The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters ar...The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters are as follows:a=11.518(4),b=14.105(7),c=15.530(6) ,α=96.61(3), β=102.74(3),γ=105.70(3)°,V=2327.7(17) ~3,Z=2,Dc=2.091g/cm^3.The structure has been refined to a final R of 0.0785.The crystal is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er(Ⅲ)and Y(Ⅲ)ion,other two carboxyl groups bridge two adjacent Er(Ⅲ)or two Y(Ⅲ)ions.展开更多
Non-Newtonian is a type of fluid that does not comply with the viscosity under the Law of Newton and is being widely used in industrial applications.These include those related to chemical industries,cosmetics manufac...Non-Newtonian is a type of fluid that does not comply with the viscosity under the Law of Newton and is being widely used in industrial applications.These include those related to chemical industries,cosmetics manufacturing,pharmaceutical field,food processing,as well as oil and gas activities.The inability of the conventional equations of Navier–Stokes to accurately depict rheological behavior for certain fluids led to an emergence study for non-Newtonian fluids’models.In line with this,a mathematical model of forced convective flow on non-Newtonian Eyring Powell fluid under temperature-dependent viscosity(TDV)circumstance is formulated.The fluid model is embedded with the Newtonian heating(NH)boundary condition as a heating circumstance and is assumed to move over a stretching sheet acting vertically.Using appropriate similarity variables,the respective model was converted into ordinary differential equations(ODE),which was later solved utilizing the Keller box approach.The present model is validated by comparing the existing output in literature at certain special limiting cases,where the validation results display a firm agreement.The current outputs for the proposed model are shown in tabular and graphical form for variation of skin friction plus Nusselt number,velocity and temperature distribution,respectively.展开更多
The viscosity of a substance or material is intensely influenced by the temperature,especially in the field of lubricant engineering where the changeable temperature is well executed.In this paper,the problem of tempe...The viscosity of a substance or material is intensely influenced by the temperature,especially in the field of lubricant engineering where the changeable temperature is well executed.In this paper,the problem of temperature-dependent viscosity on mixed convection flow of Eyring Powell fluid was studied together with Newtonian heating thermal boundary condition.The flow was assumed to move over a vertical stretching sheet.The model of the problem,which is in partial differential equations,was first transformed to ordinary differential equations using appropriate transformations.This approach was considered to reduce the complexity of the equations.Then,the transformed equations were solved using the Keller box method under the finite difference scheme approach.The validation process of the results was performed,and it was found to be in an excellent agreement.The results on the present computation are shown in tabular form and also graphical illustration.The major finding was observed where the skin friction and Nusselt number were boosted in the strong viscosity.展开更多
Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the stu...Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution.The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis(PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities;the distribution of Cr and Ni is primarily controlled by the local geological background;the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks;however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.展开更多
In this article, the biosynthetic pathways of storage oil accumulation in oilseed plants were briefly introduced, and the transcription factors, such as B3 do- main supeffamily genes, lecl gene, wril gene etc., and th...In this article, the biosynthetic pathways of storage oil accumulation in oilseed plants were briefly introduced, and the transcription factors, such as B3 do- main supeffamily genes, lecl gene, wril gene etc., and their important role in oil accumulation regulation was mainly elucidated. Overexpession of transcription factors as feasible ways of genetic manipulation to increase oJl content in oilseed crops are promising in a long-term perspective.展开更多
基金Project supported by the National Natural Science Foundation of China
文摘The title complex [ErY(Gly)_6(H_2O)_4](ClO_4)_6 5H_2O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters are as follows:a=11.518(4),b=14.105(7),c=15.530(6) ,α=96.61(3), β=102.74(3),γ=105.70(3)°,V=2327.7(17) ~3,Z=2,Dc=2.091g/cm^3.The structure has been refined to a final R of 0.0785.The crystal is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge the Er(Ⅲ)and Y(Ⅲ)ion,other two carboxyl groups bridge two adjacent Er(Ⅲ)or two Y(Ⅲ)ions.
基金Universiti Malaysia Pahang&Ministry of HigherEducation under The Fundamental Research Grant Scheme for Research Acculturation of Early CareerResearchers(FRGS-RACER)(Ref:RACER/1/2019/STG06/UMP//1)through RDU192602.
文摘Non-Newtonian is a type of fluid that does not comply with the viscosity under the Law of Newton and is being widely used in industrial applications.These include those related to chemical industries,cosmetics manufacturing,pharmaceutical field,food processing,as well as oil and gas activities.The inability of the conventional equations of Navier–Stokes to accurately depict rheological behavior for certain fluids led to an emergence study for non-Newtonian fluids’models.In line with this,a mathematical model of forced convective flow on non-Newtonian Eyring Powell fluid under temperature-dependent viscosity(TDV)circumstance is formulated.The fluid model is embedded with the Newtonian heating(NH)boundary condition as a heating circumstance and is assumed to move over a stretching sheet acting vertically.Using appropriate similarity variables,the respective model was converted into ordinary differential equations(ODE),which was later solved utilizing the Keller box approach.The present model is validated by comparing the existing output in literature at certain special limiting cases,where the validation results display a firm agreement.The current outputs for the proposed model are shown in tabular and graphical form for variation of skin friction plus Nusselt number,velocity and temperature distribution,respectively.
基金Ministry of Higher Education and Universiti Malaysia Pahang through RDU182307.
文摘The viscosity of a substance or material is intensely influenced by the temperature,especially in the field of lubricant engineering where the changeable temperature is well executed.In this paper,the problem of temperature-dependent viscosity on mixed convection flow of Eyring Powell fluid was studied together with Newtonian heating thermal boundary condition.The flow was assumed to move over a vertical stretching sheet.The model of the problem,which is in partial differential equations,was first transformed to ordinary differential equations using appropriate transformations.This approach was considered to reduce the complexity of the equations.Then,the transformed equations were solved using the Keller box method under the finite difference scheme approach.The validation process of the results was performed,and it was found to be in an excellent agreement.The results on the present computation are shown in tabular form and also graphical illustration.The major finding was observed where the skin friction and Nusselt number were boosted in the strong viscosity.
基金jointly funded by National Natural Science Foundation of China (41877398)project of the China Geological Survey (DD20221773)。
文摘Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution.The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis(PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities;the distribution of Cr and Ni is primarily controlled by the local geological background;the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks;however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.
基金Supported by Science and Technology Foundation of Guizhou Province [(2011)2089]Engineering Technology Research Center Building Fund of Guizhou Province ([2012]4006)Excellent Scientific and Educational Governor Fund of Guizhou Province ([2009]06)~~
文摘In this article, the biosynthetic pathways of storage oil accumulation in oilseed plants were briefly introduced, and the transcription factors, such as B3 do- main supeffamily genes, lecl gene, wril gene etc., and their important role in oil accumulation regulation was mainly elucidated. Overexpession of transcription factors as feasible ways of genetic manipulation to increase oJl content in oilseed crops are promising in a long-term perspective.
