Constitutional Values of Protecting Human Rights of Disadvantaged Groups

The confrontation between the disadvantaged and advantaged groups is eternal throughout the competition for survival. But the human spiritual world has its humane aspect in addition to competition. The concern for and protection of the disadvantaged group is the moral law characteristic of humanity, just as the Universal Declaration of Human Rights says in its Article 1： ＂All human beings are born free and equal in dignity and rights.

Synthesis and application of an IL-supported diol as protecting group for aldehydes

A new IL-supported diol, 1-（2,3-dihydroxypropyl）-3-methylimidazolium hexafluorophosphate has been synthesized and characterized by Fr-IR, ^1H NMR, ^13C NMR and MS （ESI）. Its physical properties such as freezing point, solubility and specific gravity and thermal stability were determined. Synthetic utilities of the resultant diol as a protecting group for aldehydes were also investigated.

Designing a Protection Scheme in Micro-Grid Systems with DG Using Central Protection Unite and Multiple Setting Group Protection Relays

Distributed generators now is widely used in electrical power networks, in some cases it works seasonally, and some types works at special weather conditions like photo voltaic systems and wind energy, and due to this continuous changes in generation condition, the fault current level in network will be affected, this changes in fault current level will affect in the coordination between protection relays and to keep the coordination at right way, an adaptive protection system is required that can adaptive its setting according to generation changes, the fault current level in each case is evaluated using ETAP software, and the required relay setting in each case is also evaluated using Grey Wolf Optimizer (GWO) algorithm, and to select suitable setting which required in each condition, to select the active setting group of protection relay according to generation capacity, central protection unite can be used, and to improve protection stability and minimizing relays tripping time, a proposed method for selecting suitable backup relay is used, which leads to decrease relays tripping time and increase system stability, output settings for relays in all cases achieved our constrains.

Single-Atom Protecting Group for on-Surface Synthesis of Graphdiyne Nanowires

On-surface synthesis of semiconducting graphdiyne nanowires usually suffer severe side reactions owing to the high reactivity of the butadiynylene units at noble metal surfaces,limiting the production of isolated nanowires. In this work, we report the high-yield synthesis of branchless graphdiyne nanowires [-C≡C-Ph2-C≡C-]nvia on-surface Ullmann coupling of 1,4-bis（4-bromophenyl）-1,3-butadiyne molecules with chemical vapor deposition method.Non-contact atomic force microscopy with single-bond resolution reveals that single gold adatoms act as effective protecting groups for butadiynylene units by forming Au-π ligand bonds, preventing unwanted branched coupling reactions and enabling the synthesis of ultralong isolated graphdiyne nanowires. This study will stimulate further investigation on the role of various surface adatoms in protecting on-surface reactions.

The Compatibility of Groups Used to Protect Phenolic Functionality during Oxone-Mediated Oxidative Esterification

Protecting groups often play an essential role in organic synthesis, particularly for multi-step synthesis or natural product total synthesis. Various protecting groups areavailable to mask the vulnerable functionality;phenolic hydroxy groups are noteworthy examples, but their stability differs when protected. Herein, the compatibility of protective phenolic functionality was investigated with the implementation of indium (III) triflate-catalyzed oxidative esterification using Oxone in methanol. A wide range of protective moieties was selected and subjected to Oxone-mediated oxidative esterification. For example, sulfonates were found to be sufficiently stable and inert whereas acetals were susceptible to reaction conditions. The details of this investigation are provided.

Investigation into Protective Groups for Anilino Functionality upon Oxone-Mediated Oxidative Esterification

In the course of organic synthesis, particularly for multi-step synthesis or natural product total synthesis, the selection of appropriate protective groups for the intended functionality is crucial in order to achieve chemoselective synthetic goals. The development of many useful protective groups has been reported based on the functionality of the anilino group. Herein, we discuss our study of various protective groups and the processes we used to establish compatibility with anilino functionality via the implementation of Oxone-mediated oxidative esterification in methanol. The results and the details of our experiments are reported herein.

Academic Forum on Protection of Vulnerable Groups' Rights

On March 19, an academic forum was held in Jinan City, Shandong Province, on protection of vulnerable groups’ rights. Sponsored by the Law School of Shandong University, it gathered some 50 experts from the Central Patty School, Chinese Academy of Social Sciences, China Society for Human Rights Studies, Shandong Higher People’s Court, as well as some research universities in the country. Four subjects were discussed at the forum: definition of vulnerable groups, legal principles for protection of vulnerable groups’

Development of the Protection of the Rights of Specific Groups in China in the Recent Ten Years——Based on an Analysis of the Annual Report on China’s Human Rights

specific groups such as women,children,ethnic minorities,the elderly,and persons with disabilities are facing special difficulties in exercising their rights The protection of their rights is an important part of the development of China’s human rights cause The Annual Report on China’s Human Rights have outlined the tremendous achievements China has made in protecting the rights of specific groups over the past ten years It also reflects that all human rights actors have born fruitful results of innovation in values,legal systems,paths for practice,and international cooperation of rights protection,which will continue to inspire and en courage people to participate in the common cause of human rights protection.

Effect of Wave Groups on Wave Run-up

-The effect of wave group on wave run-up on a slope dike is mainly discussed in this paper. Two simulating methods of wave group and their applications in laboratory are introduced. Synthesizing the research results of wave run-up on a slope dike, the effect of wave group on wave run-up on a slope dike in coastal protection engineering is studied as the main point.

A NEW POLYMER-BOUND 1,2-DIOL AS A PROTECTING AGENT FOR SYMMETRICAL DIALDEHYDE

A novel polymer-bound 1,2-diol, 3-polystyrylsulfonyl-1,2-propanediol (6) had been prepared by the reaction of sodium polystyrylsulfinate with allyl bromide, followed by oxidation and. hydrolysis or directly with 3-chloro-1,2-propanediol in the presence of a phase transfer catalyst, n-tetrabutylammonium iodide. The capacity of resin 6 for terephthaidehyde reached 1.43 mmol/g. The aldehydic groups attached to polymer 6 reacted with hydroxylamine hydrochloride or reduced by sodium borohydride giving p-formylbenzaldoxime (yield: 89%)and p-formyl-benzalcohol (yield: 734%), respectively. The high yields of these polymer-supported reactions showed that the polymer 6 possessed the effective isolation of its reactive sites.

Design and construction of scour protection for deep-water group pile foundation structures of two pylons in the Sutong Bridge project

Sutong Bridge,as a world-record cable-stayed bridge with its main span exceeding 1 000 m constructed in Yangtze River estuary region in China,is located at a site with complicated hydrologic conditions and poor geotechnical conditions and therefore,scour protection will be a decisive factor for ensuring smooth and successful construction of this bridge.This paper,starting from structural description of deep-water group pile foundation,analyzes impact to the bridge safety introduced by scour and its protection and further presents different solutions of scour protection for foundation structures of this bridge.

Enhancing hydrolytic stability of dynamic imine bonds and polymers in acidic media with internal protecting groups

Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting groups for improving the kinetic stability of dynamic imine bonds and polymers.Systematic examination of structure-reactivity relationship of a series of aldehydes/imines bearing a neighboring carboxyl allowed uncovering of required structural features for dynamically masking imine bonds with cyclic structures.Mechanistic studies indicated that noncovalent interactions along with sterics control the ringchain equilibrium and the stability of imine bonds.The incorporation of internal protecting groups into imine polymers further enabled their controlled stability in acidic media.Moreover,a combination of dynamic covalent network and coordination supramolecular network provided a facile means for the modulation of luminescent and mechanical properties of polymers.The strategies and results reported should be beneficial to molecular assemblies,dynamic polymers,biological delivery,and intelligent materials.

Groupon式团购网站与商家合作关系的法律分析

从法律的角度分析发现,在不同的网络团购环境下,电子券的运用和网站收取货款是两个关键要点;团购网站和商家具有完全不同性质的合作关系,即;Groupon式团购网站和商家之间首先应当是一种委托关系,然后商家又以自己的名义跟消费者发生了直接的团购交易关系,进而Groupon式团购网站又从商家处获得相应的佣金报酬。因此,将Groupon式团购网站、商家和消费者三者间的关系界定为行纪合同关系更为合理。

Regioselective protection of 10-deacetylbaccatin Ⅲ and semi-synthesis of paclitaxel

Semi-synthesis of paclitaxel was achieved in four steps from 10-deacetylbaccatin HI （10-DAB HI）. The key steps are the regioselective protection at the hydroxyl group at C-7 of 10-DAB HI, using 1,1′-thiocarbonyldiimidazole as a selective reagent, and the deprotection of the protected paclitaxel with a mixture of p-toluenesulfonic acid and 0.1 mol/L aqueous hydrochloride.

Highly efficient removal of allyloxycarbonyl(Alloc)function provides a practical orthogonal protective strategy for carbohydrates

Highly efficient removal of allyloxycarbonyl （Alloc） group was achieved in the presence of CH3COONH4, Pd[P（C6H5）3]4, and NaBH4 in MeOH-THF, within 5 min in almost quantitative yields （〉90%, isolated yield） without affecting acetyl, benzoyl, isopropylidene, benzylidene, allyl, benzyl, benzyl carbonate, or azido groups.

How to Make Virtual Community More Active and Cohesive:From Brand and Perceived Protection Perspectives

With the increasing popularity of the Internet and mobile Internet, the Virtual Community （VC） is becoming an important medium for person-to-person communication. To realise the potential of the VC, it is neces- sary to cultivate within it good group cohesion and vitality. Using empirical and experimental research methods, this study explores the ef- fect of users＇ trust in the VC Platform （VCP） on group cohesion and vitality and how brand and perceived privacy security can affect us- ers＇ trust in the VC. The research results indi- cate that the brand of the VCP can directly af- fect users＇ trust in the VC, and can also influe- nce it indirectly through users＇ perceived pri- vacy protection and perceived security protec- tion. Further, this study also confu＇ms that the performance of the VC （group cohesion and vitality） is significantly affected by users＇ trust in the VC. The results of this study can provide theoretical guidance for internet companies to maintain and enhance the value of VCs.

Aryl groups,supplement of amino protecting group chemistry!

Amino group protective strategy has consequently emerged in multistep organic synthesis.Easy and selective deprotection procedures are crucial to facilitate the chemical transformation.Recently,Zhang’s group from Henan Normal University collaborating with Chen’s group of Nankai University developed a novel strategy for the regiospecific cleavage of inert aryl C-N bonds in N-aryl amides by hypervalent iodine(V)reagents.These procedures allow removal of sort of aryl groups under mild conditions to give primary amides in high efficiency.It bestows these aryl groups with the characteristics of amino protecting groups that might be the supplement of amino protecting group chemistry.

The Development of Human Rights Protection in Cross-border Personality Rights and Tort Conflict Laws

Personality rights are basic rights related to human dignity in the concept of human rights protection,and respect for personality rights is the basic prerequisite for safeguarding other human rights.Human rights protection exerts a profound impact on the value of legislation and enforcement practices of private international laws in the field of cross-border personality rights infringement in various countries,which is mainly manifested in the integration of substantive justice and the humanistic care concept of protecting the rights of vulnerable groups into formal justice,and expands the development space of human rights protection ideas in cross-border personality rights and tort conflict laws.the diversity of human rights protection values determines that cross-border personality rights infringement may lead to conflicts between personality rights and other basic rights,such as freedom of speech.to reconcile such conflicts,a workable method is to prioritize personality rights protection in accordance with the hierarchy of rights theory in the value judgment of public order reservation or to clarify the limits of the right holder’s tolerance obligation through the limited application of the principle of proportionality.China’s current cross-border personality rights and tort conflict law can optimize the protection of the rights of vulnerable groups by diversifying the options of available legal methods,and establish a balancing mechanism between personality rights and freedom of speech,so as to improve China’s legal protection system for human rights in the field of foreign-related civil and commercial affairs.

一种基于区块链的医疗数据隐私保护方法

为解决医疗数据的泄露或恶意被窜改以及医疗纠纷问题,提出一种基于区块链的医疗数据隐私保护方法。利用哈希算法加密患者的身份信息,治疗结果通过AES(advanced encryption standard)算法加密,而AES的密钥使用ECC(ellipse curve ctyptography)算法加密,所有的加密密钥、治疗结果、患者身份信息存储到联盟链上。采用群签名技术追溯签名医院,群管理员可以解密医疗数据,将其作为重要依据协助第三方解决医疗纠纷。效率分析表明,在安全性相同的情况下,该方法的加/解密效率比对比方案分别提高了14%和46%,同时分析了群签名各类算法的时间开销。通过与同类方法对比,该方法既可实现患者身份、医疗数据的分类隐私保护,又可保证交易存储开销是合理的,在医疗数据隐私保护领域具有一定的应用价值。

电快速瞬变脉冲群串扰耦合分析及防护措施研究

EFT产生的瞬态脉冲干扰可通过电缆耦合进入电子系统的内部,损伤电子设备。为降低瞬态脉冲对电缆串扰耦合的影响,首先利用电磁仿真软件CST建立平行电缆耦合仿真模型,当电压等级为4 kV时,测试电缆的近端串扰电压达到71.2 V,远高于部分敏感器件的阈值;然后通过分析电快速瞬变脉冲群的频谱特性,瞬态脉冲的干扰能量主要集中在1~10 MHz的范围内;最后利用仿真软件Filter Solution设计合理的防护电路。结果表明,防护电路能有效降低瞬态脉冲对电路的影响。