9:30 a.m.on July 16,2021,the national carbon emission trading market started operation at Shanghai Environment and Energy Exchange.On the first day,the carbon emission quota totaled 4.244 million tons,with a turnover of 210 million yuan and an average transaction price of 51.23 yuan/ton.The carbon trading price is on the rise.With the gradual maturity and improvement of conditions,there will be about 8,000 to 10,000 emission control enterprises under the eight major industries in the future,and China’s carbon market will become the largest market covering greenhouse gas emissions worldwide.It can be seen that carbon trading is a“big deal.”If enterprises participate well,they will form carbon assets,but if they do not participate well,they will form carbon liabilities.This paper analyzes the opportunities and challenges faced by quasi emission control enterprises under the background of low-carbon economy.This provides certain reference significance for these enterprises to actively participate in the national carbon trading market in the future.

Low Carbon Building Design Optimization Based on Intelligent Energy Management System

The construction of relevant standards for building carbon emission assessment in China has just started,and the quantitative analysis method and evaluation system are still imperfect,which hinders the development of low-carbon building design.Therefore,the use of intelligent energy management system is very necessary.The purpose of this paper is to explore the design optimization of low-carbon buildings based on intelligent energy management systems.Based on the proposed quantitative method of building carbon emission,this paper establishes the quota theoretical system of building carbon emission analysis,and develops the quota based carbon emission calculation software.Smart energy management system is a low-carbon energy-saving system based on the reference of large-scale building energy-saving system and combined with energy consumption.It provides a fast and effective calculation tool for the quantitative evaluation of carbon emission of construction projects,so as to realize the carbon emission control and optimization in the early stage of architectural design and construction.On this basis,the evaluation,analysis and calculation method of building structure based on carbon reduction target is proposed,combined with the carbon emission quota management standard proposed in this paper.Taking small high-rise residential buildings as an example,this paper compares and analyzes different building structural systems from the perspectives of structural performance,economy and carbon emission level.It provides a reference for the design and evaluation of low-carbon building structures.The smart energy management system collects user energy use parameters.It uses time period and time sequence to obtain a large amount of data for analysis and integration,which provides users with intuitive energy consumption data.Compared with the traditional architectural design method,the industrialized construction method can save 589.22 megajoules(MJ)per square meter.Based on 29270 megajoules(MJ)per ton of standard coal,the construction area of the case is about 8000 m2,and the energy saving of residential buildings is 161.04 tons of standard coal.This research is of great significance in reducing the carbon emission intensity of buildings.

Geographical Distribution of Atmospheric Nitrogen Deposition in China and Its Response to Emission Control Policy

Atmospheric nitrogen(N)deposition has experienced significant change because of anthropogenic emissions,thereby exerting a pronounced impact on global ecosystem services.With the rapid development of industry and agriculture and the swift expansion of urban areas in China since the 1980s,reactive nitrogen(Nr)emissions and N deposition have substantially increased.In pursuit of im-proving air quality,China has implemented a series of environmental protection policies and undertaken diverse measures to reduce pol-lutant emissions.This paper is a review of multivariate data sources of atmospheric N deposition based on the results of literature from 1980 to 2023,and the original data from 1980 to 2020 are summarized,counted and calculated.The main findings are as follows:1)the annual average atmospheric N deposition ranged from approximately 20-40 kg/(ha·yr),with the variability primarily linked to different assessment methods;2)regional disparities were evident in the spatial distribution of N deposition,with elevated values concentrated in areas with intense Nr emissions;3)atmospheric N deposition significantly declined after 2010,particularly the deposition of oxidized N,while reduced N deposition remained stable.These results reflect the effects of China's serious control policies on nitrogen oxide(NO.)emissions and strengthen the importance of agricultural NH3 emission mitigation.This study contributes to a comprehensive understanding of the N dynamics in the emission-deposition process,and provides a scientific foundation for the research of environmental protection,climate change,and sustainable development.

How Do Power Enterprises Deal with Total Quantity Control

This paper describes the relation and difference of "emission up to standards" and "total quantity control" ofmain atmospheric pollutants, as well as their legal status. It points out that the total quantity control is a good approachto solve a problem that environmental quality do not yet reach the requirements in an area where emission concentrationhas came up to standards, or to solve a problem that the interregional transportation of pollutants (e. g. acid rain) arises.And further, it put forward five proposals for the total quantity control.[

Atmospheric Environmental Capacity of S_2 in Winter over Lanzhou in China:A Case Study

The total emission control method based on atmospheric environmental capacity is the most effective in air pollution mitigation. The atmospheric environmental capacities of SO2 on representative days over Lanzhou are estimated using the numerical models RAMS, HYPACT and a linear programming model, according to the national ambient air quality standard of China （NAAQSCHN）. The results show that the fields of meteorological elements and SO2 simulated by the models agree reasonably well with observations. The atmospheric environmental capacity of SO2 over Lanzhou is around 111.7 × 10^3 kg d^-1, and in order to meet the air quality level Ⅱ of the NAAQSCHN, SO2 emissions need to be reduced by 20%.

Game theory approach to optimal capital cost allocation in pollution control

This paper tries to integrate game theory, a very useful tool to resolve conflict phenomena, with optimal capital cost allocation issue in total emission control. First the necessity of allocating optimal capital costs fairly and reasonably among polluters in total emission control was analyzed. Then the possibility of applying game theory to the issue of the optimal capital cost allocation was expounded. Next the cooperative N person game model of the optimal capital cost allocation and its solution ways including method based on Shapley value, least core method, weak least core methods, proportional least core method, CGA method, MCRS method and so on were delineated. Finally through application of these methods it was concluded that to apply game theory in the optimal capital cost allocation issue is helpful to implement the total emission control planning schemes successfully, to control pollution effectively, and to ensure sustainable development.

Preparation and characterization of Mn/MgAlFe as transfer catalyst for SO_x abatement

A series of manganese-promoted MgAlFe mixed oxides, used as sulfur transfer catalysts, were prepared by acid-processed gelatin method and characterized by TGA-DTA, XRD, N2 adsorption-desorption and FT-IR techniques. It was found that the sulfur transfer catalysts with 0.5？3.0 wt% manganese showed its good dispersion in the precursor. The novel Mn/MgAlFe catalysts with 0.5？5.0 wt% manganese oxide showed a high oxidative adsorption rate and sulfur adsorption capacity, and 5.0 wt% Mn/MgAlFe sample was superior to the others for SO2 removal. Moreover, the presence of CO had no obvious effect on the adsorption activity of sulfur transfer catalysts for SO2 uptake.

A comparative study of the thermal and hydrothermal aging effect on Cu-SSZ-13 for the selective catalytic reduction of NOx with NH_(3)

In this work,the characterizations of Cu-SSZ-13 after hydrothermal aging(HTA)and thermal aging(TA)at different temperatures(750,800,and 850°C)are compared,and the differences between those two serious aged samples are analyzed.With this data,the effect of steam on catalysts deactivation during hydrothermal aging is analyzed.The TA at 750 and 800°C causes the dealumination and the agglomeration of Cu^(2+)ions to Cu O,resulting in the activity loss of Cu-SSZ-13.The presence of steam upon HTA at750 and 800°C aggravates the catalyst deactivation by increasing the Al detachment and the Cu^(2+)agglomeration.The structure and cupric state are almost the same in the Cu-SSZ-13 after TA and HTA at 850°C,respectively,indicating that the steam has little influence on the deactivation.The formation of CuAl_(2)O_(4) spinel is the primary reason for the deactivation after both HTA and TA at 850°C,probably attributed to the strong interaction between Cu^(2+)ions and framework Al sites at high temperatures.

Durability of three-way and close-coupled catalysts for Euro IV regulation

The durability of three-way catalyst （TWC） and corresponding close-coupled catalyst （CCC） for Euro Ⅳ stage regulation was investigated through Vehicle Road Running Mode tests, whereas emissions of regulated pollutants of three car fleet were investigated at every 100,000 km miles. The results showed that HC, NOx, and CO emission values could meet Euro Ⅳ regulation limits at every point. The redox properties of TWC and CCC were measured by CO reduction during each isothermal. It was obvious that both aged TWC and aged CCC behaved a good redox property at 673 and 773 K. Based on XRD and BET measurement results, TWC and CCC washcoat were characterized with good thermal stability.

A case study of air quality control in Beijing and the surrounding area during the 2015 World Championships and Parade

Based on satellite observations, the effects of emission reduction measures on air pollutants （NO2 （nitrogen dioxide）, SO2 （sulfur dioxide）, and aerosols） were estimated in Beijing and its surroundings during the 2015 World Championships and Parade （WCP） held in Beijing. Compared with the same period in the previous three years （2012-2014）, the tropospheric vertical column densities of NO2 and SO2 in 2015 were significantly reduced in Beijing and its surroundings. During the WCP, aerosol optical depth was reduced most significantly in Beijing, while NO2 and SO2 were reduced most significantly in Hebei and Tianjin, respectively. The meteorological conditions were also favorable during this period. During the WCP, the North China Plain was located under high pressure from the north of China. A southward pressure gradient force and weak northerly and northeasterly winds blocked the transport of pollution from southern and western parts of the industrial area （Hebei, Shanxi and Shandong provinces）. Cold air masses pushed southwards weakly. These conditions were beneficial to the removal of air pollutants in Beijing.