Implementation of the Concept of Energy and Technological Compliance of Components in the Technology of Fluorocomposites

Structural and technological aspects of obtaining and processing functional composite materials based on PTFE(polytetrafluoroethylene)are considered.It is shown that,due to the features of the molecular structure of the matrix polymer,within the framework of the traditional technological paradigm,prerequisites are created for the implementation of a structural paradox,which manifests itself in a decrease in the parameters of the stress-strain and tribological characteristics of composites with an increase in the degree of filling.Within the framework of the concept of multilevel modification,methodological approaches to the implementation of the energy and technological compliance of components,which reduce the negative impact of the structural paradox,are considered.

Theoretical Study on Xe…N non-Covalent Interactions:Three Hybridization N with XeO_(3) and XeOF_(2)

The interactions of complexes of XeOF_(2) and XeO_(3) with a series of different hybridization N-containing donors are studied by means of DFT and MP_(2) calculations.The aerogen bonding interaction energies range from 6.5 kcal/mol to19.9 kcal/mol between XeO_(3) or XeOF_(2) and typical N-containing donors.The sequence of interaction for N-containing hy-bridization is sp^(3)>sp^(2)>sp,and XeO_(3)is higher than XeOF_(2).For some donors of sp^(2)and sp^(3) hybridization,the steric effect plays a minor role in the interaction with the evidence of reduced density gradient plots.The dominant stable part is the electrostatic interaction.In complex of XeO_(3),the weight of polarization is larger than dispersion,while the situation is opposite for XeOF_(2)complexes.Except for the sum of the maximum value of molecular electrostatic potential on Xe atom and minimum value of molecular electrostatic potential on N atom,the other five interaction parameters including the potential energy density at bond critical point,the equilibrium distances,interaction energies with the basis set superposition error correction,localized molecular orbital energy decomposition analysis interaction energies,and the electron charge density,show great linear correlation coefficients with each other.

IMPROVED COVARIANCE DRIVEN BLIND SUBSPACE IDENTIFICATION METHOD

An improved covariance driven subspace identification method is presented to identify the weakly excited modes. In this method, the traditional Hankel matrix is replaced by a reformed one to enhance the identifiability of weak characteristics. The robustness of eigenparameter estimation to noise contamination is reinforced by the improved Hankel matrix, in combination with component energy index （CEI） which indicates the vibration intensity of signal components, an alternative stabilization diagram is adopted to effectively separate spurious and physical modes. Simulation of a vibration system of multiple-degree-of-freedom and experiment of a frame structure subject to wind excitation are presented to demonstrate the improvement of the proposed blind method. The performance of this blind method is assessed in terms of its capability in extracting the weak modes as well as the accuracy of estimated parameters. The results have shown that the proposed blind method gives a better estimation of the weak modes from response signals of small signal to noise ratio （SNR）and gives a reliable separation of spurious and physical estimates.

Kazakhstan-China Pipeline Pours 4 Million Tons of Oil into China in 1st Year

China has imported 4 million tons of oil through the Kazakhstan-China pipeline in its first year of operation, customs officials said.

Optimal Initialization and Starting Approach of Synchronous Condenser Integrated Power Grid

Synchronous condensers(SCs)are generally used at the receiving-end stations of ultra-high-voltage direct current(UHVDC)transmission systems due to their strong reactive power support and flexible regulation of reactive power according to the interconnected grids operating conditions.In this paper,different starting control schemes of a SC integrated power grid are investigated providing four main contributions:1)The principle of reactive power support of the SC on the interconnected power grid is analytically studied,providing the establishment of mathematical models.2)Four different starting control schemes are developed for the initialization and SC integration,i.e.in Scheme 1,a preset initial falling speed is directly utilized without initialization;in Scheme 2,a black start sequential control approach with a static frequency converter(SFC)is proposed;in Scheme 3,PI/PD/PID controllers are respectively applied for the excitation device at the speed-falling stage;in Scheme 4,a pre-insertion approach of an energy absorption component with R/L/RL is utilized to suppress the surges at the SC integration instant.3)The dynamic behaviors of four different starting schemes at specific operating stages are evaluated.4)The success rate of SC integration is analyzed to evaluate starting control performance.Performance of the SC interconnected system with four different starting control schemes is evaluated in the timedomain simulation environment PSCAD/EMTDC^(TM).The results prove the superiority of the proposed starting control approach in Scheme 4.

Surface-induced Microstructure and Performance Changes in P3HT Ultrathin Films

In this work,poly(3-hexylthiophene)(P3HT)ultrathin films(P3HT-T)were prepared by spin-coating a dilute P3HT solution(in a toluene:o-dichlorobenzene(Tol:ODCB)blend with a volume ratio of 80:20)with ultrasonication and the addition of the nucleating agent bicycle[2.2.1]heptane-2,3-dicarboxylic acid disodium salt(HPN-68L)on glass,Si wafers and indium tin oxide(ITO)substrates.The electrical and mechanical properties of the P3HT-T ultrathin films were investigated,and it was found that the conductivity and crack onset strain(COS)were simultaneously improved in comparison with those of the corresponding pristine P3HT film(P3HT-0,without ultrasonication and nucleating agent)on the same substrate,regardless of what substrate was used.Moreover,the conductivity of P3HT-T ultrathin films on different substrates was similar(varying from 3.7 S·cm^(-1)to 4.4 S·cm^(-1)),yet the COS increased from 97%to 138%by varying the substrate from a Si wafer to ITO.Combining grazing-incidence wide-angle X-ray diffraction(GIXRD),UV-visible(UV-Vis)spectroscopy and atomic force microscopy(AFM),we found that the solid order and crystallinity of the P3HT-T ultrathin film on the Si wafer are highest,followed by those on glass,and much lower on ITO.Finally,the surface energy and roughness of three substrates were investigated,and it was found that the polar component of the surface energyγp plays a critical role in determining the crystalline microstructures of P3HT ultrathin films on different substrates.Our work indicates that the P3HT ultrathin film can obviously improve the stretchability and simultaneously retain similar electrical performance when a suitable substrate is chosen.These findings offer a new direction for research on stretchable CP ultrathin films to facilitate future practical applications.

Spatial distribution of surface energy fluxes over the Loess Plateau in China and its relationship with climate and the environment

China's Loess Plateau is located at the edge of the Asian summer monsoon in a transition zone of climate and ecology. In the Loess Plateau, climate and environments change along with space, which has an obvious impact on the spatial distribution of surface energy fluxes. Because of scarce land-surface observation sites and short observation time in this area, previous studies have failed to fully understand the land-surface energy balance characteristics over the entire the Loess Plateau and their effect mechanisms. In this paper, we first test the simulation ability of the Community Land Model(CLM) model by comparing its simulated data with observed data. Based on the simulation data for the Loess Plateau over the past thirty years, we then analyze the spatial distribution of surface energy fluxes and compare the pattern differences between the area averages for the driest year and wettest year. Furthermore, we analyze the relationship between the spatial distribution of the components of the surface energy balance with longitude, latitude, altitude, precipitation and temperature. The main results are as follows: the spatial distribution of surface energy fluxes are significantly different, with the surface net radiation and sensible heat flux increasing from south to north and latent heat flux and soil heat flux decreasing from southeast to northwest. The sensible heat flux at the driest point is nearly twice as high as that at the wettest point, whereas the latent heat flux and soil heat flux at the driest point are half as much as that at the wettest point. The impact of variations of annual precipitation on the components of the surface energy balance is also obvious, and the maximum magnitude of the changes to the sensible heat flux and latent heat flux is nearly 30%. To a certain extent, geographical factors(including longitude, latitude, and altitude) and climate factors(including temperature and precipitation) affect the surface energy fluxes. However, the surface net radiation is more closely related to latitude and altitude, sensible heat flux is more closely related to the monsoon rainfall and latitude, and latent heat flux and soil heat flux are more closely related to the monsoon rainfall.