The chemical equilibrium and reaction kinetic behavior in the synthesis of polyoxymethylene dimethyl ethers （DMMn） were investigated over sulfated titania in order to reveal the decisive factor controlling the react...The chemical equilibrium and reaction kinetic behavior in the synthesis of polyoxymethylene dimethyl ethers （DMMn） were investigated over sulfated titania in order to reveal the decisive factor controlling the reaction. The results showed that the molar ratio of adjacent DMMn products in equilibrium solution had the same value, which depended absolutely on the reaction temperature. Meanwhile, the reactions had the same DMMn products distributions under varied reaction conditions. The equilibrium constants of the related step-wise reactions for DMMn formation were equal, which were calculated based on the bulk compositions of the reaction solution. And thus, the selectivity to DMMn was mainly controlled by the chemical equilibrium, i.e., thermodynamic control. In brief, the present results provide some guidance for future synthesis of DMMn.展开更多
The space effects of oval-shaped furrow pit slopes were analyzed by the elastic mechanics principle.The interaction of limit equilibrium slope angle,friction coefficient,cohesion and horizontal radius of oval-shaped f...The space effects of oval-shaped furrow pit slopes were analyzed by the elastic mechanics principle.The interaction of limit equilibrium slope angle,friction coefficient,cohesion and horizontal radius of oval-shaped furrow pits has been derived.The oval trumpet-like rock mass is homogeneous and elastic while only loaded by its dead weight.The interaction indicates that the deeper an oval-shaped furrow pit is excavated,the greater the limit equilibrium slope angle.Both the theory base for reducing stripping waste rock in an oval-shaped furrow pit and the basic way to determine the configuration of a stable slope were developed from the mentioned interaction.The theory includes the preceding principles of stability analysis of slopes.Compared with the configuration determined by traditional theory of slope stability,a great quantity of stripping waste rock can be reduced by that determined in this paper under stable conditions.展开更多
The following equation is proposed in this paper to estimate the crustal growth rate of the North China Platform on the basis of mass equilibrium between the crust and the mantle:The results indicate that the mass fra...The following equation is proposed in this paper to estimate the crustal growth rate of the North China Platform on the basis of mass equilibrium between the crust and the mantle:The results indicate that the mass fractions of the crust during different geological periods are close to the real mass fractions of the crust in the upper mantle and the whole mantle (2-2.5% and 0.5 -0.6%, respectively, Hofmann, 1986), and the discrepancy of the results is probably related to that the heterogeneous contribution of the mantle to the crust both in space and in element. The results also show that the mass of the Archaean crust is only half that of the Proterozoic crust, and the crustal mass remained unchanged from Proterozoic to Paleozoic. suggesting that the plate movement at least started from the Late Proterozoic.展开更多
In this paper, a SEIR model with ratio-dependent transmission rate in the form ?is studied and the basic reproduction number which determines the disease’s extinction or continued existence is obtained. By constructi...In this paper, a SEIR model with ratio-dependent transmission rate in the form ?is studied and the basic reproduction number which determines the disease’s extinction or continued existence is obtained. By constructing the proper Lyapunov function, we prove that if R0 ≤ 1, the disease-free equilibrium point of the model is globally asymptotically stable and the disease always dies out;if R0 > 1, the endemic equilibrium point is globally asymptotically stable and the disease persists.展开更多
Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states i...Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states is obtained in drying and wetting process.At high suctions,the hysteresis behaviour is not obvious in relationship between water content and suction,while the opposite holds between degree of saturation and suction.The suction variation can change its water retention behaviour and void ratio.Moreover,changes of void ratio can bring about changes in degree of saturation.Therefore,the total change in degree of saturation includes changes caused by suction and that by void ratio.In the space of degree of saturation and suction,the SWRC at constant void ratio shifts to the direction of higher suctions with decreasing void ratio.However,the relationship between water content and suction is less affected by changes of void ratio.The degree of saturation decreases approximately linearly with increasing void ratio at a constant suction.Moreover,the slope of the line decreases with increasing suction and they show an approximately linear relationship in semi-logarithmical scale.From this linear relationship,the variation of degree of saturation caused by the change in void ratio can be obtained.Correspondingly,SWRC at a constant void ratio can be determined from SWRC at different void ratios.展开更多
惠州26-6构造目的层面临流体类型复杂、流体判识难度大的问题,而传统气测录井方法受仪器精度影响,凝析气与轻质油的气测录井响应差异不明显。针对上述复杂问题,基于实时流体录井(fluids logging&analysis in real-time,FLAIR)资料,...惠州26-6构造目的层面临流体类型复杂、流体判识难度大的问题,而传统气测录井方法受仪器精度影响,凝析气与轻质油的气测录井响应差异不明显。针对上述复杂问题,基于实时流体录井(fluids logging&analysis in real-time,FLAIR)资料,在统计区域内气层、凝析气层及油层的烃组分比值特征基础上,优选烃组分参数,结合测井、取样及测试资料,提出了研究区目的层潜山气油界面划分及流体识别技术体系。研究表明:FLAIR烃湿度比(humidity ratio,WH)、烃平衡比(equilibrium ratio,BH)建立定性流体识别图版可以较好地识别凝析气组分和轻质油响应,凝析气的烃组分甲烷(methane,C_(1))、乙烷(ethane,C_(2))占比高,而轻质油的烃组分丙烷(propane,C_(3))、丁烷(butane,C_(4))、戊烷(pentane,C_(5))、己烷(hexane,C_(6))占比高;利用气油比指数R与测试、电缆泵抽取样气油比建立关系模型。结果表明,干气:BH>20,WH<11,气油比指数R>61.54;凝析气:BH>15,WH<19,气油比指数R介于2.16~61.54;油:BH<15,WH>19,气油比指数R<2.16。通过两种方法相结合,有效解决了研究区目的层潜山气油界面划分及流体识别难题,证实该方法在复杂储集层及流体条件下具有广泛的推广应用价值。展开更多
基金supported by the National Natural Science Foundation of China(NSFC,No.21203220 and 21133011)China Postdoctoral Science Foundation(No.2014M551674)+1 种基金Jiangsu Planned Projects for Postdoctoral Research Funds(No.1302070C)the National Basic Research Program of China(973 Program,No.2011CB201404)
文摘The chemical equilibrium and reaction kinetic behavior in the synthesis of polyoxymethylene dimethyl ethers （DMMn） were investigated over sulfated titania in order to reveal the decisive factor controlling the reaction. The results showed that the molar ratio of adjacent DMMn products in equilibrium solution had the same value, which depended absolutely on the reaction temperature. Meanwhile, the reactions had the same DMMn products distributions under varied reaction conditions. The equilibrium constants of the related step-wise reactions for DMMn formation were equal, which were calculated based on the bulk compositions of the reaction solution. And thus, the selectivity to DMMn was mainly controlled by the chemical equilibrium, i.e., thermodynamic control. In brief, the present results provide some guidance for future synthesis of DMMn.
文摘The space effects of oval-shaped furrow pit slopes were analyzed by the elastic mechanics principle.The interaction of limit equilibrium slope angle,friction coefficient,cohesion and horizontal radius of oval-shaped furrow pits has been derived.The oval trumpet-like rock mass is homogeneous and elastic while only loaded by its dead weight.The interaction indicates that the deeper an oval-shaped furrow pit is excavated,the greater the limit equilibrium slope angle.Both the theory base for reducing stripping waste rock in an oval-shaped furrow pit and the basic way to determine the configuration of a stable slope were developed from the mentioned interaction.The theory includes the preceding principles of stability analysis of slopes.Compared with the configuration determined by traditional theory of slope stability,a great quantity of stripping waste rock can be reduced by that determined in this paper under stable conditions.
文摘The following equation is proposed in this paper to estimate the crustal growth rate of the North China Platform on the basis of mass equilibrium between the crust and the mantle:The results indicate that the mass fractions of the crust during different geological periods are close to the real mass fractions of the crust in the upper mantle and the whole mantle (2-2.5% and 0.5 -0.6%, respectively, Hofmann, 1986), and the discrepancy of the results is probably related to that the heterogeneous contribution of the mantle to the crust both in space and in element. The results also show that the mass of the Archaean crust is only half that of the Proterozoic crust, and the crustal mass remained unchanged from Proterozoic to Paleozoic. suggesting that the plate movement at least started from the Late Proterozoic.
文摘In this paper, a SEIR model with ratio-dependent transmission rate in the form ?is studied and the basic reproduction number which determines the disease’s extinction or continued existence is obtained. By constructing the proper Lyapunov function, we prove that if R0 ≤ 1, the disease-free equilibrium point of the model is globally asymptotically stable and the disease always dies out;if R0 > 1, the endemic equilibrium point is globally asymptotically stable and the disease persists.
基金the National Natural Sciences Foundation of China (No. 41102163)
文摘Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states is obtained in drying and wetting process.At high suctions,the hysteresis behaviour is not obvious in relationship between water content and suction,while the opposite holds between degree of saturation and suction.The suction variation can change its water retention behaviour and void ratio.Moreover,changes of void ratio can bring about changes in degree of saturation.Therefore,the total change in degree of saturation includes changes caused by suction and that by void ratio.In the space of degree of saturation and suction,the SWRC at constant void ratio shifts to the direction of higher suctions with decreasing void ratio.However,the relationship between water content and suction is less affected by changes of void ratio.The degree of saturation decreases approximately linearly with increasing void ratio at a constant suction.Moreover,the slope of the line decreases with increasing suction and they show an approximately linear relationship in semi-logarithmical scale.From this linear relationship,the variation of degree of saturation caused by the change in void ratio can be obtained.Correspondingly,SWRC at a constant void ratio can be determined from SWRC at different void ratios.
