Melting temperatures have been measured and the solid-liquid phase diagrams constructed for 1-hexanol＋o-xylene, 1-hexallol＋m-xylene and 1-hexanol＋p-xylene. They are simple eutectic systems. Excess mole Gibbs free e...Melting temperatures have been measured and the solid-liquid phase diagrams constructed for 1-hexanol＋o-xylene, 1-hexallol＋m-xylene and 1-hexanol＋p-xylene. They are simple eutectic systems. Excess mole Gibbs free energies were calculated at 298.15K, showing larger positive deviations from ideal-solution behavior. The largest values of GEm are 711、 650 and 800 J·mol-1 for {o-C6H4(CH3)2＋C6H13OH}、 {m-C6H4(CH3)2 ＋ C6H13OH} and {p-C6H4(CH3)2＋C6H13OH} respectively.展开更多
文摘Melting temperatures have been measured and the solid-liquid phase diagrams constructed for 1-hexanol＋o-xylene, 1-hexallol＋m-xylene and 1-hexanol＋p-xylene. They are simple eutectic systems. Excess mole Gibbs free energies were calculated at 298.15K, showing larger positive deviations from ideal-solution behavior. The largest values of GEm are 711、 650 and 800 J·mol-1 for {o-C6H4(CH3)2＋C6H13OH}、 {m-C6H4(CH3)2 ＋ C6H13OH} and {p-C6H4(CH3)2＋C6H13OH} respectively.
