Renewable energy sources are essential formitigating the greenhouse effect and supplying energy to resource-scarce regions.However,their intermittent nature necessitates efficient storage solutions to enhance system e...Renewable energy sources are essential formitigating the greenhouse effect and supplying energy to resource-scarce regions.However,their intermittent nature necessitates efficient storage solutions to enhance system efficiency and manage energy costs.This paper investigates renewable and clean storage systems,specifically examining the storage of electricity generated from renewable sources using hydropower plants and hydrogen,both of which are highly efficient and promising for future energy production and storage.The study utilizes extensive literature data to analyze the impact of various parameters on the cost per kWh of electricity production in hybrid renewable systems incorporating hydropower and hydrogen storage plants.Results indicate that these hybrid systems can store electricity efficiently and cost-effectively,with production costs ranging from 0.126 to 0.3$/kWh for renewablehydropower systems and 0.118 to 0.42$/kWh for renewable-hydrogen systems,with expected cost reductions over the next decade due to technological advancements and increased market adoption.The novelty of this study lies in its comprehensive comparison of hybrid renewable systems integrating hydropower and hydrogen storage,providing detailed cost analysis and future projections.It identifies key parameters influencing the cost and efficiency of these systems,offering insights into optimizing storage solutions for renewable energy.Moreover,this research underscores the potential of hybrid systems to reduce dependency on fossil fuels,particularly during peak demand periods,and emphasizes the importance of seasonal and geographic considerations in selecting energy sources.The study highlights the importance of policy support and investment in hybrid renewable systems and calls for further research into optimizing these systems for different seasonal and geographic conditions.Overall,the integration of renewable energy sources with hydropower and hydrogen storage offers a promising pathway to a sustainable,economical,and resilient energy future.展开更多
Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was pr...Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.展开更多
Hydrogen energy as a sustainable energy source has most recently become an increasingly important renewable energy resource due to its ability to power fuel cells in zero-emission vehicles and its help in lowering the...Hydrogen energy as a sustainable energy source has most recently become an increasingly important renewable energy resource due to its ability to power fuel cells in zero-emission vehicles and its help in lowering the levels of CO2</sub> emissions. Also, hydrogen has a high energy density and can be utilized in a wide range of applications. It is indeed the fuel of the future but, it is still not entirely apparent how to analyze the most successful ways for hydrogen storage based on technological configuration, nature, and efficiency mechanisms. The historical hydrogen storage technologies as they are presented by the current research have been evaluated, analyzed, and examined in this study. The two categories of hydrogen storage systems are physical-based and material-based.The first category involves storing hydrogen as liquid, cold/cryo-compressed, and compressed gas. Chemical sorption/chemisorption and physical sorption/physisorption are the two primary sub-groups of material-based storage, respectively. The quantitative and qualitative analyses of storage technologies for hydrogen are evaluated in this paper. Also, this report reviews the major safety and reliability issues currently facing hydrogen storage systems. Suggestions are made to assist lay the groundwork for future risk and reliability analysis to ensure safe, dependable operation.展开更多
Electrocatalytic water splitting for hydrogen production is an appealing strategy to reduce carbon emissions and generate renewable fuels.This promising process,however,is limited by its sluggish reaction kinetics and...Electrocatalytic water splitting for hydrogen production is an appealing strategy to reduce carbon emissions and generate renewable fuels.This promising process,however,is limited by its sluggish reaction kinetics and high-cost catalysts.The two-dimensional(2D)transition metal dichalcogenides(TMDCs)have presented great potential as electrocatalytic materials due to their tunable bandgaps,abundant defective active sites,and good chemical stability.Consequently,phase engineering,defect engineering and interface engineering have been adopted to manipulate the electronic structure of TMDCs for boosting their exceptional catalytic performance.Particularly,it is essential to clarify the local structure of catalytically active sites of TMDCs and their structural evolution in catalytic reactions using atomic resolution electron microscopy and the booming in situ technologies,which is beneficial for exploring the underlying reaction mechanism.In this review,the growth regulation,characterization,particularly atomic configurations of active sites in TMDCs are summarized.The significant role of electron microscopy in the understanding of the growth mechanism,the controlled synthesis and functional optimization of 2D TMDCs are discussed.This review will shed light on the design and synthesis of novel electrocatalysts with high performance,as well as prompt the application of advanced electron microscopy in the research of materials science.展开更多
Underground hydrogen storage(UHS)and compressed air energy storage(CAES)are two viable largescale energy storage technologies for mitigating the intermittency of wind and solar power.Therefore,it is meaningful to comp...Underground hydrogen storage(UHS)and compressed air energy storage(CAES)are two viable largescale energy storage technologies for mitigating the intermittency of wind and solar power.Therefore,it is meaningful to compare the properties of hydrogen and air with typical thermodynamic storage processes.This study employs a multi-physical coupling model to compare the operations of CAES and UHS,integrating gas thermodynamics within caverns,thermal conduction,and mechanical deformation around rock caverns.Gas thermodynamic responses are validated using additional simulations and the field test data.Temperature and pressure variations of air and hydrogen within rock caverns exhibit similarities under both adiabatic and diabatic simulation modes.Hydrogen reaches higher temperature and pressure following gas charging stage compared to air,and the ideal gas assumption may lead to overestimation of gas temperature and pressure.Unlike steel lining of CAES,the sealing layer(fibre-reinforced plastic FRP)in UHS is prone to deformation but can effectively mitigates stress in the sealing layer.In CAES,the first principal stress on the surface of the sealing layer and concrete lining is tensile stress,whereas UHS exhibits compressive stress in the same areas.Our present research can provide references for the selection of energy storage methods.展开更多
The global shift toward next-generation energy systems is propelled by the urgent need to combat climate change and the dwindling supply of fossil fuels.This review explores the intricate challenges and opportunities ...The global shift toward next-generation energy systems is propelled by the urgent need to combat climate change and the dwindling supply of fossil fuels.This review explores the intricate challenges and opportunities for transitioning to sustainable renewable energy sources such as solar,wind,and hydrogen.This transition economically challenges traditional energy sectors while fostering new industries,promoting job growth,and sustainable economic development.The transition to renewable energy demands social equity,ensuring universal access to affordable energy,and considering community impact.The environmental benefits include a significant reduction in greenhouse gas emissions and a lesser ecological footprint.This study highlights the rapid growth of the global wind power market,which is projected to increase from$112.23 billion in 2022 to$278.43 billion by 2030,with a compound annual growth rate of 13.67%.In addition,the demand for hydrogen is expected to increase,significantly impacting the market with potential cost reductions and making it a critical renewable energy source owing to its affordability and zero emissions.By 2028,renewables are predicted to account for 42%of global electricity generation,with significant contributions from wind and solar photovoltaic(PV)technology,particularly in China,the European Union,the United States,and India.These developments signify a global commitment to diversifying energy sources,reducing emissions,and moving toward cleaner and more sustainable energy solutions.This review offers stakeholders the insights required to smoothly transition to sustainable energy,setting the stage for a resilient future.展开更多
This study presents a comparative analysis of electricity, hydrogen, and biodiesel as energy vectors, with a focus on powering an aluminum smelter in southern Italy. It evaluates these vectors in terms of efficiency, ...This study presents a comparative analysis of electricity, hydrogen, and biodiesel as energy vectors, with a focus on powering an aluminum smelter in southern Italy. It evaluates these vectors in terms of efficiency, land requirements for carbon-neutral energy production, and capital expenditure, providing insights throughout the entire supply chain (upstream, midstream, and downstream) into their feasibility for industrial applications. The research reveals that biodiesel, despite being carbon neutral, is impractical due to extensive land requirements and lower efficiency if compared to other vectors. Hydrogen, downstream explored in two forms as thermal power generation and fuel cell technology, shows lower efficiency and higher capital expenditure compared to electricity. Additionally, green hydrogen production’s land requirements significantly exceed those of electricity-based systems. Electricity emerges as the most viable option, offering an overall higher efficiency, lower land requirements for its green production, and comparatively lower capital expenditure. The study’s findings highlight the importance of a holistic assessment of energy vectors, considering economic, environmental, and practical aspects along the entire energy supply chain, especially in industrial applications where the balance of these factors is crucial for long-term sustainability and feasibility. This comprehensive analysis provides valuable guidance for similar industrial applications, emphasizing the need for a balanced approach in the selection of energy vectors.展开更多
Given the“double carbon”objective and the drive toward low-carbon power,investigating the integration and interaction within the carbon-electricity market can enhance renewable energy utilization and facilitate ener...Given the“double carbon”objective and the drive toward low-carbon power,investigating the integration and interaction within the carbon-electricity market can enhance renewable energy utilization and facilitate energy conservation and emission reduction endeavors.However,further research is necessary to explore operational optimization methods for establishing a regional energy system using Power-to-Hydrogen(P2H)technology,focusing on participating in combined carbon-electricity market transactions.This study introduces an innovative Electro-Hydrogen Regional Energy System(EHRES)in this context.This system integrates renewable energy sources,a P2H system,cogeneration units,and energy storage devices.The core purpose of this integration is to optimize renewable energy utilization and minimize carbon emissions.This study aims to formulate an optimal operational strategy for EHRES,enabling its dynamic engagement in carbon-electricity market transactions.The initial phase entails establishing the technological framework of the electricity-hydrogen coupling system integrated with P2H.Subsequently,an analysis is conducted to examine the operational mode of EHRES as it participates in carbon-electricity market transactions.Additionally,the system scheduling model includes a stepped carbon trading price mechanism,considering the combined heat and power generation characteristics of the Hydrogen Fuel Cell(HFC).This facilitates the establishment of an optimal operational model for EHRES,aiming to minimize the overall operating cost.The simulation example illustrates that the coordinated operation of EHRES in carbon-electricity market transactions holds the potential to improve renewable energy utilization and reduce the overall system cost.This result carries significant implications for attaining advantages in both low-carbon and economic aspects.展开更多
Most advanced hydrogen evolution reaction(HER)catalysts show high activity under alkaline conditions.However,the performance deteriorates at a natural and acidic pH,which is often problematic in practical applications...Most advanced hydrogen evolution reaction(HER)catalysts show high activity under alkaline conditions.However,the performance deteriorates at a natural and acidic pH,which is often problematic in practical applications.Herein,a rhenium(Re)sulfide–transition-metal dichalcogenide heterojunc-tion catalyst with Re-rich vacancies(NiS_(2)-ReS_(2)-V)has been constructed.The optimized catalyst shows extraordinary electrocatalytic HER performance over a wide range of pH,with ultralow overpotentials of 42,85,and 122 mV under alkaline,acidic,and neutral conditions,respectively.Moreover,the two-electrode system with NiS_(2)-ReS_(2)-V1 as the cathode provides a voltage of 1.73 V at 500 mA cm^(-2),superior to industrial systems.Besides,the open-circuit voltage of a single Zn–H_(2)O cell with NiS_(2)-ReS_(2)-V1 as the cathode can reach an impressive 90.9% of the theoretical value,with a maximum power density of up to 31.6 mW cm^(-2).Moreover,it shows remarkable stability,with sustained discharge for approximately 120 h at 10 mA cm^(-2),significantly outperforming commercial Pt/C catalysts under the same conditions in all aspects.A series of systematic characterizations and theoretical calculations demonstrate that Re vacancies on the heterojunction interface would generate a stronger built-in electric field,which profoundly affects surface charge distribution and subsequently enhances HER performance.展开更多
Karamay,a city built on oil in China's far west,is transitioning into a hydrogen hub,marking a significant shift from its 68-year history as a petroleum powerhouse.In 1955,the discovery of oil at Well No.Ⅰin Kara...Karamay,a city built on oil in China's far west,is transitioning into a hydrogen hub,marking a significant shift from its 68-year history as a petroleum powerhouse.In 1955,the discovery of oil at Well No.Ⅰin Karamay marked the birth of China's first major oilfield and the city itself.For decades,Karamay was fueled by oil.But in recent years,driven by China's dual carbon goals,it has been actively exploring new pathways for energy transition and low-carbon development.展开更多
Distributed photovoltaic(PV)is one of the important power sources for building a new power system with new energy as the main body.The rapid development of distributed PV has brought new challenges to the operation of...Distributed photovoltaic(PV)is one of the important power sources for building a new power system with new energy as the main body.The rapid development of distributed PV has brought new challenges to the operation of distribution networks.In order to improve the absorption ability of large-scale distributed PV access to the distribution network,the AC/DC hybrid distribution network is constructed based on flexible interconnection technology,and a coordinated scheduling strategy model of hydrogen energy storage(HS)and distributed PV is established.Firstly,the mathematical model of distributed PV and HS system is established,and a comprehensive energy storage system combining seasonal hydrogen energy storage(SHS)and battery(BT)is proposed.Then,a flexible interconnected distribution network scheduling optimization model is established to minimize the total active power loss,voltage deviation and system operating cost.Finally,simulation analysis is carried out on the improved IEEE33 node,the NSGA-II algorithm is used to solve specific examples,and the optimal scheduling results of the comprehensive economy and power quality of the distribution network are obtained.Compared with the method that does not consider HS and flexible interconnection technology,the network loss and voltage deviation of this method are lower,and the total system cost can be reduced by 3.55%,which verifies the effectiveness of the proposed method.展开更多
Solar-driven photocatalytic water/seawater splitting holds great potential for green hydrogen production.However,the practical application is hindered by the relatively low conversion efficiency resulting from the ina...Solar-driven photocatalytic water/seawater splitting holds great potential for green hydrogen production.However,the practical application is hindered by the relatively low conversion efficiency resulting from the inadequate utilization of solar spectrum with significant waste in the form of heat.Moreover,current equipment struggles to maintain all-day operation subjected to the lack of light during nighttime.Herein,a novel hybrid system integrating photothermal catalytic(PTC)reactor,thermoelectric generator(TEG),and phase change materials(PCM)was proposed and designed(named as PTC-TEG-PCM)to address these challenges and enable simultaneous overall seawater splitting and 24-hour power generation.The PTC system effectively maintains in an optimal temperature range to maximize photothermal-assisted photocatalytic hydrogen production.The TEG component recycles the low-grade waste heat for power generation,complementing the shortcoming of photocatalytic conversion and achieving cascade utilization of full-spectrum solar energy.Furthermore,exceptional thermal storage capability of PCM allow for the conversion of released heat into electricity during nighttime,contributing significantly to the overall power output and enabling PTC-TEG-PCM to operate for more than 12 h under the actual condition.Compared to traditional PTC system,the overall energy conversion efficiency of the PTC-TEG-PCM system can be increased by∼500%,while maintaining the solar-to-hydrogen efficiency.The advancement of this novel system demonstrated that recycling waste heat from the PTC system and utilizing heat absorption/release capability of PCM for thermoelectric application are effective strategies to improve solar energy conversion.With flexible parameter designing,PTC-TEG-PCM can be applied in various scenarios,offering high efficiency,stability,and sustainability.展开更多
One of the impacts of the Fukushima disaster was the shutdown of all nuclear power plants in Japan,reaching zero production in 2015.In response,the country started importing more fossil energy including coal,oil,and n...One of the impacts of the Fukushima disaster was the shutdown of all nuclear power plants in Japan,reaching zero production in 2015.In response,the country started importing more fossil energy including coal,oil,and natural gas to fill the energy gap.However,this led to a significant increase in carbon emissions,hindering the efforts to reduce its carbon footprint.In the current situation,Japan is actively working to balance its energy requirements with environmental considerations,including the utilization of hydrogen fuel.Therefore,this paper aims to explore the feasibility and implications of using hydrogen power plants as a means to reduce emissions,and this analysis will be conducted using the energy modeling of the MARKAL-TIMES Japan framework.The hydrogen scenario(HS)is assumed with the extensive integration of hydrogen into the power generation sector,supported by a hydrogen import scheme.Additionally,this scenario will be compared with the Business as Usual(BAU)scenario.The results showed that the generation capacities of the BAU and HS scenarios have significantly different primary energy supplies.The BAU scenario is highly dependent on fossil fuels,while the HS scenario integrates hydrogen contribution along with an increase in renewable energy,reaching a peak contribution of 2,160 PJ in 2050.In the HS scenario,the target of reducing CO_(2) emissions by 80%is achieved through significant hydrogen penetration.By 2050,the total CO_(2) emissions are estimated to be 939 million tons for the BAU scenario and 261 million tons for the Hydrogen scenario.In addition,the contribution of hydrogen to electricity generation is expected to be 153 TWh,smaller than PV and wind power.展开更多
The economics,infrastructure,transportation,and level of living of a country are all influenced by energy.The gap between energy usage and availabil-ity is a global issue.Currently,all countries rely on fossil fuels fo...The economics,infrastructure,transportation,and level of living of a country are all influenced by energy.The gap between energy usage and availabil-ity is a global issue.Currently,all countries rely on fossil fuels for energy genera-tion,and these fossil fuels are not sustainable.The hydrogen proton exchange membrane fuel cell(PEMFC)power system is both clean and efficient.The fuel delivery system and the PEMFC make up the majority of the PEMFC power sys-tem.The lack of an efficient,safe,and cost-effective hydrogen storage system is still a major barrier to its widespread use.Solid hydrogen storage has the large capacity,safety and good reversibility.As a hydrogen source system,the hydro-gen supply characteristics affect the characteristics of the PEMFC at the output.In this paper,a mathematical model of a hydrogen source reactor and PEMFC based on chemical absorption/desorption of solid hydrogen storage is established,and a simulation model of a PEMFC power system coupled with solid hydrogen storage is established using MATLAB/SIMULINK software,and the hydrogen supply of the reactor is analyzed in detail.The influence of prominent factors is evaluated.The research results show that the proposed method improved the system perfor-mance.At the same time,increasing the PEMFC temperature,increasing the area of the proton exchange membrane and the oxygen supply pressure can increase the output power of the power system.展开更多
Solar system design for green hydrogen production has become the most prominent renewable energy research area, and this has also actively fueled the desire to achieve net-zero emissions. Hydrogen is a promising energ...Solar system design for green hydrogen production has become the most prominent renewable energy research area, and this has also actively fueled the desire to achieve net-zero emissions. Hydrogen is a promising energy carrier because it possesses more energy capacity than fossil fuels and the abundant nature of renewable energy systems can be utilized for green hydrogen production. However, the design of an optimized electrical energy system required for hydrogen production is crucial. Solar energy is indeed beneficial for green hydrogen production and this research designed, discussed, and provided high-level research on HOMER design for green hydrogen production and deployed the energy requirement with ASPEN Plus to optimize the energy system, while also incorporating fuzzy logic and PID control approaches. In addition, a promising technology with a high potential for renewable hydrogen energy is the proton exchange membrane (PEM) electrolyzer. Since its cathode (hydrogen electrode) may be operated over a wide range of pressure, a control process must be added to the system in order for it to work dynamically efficiently. This system can be characterized as an analogous circuit that consists of a resistor, capacitor, and reversible voltage. As a result, this research work also explores the Fuzzy-PID control of the PEM electrolysis system. Both the PID and Fuzzy Logic control systems were simulated using the control simulation program Matlab R2018a, which makes use of Matlab script files and the Simulink environment. Based on the circuit diagram, a transfer function that represents the mathematical model of the plant was created, and the PEM electrolysis control system is determined to be highly significant and applicable to the two control systems. The PI controller, however, has a 30.8% overshoot deficit, but when the fuzzy control system is compared to the PID controller, it is found that the fuzzy control system achieves stability more quickly, demonstrating its benefit over PID.展开更多
Einstein’s energy-momentum relationship, which holds in an isolated system in free space, contains two formulas for relativistic kinetic energy. Einstein’s relationship is not applicable in a hydrogen atom, where po...Einstein’s energy-momentum relationship, which holds in an isolated system in free space, contains two formulas for relativistic kinetic energy. Einstein’s relationship is not applicable in a hydrogen atom, where potential energy is present. However, a relationship similar to that can be derived. That derived relationship also contains two formulas, for the relativistic kinetic energy of an electron in a hydrogen atom. Furthermore, it is possible to derive a third formula for the relativistic kinetic energy of an electron from that relationship. Next, the paper looks at the fact that the electron has a wave nature. Five more formulas can be derived based on considerations relating to the phase velocity and group velocity of the electron. This paper presents eight formulas for the relativistic kinetic energy of an electron in a hydrogen atom.展开更多
The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly pro...The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly promotes the sustainable development of green hydrogen energy.Currently,diverse waste-derived catalysts have exhibited excellent catalytic performance toward hydrogen evolution reaction(HER),oxygen evolution reaction(OER),and overall water electrolysis(OWE).Herein,we systematically examine recent achievements in waste-derived electrocatalysts for water electrolysis.The general principles of water electrolysis and design principles of efficient electrocatalysts are discussed,followed by the illustration of current strategies for transforming wastes into electrocatalysts.Then,applications of waste-derived catalysts(i.e.,carbon-based catalysts,transitional metal-based catalysts,and carbon-based heterostructure catalysts)in HER,OER,and OWE are reviewed successively.An emphasis is put on correlating the catalysts’structure-performance relationship.Also,challenges and research directions in this booming field are finally highlighted.This review would provide useful insights into the design,synthesis,and applications of waste-derived electrocatalysts,and thus accelerate the development of the circular economy-driven green hydrogen energy scheme.展开更多
The versatility of hydrogen will provide opportunities in large scale,long duration energy storage,and the decarbonization of industry.Hydrogen energy carriers are molecules and materials that store hydrogen at higher...The versatility of hydrogen will provide opportunities in large scale,long duration energy storage,and the decarbonization of industry.Hydrogen energy carriers are molecules and materials that store hydrogen at higher volumetric density than possible using gas phase hydrogen.展开更多
A robust low-carbon economic optimal scheduling method that considers source-load uncertainty and hydrogen energy utilization is developed.The proposed method overcomes the challenge of source-load random fluctuations...A robust low-carbon economic optimal scheduling method that considers source-load uncertainty and hydrogen energy utilization is developed.The proposed method overcomes the challenge of source-load random fluctuations in integrated energy systems(IESs)in the operation scheduling problem of integrated energy production units(IEPUs).First,to solve the problem of inaccurate prediction of renewable energy output,an improved robust kernel density estimation method is proposed to construct a data-driven uncertainty output set of renewable energy sources statistically and build a typical scenario of load uncertainty using stochastic scenario reduction.Subsequently,to resolve the problem of insufficient utilization of hydrogen energy in existing IEPUs,a robust low-carbon economic optimal scheduling model of the source-load interaction of an IES with a hydrogen energy system is established.The system considers the further utilization of energy using hydrogen energy coupling equipment(such as hydrogen storage devices and fuel cells)and the comprehensive demand response of load-side schedulable resources.The simulation results show that the proposed robust stochastic optimization model driven by data can effectively reduce carbon dioxide emissions,improve the source-load interaction of the IES,realize the efficient use of hydrogen energy,and improve system robustness.展开更多
The construction of high-efficiency and low-cost non-noble metal bifunctional electrocatalysts for water electrolysis is crucial for commercial large-scale application of hydrogen energy.Here,we report a novel strateg...The construction of high-efficiency and low-cost non-noble metal bifunctional electrocatalysts for water electrolysis is crucial for commercial large-scale application of hydrogen energy.Here,we report a novel strategy with erbiumdoped NiCoP nanowire arrays in situ grown on conductive nickel foam(Er-NiCoP/NF).Significantly,the developed electrode shows exceptional bifunctional catalytic activity,which only requires overpotentials of 46 and 225 mV to afford a current density of 10 mAcm^(−2) for the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER),respectively.Density functional theory calculations reveal that the appropriate Er incorporation into the NiCoP lattice can significantly modulate the electronic structure with the d-band centers of Ni and Co atoms by shifting to lower energies with respect to the Fermi level,and optimize the Gibbs free energies of HER/OER intermediates,thereby accelerating water-splitting kinetics.When assembled as a solar-driven overall water-splitting electrolyzer,the as-prepared electrode shows a high and stable solar-to-hydrogen efficiency of 19.6%,indicating its potential for practical storage of intermittent energy.展开更多
文摘Renewable energy sources are essential formitigating the greenhouse effect and supplying energy to resource-scarce regions.However,their intermittent nature necessitates efficient storage solutions to enhance system efficiency and manage energy costs.This paper investigates renewable and clean storage systems,specifically examining the storage of electricity generated from renewable sources using hydropower plants and hydrogen,both of which are highly efficient and promising for future energy production and storage.The study utilizes extensive literature data to analyze the impact of various parameters on the cost per kWh of electricity production in hybrid renewable systems incorporating hydropower and hydrogen storage plants.Results indicate that these hybrid systems can store electricity efficiently and cost-effectively,with production costs ranging from 0.126 to 0.3$/kWh for renewablehydropower systems and 0.118 to 0.42$/kWh for renewable-hydrogen systems,with expected cost reductions over the next decade due to technological advancements and increased market adoption.The novelty of this study lies in its comprehensive comparison of hybrid renewable systems integrating hydropower and hydrogen storage,providing detailed cost analysis and future projections.It identifies key parameters influencing the cost and efficiency of these systems,offering insights into optimizing storage solutions for renewable energy.Moreover,this research underscores the potential of hybrid systems to reduce dependency on fossil fuels,particularly during peak demand periods,and emphasizes the importance of seasonal and geographic considerations in selecting energy sources.The study highlights the importance of policy support and investment in hybrid renewable systems and calls for further research into optimizing these systems for different seasonal and geographic conditions.Overall,the integration of renewable energy sources with hydropower and hydrogen storage offers a promising pathway to a sustainable,economical,and resilient energy future.
基金supported by the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology(BE2020081).
文摘Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.
文摘Hydrogen energy as a sustainable energy source has most recently become an increasingly important renewable energy resource due to its ability to power fuel cells in zero-emission vehicles and its help in lowering the levels of CO2</sub> emissions. Also, hydrogen has a high energy density and can be utilized in a wide range of applications. It is indeed the fuel of the future but, it is still not entirely apparent how to analyze the most successful ways for hydrogen storage based on technological configuration, nature, and efficiency mechanisms. The historical hydrogen storage technologies as they are presented by the current research have been evaluated, analyzed, and examined in this study. The two categories of hydrogen storage systems are physical-based and material-based.The first category involves storing hydrogen as liquid, cold/cryo-compressed, and compressed gas. Chemical sorption/chemisorption and physical sorption/physisorption are the two primary sub-groups of material-based storage, respectively. The quantitative and qualitative analyses of storage technologies for hydrogen are evaluated in this paper. Also, this report reviews the major safety and reliability issues currently facing hydrogen storage systems. Suggestions are made to assist lay the groundwork for future risk and reliability analysis to ensure safe, dependable operation.
基金the National Natural Science Foundation of China(Grant Nos.U21A20174 and 52001222)the Science and Technology Innovation Talent Team Project of Shanxi Province(Grant No.202304051001010)+3 种基金the Key National Scientific and Technological Co-operation Projects of Shanxi Province(Grant No.202104041101008)the Natural Science Foundation of Shanxi Province(Grant No.202303021221045)the Program for the Innovative Talents of Higher Education Institutions of Shanxi(PTIT)and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(STIP)(Grant No.2022L036).
文摘Electrocatalytic water splitting for hydrogen production is an appealing strategy to reduce carbon emissions and generate renewable fuels.This promising process,however,is limited by its sluggish reaction kinetics and high-cost catalysts.The two-dimensional(2D)transition metal dichalcogenides(TMDCs)have presented great potential as electrocatalytic materials due to their tunable bandgaps,abundant defective active sites,and good chemical stability.Consequently,phase engineering,defect engineering and interface engineering have been adopted to manipulate the electronic structure of TMDCs for boosting their exceptional catalytic performance.Particularly,it is essential to clarify the local structure of catalytically active sites of TMDCs and their structural evolution in catalytic reactions using atomic resolution electron microscopy and the booming in situ technologies,which is beneficial for exploring the underlying reaction mechanism.In this review,the growth regulation,characterization,particularly atomic configurations of active sites in TMDCs are summarized.The significant role of electron microscopy in the understanding of the growth mechanism,the controlled synthesis and functional optimization of 2D TMDCs are discussed.This review will shed light on the design and synthesis of novel electrocatalysts with high performance,as well as prompt the application of advanced electron microscopy in the research of materials science.
基金the financial support from the Natural Science Foundation of China (Nos.52179118,52209151 and 42307238)the Science and Technology Project of Jiangsu Provincial Department of Science and Technology-Carbon Emissions Peak and Carbon Neutrality Science and Technology Innovation Specia Fund Project (No.BK20220025)+3 种基金the Excellent Postdoctoral Program of Jiangsu Province (No.2023ZB602)the China Postdoctora Science Foundation (Nos.2023M733773 and 2023M733772)Xuzhou City Science and Technology Innovation Special Basic Research Plan (KC23045)State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering,China University of Mining&Technology (No SKLGDUEK1916)。
文摘Underground hydrogen storage(UHS)and compressed air energy storage(CAES)are two viable largescale energy storage technologies for mitigating the intermittency of wind and solar power.Therefore,it is meaningful to compare the properties of hydrogen and air with typical thermodynamic storage processes.This study employs a multi-physical coupling model to compare the operations of CAES and UHS,integrating gas thermodynamics within caverns,thermal conduction,and mechanical deformation around rock caverns.Gas thermodynamic responses are validated using additional simulations and the field test data.Temperature and pressure variations of air and hydrogen within rock caverns exhibit similarities under both adiabatic and diabatic simulation modes.Hydrogen reaches higher temperature and pressure following gas charging stage compared to air,and the ideal gas assumption may lead to overestimation of gas temperature and pressure.Unlike steel lining of CAES,the sealing layer(fibre-reinforced plastic FRP)in UHS is prone to deformation but can effectively mitigates stress in the sealing layer.In CAES,the first principal stress on the surface of the sealing layer and concrete lining is tensile stress,whereas UHS exhibits compressive stress in the same areas.Our present research can provide references for the selection of energy storage methods.
文摘The global shift toward next-generation energy systems is propelled by the urgent need to combat climate change and the dwindling supply of fossil fuels.This review explores the intricate challenges and opportunities for transitioning to sustainable renewable energy sources such as solar,wind,and hydrogen.This transition economically challenges traditional energy sectors while fostering new industries,promoting job growth,and sustainable economic development.The transition to renewable energy demands social equity,ensuring universal access to affordable energy,and considering community impact.The environmental benefits include a significant reduction in greenhouse gas emissions and a lesser ecological footprint.This study highlights the rapid growth of the global wind power market,which is projected to increase from$112.23 billion in 2022 to$278.43 billion by 2030,with a compound annual growth rate of 13.67%.In addition,the demand for hydrogen is expected to increase,significantly impacting the market with potential cost reductions and making it a critical renewable energy source owing to its affordability and zero emissions.By 2028,renewables are predicted to account for 42%of global electricity generation,with significant contributions from wind and solar photovoltaic(PV)technology,particularly in China,the European Union,the United States,and India.These developments signify a global commitment to diversifying energy sources,reducing emissions,and moving toward cleaner and more sustainable energy solutions.This review offers stakeholders the insights required to smoothly transition to sustainable energy,setting the stage for a resilient future.
文摘This study presents a comparative analysis of electricity, hydrogen, and biodiesel as energy vectors, with a focus on powering an aluminum smelter in southern Italy. It evaluates these vectors in terms of efficiency, land requirements for carbon-neutral energy production, and capital expenditure, providing insights throughout the entire supply chain (upstream, midstream, and downstream) into their feasibility for industrial applications. The research reveals that biodiesel, despite being carbon neutral, is impractical due to extensive land requirements and lower efficiency if compared to other vectors. Hydrogen, downstream explored in two forms as thermal power generation and fuel cell technology, shows lower efficiency and higher capital expenditure compared to electricity. Additionally, green hydrogen production’s land requirements significantly exceed those of electricity-based systems. Electricity emerges as the most viable option, offering an overall higher efficiency, lower land requirements for its green production, and comparatively lower capital expenditure. The study’s findings highlight the importance of a holistic assessment of energy vectors, considering economic, environmental, and practical aspects along the entire energy supply chain, especially in industrial applications where the balance of these factors is crucial for long-term sustainability and feasibility. This comprehensive analysis provides valuable guidance for similar industrial applications, emphasizing the need for a balanced approach in the selection of energy vectors.
基金supported financially by InnerMongoliaKey Lab of Electrical Power Conversion,Transmission,and Control under Grant IMEECTC2022001the S&TMajor Project of Inner Mongolia Autonomous Region in China(2021ZD0040).
文摘Given the“double carbon”objective and the drive toward low-carbon power,investigating the integration and interaction within the carbon-electricity market can enhance renewable energy utilization and facilitate energy conservation and emission reduction endeavors.However,further research is necessary to explore operational optimization methods for establishing a regional energy system using Power-to-Hydrogen(P2H)technology,focusing on participating in combined carbon-electricity market transactions.This study introduces an innovative Electro-Hydrogen Regional Energy System(EHRES)in this context.This system integrates renewable energy sources,a P2H system,cogeneration units,and energy storage devices.The core purpose of this integration is to optimize renewable energy utilization and minimize carbon emissions.This study aims to formulate an optimal operational strategy for EHRES,enabling its dynamic engagement in carbon-electricity market transactions.The initial phase entails establishing the technological framework of the electricity-hydrogen coupling system integrated with P2H.Subsequently,an analysis is conducted to examine the operational mode of EHRES as it participates in carbon-electricity market transactions.Additionally,the system scheduling model includes a stepped carbon trading price mechanism,considering the combined heat and power generation characteristics of the Hydrogen Fuel Cell(HFC).This facilitates the establishment of an optimal operational model for EHRES,aiming to minimize the overall operating cost.The simulation example illustrates that the coordinated operation of EHRES in carbon-electricity market transactions holds the potential to improve renewable energy utilization and reduce the overall system cost.This result carries significant implications for attaining advantages in both low-carbon and economic aspects.
基金This study was supported by the National Research Foundation of Korea(NRF-2021R1A2C4001777,NRF-2022M3H4A1A04096482 and RS-2023-00229679),the National Natural Science Foundation of China(No.21965005,52363028)the Natural Science Foundation of Guangxi Province(2021GXNSFAA076001)the Guangxi Technology Base and Talent Subject(GUIKE AD20297039).
文摘Most advanced hydrogen evolution reaction(HER)catalysts show high activity under alkaline conditions.However,the performance deteriorates at a natural and acidic pH,which is often problematic in practical applications.Herein,a rhenium(Re)sulfide–transition-metal dichalcogenide heterojunc-tion catalyst with Re-rich vacancies(NiS_(2)-ReS_(2)-V)has been constructed.The optimized catalyst shows extraordinary electrocatalytic HER performance over a wide range of pH,with ultralow overpotentials of 42,85,and 122 mV under alkaline,acidic,and neutral conditions,respectively.Moreover,the two-electrode system with NiS_(2)-ReS_(2)-V1 as the cathode provides a voltage of 1.73 V at 500 mA cm^(-2),superior to industrial systems.Besides,the open-circuit voltage of a single Zn–H_(2)O cell with NiS_(2)-ReS_(2)-V1 as the cathode can reach an impressive 90.9% of the theoretical value,with a maximum power density of up to 31.6 mW cm^(-2).Moreover,it shows remarkable stability,with sustained discharge for approximately 120 h at 10 mA cm^(-2),significantly outperforming commercial Pt/C catalysts under the same conditions in all aspects.A series of systematic characterizations and theoretical calculations demonstrate that Re vacancies on the heterojunction interface would generate a stronger built-in electric field,which profoundly affects surface charge distribution and subsequently enhances HER performance.
文摘Karamay,a city built on oil in China's far west,is transitioning into a hydrogen hub,marking a significant shift from its 68-year history as a petroleum powerhouse.In 1955,the discovery of oil at Well No.Ⅰin Karamay marked the birth of China's first major oilfield and the city itself.For decades,Karamay was fueled by oil.But in recent years,driven by China's dual carbon goals,it has been actively exploring new pathways for energy transition and low-carbon development.
文摘Distributed photovoltaic(PV)is one of the important power sources for building a new power system with new energy as the main body.The rapid development of distributed PV has brought new challenges to the operation of distribution networks.In order to improve the absorption ability of large-scale distributed PV access to the distribution network,the AC/DC hybrid distribution network is constructed based on flexible interconnection technology,and a coordinated scheduling strategy model of hydrogen energy storage(HS)and distributed PV is established.Firstly,the mathematical model of distributed PV and HS system is established,and a comprehensive energy storage system combining seasonal hydrogen energy storage(SHS)and battery(BT)is proposed.Then,a flexible interconnected distribution network scheduling optimization model is established to minimize the total active power loss,voltage deviation and system operating cost.Finally,simulation analysis is carried out on the improved IEEE33 node,the NSGA-II algorithm is used to solve specific examples,and the optimal scheduling results of the comprehensive economy and power quality of the distribution network are obtained.Compared with the method that does not consider HS and flexible interconnection technology,the network loss and voltage deviation of this method are lower,and the total system cost can be reduced by 3.55%,which verifies the effectiveness of the proposed method.
基金supported by the Basic Science Center Program for Ordered Energy Conversion of the National Natural Science Foundation of China(52488201)the National Natural Science Foundation of China(52376209)+1 种基金the China Postdoctoral Science Foundation(2020T130503 and 2020M673386)the China Fundamental Research Funds for the Central Universities.
文摘Solar-driven photocatalytic water/seawater splitting holds great potential for green hydrogen production.However,the practical application is hindered by the relatively low conversion efficiency resulting from the inadequate utilization of solar spectrum with significant waste in the form of heat.Moreover,current equipment struggles to maintain all-day operation subjected to the lack of light during nighttime.Herein,a novel hybrid system integrating photothermal catalytic(PTC)reactor,thermoelectric generator(TEG),and phase change materials(PCM)was proposed and designed(named as PTC-TEG-PCM)to address these challenges and enable simultaneous overall seawater splitting and 24-hour power generation.The PTC system effectively maintains in an optimal temperature range to maximize photothermal-assisted photocatalytic hydrogen production.The TEG component recycles the low-grade waste heat for power generation,complementing the shortcoming of photocatalytic conversion and achieving cascade utilization of full-spectrum solar energy.Furthermore,exceptional thermal storage capability of PCM allow for the conversion of released heat into electricity during nighttime,contributing significantly to the overall power output and enabling PTC-TEG-PCM to operate for more than 12 h under the actual condition.Compared to traditional PTC system,the overall energy conversion efficiency of the PTC-TEG-PCM system can be increased by∼500%,while maintaining the solar-to-hydrogen efficiency.The advancement of this novel system demonstrated that recycling waste heat from the PTC system and utilizing heat absorption/release capability of PCM for thermoelectric application are effective strategies to improve solar energy conversion.With flexible parameter designing,PTC-TEG-PCM can be applied in various scenarios,offering high efficiency,stability,and sustainability.
文摘One of the impacts of the Fukushima disaster was the shutdown of all nuclear power plants in Japan,reaching zero production in 2015.In response,the country started importing more fossil energy including coal,oil,and natural gas to fill the energy gap.However,this led to a significant increase in carbon emissions,hindering the efforts to reduce its carbon footprint.In the current situation,Japan is actively working to balance its energy requirements with environmental considerations,including the utilization of hydrogen fuel.Therefore,this paper aims to explore the feasibility and implications of using hydrogen power plants as a means to reduce emissions,and this analysis will be conducted using the energy modeling of the MARKAL-TIMES Japan framework.The hydrogen scenario(HS)is assumed with the extensive integration of hydrogen into the power generation sector,supported by a hydrogen import scheme.Additionally,this scenario will be compared with the Business as Usual(BAU)scenario.The results showed that the generation capacities of the BAU and HS scenarios have significantly different primary energy supplies.The BAU scenario is highly dependent on fossil fuels,while the HS scenario integrates hydrogen contribution along with an increase in renewable energy,reaching a peak contribution of 2,160 PJ in 2050.In the HS scenario,the target of reducing CO_(2) emissions by 80%is achieved through significant hydrogen penetration.By 2050,the total CO_(2) emissions are estimated to be 939 million tons for the BAU scenario and 261 million tons for the Hydrogen scenario.In addition,the contribution of hydrogen to electricity generation is expected to be 153 TWh,smaller than PV and wind power.
基金funded by King Abdulaziz University,Jedda Saudi Arabia and King Abdulah City for Atomic and Renewable Energy,Riyadh,Saudi Arabia Grant No.(KCR-KFL-13-20)thereforethe authors gratefully acknowledge their technical and financial support.
文摘The economics,infrastructure,transportation,and level of living of a country are all influenced by energy.The gap between energy usage and availabil-ity is a global issue.Currently,all countries rely on fossil fuels for energy genera-tion,and these fossil fuels are not sustainable.The hydrogen proton exchange membrane fuel cell(PEMFC)power system is both clean and efficient.The fuel delivery system and the PEMFC make up the majority of the PEMFC power sys-tem.The lack of an efficient,safe,and cost-effective hydrogen storage system is still a major barrier to its widespread use.Solid hydrogen storage has the large capacity,safety and good reversibility.As a hydrogen source system,the hydro-gen supply characteristics affect the characteristics of the PEMFC at the output.In this paper,a mathematical model of a hydrogen source reactor and PEMFC based on chemical absorption/desorption of solid hydrogen storage is established,and a simulation model of a PEMFC power system coupled with solid hydrogen storage is established using MATLAB/SIMULINK software,and the hydrogen supply of the reactor is analyzed in detail.The influence of prominent factors is evaluated.The research results show that the proposed method improved the system perfor-mance.At the same time,increasing the PEMFC temperature,increasing the area of the proton exchange membrane and the oxygen supply pressure can increase the output power of the power system.
文摘Solar system design for green hydrogen production has become the most prominent renewable energy research area, and this has also actively fueled the desire to achieve net-zero emissions. Hydrogen is a promising energy carrier because it possesses more energy capacity than fossil fuels and the abundant nature of renewable energy systems can be utilized for green hydrogen production. However, the design of an optimized electrical energy system required for hydrogen production is crucial. Solar energy is indeed beneficial for green hydrogen production and this research designed, discussed, and provided high-level research on HOMER design for green hydrogen production and deployed the energy requirement with ASPEN Plus to optimize the energy system, while also incorporating fuzzy logic and PID control approaches. In addition, a promising technology with a high potential for renewable hydrogen energy is the proton exchange membrane (PEM) electrolyzer. Since its cathode (hydrogen electrode) may be operated over a wide range of pressure, a control process must be added to the system in order for it to work dynamically efficiently. This system can be characterized as an analogous circuit that consists of a resistor, capacitor, and reversible voltage. As a result, this research work also explores the Fuzzy-PID control of the PEM electrolysis system. Both the PID and Fuzzy Logic control systems were simulated using the control simulation program Matlab R2018a, which makes use of Matlab script files and the Simulink environment. Based on the circuit diagram, a transfer function that represents the mathematical model of the plant was created, and the PEM electrolysis control system is determined to be highly significant and applicable to the two control systems. The PI controller, however, has a 30.8% overshoot deficit, but when the fuzzy control system is compared to the PID controller, it is found that the fuzzy control system achieves stability more quickly, demonstrating its benefit over PID.
文摘Einstein’s energy-momentum relationship, which holds in an isolated system in free space, contains two formulas for relativistic kinetic energy. Einstein’s relationship is not applicable in a hydrogen atom, where potential energy is present. However, a relationship similar to that can be derived. That derived relationship also contains two formulas, for the relativistic kinetic energy of an electron in a hydrogen atom. Furthermore, it is possible to derive a third formula for the relativistic kinetic energy of an electron from that relationship. Next, the paper looks at the fact that the electron has a wave nature. Five more formulas can be derived based on considerations relating to the phase velocity and group velocity of the electron. This paper presents eight formulas for the relativistic kinetic energy of an electron in a hydrogen atom.
基金supported by the Australian Research Council (ARC) Discovery Project (DP220101139)support of the Australian Research Council (ARC) through Project DE220100530support of the Australian Research Council (ARC) through Project DE200100970
文摘The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts.By following the circular economy principle,the utilization of waste-derived catalysts significantly promotes the sustainable development of green hydrogen energy.Currently,diverse waste-derived catalysts have exhibited excellent catalytic performance toward hydrogen evolution reaction(HER),oxygen evolution reaction(OER),and overall water electrolysis(OWE).Herein,we systematically examine recent achievements in waste-derived electrocatalysts for water electrolysis.The general principles of water electrolysis and design principles of efficient electrocatalysts are discussed,followed by the illustration of current strategies for transforming wastes into electrocatalysts.Then,applications of waste-derived catalysts(i.e.,carbon-based catalysts,transitional metal-based catalysts,and carbon-based heterostructure catalysts)in HER,OER,and OWE are reviewed successively.An emphasis is put on correlating the catalysts’structure-performance relationship.Also,challenges and research directions in this booming field are finally highlighted.This review would provide useful insights into the design,synthesis,and applications of waste-derived electrocatalysts,and thus accelerate the development of the circular economy-driven green hydrogen energy scheme.
基金supported by the U.S.Department of Energy,Office of Science,Basic Energy Sciences,Physical Behavior of Materials under Award No.80110operated by Battelle for the US Department of Energy under Contract DE-AC05-76RL01830financial support by the Liao Ning Revitalization Talents Program XLYC2002076。
文摘The versatility of hydrogen will provide opportunities in large scale,long duration energy storage,and the decarbonization of industry.Hydrogen energy carriers are molecules and materials that store hydrogen at higher volumetric density than possible using gas phase hydrogen.
基金supported by the National Key Research and Development Project of China(2018YFE0122200).
文摘A robust low-carbon economic optimal scheduling method that considers source-load uncertainty and hydrogen energy utilization is developed.The proposed method overcomes the challenge of source-load random fluctuations in integrated energy systems(IESs)in the operation scheduling problem of integrated energy production units(IEPUs).First,to solve the problem of inaccurate prediction of renewable energy output,an improved robust kernel density estimation method is proposed to construct a data-driven uncertainty output set of renewable energy sources statistically and build a typical scenario of load uncertainty using stochastic scenario reduction.Subsequently,to resolve the problem of insufficient utilization of hydrogen energy in existing IEPUs,a robust low-carbon economic optimal scheduling model of the source-load interaction of an IES with a hydrogen energy system is established.The system considers the further utilization of energy using hydrogen energy coupling equipment(such as hydrogen storage devices and fuel cells)and the comprehensive demand response of load-side schedulable resources.The simulation results show that the proposed robust stochastic optimization model driven by data can effectively reduce carbon dioxide emissions,improve the source-load interaction of the IES,realize the efficient use of hydrogen energy,and improve system robustness.
基金supported by the Double Tops Joint Fund of the Yunnan Science and Technology Bureau and Yunnan University(2019FY003025)the National Natural Science Foundation of China(U2002213 and 51621001)+2 种基金the East-Land Middle-aged and Young Backbone Teacher of Yunnan University(No.C176220200)Yunnan Applied Basic Research Projects(202001BB050006,202001BB050007)the Double-First Class University Plan(C176220100042).
文摘The construction of high-efficiency and low-cost non-noble metal bifunctional electrocatalysts for water electrolysis is crucial for commercial large-scale application of hydrogen energy.Here,we report a novel strategy with erbiumdoped NiCoP nanowire arrays in situ grown on conductive nickel foam(Er-NiCoP/NF).Significantly,the developed electrode shows exceptional bifunctional catalytic activity,which only requires overpotentials of 46 and 225 mV to afford a current density of 10 mAcm^(−2) for the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER),respectively.Density functional theory calculations reveal that the appropriate Er incorporation into the NiCoP lattice can significantly modulate the electronic structure with the d-band centers of Ni and Co atoms by shifting to lower energies with respect to the Fermi level,and optimize the Gibbs free energies of HER/OER intermediates,thereby accelerating water-splitting kinetics.When assembled as a solar-driven overall water-splitting electrolyzer,the as-prepared electrode shows a high and stable solar-to-hydrogen efficiency of 19.6%,indicating its potential for practical storage of intermittent energy.