The title complex [ErY(Gly)_6(H_2O)4](ClO_4)_6·51H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P.The unit cell parameter...The title complex [ErY(Gly)_6(H_2O)4](ClO_4)_6·51H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P.The unit cell parameters are as follows:a=1.1518(4) nm,b=1.4105(7) nm,c=1.5530(6) nm,α=96.61(3)°,β=102.74(3)°, γ=105.70(3)°,V=2.3277(17) nm^3,Z=2,D_(calc)=2.091 g/cm^3.The structure has been refined to a final R of 0.0785.The crystal-is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er^(3+) and Y^(3+) ions,and the other two carboxyl groups bridge two adjacent Er^(3+) or Y^(3+) ions.展开更多
The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters ar...The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters are as follows:a=11.518(4),b=14.105(7),c=15.530(6) ,α=96.61(3), β=102.74(3),γ=105.70(3)°,V=2327.7(17) ~3,Z=2,Dc=2.091g/cm^3.The structure has been refined to a final R of 0.0785.The crystal is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er(Ⅲ)and Y(Ⅲ)ion,other two carboxyl groups bridge two adjacent Er(Ⅲ)or two Y(Ⅲ)ions.展开更多
目的:比较使用不同模式Er:YAG激光以及传统车针去龋后牙本质与复合树脂的粘接强度。方法:选用人类离体磨牙模拟龋坏,分别采用Er:YAG激光中短脉冲(medium short pulse,MSP)模式、Er:YAG激光超短脉冲(super short pulse,SSP)模式和传统车...目的:比较使用不同模式Er:YAG激光以及传统车针去龋后牙本质与复合树脂的粘接强度。方法:选用人类离体磨牙模拟龋坏,分别采用Er:YAG激光中短脉冲(medium short pulse,MSP)模式、Er:YAG激光超短脉冲(super short pulse,SSP)模式和传统车针去除模拟的龋坏后,采用自酸蚀粘接剂将牙体标本与复合树脂粘接制成试件。使用万能试验机对试件进行拉伸试验,测得断裂负荷和粘接强度,并采用单因素方差分析和Tukey多重比较进行统计学分析。采用扫描电子显微镜观察3种不同去龋方式处理后的牙本质表面形态,以及涂布自酸蚀粘接剂并固化后试件的横截面形态。结果:使用Er:YAG激光MSP模式处理后牙本质与复合树脂的粘接强度最高,SSP模式处理后次之,传统车针处理后最低,但差异无统计学意义(P>0.05)。扫描电子显微镜图像显示,Er:YAG激光MSP模式处理后的牙本质表面较平坦,牙本质小管内几乎没有残屑;Er:YAG激光SSP模式处理后的牙本质表面呈现鳞片状,牙本质小管内可见少量碎屑;而传统车针处理后牙本质小管大部分处于被表面牙本质部分甚至完全遮盖的状态,牙本质小管内充满残屑。结论:使用Er:YAG激光去龋相比传统车针去龋可以获得较好的牙本质粘接强度,且对牙本质小管的处理深度和洁净度明显优于传统车针去龋,其中MSP模式更佳。展开更多
基金The Project supported by the National Natural Science Foundation of China
文摘The title complex [ErY(Gly)_6(H_2O)4](ClO_4)_6·51H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P.The unit cell parameters are as follows:a=1.1518(4) nm,b=1.4105(7) nm,c=1.5530(6) nm,α=96.61(3)°,β=102.74(3)°, γ=105.70(3)°,V=2.3277(17) nm^3,Z=2,D_(calc)=2.091 g/cm^3.The structure has been refined to a final R of 0.0785.The crystal-is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er^(3+) and Y^(3+) ions,and the other two carboxyl groups bridge two adjacent Er^(3+) or Y^(3+) ions.
基金Project supported by the National Natural Science Foundation of China
文摘The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters are as follows:a=11.518(4),b=14.105(7),c=15.530(6) ,α=96.61(3), β=102.74(3),γ=105.70(3)°,V=2327.7(17) ~3,Z=2,Dc=2.091g/cm^3.The structure has been refined to a final R of 0.0785.The crystal is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er(Ⅲ)and Y(Ⅲ)ion,other two carboxyl groups bridge two adjacent Er(Ⅲ)or two Y(Ⅲ)ions.
文摘目的:比较使用不同模式Er:YAG激光以及传统车针去龋后牙本质与复合树脂的粘接强度。方法:选用人类离体磨牙模拟龋坏,分别采用Er:YAG激光中短脉冲(medium short pulse,MSP)模式、Er:YAG激光超短脉冲(super short pulse,SSP)模式和传统车针去除模拟的龋坏后,采用自酸蚀粘接剂将牙体标本与复合树脂粘接制成试件。使用万能试验机对试件进行拉伸试验,测得断裂负荷和粘接强度,并采用单因素方差分析和Tukey多重比较进行统计学分析。采用扫描电子显微镜观察3种不同去龋方式处理后的牙本质表面形态,以及涂布自酸蚀粘接剂并固化后试件的横截面形态。结果:使用Er:YAG激光MSP模式处理后牙本质与复合树脂的粘接强度最高,SSP模式处理后次之,传统车针处理后最低,但差异无统计学意义(P>0.05)。扫描电子显微镜图像显示,Er:YAG激光MSP模式处理后的牙本质表面较平坦,牙本质小管内几乎没有残屑;Er:YAG激光SSP模式处理后的牙本质表面呈现鳞片状,牙本质小管内可见少量碎屑;而传统车针处理后牙本质小管大部分处于被表面牙本质部分甚至完全遮盖的状态,牙本质小管内充满残屑。结论:使用Er:YAG激光去龋相比传统车针去龋可以获得较好的牙本质粘接强度,且对牙本质小管的处理深度和洁净度明显优于传统车针去龋,其中MSP模式更佳。
