Co-Harvest Phase-Change Enthalpy and Isomerization Energy for High-Energy Heat Output by Controlling Crystallization of Alkyl-Grafted Azobenzene Molecules

Photoisomerization-induced phase change are important for co-harvesting the latent heat and isomerization energy of azobenzene molecules.Chemically optimizing heat output and energy delivery at alternating temperatures are challenging because of the differences in crystallizability and isomerization.This article reports two series of asymmetrically alkyl-grafted azobenzene(Azo-g),with and without a methyl group,that have an optically triggered phase change.Three exothermic modes were designed to utilize crystallization enthalpy(△H_(c))and photothermal(isomerization)energy(△H_(p))at different temperatures determined by the crystallization.Azo-g has high heat output(275-303 J g^(-1))by synchronously releasing△H_(c)and△H_(p)over a wide temperature range(-79℃to 25℃).We fabricated a new distributed energy utilization and delivery system to realize a temperature increase of 6.6℃at a temperature of-8℃.The findings offer insight into selective utilization of latent heat and isomerization energy by molecular optimization of crystallization and isomerization processes.

Performances of an air thermal energy utilization system developed with fan-coil units in large-scale plastic tunnels covered with external blanket

To improve the problem of low temperature at night in winter due to the lack of thermal storage in large-span plastic tunnels,an air thermal energy utilization system(ATEUS)was developed with fan-coil units to heat a large-scale plastic tunnel covered with an external blanket(LPTEB)on winter nights.The ATEUS was composed of nine fan-coil units mounted on top of the LPTEB,a water reservoir,pipes,and a water circulation pump.With the heat exchange between the air and the water flowing through the coils,the thermal energy from the air can be collected in the daytime,or the thermal energy in the water can be released into the LPTEB at night.On sunny days,the collected thermal energy from the air in the daytime(E_(c))and released thermal energy at night(E_(r))were 0.25-0.44 MJ/m^(2) and 0.24-0.38 MJ/m^(2),respectively.Used ATEUS as a heating system,its coefficient of performance(COP),which is the ratio of the heat consumption of LPTEB to the power consumption of ATEUS,ranged from 1.6-2.1.A dynamic model was also developed to simulate the water temperature(T_(w)).Based on the simulation,E_(c) and E_(r) on sunny days can be increased by 60%-73%and 38%-62%,respectively,by diminishing the heat loss of the water reservoir and increasing the indoor air temperature in the period of collecting thermal energy.Then,the COP can reach 2.6-3.8,and the developed ATEUS can be applied to heating the LPTEB in a way that conserves energy.

Dietary supplementation with xylooligosaccharides and exogenous enzyme improves milk production,energy utilization efficiency and reduces enteric methane emissions of Jersey cows

Background Sustainable strategies for enteric methane(CH_(4))mitigation of dairy cows have been extensively explored to improve production performance and alleviate environmental pressure.The present study aimed to investigate the effects of dietary xylooligosaccharides(XOS)and exogenous enzyme(EXE)supplementation on milk production,nutrient digestibility,enteric CH_(4) emissions,energy utilization efficiency of lactating Jersey dairy cows.Forty-eight lactating cows were randomly assigned to one of 4 treatments:(1)control diet(CON),(2)CON with 25 g/d XOS(XOS),(3)CON with 15 g/d EXE(EXE),and(4)CON with 25 g/d XOS and 15 g/d EXE(XOS+EXE).The 60-d experimental period consisted of a 14-d adaptation period and a 46-d sampling period.The enteric CO_(2)and CH_(4) emissions and O2 consumption were measured using two GreenFeed units,which were further used to determine the energy utilization efficiency of cows.Results Compared with CON,cows fed XOS,EXE or XOS+EXE significantly(P<0.05)increased milk yield,true protein and fat concentration,and energy-corrected milk yield(ECM)/DM intake,which could be reflected by the significant improvement(P<0.05)of dietary NDF and ADF digestibility.The results showed that dietary supplementation of XOS,EXE or XOS+EXE significantly(P<0.05)reduced CH_(4) emission,CH_(4)/milk yield,and CH_(4)/ECM.Furthermore,cows fed XOS demonstrated highest(P<0.05)metabolizable energy intake,milk energy output but lowest(P<0.05)of CH_(4) energy output and CH_(4) energy output as a proportion of gross energy intake compared with the remaining treatments.Conclusions Dietary supplementary of XOS,EXE or combination of XOS and EXE contributed to the improvement of lactation performance,nutrient digestibility,and energy utilization efficiency,as well as reduction of enteric CH_(4) emissions of lactating Jersey cows.This promising mitigation method may need further research to validate its long-term effect and mode of action for dairy cows.

Comparison of two schemes for district cooling system utilizing cold energy of liquefied natural gas

Two schemes（scheme Ⅰ and scheme Ⅱ）for designing a district cooling system（DCS）utilizing cold energy of liquefied natural gas（LNG）are presented.In scheme Ⅰ,LNG cold energy is used to produce ice,and then ice is transported to the central cooling plant of the DCS.In scheme Ⅱ,return water from the DCS is directly chilled by LNG cold energy,and the chilled water is then sent back to the central plant.The heat transportation loss is the main negative impact in the DCS and is emphatically analyzed when evaluating the efficiency of each scheme.The results show that the DCS utilizing LNG cold energy is feasible and valuable.The cooling supply distance of scheme Ⅱ is limited within 13 km while scheme Ⅰ has no distance limit.When the distance is between 6 and 13 km,scheme Ⅱ is more practical and effective.Contrarily,scheme Ⅰ has a better economic performance when the distance is shorter than 6 km or longer than 13 km.

Integration of Low-level Waste Heat Recovery and Liquefied Nature Gas Cold Energy Utilization

Two novel thermal cycles based on Brayton cycle and Rankine cycle are proposed, respectively, which integrate the recovery of low-level waste heat and Liquefied Nature Gas （LNG） cold energy utilization for power generation. Cascade utilization of energy is realized in the two thermal cycles, where low-level waste heat,low-temperature exergy and pressure exergy of LNG are utilized efficiently through the system synthesis. The simulations are carried out using the commercial Aspen Plus 10.2, and the results are analyzed. Compared with the conventional Brayton cycle and Rankine cycle, the two novel cycles bring 60.94% and 60% in exergy efficiency, respectively and 53.08% and 52.31% in thermal efficiency, respectively.

Clean Processing and Utilization of Coal Energy

The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning,which is a highly efficient,clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.

Improving energy utilization efficiency of electrical discharge milling in titanium alloys machining

Electrical discharge milling(ED-milling) can be a good choice for titanium alloys machining and it was proven that its machining efficiency can be improved to compete with mechanical cutting. In order to improve energy utilization efficiency of ED-milling process, unstable arc discharge and stable arc discharge combined with normal discharge were implemented for material removal by adjusting servo control strategy. The influence of electrode rotating speed and dielectric flushing pressure on machining performance was investigated by experiments. It was found that the rotating of electrode could move the position of discharge plasma channel, and high pressure flushing could wash melted debris out the discharge gap effectively. Both electrode rotating motion and high pressure flushing are contributed to the improvement of machining efficiency.

A Novel Process for Natural Gas Liquids Recovery from Oil Field Associated Gas with Liquefied Natural Gas Cryogenic Energy Utilization

A novel process to recovery natural gas liquids from oil field associated gas with liquefied natural gas (LNG)cryogenic energy utilization is proposed.Compared to the current electric refrigeration process,the proposed process uses the cryogenic energy of LNG and saves 62.6%of electricity.The proposed process recovers ethane, liquid petroleum gas(propane and butane)and heavier hydrocarbons,with total recovery rate of natural gas liquids up to 96.8%.In this paper,exergy analysis and the energy utilization diagram method(EUD)are used to assess the new process and identify the key operation units with large exergy loss.The results show that exergy efficiency of the new process is 44.3%.Compared to the electric refrigeration process,exergy efficiency of the new process is improved by 16%.The proposed process has been applied and implemented in a conceptual design scheme of the cryogenic energy utilization for a 300 million tons/yr LNG receiving terminal in a northern Chinese harbor.

Optimal Design of Water Utilization Network with Energy Integration in Process Industries

Effective utilization of water and energy is the key factor of sustainable development in process industries, and also an important science and technology problem to be solved in systems engineering. In this paper,two new methods of optimal design of water utilization network with energy integration in process industries are presented, that is, stepwise and simultaneous optimization methods. They are suitable for both single contaminant and multi-contaminant systems, and the integration of energy can be carried out in the whole process system, not only limited in water network, so that energy can be utilized effectively. The two methods are illustrated by case study.

Current Situation and Suggestions for Energy Utilization of Agricultural Waste in Hubei Province

Energy utilization is high-value use pattern of agricultural waste, and is main development direction of agricultural biomass energy industry in China. Planting and breeding industry in Hubei Province occupies important position in whole country. Agricultural waste resources are rich, and it has huge potential for developing agriculturel biomass energy. By statistical data during 2000 -2011, we analyzed current situation and problem for energy utilization of agricultural waste in Hubei Province, and put forward several countermeasures and suggestions, vigorously promoting energy utilization of agricultural waste.

Guangdong Dapeng LNG cold energy utilization-C_2++ extraction process integration

This paper makes a study of some technical and engineering aspects by using C2 ＋ hydrocarbon separation facility at Guangdong Dapeng liquefied natural gas （GDLNG） terminal. In the C2＋ hydrocarbon extraction process, the cold energy contained in LNG will be utilized. In order to ensure the optimum operating conditions of the temlinal and C2 ＋ hydrocarbon extraction facility by optimizing the current operating processes of the terminal, the C2 ＋ hydrocarbon extraction facility construction plan is proposed. We conducted numerous calculations and simulations using such specific analysis software as PRO II 〈 version 7.0 〉. Additionally available flow data are used to verify the cyclic send-out rates from the terminal, thus establishing the current and future projected load factors. This study is intended to make sure that GDLNG can continue to supply gas via the pipeline system safely without interruptions and most significantly solves the effects of flow fluctuations at the terminal gasification send-out facility on the hydrocarbons extraction, ensuring optimum pipeline operations and ensuring safe and effective means for such C2＋ hydrocarbons extraction process as well. At the same time, the terminal is also in the optimum operation condition. This is very significant to the terminal safety operation and the energy conservation and emission reduction.

Performance Analysis of Multi-Energy Hybrid System Based on Molten Salt Energy Storage

This paper briefly summarizes the current status of typical solar thermal power plant system,including system composition,thermal energy storage medium and performance.The thermo-physical properties of the storage medium are some of the most important factors that affect overall efficiency of the system,because some renewable energy sources such as solar and wind are unpredictable.A thermal storage system is therefore necessary to store energy for continuous usage.Based on the form of storage or the mode of system connection,heat exchangers of a thermal storage system can produce different temperature ranges of heat transfer fluid to realize energy cascade utilization.Founded upon the review,a small hybrid energy system with a molten-salt energy storage system is proposed to solve the problems of heating,cooling,and electricity consumption of a 1000 m2 training hall at school.The system uses molten-salt storage tank,water tank and steam generator to change the temperature of heat transfer fluid,in order to realize thermal energy cascade utilization.Compared to the existing heating and cooling system,the proposed system needs more renewable energy and less municipal energy to achieve the same results according to simulation analysis.Furthermore,by improving the original heating and cooling system,PMV has been improved.The comprehensive efficiency of solar energy utilization has been increased to 83%.

Distribution,exploitation,and utilization of intermediate-to-deep geothermal resources in eastern China

The part of China,east of the Hu Huanyong Line,is commonly referred to as eastern China.It is characterized by a high population density and a well-developed economy;it also has huge energy demands.This study assesses and promotes the large-scale development of geothermal resources in eastern China by analyzing deep geological structures,geothermal regimes,and typical geothermal systems.These analyses are based on data collected from geotectology,deep geophysics,geothermics,structural geology,and petrology.Determining the distribution patterns of intermediate-to-deep geothermal resources in the region helps develop prospects for their exploitation and utilization.Eastern China hosts superimposed layers of rocks from three major,global tectonic domainsd namely Paleo-Asian,Circum-Pacific,and Tethyan rocks.The structure of its crust and mantle exhibits a special flyover pattern,with basins and mountains as well as well-spaced uplifts and depressions alternatively on top.The lithosphere in Northeast China and North China is characterized by a thin,low density crust and mantle,whereas the lithosphere in South China has a thin,low density crust and a thick,high density mantle.The middle and upper crust contain geobodies with high conductivity and low velocity,with varying degrees of development that create favorable conditions for the formation and enrichment of geothermal resources.Moderate-to-high temperature geothermal resources are distributed in the MesozoiceCenozoic basins in eastern China,although moderate temperature geothermal resources with low abundance dominate.Porous sandstone reservoirs,karstified fractured-vuggy carbonate reservoirs,and fissured granite reservoirs are the main types of geothermal reservoirs in this region.Under the currently available technical conditions,the exploitation and utilization of geothermal resources in eastern China favor direct utilization over large-scale geothermal power generation.In Northeast China and North China,geothermal resources could be applied for large-scale geothermal heating purposes;geothermal heating could be applied during winter along parts of the Yangtze River while geothermal cooling would be more suitable for summer there;geothermal cooling could also be applied to much of South China.Geothermal resources can also be applied to high value-added industries,to aid agricultural practices,and for tourism.

The Develoyment Program of Energy Conservation and Comprehensive Utilization 2005-2007

Jointly published by 14 Department headed by Standardization Administraion ofChina(SAC) Subtitle: China will formulate and reformulate 926 standards for energy conservation andcomprehensive u-tilization during 2005 and 2007. In the past few days, 14 departments jointlypublished the Development Program of Energy Conservation and Comprehensive Utilization 2005-2007,(Program for short). They are Standardization Administration of China, National Development andReform Commission, Ministry of Land and Resources, Ministry of Establishment, Ministry ofCommunications, Ministry of Information Industry, Ministry of Waster Resources, Ministry ofAgriculture, Ministry of Commerce, General Administration of Quality Supervision, Inspection andQuarantine of the PRC, State Environmental Protection Administration, State Forestry Bureau, StateOceanic Administration and China Meteorological Bureau.

Analysis and Economic Evaluation of Hourly Operation Strategy Based on MSW Classification and LNG Multi-Generation System

In this study,a model of combined cooling,heating and power system with municipal solid waste(MSW)and liquefied natural gas(LNG)as energy sources was proposed and developed based on the energy demand of a large community,andMSW was classified and utilized.The systemoperated by determining power by heating load,and measures were taken to reduce operating costs by purchasing and selling LNG,natural gas(NG),cooling,heating,and power.Based on this system model,three operation strategies were proposed based on whether MSW was classified and the length of kitchen waste fermentation time,and each strategy was simulated hourly throughout the year.The results showed that the strategy of MSW classified and centralized fermentation of kitchen waste in summer(i.e.,strategy 3)required the least total amount of LNG for the whole year,which was 47701.77 t.In terms of total annual cost expenditure,strategy 3 had the best overall economy,with the lowest total annual expenditure of 2.7730×108 RMB at LNG and NG unit prices of 4 and 4.2 RMB/kg,respectively.The lower heating value of biogas produced by fermentation of kitchen waste from MSW being classified was higher than that of MSW before being classified,so the average annual thermal economy of the operating strategy of MSW being classified was better than that of MSW not being classified.Among the strategies in which MSW was classified and utilized,strategy 3 could better meet the load demand of users in the corresponding season,and thus this strategy had better thermal economy than the strategy of year-round fermentation of kitchen waste(i.e.,strategy 2).The hourly analysis data showed that the net electrical efficiency of the system varies in the same trend as the cooling,heating and power loads in all seasons,while the relationship between the energy utilization efficiency and load varied from season to season.This study can provide guidance for the practical application of MSW being classified in the system.

Regional Renewable Energy Optimization Based on Economic Benefits and Carbon Emissions

With increasing renewable energy utilization,the industry needs an accurate tool to select and size renewable energy equipment and evaluate the corresponding renewable energy plans.This study aims to bring new insights into sustainable and energy-efficient urban planning by developing a practical method for optimizing the production of renewable energy and carbon emission in urban areas.First,we provide a detailed formulation to calculate the renewable energy demand based on total energy demand.Second,we construct a dual-objective optimization model that represents the life cycle cost and carbon emission of renewable energy systems,after which we apply the differential evolution algorithmto solve the optimization result.Finally,we conduct a case study in Qingdao,China,to demonstrate the effectiveness of this optimizationmodel.Compared to the baseline design,the proposedmodel reduced annual costs and annual carbon emissions by 14.39%and 72.65%,respectively.These results revealed that dual-objective optimization is an effective method to optimize economic benefits and reduce carbon emissions.Overall,this study will assist energy planners in evaluating the impacts of urban renewable energy projects on the economy and carbon emissions during the planning stage.

Progress and Development Strategy of Biomass Energy Utilization Technologies in China

I. Preface Biomass includes the residues of agriculture, forest and stock breeding, as well as straw, algae and energy crops. In its broad meaning, biomass is a kind of organic matter produced by the photosynthesis of plants, which is not only renewable, but also contains plentiful energy.

An Optimized Oxygen System Scheduling With Electricity Cost Consideration in Steel Industry

As an essential energy resource in steel industry, oxygen is widely utilized in many production procedures. With different demands of the oxygen amount, a gap between the generation and consumption always occurs. Therefore, its related optimization and scheduling work along with the electricity cost to fill the gap has a great impact on daily production and efficient energy utilization in steel plant. Considering an oxygen system in a steel plant in China, a nonlinear programming model for oxygen system scheduling is proposed in this study, which concerns not only the practical characteristics of the energy pipeline network, but also the electricity cost acquired by a fitting regression modeling between the load of air separation units U+0028 ASU U+0029 and its corresponding electricity consumption. A set of constraints is formulated for restricting the practical adjusting capacity and filling the imbalance gap of oxygen. To solve the proposed scheduling model with electricity cost consideration, a particle swarm optimization U+0028 PSO U+0029 algorithm is then adopted. To verify the effectiveness of the proposed approach, a large number of experiments employing the real data from this plant are carried out, both for the fitting regression and the scheduling optimization phases. And the results demonstrate that such a practice-based solution successfully resolves the oxygen scheduling problem and simultaneously minimizes the electricity cost, which will be beneficial for the enterprise. © 2017 Chinese Association of Automation.

Cost Minimization of Wireless Sensor Networks with Unlimited-lifetime Energy for Monitoring Oil Pipelines

Cyber-physical-system (CPS) has been widely used in both civil and military applications. Wireless sensor network (WSN) as the part and parcel of CPS faces energy problem because sensors are battery powered, which results in limited lifetime of the network. To address this energy problem, we take advantage of energy harvesting device (EHD) and study how to indefinitely prolong oil pipeline monitoring network lifetime by reasonable selecting EHD. Firstly, we propose a general strategy worst case-energy balance strategy (WC-EBS), which defines worst case energy consumption (WCEC) as the maximum energy sensor node could expend for oil pipeline monitoring WSN. When the energy collected by EHD is equal or greater than WCEC, network can have an unlimited lifetime. However, energy harvesting rate is proportional to the price of EHD, WC-EBS will cause high network cost. To reduce network cost, we present two optimization strategies, optimization workloadenergy balance strategy (OW-EBS ) and optimization first nodeenergy balance strategy (OF-EBS). The main idea of OW-EBS is to cut down WCEC by reducing critical node transmission workload; OF-EBS confirms critical node by optimizing each sensor node transmission range, then we get the optimal energy harvesting rate in OF-EBS. The experimental results demonstrate that OF-EBS can indefinitely extend network lifetime with lower cost than WC-EBS and OW-EBS, and energy harvesting rate P in each strategy satisfies POF-EBS ≤POW-EBS ≤PWC-EBS. © 2014 Chinese Association of Automation.

Reliability analysis for WSN based on a modular k-out-of-n system

A hierarchical clustering model for a wireless sensor network (WSN) which takes into account the node fault and the balance of energy consumption is built. With the sensing and transmission as the main tasks of the WSN, its working mode is converted to a modular k-out-of-n system whose each modular is also a k-out-of-n structure. By using the theory of signature and its extending, the reliability of the WSN is computed. Finally, the reliability of WSN changing with the number of nodes, coverage requirements and node lifetimes is given by the numerical analysis. The proposed reliability analysis model is suitable for a large-scale WSN. © 2017 Beijing Institute of Aerospace Information.