Glass-compatible and self-powered temperature alarm system by temperature-responsive organic manganese halides via backward energy transfer process

A pioneering glass-compatible transparent temperature alarm system self-powered by luminescent solar concentrators(LSCs) is reported.Single green-emitted organic manganese halides(OMHs) of PEA_(2)MnBr_(2)I_(2),which has a unique temperature-dependent backward energy transfer process from selftrapped state to^(4)T_(1)energy level of Mn,is used for triggering the temperature alarm.The LSC with redemitted CsPbI_(3)perovskite-polymer composite films on the glass substrate is used for power supply.The spectrally separated nature between the green-emitted OMHs for temperature alarm and red-emitted CsPbI3in LSC for power supply allows for probing the signal light of temperature-responsive OMHs without the interference of LSCs,making it possible to calibrate the temperature visually just by a self-powered brightness detection circuit with LED indicators.Taking advantage of LSC without hot spot effects plaguing the solar cells,as-prepared temperature alarm system can operate well on both sunny and cloudy day.

Main Energy Paths and Energy Cascade Processes of the Two Types of Persistent Heavy Rainfall Events over the Yangtze River–Huaihe River Basin

Two types of persistent heavy rainfall events （PHREs） over the Yangtze River-Huaihe River Basin were determined in a recent statistical study： type A, whose precipitation is mainly located to the south of the Yangtze River; and type B, whose precipitation is mainly located to the north of the river. The present study investigated these two PHRE types using a newly derived set of energy equations to show the scale interaction and main energy paths contributing to the persistence of the precipitation. The main results were as follows. The available potential energy （APE） and kinetic energy （KE） associated with both PHRE types generally increased upward in the troposphere, with the energy of the type-A PHREs stronger than that of the type-B PHREs （except for in the middle troposphere）. There were two main common and universal energy paths of the two PHRE types： （1） the baroclinic energy conversion from APE to KE was the dominant energy source for the evolution of large-scale background circulations; and （2） the downscaled energy cascade processes of KE and APE were vital for sustaining the eddy flow, which directly caused the PHREs. The significant differences between the two PHRE types mainly appeared in the lower troposphere, where the baroclinic energy conversion associated with the eddy flow in type-A PHREs was from KE to APE, which reduced the intensity of the precipitation-related eddy flow; whereas, the conversion in type-B PHREs was from APE to KE, which enhanced the eddy flow.

High Energy and High Coercivity Sintered NdFeB Magnets by Low Oxygen Process

Using ball milling and single direction pressing, we can produce high performance NdFeB sintered magnets. The oxygen content of sintered magnets can be controlled under 1500xl0^-6 and the magnetic performance can be improved by using low oxygen processing. The high preformance NdFeB sintered magnets with Br=(1.4 ± 0.2)T, iHc>796 kA/m and (BH)max=(390± 16) kJ/m^3, have been batch produced.

Ehrenfest Approach to the Adiabatic Invariants and Calculation of the Intervals of Time Entering the Energy Emission Process in Simple Quantum Systems

In the first step, the Ehrenfest reasoning concerning the adiabatic invariance of the angular orbital momentum is applied to the electron motion in the hydrogen atom. It is demonstrated that the time of the energy emission from the quantum level n+1 to level n can be deduced from the orbital angular momentum examined in the hydrogen atom. This time is found precisely equal to the time interval dictated by the Joule-Lenz law governing the electron transition between the levels n+1 and n. In the next step, the mechanical parameters entering the quantum systems are applied in calculating the time intervals characteristic for the electron transitions. This concerns the neighbouring energy levels in the hydrogen atom as well as the Landau levels in the electron gas submitted to the action of a constant magnetic field.

Optimal Size for Maximal Energy Efficiency in Information Processing of Biological Systems Due to Bistability

Energy efficiency is closely related to the evolution of biological systems and is important to their information processing. In this work, we calculate the excitation probability of a simple model of a bistable biological unit in response to pulsatile inputs, and its spontaneous excitation rate due to noise perturbation. Then we analytically calculate the mutual information, energy cost, and energy efficiency of an array of these bistable units. We find that the optimal number of units could maximize this array＇s energy efficiency in encoding pulse inputs, which depends on the fixed energy cost. We conclude that demand for energy efficiency in biological systems may strongly influence the size of these systems under the pressure of natural selection.

Hot Vertical-Displacement-Event Process due to Internal Energy Perturbations for HL-2M Tokamak Plasma

During the tokamak operation, variation of the stored energy can cause internal perturbations of the plasma. These perturbations may develop into large-scale vertical movement of the whole column for the vertically elon- gated tokamak, eventually generating the hot vertical displacement event （VIDE,）. It will cause considerable damage to the machine. In this work, the hot VDE process due to stored energy perturbations is investigated by a mature non-linear time-evolution code DINA. The influence on the vertical instability, the displacement direction and the electromagnetic loads on in-vessel components during the hot VDE are analyzed. It is shown that a larger perturbation leads to faster development of the vertical instability. Meanwhile the variation of the Shafranov shift, due to the energy change, is related to the VDE direction. The vertical electromagnetic force on the vacuum vessel and the halo current flowing in the divertor baffle become larger in the case of VDE moving towards the X point.

An Energy Saving Glass Deep Processing Line Put into Production in Hubei

On July 16, 2013, the first low-E energy saving glass deep processing line of Hubei Zhongyi Glass Co., Ltd. was put into production in Changyang County of Hubei Province. Low-E glass is a kind of new glass featured with good lighting, thermal insulation, and ultraviolet radiation resistance. So far contracts worth about CNY 50 million have been signed.

Electron-Vibrational Energy Exchange in Nitrogen-Containing Plasma:a Comparison Between an Analytical Approach and a Kinetic Model

This paper investigates the electron-vibrational（e-V）energy exchange in nitrogencontaining plasma,which is very efficient in the case of gas discharge and high speed flow.Based on Harmonic oscillator approximation and the assumption of the e-V relaxation through a continuous series of Boltzmann distributions over the vibrational states,an analytic approach is derived from the proposed scaling relation of e-V transition rates.A full kinetic model is then investigated by numerically solving the state-to-state master equation for all vibrational levels.The analytical approach leads to a Landau-Teller（LT）-type equation for relaxation of vibrational energy,and predicts the relaxation time on the right order of magnitude.By comparison with the kinetic model,the LT-type equation is valid in typical electron temperatures in gas discharge.However,the analytical approach is not capable of describing the vibrational distribution function during the e-V process in which a full kinetic model is required.

Pore Formation Mechanism in W-C Hard Coatings Using Directed Energy Deposition on Tungsten Alloy

Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy deposition(DED)are systematically investigated.The forming quality of the tracks,the distribution of the pores,and the elemental distribution near the pores are analyzed by the observations of the cross-sections of the tracks.The temperature field of the melt pool is discussed comprehensively to reveal the pore formation mechanism.The results confirm that Ni and Co evaporated during the DED process due to the high temperature of the melt pool.Pores were continuously produced adjacent to the fusion line when the melt pool was about to solidify since the temperature at the solidification front was higher than the boiling point of Ni.The vaporization area at the fusion line was proposed,where Ni could also evaporate at the time the melt pool started to solidify.The relationship between the solidification rate,the size of the vaporization area and the DED parameters(laser power and scanning speed)was established to discuss the causes of severe pores above the fusion line.This work contains a practical guide to reduce or eliminate the porosity in the coating preparation process on the surface of the tungsten alloy.

A Novel Control Strategy of PWM Rectifier with LCL Filter Under Unbalanced Grid Condition

The paper presents a successful design and good result of grid voltage feed-forward control strategy with no damping regulator of LCL filter applied in Three-phase Pulse Width Modulation( PWM) rectifier under unbalance grid condition for renewable energy processing. It is demonstrated that the closed-loop current control is decoupled with the grid voltage feed-forward control,and good waveform of grid current with low order harmonics is obtained under unbalance grid condition. This novel strategy is simple and reliable,applied with PI regulator but no resonant controller in α,β two-phase stationary frame. Moreover,the results of experiment and simulation are also illustrated to validate the novel strategy well applied in the closed-loop current control system under unbalanced grid condition.

An input-output model for energy accounting and analysis of industrial production processes： a case study of an integrated steel plant

To promote sustainability, it has become increasingly vital to properly account material and energy flows in industrial production processes. Therefore, a generic process-level input-output （IO） model was developed to provide an integrated energy （material） accounting and analysis approach for industrial production processes. By extending the existing processlevel IO models, the production, usage, export and loss of by-products were explicitly considered in the proposed IO model. Moreover, the by-products allocation procedures were incorporated into the proposed IO model to reflect individual contributions of products to energy consumption. Finally, the proposed model enabled calculating embodied energy of main products and total energy consumption under hierarchical accounting scope. Plant managers, energy management consultants, governmental officials and academic researchers could use this input-output model to account material and energy flows, thus calculating energy consumption indicators of a production process with their specific system boundary requirements. The accounting results could be further used for energy labeling, identifying bottlenecks of production activities, evaluating industrial symbiosis effects, improving materials and energy utilization efficiency, etc. The model could also be used as a planning tool to determine the effect that a particular change of technology and supply chains may have on the industrial production processes. The proposed model was tested and applied in a real integrated steel mill, which also provided the reference results for related researches. At last, some concepts, computational issues and limi- tations of the proposed model were discussed.

Luminescence Characteristic of a New Novel Coprecipitate Rare Earth Complexes

The Tb 3+ ion was introduced in the Tb x Eu 1- x (BSA) 3phen as a bridge to make the energy transfer process from ligand to the Eu 3+ complex more efficient. The characteristics of the device used Tb x Eu 1- x (BSA) 3phen as the emission material with the different ratio of x were discussed. When x is 0.5, the device emits pure red color with the maximal brightness of 100 cd·m -2 and has good commutation property. The role of the Tb 3+ ion in the energy transfer process between the ligand and the Eu 3+ ion and the mechanism of energy transfer process were also discussed.

White emission from Tm^(3+)/Tb^(3+)/Eu^(3+) co-doped fluoride zirconate under ultraviolet excitation

We synthesize Tm3＋/Tb3＋/Eu3＋ triply-doped ZrF4-BaF2-LaF3-A1F3-NaF （ZBLAN） transparent glass by using a melt-quenching method. Under excitation of 365 nm, the white emission with Commission internationale deL＇Eclairage （CIE） coordinates of （0.33, 0.33） is achieved at the Eu3＋ concentration of 1.1 mol%. The mechanisms for white emission and the energy transfer process of Tb3＋→ Eu3＋ are discussed in terms of the photoluminescence, photoluminescence excitation spectra, and the light emission decay curves. The nature for the Tb3＋ → Eu3＋ energy transfer is described with the aid of an energy level diagram.

Luminescent characteristics of Tm^(3+)/Tb^(3+)/Eu^(3+) tri-doped Na_(5)Y_(9)F_(32) single crystals for white emission with high thermal stability

By using an improved Bridgman method,0.3 mol%Tm^(3+)/0.6 mol%Tb^(3+)/y mol%Eu^(3+)(y=0,0.4,0.6,0.8)doped Na_(5)Y_(9)F_(32)single crystals were prepared.The x-ray diffraction,excitation spectra,emission spectra and fluorescence decay curves were used to explore the crystal structure and optical performance of the obtained samples.When excited by 362 nm light,the cool white emission was realized by Na_(5)Y_(9)F_(32)single crystal triply-doped with 0.3 mol%Tm^(3+)/0.6 mol%Tb^(3+)/0.8 mol%Eu^(3+),in which the Commission Internationale de l’Eclairage(CIE)chromaticity coordinate was(0.2995,0.3298)and the correlated color temperature(CCT)was 6586 K.The integrated normalized emission intensity of the tridoped single crystal at 448 K could keep 62%of that at 298 K.The internal quantum yield(QY)was calculated to be~15.16%by integrating spheres.These results suggested that the single crystals tri-doped with Tm^(3+),Tb^(3+)and Eu^(3+)ions have a promising potential application for white light-emitting diodes(w-LEDs).

Calculation of vibrational energy transition rates in acoustic relaxation processes for excitable gas molecules

To research the correlation between vibrational energy transition rates and acoustic relaxation processes in excitable gases, the vibrational relaxation theory provided by Tanczos [J. Chem. Phy3. 25, 439 （1956）] is applied to calculate the energy transition rates of Vibrational- Vibrational （V-V） and Vibrational-Translational （V-T） energy transfer in gas mixtures. The results of calculation for the multi-relaxation processes in various gas mixtures, consisting of carbon dioxide, methane, chlorine, nitrogen, and oxygen at room temperature, demonstrate that the acoustic energy stagnated in every vibrational mode is coupled with each other through V-V energy exchanges. The vibrational excitation energy will relax through the V-T de-excitation path of the lowest mode because of its fastest V-T transition rate, resulting in that only one absorption peak can be measured for most of excitable gas mixtures. Thus, an effective model is provided to analyze how the vibrational energy transition rates affect the characteristics of acoustic relaxation processes and acoustic propagation in excitable gas mixtures.

Mild construction of N-fused polycyclic compounds via Rh(Ⅲ)/EosinY co-catalyze C—H activation

The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported.This novel work has successfully realized LED irradiated C—H activation of iodonium ylides.The strategy shows wide substrate scope and ideal functional group tolerance.Our work would be useful for the construction of various heterocyclic compounds.

A new process to improve short-chain fatty acids and bio-methane generation from waste activated sludge

As an important intermediate product, short-chain fatty acids（SCFAs） can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS（6.8 times higher than the blank test） and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated.

The Observed Near-Surface Energy Exchange Processes over Arctic Glacier in Summer

Under Arctic warming,near-surface energy transfers have significantly changed,but few studies have focused on energy exchange over Arctic glacier due to limitations in available observations.In this study,the atmospheric energy exchange processes over the Arctic glacier surface were analyzed by using observational data obtained in summer 2019 in comparison with those over the Arctic tundra surface.The energy budget over the glacier greatly differed from that over the tundra,characterized by less net shortwave radiation and downward sensible heat flux,due to the high albedo and icy surface.Most of the incoming solar radiation was injected into the glacier in summer,leading to snow ice melting.During the observation period,strong daily variations in near-surface heat transfer occurred over the Arctic glacier,with the maximum downward and upward heat fluxes occurring on 2 and 6 July 2019,respectively.Further analyses suggested that the maximum downward heat flux is mainly caused by the strong local thermal contrast above the glacier surface,while the maximum upward heat transfer cannot be explained by the classical turbulent heat transfer theory,possibly caused by countergradient heat transfer.Our results indicated that the near-surface energy exchange processes over Arctic glacier may be strongly related to local forcings,but a more in-depth investigation will be needed in the future when more observational data become available.