Surface coating technology is an effective way to solve the interface insulation problem of DC GIS/GIL basin insulators, but the performance of the coating will change greatly, and the insulation strength will be comp...Surface coating technology is an effective way to solve the interface insulation problem of DC GIS/GIL basin insulators, but the performance of the coating will change greatly, and the insulation strength will be completely lost, after long-term use in the extreme conditions of corona erosion. In this research, the multi-needle-plate electrode platform was constructed to explore the long-term use performance of Si C-doped nanocomposite exposed to corona discharge in SF6gas. Samples with a high Si C content have advantages in maintaining physical and chemical properties such as elemental composition, erosion depth, surface roughness and mass loss. The nanocomposite doped with 6 wt.% Si C has prominent surface insulation strength after long term exposure to corona, and the others are close to losing, or have completely lost,their insulating properties. Furthermore, the degradation mechanism of physicochemical properties of composite exposed to corona discharge was investigated with the proposed Reax FF MD model of energetic particles from SF6decomposition bombarding the epoxy surface. The reaction process of SF particles and F particles with the cross-linked epoxy resin, and the Si C nanoparticles providing shelter to the surrounding polymer and mitigating their suffering direct bombardment, have been established. The damage propagation depth, mass loss and surface roughness change of nanocomposite material bombarded by SF6decomposition products is reproduced in this simulation. Finally, the deterioration mechanism of insulation properties for the Si C-doped composite was elucidated with DFT analysis. The band gap of the molecule containing S drops directly from the initial 7.785 e V to 1.875 e V, which causes the deterioration of surface electric properties.展开更多
A novel polyamide 6/silica nanocomposite containing epoxy resins(EPA6N) was prepared via in situ polymerization using tetraethoxysilane(TEOS) as the precursor of silica.The dynamic rheological properties of pure PA6 a...A novel polyamide 6/silica nanocomposite containing epoxy resins(EPA6N) was prepared via in situ polymerization using tetraethoxysilane(TEOS) as the precursor of silica.The dynamic rheological properties of pure PA6 and EPA6N at temperatures of 225 and 235 ℃ were investigated.The results of transmission electron microscopy(TEM) and atomic force microscopy(AFM) indicate that the silica particles are well dispersed in the polyamide 6 matrix on about 30 nm in diameter,which demonstrates that this method can effectively avoid agglomeration of the inorganic particles.The rheological results suggest that pure PA6 shows Newtonian behavior.However,the novel EPA6N exhibits a solid-like rheological behavior,which is due to the small size,large surface of silica particles and the stronger polyamide 6-silica chemical bond formed through the reactions of epoxy resins with end groups of PA6 molecular chains.The EPA6N also exhibits higher melt viscosity,storage modulus and loss modulus than those of pure PA6.展开更多
The bio-based epoxy nanocomposite(GAER/DOPO-POSS)was prepared from gallic epoxy resin(GAER)and polyhedral oligomeric silsesquioxane(which containing 9,10-dihydrogen-9-oxo-10-phosphorus-phenanthrene-10-oxide groups,cal...The bio-based epoxy nanocomposite(GAER/DOPO-POSS)was prepared from gallic epoxy resin(GAER)and polyhedral oligomeric silsesquioxane(which containing 9,10-dihydrogen-9-oxo-10-phosphorus-phenanthrene-10-oxide groups,called DOPO-POSS).The polyhedral oligomeric silsesquioxane containing epoxy groups(E-POSS)was grafted onto aminated graphene oxide(E-GO),then the novel POSS-E-GO was obtained.The POSS-E-GO was used as modifier for GAER/DOPO-POSS nanocomposite.The influences of POSS-E-GO content on mechanical properties,dynamic mechanical properties and thermal stability of GAER/DOPO-POSS nanocomposites were determined.The experimental results show that POSS-E-GO can significantly improve the toughness of the GAER/DOPO-POSS nanocomposite.When 0.5wt% POSS-E-GO was added in GAER/DOPO-POSS nanocomposite,the impact strength of the nanocomposite was 4.74 kJ/m^(2) higher than that in the absence of POSS-E-GO,meantime the initial thermal degradation temperature was 277℃.展开更多
Massive limestones were used in construction of ancient Egyptian tombs, temples, obelisks and other sculptures. These stones are always exposed to physico-mechanical deterioration and destructive forces, leading to pa...Massive limestones were used in construction of ancient Egyptian tombs, temples, obelisks and other sculptures. These stones are always exposed to physico-mechanical deterioration and destructive forces, leading to partial or total collapse. The task of reassembling this type of artifacts represents a big challenge for the conservators. Recently, the researchers are turning to new technologies to improve the properties of traditional adhesive materials and techniques used in re-assembly of broken massive stones. The epoxy resins are used extensively in stone conservation and re-assembly of broken stones because of their outstanding mechanical properties. The adding of nanoparticles to polymeric adhesives at low percentages may lead to substantial improvements of their mechanical performances in structural joints and massive objects. The aim of this study is to evaluate the effectiveness of montmorillonite clay, calcium carbonate, and silicon dioxide nanoparticles for enhancing the performances of epoxy adhesives used in re-assembly of archaeological massive limestones. Scanning electron microscopy (SEM) was employed in order to investigate the morphology of the prepared nanocomposites, and the distribution of nanoparticles inside the composites. Artificial aging, tensile, compressive, and elongation strength tests were used to evaluate the efficiency of epoxy-nanocomposites. The results showed that the epoxy-clay nanocomposites exhibited superior tensile, compressive, and elongation strength, in addition to improving the mechanical properties of stone joints.展开更多
Epoxy resin nanocomposites reinforced with three different ionic liquid functionalized carbon nanotubes(f-CNTs)were fabricated by an in situ polymerization method.The influence of the anions on the curing process was ...Epoxy resin nanocomposites reinforced with three different ionic liquid functionalized carbon nanotubes(f-CNTs)were fabricated by an in situ polymerization method.The influence of the anions on the curing process was studied through differential scanning calorimetry(DSC)and normalized Fourier transform infrared(FTIR)spectroscopy.The composition of the nanocomposites was analyzed by X-ray photoelectron spectroscopy.Two different mechanisms are proposed to explain the curing process of the neat epoxy and its composites.The electric conductivity and mechanical properties of the nanocomposites are also reported.The tensile strength was increased dramatically due to the insertion of f-CNTs.Scanning electron microsopy fracture surface analysis indicates a strong interfacial bonding between the carbon nanotubes and the polymer matrix.展开更多
ZnS/bacterial cellulose/epoxy resin (ZnS/BC/E56) nanocomposites with good transparency and flexibil-ity were prepared and characterized. When the precursor Zn^2+ concentrations were not more than I wt%, the size of...ZnS/bacterial cellulose/epoxy resin (ZnS/BC/E56) nanocomposites with good transparency and flexibil-ity were prepared and characterized. When the precursor Zn^2+ concentrations were not more than I wt%, the size of the introduced ZnS nanoparticles was smaller than 50 nm and the distribution was homo-geneous within the composites. Under the condition, outstanding transmittance more than 70g in the visible light was obtained. By incorporation of ZnS nanoparticles with excellent thermo-optic stability to the composites, the thermo-optic coefficient was obviously increased from -361 × 10^-6 to -310 × 10^-6K^-1. The good flexibility, optical and mechanical properties endow the nanocomposites potential applica- tions in the flexible optoelectronic materials.展开更多
为研究石墨烯导电填料的加入对环氧材料电导机理的影响,制备了不同填料质量比下石墨烯/环氧树脂复合材料。通过测量得到该复合体系的渗流阈值为质量分数1.35%,选择了石墨烯填料质量分数为0.3%、远低于渗流阈值的复合材料进行研究。利用...为研究石墨烯导电填料的加入对环氧材料电导机理的影响,制备了不同填料质量比下石墨烯/环氧树脂复合材料。通过测量得到该复合体系的渗流阈值为质量分数1.35%,选择了石墨烯填料质量分数为0.3%、远低于渗流阈值的复合材料进行研究。利用高温高场强电导电流测试系统,测量了纯环氧材料和石墨烯/环氧复合材料在50、80和100℃下和0.24~14.4 k V/mm场强下的极化电流曲线。研究结果表明:直流电压作用下,两种材料的极化电流衰减速率均随场强和温度的增加而增大。随着场强的增大,两种材料的电导机理均发生了从欧姆电导到空间电荷限制电流理论(SCLC)为主导的转变,且这种转变电导电流场强阈值(Ethi)随温度的升高而降低。石墨烯填料的加入使环氧材料电导电流密度活化能增大,且活化能随着场强的增加逐渐降低,石墨烯/环氧复合材料在高场强区的电导机理受SCLC和隧道效应共同影响。展开更多
基金supported by National Natural Science Foundation of China(Nos.51737005,51929701,52177147 and 52127812)。
文摘Surface coating technology is an effective way to solve the interface insulation problem of DC GIS/GIL basin insulators, but the performance of the coating will change greatly, and the insulation strength will be completely lost, after long-term use in the extreme conditions of corona erosion. In this research, the multi-needle-plate electrode platform was constructed to explore the long-term use performance of Si C-doped nanocomposite exposed to corona discharge in SF6gas. Samples with a high Si C content have advantages in maintaining physical and chemical properties such as elemental composition, erosion depth, surface roughness and mass loss. The nanocomposite doped with 6 wt.% Si C has prominent surface insulation strength after long term exposure to corona, and the others are close to losing, or have completely lost,their insulating properties. Furthermore, the degradation mechanism of physicochemical properties of composite exposed to corona discharge was investigated with the proposed Reax FF MD model of energetic particles from SF6decomposition bombarding the epoxy surface. The reaction process of SF particles and F particles with the cross-linked epoxy resin, and the Si C nanoparticles providing shelter to the surrounding polymer and mitigating their suffering direct bombardment, have been established. The damage propagation depth, mass loss and surface roughness change of nanocomposite material bombarded by SF6decomposition products is reproduced in this simulation. Finally, the deterioration mechanism of insulation properties for the Si C-doped composite was elucidated with DFT analysis. The band gap of the molecule containing S drops directly from the initial 7.785 e V to 1.875 e V, which causes the deterioration of surface electric properties.
基金Project(07A071) supported by the Scientific Research Foundation of Hunan Provincial Education Department
文摘A novel polyamide 6/silica nanocomposite containing epoxy resins(EPA6N) was prepared via in situ polymerization using tetraethoxysilane(TEOS) as the precursor of silica.The dynamic rheological properties of pure PA6 and EPA6N at temperatures of 225 and 235 ℃ were investigated.The results of transmission electron microscopy(TEM) and atomic force microscopy(AFM) indicate that the silica particles are well dispersed in the polyamide 6 matrix on about 30 nm in diameter,which demonstrates that this method can effectively avoid agglomeration of the inorganic particles.The rheological results suggest that pure PA6 shows Newtonian behavior.However,the novel EPA6N exhibits a solid-like rheological behavior,which is due to the small size,large surface of silica particles and the stronger polyamide 6-silica chemical bond formed through the reactions of epoxy resins with end groups of PA6 molecular chains.The EPA6N also exhibits higher melt viscosity,storage modulus and loss modulus than those of pure PA6.
基金Funded by the Natural Science Foundation of Hebei Province(No.B2019210221)the Project by S&T Program of Hebei(No.206Z1202G)。
文摘The bio-based epoxy nanocomposite(GAER/DOPO-POSS)was prepared from gallic epoxy resin(GAER)and polyhedral oligomeric silsesquioxane(which containing 9,10-dihydrogen-9-oxo-10-phosphorus-phenanthrene-10-oxide groups,called DOPO-POSS).The polyhedral oligomeric silsesquioxane containing epoxy groups(E-POSS)was grafted onto aminated graphene oxide(E-GO),then the novel POSS-E-GO was obtained.The POSS-E-GO was used as modifier for GAER/DOPO-POSS nanocomposite.The influences of POSS-E-GO content on mechanical properties,dynamic mechanical properties and thermal stability of GAER/DOPO-POSS nanocomposites were determined.The experimental results show that POSS-E-GO can significantly improve the toughness of the GAER/DOPO-POSS nanocomposite.When 0.5wt% POSS-E-GO was added in GAER/DOPO-POSS nanocomposite,the impact strength of the nanocomposite was 4.74 kJ/m^(2) higher than that in the absence of POSS-E-GO,meantime the initial thermal degradation temperature was 277℃.
文摘Massive limestones were used in construction of ancient Egyptian tombs, temples, obelisks and other sculptures. These stones are always exposed to physico-mechanical deterioration and destructive forces, leading to partial or total collapse. The task of reassembling this type of artifacts represents a big challenge for the conservators. Recently, the researchers are turning to new technologies to improve the properties of traditional adhesive materials and techniques used in re-assembly of broken massive stones. The epoxy resins are used extensively in stone conservation and re-assembly of broken stones because of their outstanding mechanical properties. The adding of nanoparticles to polymeric adhesives at low percentages may lead to substantial improvements of their mechanical performances in structural joints and massive objects. The aim of this study is to evaluate the effectiveness of montmorillonite clay, calcium carbonate, and silicon dioxide nanoparticles for enhancing the performances of epoxy adhesives used in re-assembly of archaeological massive limestones. Scanning electron microscopy (SEM) was employed in order to investigate the morphology of the prepared nanocomposites, and the distribution of nanoparticles inside the composites. Artificial aging, tensile, compressive, and elongation strength tests were used to evaluate the efficiency of epoxy-nanocomposites. The results showed that the epoxy-clay nanocomposites exhibited superior tensile, compressive, and elongation strength, in addition to improving the mechanical properties of stone joints.
基金supported by the NBIT Program funded jointly by the Ministry of Science and Technology of Korea and the US Air Force Office of Scientific Research.Dr.Z.Guo appreciatessupport from the National Science Foundation-Nanoscale Interdisciplinary Research Team(NIRT)Materials Processing and Manufacturing(CMMI 10-30755)。
文摘Epoxy resin nanocomposites reinforced with three different ionic liquid functionalized carbon nanotubes(f-CNTs)were fabricated by an in situ polymerization method.The influence of the anions on the curing process was studied through differential scanning calorimetry(DSC)and normalized Fourier transform infrared(FTIR)spectroscopy.The composition of the nanocomposites was analyzed by X-ray photoelectron spectroscopy.Two different mechanisms are proposed to explain the curing process of the neat epoxy and its composites.The electric conductivity and mechanical properties of the nanocomposites are also reported.The tensile strength was increased dramatically due to the insertion of f-CNTs.Scanning electron microsopy fracture surface analysis indicates a strong interfacial bonding between the carbon nanotubes and the polymer matrix.
基金financially supported by the Program of Introducing Talents of Discipline to Universities (No. B07024)the Shanghai Leading Academic Discipline Project (No. B603)+1 种基金the National Natural Science Foundation of China (No. 51273043)the Project of the Action on Scientists and Engineers to Serve Enterprises (No. 2009GJE20016)
文摘ZnS/bacterial cellulose/epoxy resin (ZnS/BC/E56) nanocomposites with good transparency and flexibil-ity were prepared and characterized. When the precursor Zn^2+ concentrations were not more than I wt%, the size of the introduced ZnS nanoparticles was smaller than 50 nm and the distribution was homo-geneous within the composites. Under the condition, outstanding transmittance more than 70g in the visible light was obtained. By incorporation of ZnS nanoparticles with excellent thermo-optic stability to the composites, the thermo-optic coefficient was obviously increased from -361 × 10^-6 to -310 × 10^-6K^-1. The good flexibility, optical and mechanical properties endow the nanocomposites potential applica- tions in the flexible optoelectronic materials.
文摘为研究石墨烯导电填料的加入对环氧材料电导机理的影响,制备了不同填料质量比下石墨烯/环氧树脂复合材料。通过测量得到该复合体系的渗流阈值为质量分数1.35%,选择了石墨烯填料质量分数为0.3%、远低于渗流阈值的复合材料进行研究。利用高温高场强电导电流测试系统,测量了纯环氧材料和石墨烯/环氧复合材料在50、80和100℃下和0.24~14.4 k V/mm场强下的极化电流曲线。研究结果表明:直流电压作用下,两种材料的极化电流衰减速率均随场强和温度的增加而增大。随着场强的增大,两种材料的电导机理均发生了从欧姆电导到空间电荷限制电流理论(SCLC)为主导的转变,且这种转变电导电流场强阈值(Ethi)随温度的升高而降低。石墨烯填料的加入使环氧材料电导电流密度活化能增大,且活化能随着场强的增加逐渐降低,石墨烯/环氧复合材料在高场强区的电导机理受SCLC和隧道效应共同影响。