A ^(13)C-NMR method is presented for a quantitative determination of the respective monomercomposition and sequence distributions in ethylene-1-octene copolymers prepared with supportedtitanium/magnesium catalyst. On ...A ^(13)C-NMR method is presented for a quantitative determination of the respective monomercomposition and sequence distributions in ethylene-1-octene copolymers prepared with supportedtitanium/magnesium catalyst. On the basis of the sequence distributions, the ethylene-1-octenecopolymerization mechanism was studied. It was found that the observed sequence distributions inethylene-1-octene copolymers are satisfactorily predicted by the two-site model M/M,in whichthe copolymerization proceeds according to first-order Markovian statistics at the two differentsites.展开更多
Three ethylene-vinyl alcohol copolymers were studied by means of the substituent chemical shift (SCS) method. The SCS parameters of hydroxy (-OH) in two different solvents were obtained: in deuterium oxide/phenol (20/...Three ethylene-vinyl alcohol copolymers were studied by means of the substituent chemical shift (SCS) method. The SCS parameters of hydroxy (-OH) in two different solvents were obtained: in deuterium oxide/phenol (20/80 W/W ) the parameters are S_1 = 42.77±0.08ppm, S_2 = 7.15±0.06 ppm, S_3 (s)= -4.08±0.02ppm, S_3 (t) =-3.09±0.20ppm,S_4 = 0.48±0.03ppm, S_5 = 0.26±0.05ppm. In o-dichloro-benzen-d_4 S_1(s)=44.79±0.61ppm, S_2=7.40±0.00ppm, S_3(s)=-4.51±0.17ppm, S_3(t)=-3.13 ±0.00 ppm, S_4 =0.63±0.04ppm, S_5=0.36±0.00ppm.Simultaneously the ^(13)CNMR spectra of EVA copolymers were assigned by using the SCS parameters obtained.展开更多
The effects of Ethylene-Vinyl Acetate copolymer （EVA） latex as an additive or a glass fiber surface modifier on the properties of Glass-Fiber （ GF ）/ Magnesium Oxychloride Cement （MOC） composites was studied. Th...The effects of Ethylene-Vinyl Acetate copolymer （EVA） latex as an additive or a glass fiber surface modifier on the properties of Glass-Fiber （ GF ）/ Magnesium Oxychloride Cement （MOC） composites was studied. The mechanical properties, water resistance aud aging resistance of the cured GF/ MOC composites were estimated and chemical ingredients analysis and morphological study of the GF/ MOC composites were also performed. It is found that EVA added to the MOC matrix could substantially improve the interfacial adhesion, water resistance aud aging resistance of GF/ MOC composites. EVA treatment on glass fibers resulted in decreasing initial flexural strength of GF/ MOC composites while enhancing the soft coefficients. In addition, the drying time and dilution of the EVA treatment on glass fibers also had an otwioas effect on the properties of GF/ MOC composites. However, excessive EVA interfered with the growth of the 5 Mg（ OH）2· MgCl2 ·8H2O crystal and the properties of GF / MOC composites.展开更多
A refined double integral method has been applied to the problem encountered in the diffu-sion release of a drug from a polymeric matrix.The finite external mass transfer resistance has alsobeen incorporated into the ...A refined double integral method has been applied to the problem encountered in the diffu-sion release of a drug from a polymeric matrix.The finite external mass transfer resistance has alsobeen incorporated into the present analysis.Experimental release rates of 5-fluorouracil fromethylene-vinyl alcohol copolymer into distilled water were measured in order to test the applicabilityof these models.All system parameters were measured by experiments and models were built up.Themodels presented here are much more accurate than Higuchi model and much easier than the exactsolutions.In view of accuracy,the models are almost the same as the exact solutions.The experi-mental release data agree Well with the computed展开更多
基金This work was supported by the National Natural Science Foundation of China
文摘A ^(13)C-NMR method is presented for a quantitative determination of the respective monomercomposition and sequence distributions in ethylene-1-octene copolymers prepared with supportedtitanium/magnesium catalyst. On the basis of the sequence distributions, the ethylene-1-octenecopolymerization mechanism was studied. It was found that the observed sequence distributions inethylene-1-octene copolymers are satisfactorily predicted by the two-site model M/M,in whichthe copolymerization proceeds according to first-order Markovian statistics at the two differentsites.
文摘Three ethylene-vinyl alcohol copolymers were studied by means of the substituent chemical shift (SCS) method. The SCS parameters of hydroxy (-OH) in two different solvents were obtained: in deuterium oxide/phenol (20/80 W/W ) the parameters are S_1 = 42.77±0.08ppm, S_2 = 7.15±0.06 ppm, S_3 (s)= -4.08±0.02ppm, S_3 (t) =-3.09±0.20ppm,S_4 = 0.48±0.03ppm, S_5 = 0.26±0.05ppm. In o-dichloro-benzen-d_4 S_1(s)=44.79±0.61ppm, S_2=7.40±0.00ppm, S_3(s)=-4.51±0.17ppm, S_3(t)=-3.13 ±0.00 ppm, S_4 =0.63±0.04ppm, S_5=0.36±0.00ppm.Simultaneously the ^(13)CNMR spectra of EVA copolymers were assigned by using the SCS parameters obtained.
文摘The effects of Ethylene-Vinyl Acetate copolymer （EVA） latex as an additive or a glass fiber surface modifier on the properties of Glass-Fiber （ GF ）/ Magnesium Oxychloride Cement （MOC） composites was studied. The mechanical properties, water resistance aud aging resistance of the cured GF/ MOC composites were estimated and chemical ingredients analysis and morphological study of the GF/ MOC composites were also performed. It is found that EVA added to the MOC matrix could substantially improve the interfacial adhesion, water resistance aud aging resistance of GF/ MOC composites. EVA treatment on glass fibers resulted in decreasing initial flexural strength of GF/ MOC composites while enhancing the soft coefficients. In addition, the drying time and dilution of the EVA treatment on glass fibers also had an otwioas effect on the properties of GF/ MOC composites. However, excessive EVA interfered with the growth of the 5 Mg（ OH）2· MgCl2 ·8H2O crystal and the properties of GF / MOC composites.
文摘A refined double integral method has been applied to the problem encountered in the diffu-sion release of a drug from a polymeric matrix.The finite external mass transfer resistance has alsobeen incorporated into the present analysis.Experimental release rates of 5-fluorouracil fromethylene-vinyl alcohol copolymer into distilled water were measured in order to test the applicabilityof these models.All system parameters were measured by experiments and models were built up.Themodels presented here are much more accurate than Higuchi model and much easier than the exactsolutions.In view of accuracy,the models are almost the same as the exact solutions.The experi-mental release data agree Well with the computed
