The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were ...The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were effectively synthesized. Emulsions with various characteristics have been developed by adjusting the weight ratios between the vinyl acetate monomer and the VAE component. The impacts on the mechanical, thermal, and physical properties of the films were investigated using tests for pencil hardness, tensile shear strength, pH, contact angle measurement, differential scanning calorimetry (DSC), and viscosity. When 5.0 weight percent VAE was added, the tensile shear strength in dry conditions decreased by 18.75% after a 24-hour bonding period, the heat resistance decreased by 26.29% (as per WATT 91) and the tensile shear strength decreased by approximately 36.52% in wet conditions (per EN 204). The pristine sample’s results were also confirmed by the contact angle test. The interpenetrating network (IPN) formation in hybrid PVAc emulsion as primary bonds does not directly attach to PVAc and VAE chains. The addition of VAE reduced the mechanical properties (at dry conditions) and heat resistance as per WATT 91. Contact angle analysis demonstrated that PVAc adhesives containing VAE had increased water resistance when compared to conventional PVA stabilised PVAc homopolymer-based adhesives. When compared to virgin PVAc Homo, the water resistance of the PVAc emulsion polymerization was enhanced by the addition of VAE.展开更多
Sepiolite （S9, B10, B20, B40） and boehmite have been added to an intumecent flame retardant （IFR） system to produce the halogen-free and fire-resistant ethylene-vinyl acetate copolymer （EVM） rubber. The rubber c...Sepiolite （S9, B10, B20, B40） and boehmite have been added to an intumecent flame retardant （IFR） system to produce the halogen-free and fire-resistant ethylene-vinyl acetate copolymer （EVM） rubber. The rubber contains ammonium polyphosphate （APP） as acid source, double pentaerythritol （D-PER） as carbon source and melamine （MN） as gas source. The effects of nano-filler sepiolite and boehmite on the fire-resistant property of EVM rubber based on IFR system were investigated. The test results show that the system with nano-filler of sepiolite B10 has the best fire-resistant property. The process of smoke emission and thermal decomposition, the element composition of char surface and the micro morphology of intumecent char layer of the EVM IFR system with nano-filler were also studied by NBS chamber, thermogravimetric （TG） analysis, X- ray photoelectron spectroscopy （XPS） and scanning electron microscope （SEM）.展开更多
Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of ...Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of 1.75 was selected and embedded into the ethylene vinyl acetate (EVA) elastomer as a sensing material.By measuring the electric resistance changing under the stretching,bending,longitudinally and transversely compressing of the CNT embedded EVA, the resistance changing curves and their linear correlations were obtained and analyzed. The result shows that the gage factor under the tensile test is the highest( 2.51),which is higher than the original value of CNT yarn (1.75). The gage factors of the CNT yarn embedded into EVA elastomer under bending and longitudinal and transverse compression are 2.29,1.55 and 0.79,respectively.展开更多
随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控...随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。展开更多
文摘The goal is to develop a hybrid IPN network of polyvinyl acetate (PVAc) and ethylene-vinyl acetate (VAE). In this research work, the vinyl acetate (VAc)/ VAE hybrid emulsion and polyvinyl acetate emulsion (PVAc) were effectively synthesized. Emulsions with various characteristics have been developed by adjusting the weight ratios between the vinyl acetate monomer and the VAE component. The impacts on the mechanical, thermal, and physical properties of the films were investigated using tests for pencil hardness, tensile shear strength, pH, contact angle measurement, differential scanning calorimetry (DSC), and viscosity. When 5.0 weight percent VAE was added, the tensile shear strength in dry conditions decreased by 18.75% after a 24-hour bonding period, the heat resistance decreased by 26.29% (as per WATT 91) and the tensile shear strength decreased by approximately 36.52% in wet conditions (per EN 204). The pristine sample’s results were also confirmed by the contact angle test. The interpenetrating network (IPN) formation in hybrid PVAc emulsion as primary bonds does not directly attach to PVAc and VAE chains. The addition of VAE reduced the mechanical properties (at dry conditions) and heat resistance as per WATT 91. Contact angle analysis demonstrated that PVAc adhesives containing VAE had increased water resistance when compared to conventional PVA stabilised PVAc homopolymer-based adhesives. When compared to virgin PVAc Homo, the water resistance of the PVAc emulsion polymerization was enhanced by the addition of VAE.
基金Sponsored by Project in National Key Technology R&D Program(2006BAE03B05-2)
文摘Sepiolite （S9, B10, B20, B40） and boehmite have been added to an intumecent flame retardant （IFR） system to produce the halogen-free and fire-resistant ethylene-vinyl acetate copolymer （EVM） rubber. The rubber contains ammonium polyphosphate （APP） as acid source, double pentaerythritol （D-PER） as carbon source and melamine （MN） as gas source. The effects of nano-filler sepiolite and boehmite on the fire-resistant property of EVM rubber based on IFR system were investigated. The test results show that the system with nano-filler of sepiolite B10 has the best fire-resistant property. The process of smoke emission and thermal decomposition, the element composition of char surface and the micro morphology of intumecent char layer of the EVM IFR system with nano-filler were also studied by NBS chamber, thermogravimetric （TG） analysis, X- ray photoelectron spectroscopy （XPS） and scanning electron microscope （SEM）.
基金National Natural Science Foundations of China(Nos.51303025,51503120)Shanghai Science and Technology Committee,China(No.14YF1409600)+2 种基金Shanghai Municipal Education Commission,China(No.ZZgcd14016)Fundamental Research Funds for the Central Universities,ChinaDonghua University Distinguished Young Professor Program,China
文摘Carbon nanotube (CNT) has remarkable piezoresistive properties,which makes its extremely sensitive to the mechanical force. In this study,the CNT yarn with the strength of 90 MPa and the strain sensing gage factor of 1.75 was selected and embedded into the ethylene vinyl acetate (EVA) elastomer as a sensing material.By measuring the electric resistance changing under the stretching,bending,longitudinally and transversely compressing of the CNT embedded EVA, the resistance changing curves and their linear correlations were obtained and analyzed. The result shows that the gage factor under the tensile test is the highest( 2.51),which is higher than the original value of CNT yarn (1.75). The gage factors of the CNT yarn embedded into EVA elastomer under bending and longitudinal and transverse compression are 2.29,1.55 and 0.79,respectively.
文摘随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。
