Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES te...Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES technology advances,accommodating greater depth,higher temperature and multi-energy complementarity,new research challenges emerge.This paper comprehensively provides a systematic summary of the current research status of UTES.It categorized different types of UTES systems,analyzes the applicability of key technologies of UTES,and evaluate their economic and environmental benefits.Moreover,this paper identifies existing issues with UTES,such as injection blockage,wellbore scaling and corrosion,seepage and heat transfer in cracks,etc.It suggests deepening the research on blockage formation mechanism and plugging prevention technology,improving the study of anticorrosive materials and water treatment technology,and enhancing the investigation of reservoir fracture network characterization technology and seepage heat transfer.These recommendations serve as valuable references for promoting the high-quality development of UTES.展开更多
A significant driving force behind the brisk research on rechargeable batteries,particularly lithium-ion batteries(LiBs)in high-performance applications,is the development of portable devices and electric vehicles.Car...A significant driving force behind the brisk research on rechargeable batteries,particularly lithium-ion batteries(LiBs)in high-performance applications,is the development of portable devices and electric vehicles.Carbon-based materials,which have finite specific capacity,make up the anodes of LiBs.Many attempts are being made to produce novel nanostructured composite anode materials for LiBs that display cycle stability that is superior to that of graphite using graphene oxide.Therefore,using significant amounts of waste graphene oxide from used LiBs represents a fantastic opportunity to engage in waste management and circular economy.This review outlines recent studies,developments and the current advancement of graphene oxide-based LiBs,including preparation of graphene oxide and utilization in LiBs,particularly from the perspective of energy storage technology,which has drawn more and more attention to creating high-performance electrode systems.展开更多
As a flexible power source,energy storage has many potential applications in renewable energy generation grid integration,power transmission and distribution,distributed generation,micro grid and ancillary services su...As a flexible power source,energy storage has many potential applications in renewable energy generation grid integration,power transmission and distribution,distributed generation,micro grid and ancillary services such as frequency regulation,etc.In this paper,the latest energy storage technology profile is analyzed and summarized,in terms of technology maturity,efficiency,scale,lifespan,cost and applications,taking into consideration their impact on the whole power system,including generation,transmission,distribution and utilization.The application scenarios of energy storage technologies are reviewed and investigated,and global and Chinese potential markets for energy storage applications are described.The challenges of large-scale energy storage application in power systems are presented from the aspect of technical and economic considerations.Meanwhile the development prospect of global energy storage market is forecasted,and application prospect of energy storage is analyzed.展开更多
With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting la...With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting large power grids and multiple smart distribution grids interconnections using energy storage technology for improving the system dynamic stability was studied.The segmentation validity of the large power grids and smart distribution grid inverter output interconnections power system using energy storage technology was proved in terms of theoretical analysis.Then,the influences of the energy storage device location and capacity on the proposed method were discussed in detail.The conclusion is obtained that the ESD optimal locations are allocated at the tie line terminal buses in the interconnected grid,respectively.The effectiveness of the proposed method was verified by simulations in an actual power system.展开更多
It is obvious that in the next ten years,lithium ion batteries are still the dominating power source for a wide range of products including consumable electronics,vehicles(cars,motorbikes,scooters,buses),drones,and ev...It is obvious that in the next ten years,lithium ion batteries are still the dominating power source for a wide range of products including consumable electronics,vehicles(cars,motorbikes,scooters,buses),drones,and even robots and tanks.However,in the pursuit of cost-effective,safety-reliable,and highly efficient energy storage technologies,researchers are developing展开更多
The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, di...The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, discharge capacity and high rate dischargeability of the alloys are improved after physical and chemical modification as a result of the increase of the surface area and formation of the electrocatalysis layers, which increase both the electrochemical reaction rate on the alloy surface and H diffusion rate in the alloy bulk. It is also found that both the over-coarse and over-fine particle size increase the contact resistance of the electrode, resulting in a decrease of discharge capacity, deterioration of high rate dischargeability and lower discharge plateau. In another word, a suitable particle size distribution can enhance the alloy activity, discharge capacity and high rate dischargeability. In addition, the high rate dischargeability is enhanced by increasing La content and decreasing Ce content of the alloy composition because of enlargement of the unit cell volume and the improvement of the surface activity. Moreover, B additive resultes in the formation of the second phase, and makes the alloys easier pulverization, which greatly improves the activity, discharge capacity and high rate dischargeability.展开更多
The effects of low-Co AB_5 type hydrogen storage alloys prepared by quenchingand annealing on the performances of MH-Ni batteries were investigated, and the characteristics ofthe low-Co AB_5 type hydrogen storage allo...The effects of low-Co AB_5 type hydrogen storage alloys prepared by quenchingand annealing on the performances of MH-Ni batteries were investigated, and the characteristics ofthe low-Co AB_5 type hydrogen storage alloys were compared with those of the high-Co AB_5 typehydrogen storage alloy as well. The results showed that the faster the cooling of the low-Cohydrogen storage alloy is, the better homogeneity of the chemical composition for the alloy and thelonger cycle life of the battery are, but the electrochemical discharge capacity and high-ratedischarge ability are reduced. The high-rate discharge ability and charge retention of MH-Nibatteries for the conventional as-cast annealed low-Co hydrogen storage alloy were superior to thosefor the rapidly quenched low-Co hydrogen storage alloy and the high-Co hydrogen storage alloy, buta little inferior in the cycle life.展开更多
The increasing penetration of renewables in power systems urgently entails the utilization of energy storage technologies.As the development of energy storage technologies depends highly on the profitability in electr...The increasing penetration of renewables in power systems urgently entails the utilization of energy storage technologies.As the development of energy storage technologies depends highly on the profitability in electricity markets,to evaluate the economic potentials for various types of energy storage technologies under the compre-hensive market environment is of great significance.To this end,this study aims at conducting a quantitative analysis on the economic potentials for typical energy storage technologies by establishing a joint clearing model for electric energy and ancillary service(AS)markets considering the operating features of energy storage systems(ESSs).Furthermore,a test system is adopted for numerical analysis that accurately represents for the real-world operation characteristics of power systems in China,with which the market prices,and operation schedules and profitability of ESSs are comparatively studied.The proposed methodology and results could provide benefi-cial references for the modifications on electricity markets and the development of ESSs towards the increasing penetration of renewables in power systems.展开更多
A cost-effective, high-performance and highly stable membrane has always been in intensively needed in aqueous organic-based flow batteries. Here we present a porous polybenzimidazole(PBI) membrane with positive charg...A cost-effective, high-performance and highly stable membrane has always been in intensively needed in aqueous organic-based flow batteries. Here we present a porous polybenzimidazole(PBI) membrane with positive charges that endow the membrane with a high rejection and an excellent anti-fouling ability for target organic molecule and asymmetric structure that affords a high conductivity for vanadiummethylene blue flow battery(V-MB FB). The morphologies and thickness of separating layer in particular of the porous PBI can be well adjusted by simply altering the polymer concentration in the cast solution and further afford the membrane with a controllable property in terms of both ion selectivity and ion conductivity. As a result, a V-MB FB assembled with a porous PBI membrane delivers a coulombic efficiency(CE) of 99.45% and an energy efficiency(EE) of 86.10% at a current density of 40 mA cm^(-2), which is 12% higher than that afforded by a Nafion 212 membrane. Most importantly, the V-MB FB demonstrates a methylene blue(MB) utilization of 97.55% at a theoretical capacity of 32.16 Ah L^(-1)(based on the concentration of MB in the electrolyte) because of the high ion conductivity of the membrane, which favors reducing the cost of a battery. The results suggest that the designed porous PBI membranes exhibit a very promising prospect for methylene blue-vanadium flow battery.展开更多
The restructuring of the energy industry is imperative,as New Zealand strives to reduce greenhouse gas emissions.New Zealand has abundant renewable energy resources,and about 85%of current electricity generation is fr...The restructuring of the energy industry is imperative,as New Zealand strives to reduce greenhouse gas emissions.New Zealand has abundant renewable energy resources,and about 85%of current electricity generation is from renewable energy sources.However,in recent years,it appears that a considerable fraction of wind energy has been underutilized.This article reviews the history,current status,and future trends of wind energy development in New Zealand.The main challenges to the current development of wind energy are summarized compared to other countries.The main challenges come from the bi-cultural influence,environmental influence,and economic and social influence due to the variable nature of wind power,it is critical to store and operate power safely and reliably during peak power generation periods.This article compares seven mainstream wind energy storage technologies and analyzes the best solution for wind energy storage in New Zealand.This article analyzes the feasibility of using small-scale household(standard power rating range from 0.004 to 16 kW)wind turbines in New Zealand cities regarding their construction and operation process.The life cycle and the maximum capacity coefficient of such small-scale wind turbines are overviewed via three case studies and later compared with large commercial wind turbines(standard power rating ranges from 1 to 3 MW)in power generation capacity.It has been found that small-scale household wind turbines have notable power generation potential and economic benefits in the long term.展开更多
Vanadium flow batteries(VFBs)have drawn considerable attention as an emerging technology for largescale energy storage systems(ESSs).One of the pivotal challenges is the availability of eligible ion exchange membranes...Vanadium flow batteries(VFBs)have drawn considerable attention as an emerging technology for largescale energy storage systems(ESSs).One of the pivotal challenges is the availability of eligible ion exchange membranes(ICMs)that provide high ion selectivity,proton conductivity,and stability under rigorous condition.Herein,a‘side-chain-type’strategy has been employed to fabricate highly stable phenolphthalein-based cardo poly(arylene ether ketone)s(PAEKs)membrane with low area resistance(0.058Ωcm^(2)),in which flexible alkyl spacers effectively alleviated inductive withdrawing effect from terminal ion exchange groups thus enabling a stable backbone.The assembled VFBs based on PAEKs bearing pendent alkyl chain terminated with quaternary ammonium(Q-PPhEK)demonstrated an energy efficiency above 80%over 700 cycles at 160 mA/cm^(2).Such a remarkable results revealed that the side-chain-type strategy contributed to enhancing the ICMs stability in strong oxidizing environment,meanwhile,more interesting backbones would be woken with this design engaging in stable ICMs for VFBs.展开更多
基金supported by the National Nature Science Foundation of China under grant No.42272350the Foundation of Shanxi Key Laboratory for Exploration and Exploitation of Geothermal Resources under grant No.SX202202.
文摘Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES technology advances,accommodating greater depth,higher temperature and multi-energy complementarity,new research challenges emerge.This paper comprehensively provides a systematic summary of the current research status of UTES.It categorized different types of UTES systems,analyzes the applicability of key technologies of UTES,and evaluate their economic and environmental benefits.Moreover,this paper identifies existing issues with UTES,such as injection blockage,wellbore scaling and corrosion,seepage and heat transfer in cracks,etc.It suggests deepening the research on blockage formation mechanism and plugging prevention technology,improving the study of anticorrosive materials and water treatment technology,and enhancing the investigation of reservoir fracture network characterization technology and seepage heat transfer.These recommendations serve as valuable references for promoting the high-quality development of UTES.
文摘A significant driving force behind the brisk research on rechargeable batteries,particularly lithium-ion batteries(LiBs)in high-performance applications,is the development of portable devices and electric vehicles.Carbon-based materials,which have finite specific capacity,make up the anodes of LiBs.Many attempts are being made to produce novel nanostructured composite anode materials for LiBs that display cycle stability that is superior to that of graphite using graphene oxide.Therefore,using significant amounts of waste graphene oxide from used LiBs represents a fantastic opportunity to engage in waste management and circular economy.This review outlines recent studies,developments and the current advancement of graphene oxide-based LiBs,including preparation of graphene oxide and utilization in LiBs,particularly from the perspective of energy storage technology,which has drawn more and more attention to creating high-performance electrode systems.
文摘As a flexible power source,energy storage has many potential applications in renewable energy generation grid integration,power transmission and distribution,distributed generation,micro grid and ancillary services such as frequency regulation,etc.In this paper,the latest energy storage technology profile is analyzed and summarized,in terms of technology maturity,efficiency,scale,lifespan,cost and applications,taking into consideration their impact on the whole power system,including generation,transmission,distribution and utilization.The application scenarios of energy storage technologies are reviewed and investigated,and global and Chinese potential markets for energy storage applications are described.The challenges of large-scale energy storage application in power systems are presented from the aspect of technical and economic considerations.Meanwhile the development prospect of global energy storage market is forecasted,and application prospect of energy storage is analyzed.
基金Project(N110404031)supported by the Fundamental Research Funds for the Central Universities,China
文摘With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting large power grids and multiple smart distribution grids interconnections using energy storage technology for improving the system dynamic stability was studied.The segmentation validity of the large power grids and smart distribution grid inverter output interconnections power system using energy storage technology was proved in terms of theoretical analysis.Then,the influences of the energy storage device location and capacity on the proposed method were discussed in detail.The conclusion is obtained that the ESD optimal locations are allocated at the tie line terminal buses in the interconnected grid,respectively.The effectiveness of the proposed method was verified by simulations in an actual power system.
文摘It is obvious that in the next ten years,lithium ion batteries are still the dominating power source for a wide range of products including consumable electronics,vehicles(cars,motorbikes,scooters,buses),drones,and even robots and tanks.However,in the pursuit of cost-effective,safety-reliable,and highly efficient energy storage technologies,researchers are developing
文摘The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, discharge capacity and high rate dischargeability of the alloys are improved after physical and chemical modification as a result of the increase of the surface area and formation of the electrocatalysis layers, which increase both the electrochemical reaction rate on the alloy surface and H diffusion rate in the alloy bulk. It is also found that both the over-coarse and over-fine particle size increase the contact resistance of the electrode, resulting in a decrease of discharge capacity, deterioration of high rate dischargeability and lower discharge plateau. In another word, a suitable particle size distribution can enhance the alloy activity, discharge capacity and high rate dischargeability. In addition, the high rate dischargeability is enhanced by increasing La content and decreasing Ce content of the alloy composition because of enlargement of the unit cell volume and the improvement of the surface activity. Moreover, B additive resultes in the formation of the second phase, and makes the alloys easier pulverization, which greatly improves the activity, discharge capacity and high rate dischargeability.
文摘The effects of low-Co AB_5 type hydrogen storage alloys prepared by quenchingand annealing on the performances of MH-Ni batteries were investigated, and the characteristics ofthe low-Co AB_5 type hydrogen storage alloys were compared with those of the high-Co AB_5 typehydrogen storage alloy as well. The results showed that the faster the cooling of the low-Cohydrogen storage alloy is, the better homogeneity of the chemical composition for the alloy and thelonger cycle life of the battery are, but the electrochemical discharge capacity and high-ratedischarge ability are reduced. The high-rate discharge ability and charge retention of MH-Nibatteries for the conventional as-cast annealed low-Co hydrogen storage alloy were superior to thosefor the rapidly quenched low-Co hydrogen storage alloy and the high-Co hydrogen storage alloy, buta little inferior in the cycle life.
基金Qinchuangyuan Cited High-level Innovation and Entrepreneurship Talents Project under(Grant No:2021QCYRC4-36)National Natural Science Fundation of China(Grant No.:72173095).
文摘The increasing penetration of renewables in power systems urgently entails the utilization of energy storage technologies.As the development of energy storage technologies depends highly on the profitability in electricity markets,to evaluate the economic potentials for various types of energy storage technologies under the compre-hensive market environment is of great significance.To this end,this study aims at conducting a quantitative analysis on the economic potentials for typical energy storage technologies by establishing a joint clearing model for electric energy and ancillary service(AS)markets considering the operating features of energy storage systems(ESSs).Furthermore,a test system is adopted for numerical analysis that accurately represents for the real-world operation characteristics of power systems in China,with which the market prices,and operation schedules and profitability of ESSs are comparatively studied.The proposed methodology and results could provide benefi-cial references for the modifications on electricity markets and the development of ESSs towards the increasing penetration of renewables in power systems.
基金financial support from NSFC (22075121)the Youth Innovation Promotion Association CAS (2019182)+1 种基金the Dalian Science and Technology Innovation Project (2020JJ26GX031)the DNL Cooperation Found,CAS(DNL201910)。
文摘A cost-effective, high-performance and highly stable membrane has always been in intensively needed in aqueous organic-based flow batteries. Here we present a porous polybenzimidazole(PBI) membrane with positive charges that endow the membrane with a high rejection and an excellent anti-fouling ability for target organic molecule and asymmetric structure that affords a high conductivity for vanadiummethylene blue flow battery(V-MB FB). The morphologies and thickness of separating layer in particular of the porous PBI can be well adjusted by simply altering the polymer concentration in the cast solution and further afford the membrane with a controllable property in terms of both ion selectivity and ion conductivity. As a result, a V-MB FB assembled with a porous PBI membrane delivers a coulombic efficiency(CE) of 99.45% and an energy efficiency(EE) of 86.10% at a current density of 40 mA cm^(-2), which is 12% higher than that afforded by a Nafion 212 membrane. Most importantly, the V-MB FB demonstrates a methylene blue(MB) utilization of 97.55% at a theoretical capacity of 32.16 Ah L^(-1)(based on the concentration of MB in the electrolyte) because of the high ion conductivity of the membrane, which favors reducing the cost of a battery. The results suggest that the designed porous PBI membranes exhibit a very promising prospect for methylene blue-vanadium flow battery.
基金We gratefully acknowledge the financial support from the University of Canterbury,New Zealand(grant no.452DISDZ)Singapore National Research Foundation(grant no.NRF2016-NRF-NSFC001-102)+2 种基金The first author would like to thank the financial support by National Natural Science Foundtion of China(51775188,21805244)Natural Science Foundation of Zhejiang Province(LQ21E060003,LZ21E060001)。
文摘The restructuring of the energy industry is imperative,as New Zealand strives to reduce greenhouse gas emissions.New Zealand has abundant renewable energy resources,and about 85%of current electricity generation is from renewable energy sources.However,in recent years,it appears that a considerable fraction of wind energy has been underutilized.This article reviews the history,current status,and future trends of wind energy development in New Zealand.The main challenges to the current development of wind energy are summarized compared to other countries.The main challenges come from the bi-cultural influence,environmental influence,and economic and social influence due to the variable nature of wind power,it is critical to store and operate power safely and reliably during peak power generation periods.This article compares seven mainstream wind energy storage technologies and analyzes the best solution for wind energy storage in New Zealand.This article analyzes the feasibility of using small-scale household(standard power rating range from 0.004 to 16 kW)wind turbines in New Zealand cities regarding their construction and operation process.The life cycle and the maximum capacity coefficient of such small-scale wind turbines are overviewed via three case studies and later compared with large commercial wind turbines(standard power rating ranges from 1 to 3 MW)in power generation capacity.It has been found that small-scale household wind turbines have notable power generation potential and economic benefits in the long term.
基金the financial support of the National Natural Science Foundation of China(Nos.22075276,U19A2016,U22B6012)CAS Strategic Leading Science&Technology Program(A)(No.XDA21070000)+2 种基金Dalian High Level Talent Innovation Support Program(No.2020RD05)the Development of Scientic and Technological Project of the Jilin Province(No.20210101126JC)International Partnership Program of Chinese Academy of Sciences(No.121421KYSB20210028)。
文摘Vanadium flow batteries(VFBs)have drawn considerable attention as an emerging technology for largescale energy storage systems(ESSs).One of the pivotal challenges is the availability of eligible ion exchange membranes(ICMs)that provide high ion selectivity,proton conductivity,and stability under rigorous condition.Herein,a‘side-chain-type’strategy has been employed to fabricate highly stable phenolphthalein-based cardo poly(arylene ether ketone)s(PAEKs)membrane with low area resistance(0.058Ωcm^(2)),in which flexible alkyl spacers effectively alleviated inductive withdrawing effect from terminal ion exchange groups thus enabling a stable backbone.The assembled VFBs based on PAEKs bearing pendent alkyl chain terminated with quaternary ammonium(Q-PPhEK)demonstrated an energy efficiency above 80%over 700 cycles at 160 mA/cm^(2).Such a remarkable results revealed that the side-chain-type strategy contributed to enhancing the ICMs stability in strong oxidizing environment,meanwhile,more interesting backbones would be woken with this design engaging in stable ICMs for VFBs.