An Integrated Analysis on the Synergistic Reduction of Carbon and Pollution Emissions from China’s Iron and Steel Industry

Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions in China,are challenged by the huge demand for steel.Carbon and pollutants often share common emission sources,indicating that emission reduction could be achieved synergistically.Here,we explored the inherent potential of measures to adjust feedstock composition and technological structure and to control the size of the ISI to achieve carbon emission reduction(CER)and pollution emission reduction(PER).We investigated five typical pollutants in this study,namely,petroleum hydrocarbon pollutants and chemical oxygen demand in wastewater,particulate matter,SO_(2),and NO_(x) in off gases,and examined synergies between CER and PER by employing cross elasticity for the period between 2022 and 2035.The results suggest that a reduction of 8.7%-11.7%in carbon emissions and 20%-31%in pollution emissions(except for particulate matter emissions)could be achieved by 2025 under a high steel scrap ratio(SSR)scenario.Here,the SSR and electric arc furnace(EAF)ratio serve critical roles in enhancing synergies between CER and PER(which vary with the type of pollutant).However,subject to a limited volume of steel scrap,a focused increase in the EAF ratio with neglection of the available supply of steel scrap to EAF facilities would lead to an increase carbon and pollution emissions.Although CER can be achieved through SSR and EAF ratio optimization,only when the crude steel production growth rate remains below 2.2%can these optimization measures maintain the emissions in 2030 at a similar level to that in 2021.Therefore,the synergistic effects between PER and CER should be considered when formulating a development route for the ISI in the future.

Variation of toxic pollutants emission during a feeding cycle from an updraft fixed bed gasifier for disposing rural solid waste

The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the content of oxygen in flue gas gradually increased, while SO_2 and HCl in flue gas decreased with time after feeding in a whole feeding cycle. Although large amount of CO was produced during the gasifying, low CO content in flue gas could be obtained after the heat treatment with an electric heating device. The distribution characteristics of dioxin congeners in flue gas indicted the re-synthesis of dioxins after flue gas heating, and the increase of oxygen promoted the synthesis of dioxins. The emission content of dioxins could meet the standard(0.1 ng I-TEQ·m^(-3),GB18458-2014) of China when the oxygen content was controlled below 8.3%. Hence, for a batch feeding gasifier,low oxygen condition should be offered by reducing air intake at the later stage of feeding cycle in order to decrease the re-synthesis of dioxins after the flue gas heating.

Preliminary Study on the Emission Rules of Sulfur Derivative Pollutants in Putrefactive Cyanobacteria

[Objective]The aim was to study the characteristics of the emission of sulfur derivative pollutants in cyanobacteria.[Method]Based on water odor in drink water from Gonghu Bay in Lake Taihu,the sulfur derivatives pollutants were extracted by head space solid phase microextraction（HS-SPME） and the odor substance was identified by gas chromatography and mass spectrometry（GC-MS）.Decomposed simulation was conducted in closed tube of water and cyanobacteria samples collected from Gonghu Bay in Lake Taihu.The cyanobacteria rotten odor substances was analyzed and detected by HS-SPME-GC-MS for 10 days.The sulfur derivative pollutant was expounded.[Result]The primary or secondary metabolites by cyanobacteria in water samples such as β-cyclocitral,indol,methylphenol,mercaptan and thioether were detected with scan.During the decomposition process,the emission of β-cyclocitral changed little.The maximum emission of dimethyl trisulfide appeared on the seventh and eighth day.The maximum emission of dimethyl disulfide appeared on the forth day.The maximum emission of the diethyl sulfide was on the eighth and ninth day.The maximum concentration of dimethyl trisulfide was 2 344.79 ng/L,which was much more than the olfactory threshold.[Conclusion] The sewage in Gonghu Bay in the end of May in 2007 resulted from the accumulation of cyanobacteria.

Emission characteristics and combustion instabilities in an oxy-fuel swirl-stabilized combustor

This paper presents an experimental study on the emission characteristics and combustion instabilities of oxy-fuel combustions in a swirl-stabilized combustor. Different oxygen concentrations (Xoxy=25%～45%, where Xoxy is oxygen concentra- tion by volume), equivalence ratios (φ=0.75～1.15) and combustion powers (CP=1.08～2.02 kW) were investigated in the oxy-fuel (CH4/CO2/O2) combustions, and reference cases (Xoxy=25%～35%, CH4/N2/O2 flames) were covered. The results show that the oxygen concentration in the oxidant stream significantly affects the combustion delay in the oxy-fuel flames, and the equivalence ratio has a slight effect, whereas the combustion power shows no impact. The temperature levels of the oxy-fuel flames inside the combustion chamber are much higher (up to 38.7%) than those of the reference cases. Carbon monoxide was vastly produced when Xoxy>35% or φ>0.95 in the oxy-fuel flames, while no nitric oxide was found in the exhaust gases because no N2 participates in the combustion process. The combustion instability of the oxy-fuel combustion is very different from those of the reference cases with similar oxygen content. Oxy-fuel combustions excite strong oscillations in all cases studied Xoxy=25%～45%. However, no pressure fluctuations were detected in the reference cases when Xoxy>28.6% accomplished by heavily sooting flames which were not found in the oxy-fuel combustions. Spectrum analysis shows that the frequency of dynamic pressure oscillations exhibits randomness in the range of 50～250 Hz, therefore resulting in a very small resultant amplitude. Temporal oscillations are very strong with amplitudes larger than 200 Pa, even short time fast Fourier transform (FFT) analysis (0.08 s) shows that the pressure amplitude can be larger than 40 Pa.

Impacts of Migration on Urban Environmental Pollutant Emissions in China: A Comparative Perspective

In recent years,researchers have devoted considerable attention to identifying the causes of urban environmental pollution.To determine whether migrant populations significantly affect urban environments,we examined the relationship between urban environmental pollutant emissions and migrant populations at the prefectural level using data obtained for 90 Chinese cities evidencing net in-migration.By dividing the permanent populations of these cities into natives and migrants in relation to the population structure,we constructed an improved Stochastic Impacts by Regression on Population,Affluence and Technology model(STIRPAT)that included not only environmental pollutant emission variables but also variables on the cities’attributes.We subsequently conducted detailed analyses of the results of the models to assess the impacts of natives and migrants on environmental pollutant emissions.The main findings of our study were as follows:1)Migrant populations have significant impacts on environmental emissions both in terms of their size and concentration.Specifically,migrant populations have negative impacts on Air Quality Index(AQI)as well as PM2.5 emissions and positive impacts on emissions of NO2 and CO2.2)The impacts of migrant populations on urban environmental pollutant emissions were 8 to 30 times weaker than that of local populations.3)Urban environmental pollutant emissions in different cities differ significantly according to variations in the industrial structures,public transportation facilities,and population densities.

Mercury emission and pollution in Chongqing City, China

Investigation showed that mercury emission in Chongqing City, China is about 2.1 t/a, 70% of which came from coal burning.Mercury in many water bodies have been detected, in vegetables and milk had exceeded the food standard value in some places.

Quantifying the emission＇s impact of coal mining activities on the environment and human health in process

Discharges and emissions in the coal mining process have a strong effect both on the environment and on human health. This problem is usually be a negative one and has only been recognized qualitatively, due to the lack of effective quantitative methods. Based on emergy theory and accounting methodology, a set of quantitative methods for accounting the environmental support due to pollutants emissions was first introduced. Then impacts on environment and effects on human health were quantified using the unified units. The results indicated that water pollutants caused more impacts on the environment than air pollutants did, i.e., more environmental contributions are needed to dilute and absorb water pollutants. The occupation of land caused by coal mining gangue waste stacking has led to a huge loss of environmental services over the years. Moreover, the potential damage on the human condition health caused by CO2 through climate change cannot be ignored. Finally, the impacts of mining activities on environmental and human health in unified units are shown to provide a quantitative insight into the disadvantage of coal mining. The comparable results of the method indicate the different influence of various pollutants and the contribution of ＇natural capital＇ directly. This work is a part of ongoing thermodynamic input-output analysis and life cycle analysis of coal mining systems （which are in process.）

Combustion and emission characteristics of diesel/n-butanol blends with split-injection and exhaust gas recirculation stratification

Oxygen fuels have broad application prospects and great potential for realizing efficient and clean combustion,and hence this study applies diesel/n-butanol blends to explore the influence of split-injection strategy on combustion and emission characteristics.Simultaneously,changing the way of exhaust gas recirculation(EGR)gas introduction forms uneven in-cylinder components distribution,and utilizing EGR stratification optimizes the combustion process and allows better emission results.The results show that the split-injection strategy can reduce the NO_(x)emissions and keep smoke opacity low compared with the single injection,but the rise in accumulation mode particles is noticeable.NO_(x)emissions show an upward trend as the injection interval expands,while soot emissions are significantly reduced.The increase in pre-injection proportion causes the apparent low-temperature heat release,and the two-stage heat release can be observed during the process of main combustion heat release.More pre-injection mass makes NO_(x)gradually increase,but smoke opacity reaches the lowest point at 15%pre-injection proportion.EGR stratification can optimize the emission results under the split injection strategy,especially the considerable suppression of accumulation mode particulate emissions.Above all,fuel stratification coupled with EGR stratification is beneficial for further realizing the in-cylinder purification of pollutants.

Study on the Environmental Quality Guarantee Ratio on the Basis of Total Air Pollutant Emission Amount Control

The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollutant emission is permitted under the total air pollutant emission amount control (TAPEAC) on the basis of A-value method. So the concept of the environmental quality guarantee ratio (EQGR) for TAPEAC is advanced in this paper and its quantitative formula is figured out for both hourly and daily EQGR. It is concluded that the EQGR is related with the yearly arrangement of A-value besides the pollutant type. According to the meteorological data in a lower area along Yangtze River in 2000, the yearly A-value trend is analyzed. Based on the data, the hourly EQGR of SO 2 and NO 2 is respectively 97.4% and 90.2%, and daily EQGR respectively 90.2% and 79.5%.

Analysis of the Influence of Fuel Additives on Automobile Exhaust Emission

In order to investigate the effect of a certain type of fuel additives on the emission and performance of vehicles,according to the Limits and Measurement Methods for Exhaust Pollutants from Vehicles Equipped Ignition Engine under Two-speed Idle Conditions and Simple Driving Mode Conditions(GB 18285-2005),the double idle method is used to detect the emission changes of different vehicles before and after the use of a certain type of fuel additives,and then the fuel consumption and power are evaluated.The results show that the use of fuel additives and the appropriate selection of fuel can effectively reduce the emissions of vehicle pollutants,which is of great significance for energy saving and emission reduction.

Life-Cycle Analysis of Bio-Ethanol Fuel Emissions of Transportation Vehicles in Greater Houston Area

Study is conducted on the life cycle assessment of bio-ethanol used for transportation vehicles and their emissions. The emissions that are analyzed include greenhouse gases, volatile organic compounds, sulfur oxide, carbon monoxide, nitrous oxide, particulate matter with the size less than 10 and 2.5 microns. Furthermore, various blends of bio-ethanol and gasoline are studied to learn about the impacts of higher blend on emissions. The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model software are used to simulate for emissions. The research analyzes two pathways of emissions: Well-to-Pump and Pump-to-Vehicle analyses. It is found that the fuel cell vehicles using 100% bio-ethanol have shown the most reduction in the amount of all the pollutants from the Pump-to-Vehicle emission analysis. The Well-to-Pump analysis shows that only greenhouse gases (GHGs) reduce with higher blends of bio-ethanol. All other pollutants VOC, CO, NOx, SOx, PM10 and PM2.5 emissions increase with the higher blending ratios. The Pump-to-Vehicle analysis shows that all the pollutant emissions reduce with the percentage increase of bio-ethanol in the fuel blends.

Investigation of the Effects of a Large Percentage of Dried Sludge on the Operation of a Coal-Fired Boiler

A 600 MW coal-fired boiler with a four-corner tangential combustion mode is considered here to study the combustion features and pollutant emissions at different loads for large-percentages of blending dried sludges.The influence of the over-fired air(OFA)coefficient is examined and the impact of the blending ratio on the boiler operation is explored.The results show that for low blending ratios,a slight increase in the blending ratio can improve the combustion of bituminite,whereas a further increase leads to the deterioration of the combustion of blended fuels and thus reduces the boiler efficiency.Enhancing the supporting capability of the secondary air effectively reduces the slagging degree in the bottom ash hopper and improves the burnout rate of coals.For a large-percentage blending case at full load,it is found that the OFA coefficient must be reduced appropriately,otherwise,a secondary high-temperature combustion zone can be generated in the vicinity of the furnace arches,causing high temperature slagging and superheater tube bursting.Considering the influences of combustion and pollutant emissions,the recommended OFA coefficient is 0.2.Blending dried sludge under low loads increases the flue gas temperature at the furnace exit.While reducing the flue gas temperature in the main combustion region,which is beneficial to the safe operation of the denitrification system.Increasing the blending ratio and reducing load lead to an increase in NOx concentration at the furnace exit Sludges with low nitrogen content are suggested for the practical operation of boilers.

Quantifying China's iron and steel industry's CO2 emissions and environmental health burdens:A pathway to sustainable transformation

Assessing the iron and steel industry's(ISI)impact on climate change and environmental health is vital,particularly in China,where this sector significantly influences air quality and CO_(2)emissions.There is a lack of comprehensive analyses that consider the environmental and health burdens of manufacturing processes for ISI enterprises.Here,we present an integrated emission inventory that encompasses air pollutants and CO_(2)emissions from 811 ISI enterprises and five key manufacturing processes in 2020.Our analysis shows that sintering is the primary source of air pollution in the ISI.It contributes 71%of SO_(2),73%of NO_(x),and 54%of PM_(2.5)emissions.On the other hand,81%of total CO_(2)emissions come from blast furnaces.Significantly,the contributions of ISI have resulted in an increase of 3.6 mg m^(-3)in national population-weighted PM_(2.5)concentration,causing approximately 59,035 premature deaths in 2020.Emissions from Hebei,Jiangsu,Shandong,Shanxi,and Inner Mongolia provinces contributed to 48%of PM_(2.5)-related deaths in China.Moreover,the transportation of air pollutants across provincial borders highlights a concerning trend of environmental health inequality.Based on the research findings,it is crucial for ISI manufacturers to prioritize the removal of outdated production capacities and adopt energy-efficient and advanced techniques,along with ultra-low emission technologies.This is particularly important for those manufacturers with substantial environmental footprints.These transformative actions are essential in mitigating the environmental and health impacts in the affected regions.

Relationship between Urban Industrial Land Use Size and Sulfur Dioxide Emissions:Evidence from 294 Cities in China

Although the relationship between the size of urban industrial land use and pollutant emissions has been widely discussed from different perspectives(e.g.,the scale and crowding effects),the results of various studies have revealed positive,negative,and combined impact relationships.However,how the expansion of urban industrial land use affects SO_(2) emissions remains unknown.We need to clarify this relationship in order to facilitate the realization of China’s pollution reduction and emission reduction goals.This study used the panel data from 294 cities spanning from 2011 to 2019 to construct a spatial econometric model.The objective was to explore the correlation between the scale of urban industrial land and sulfur dioxide emissions in China.The results show that a large scale of urban industrial land use corresponds to lower sulfur dioxide emissions per unit of industrial added value.By gaining a deeper understanding of the relationship between the scale of urban industrial land use and sulfur dioxide emissions,policymakers can further reduce pollutant emissions by rationalizing the planning of urban industrial land use and industrial layout.In addition to promoting industrial agglomeration and economies of scale in cities with extensive industrial land use,this strategy can support the development of efficient and environmentally friendly industries in areas with limited industrial land use.Optimizing the technology and encouraging the development of green industries can help reduce environmental pollution and promote sustainable urban development.

LARGE-EDDY SIMULATION OF TWO-PHASE REACTING FLOW IN MODEL COMBUSTOR

The gas-droplet two-phase reacting flow in a model combustor with the V-gutter flame holder is studied by an Eulerian-Lagrangian large-eddy simulation (LES) approach. The k-equation subgrid-scale model is used to simulate the subgrid eddy viscosity, and the eddy-break-up (EBU) combustion subgrid-scale model is used to determine the chemical reaction rate. A two-step turbulent combustion subgrid-scale model is employed for calculating carbon monoxide CO concentration, and the NO subgrid-scale pollutant formation model for the evaluation of the rate of NO formation. The heat flux model is applied to the prediction of radiant heat transfer. The gas phase is solved with the SIMPLE algorithm and a hybrid scheme in the staggered grid system. The liquid phase equations are solved in a Lagrangian frame in reference of the particle-source-in-cell (PSIC) algorithm. From simulation results, the exchange of mass, moment and energy between gas and particle fields for the reacting flow in the afterburner with a V-gutter flame holder can be obtained. By the comparison of experimental and simulation results, profile temperature and pollutant of the outlet are quite in agreement with experimental data. Results show that the LES approach for predicting the two-phase instantaneous reacting flow and pollutant emissions in the afterburner is feasible.

How Do Power Enterprises Deal with Total Quantity Control

This paper describes the relation and difference of "emission up to standards" and "total quantity control" ofmain atmospheric pollutants, as well as their legal status. It points out that the total quantity control is a good approachto solve a problem that environmental quality do not yet reach the requirements in an area where emission concentrationhas came up to standards, or to solve a problem that the interregional transportation of pollutants (e. g. acid rain) arises.And further, it put forward five proposals for the total quantity control.[

Development and testing of a detailed kinetic mechanism of natural gas combustion in internal combustion engine

A detailed chemical mechanism to describe the combustion of natural gas in internal combustion （IC） engine has been developed,which is consisting of 233 reversible reactions and 79 species.This mechanism accounts for the oxidation of methane,ethane,propane and nitrogen.It has been tested using IC engine model of CHEMKIN 4.1.1 and experimental measurements.The performance of the proposed mechanism was evaluated at various equivalence ratios （φ=0.6 to φ=1.3）,initial reactor conditions （Tini=500 to 3500 ℃; Pini=1.0 to 10 atm） and engine speed （2000-7000 rpm）.The proposed kinetic mechanism shows good concordances with GRI3.0 mechanism especially in the prediction of temperature,pressure and major product species （H2O,CO2） profiles at stoichiometric conditions （φ=1.0）.The experimental results of measured cylinder pressure,species fractions were also in agreement with simulation results derived from the proposed kinetic mechanism.The proposed mechanism successfully predicts the formation of gaseous pollutants （CO,NO,NO2,NH3） in the engine exhaust.Although there are some discrepancies among each simulation profile,the proposed detailed mechanism is good to represent the combustion of natural gas in IC engine.

Quantification of emission reduction potentials of primary air pollutants from residential solid fuel combustion by adopting cleaner fuels in China

Residential low efficient fuel burning is a major source of many air pollutants produced during incomplete combustions, and household air pollution has been identified as one of the top environmental risk factors. Here we compiled literature-reported emission factors of pollutants including carbon monoxide（CO）, total suspended particles（TSPs）, PM2.5, organic carbon（OC）,elemental carbon（EC） and polycyclic aromatic hydrocarbons（PAHs） for different household energy sources, and quantified the potential for emission reduction by clean fuel adoption. The burning of crop straws, firewood and coal chunks in residential stoves had high emissions per unit fuel mass but lower thermal efficiencies, resulting in high levels of pollution emissions per unit of useful energy, whereas pelletized biofuels and coal briquettes had lower pollutant emissions and higher thermal efficiencies. Briquetting coal may lead to 82%–88% CO, 74%–99%TSP, 73%–76% PM2.5, 64%–98% OC, 92%–99% EC and 80%–83% PAH reductions compared to raw chunk coal. Biomass pelletizing technology would achieve 88%–97% CO, 73%–87% TSP, 79%–88%PM2.5, 94%–96% OC, 91%–99% EC and 63%–96% PAH reduction compared to biomass burning. The adoption of gas fuels（i.e., liquid petroleum gas, natural gas） would achieve significant pollutant reduction, nearly 96% for targeted pollutants. The reduction is related not only to fuel change, but also to the usage of high efficiency stoves.

Numerical Study of Air Nozzles on Mild Combustion for Application to Forward Flow Furnace

An attempt was made to extend mild combustion to forward flow furnace, such as the refinery and petrochemical tube furnace. Three dimensional numerical simulation was carried out to study the performance of this furnace. The Eddy Dissipation Concept(EDC) model coupled with the reaction mechanism DRM-19 was used. The prediction showed a good agreement with the measurement. The effect of air nozzle circle(D), air nozzle diameter(d), air nozzle number(N), and air preheating temperature(Tair) on the flow, temperature and species fields, and the CO and NO emissions was investigated. The results indicate that there are four zones in the furnace, viz.: a central jet zone, an ignition zone, a combustion reaction zone, and a flue gas zone, according to the distribution profiles of H_2 CO and OH. The central jet entrains more flue gas in the furnace upstream with an increasing D while the effect of D is negligible in the downstream. The air jet momentum increases with a decreasing d or an increasing Tair, and entrains more flue gas. The effect of N is mainly identified near the burner exit. More heat is absorbed in the radiant section and less heat is discharged to the atmosphere with a decreasing d and an increasing N as evidenced by the flue gas temperature. The CO and NO emissions are less than 50 μL/L and 10 μL/L, respectively, in most of conditions.

Opacity Evaluation for Passenger Diesel Vehicle Cars in Tirana

The study includes both the estimation and evaluation of the gas smoke opacity exhausted by a diesel vehicle engine and the opacity control. The evaluation and estimations were accomplished by MAHA sottware. This research work has been focused in the evaluation of the opacity coefficient and the sources that can influence in opacity value of the vehicles used in Albania.