An enhancive synthesis of (±)-1β, 11-diol-4-en-eudesmol, starting from 2-chloroacrylonitrile, is described. The effect of temperature on the Diels-Alder reaction of 2-chloroacrylonitrile with 2-methylfuran and t...An enhancive synthesis of (±)-1β, 11-diol-4-en-eudesmol, starting from 2-chloroacrylonitrile, is described. The effect of temperature on the Diels-Alder reaction of 2-chloroacrylonitrile with 2-methylfuran and the condition of cationic cyclization of diene were discussed in detail.展开更多
基金Project supported by the National Natural Science Foundation of China(No.20272021).
文摘An enhancive synthesis of (±)-1β, 11-diol-4-en-eudesmol, starting from 2-chloroacrylonitrile, is described. The effect of temperature on the Diels-Alder reaction of 2-chloroacrylonitrile with 2-methylfuran and the condition of cationic cyclization of diene were discussed in detail.