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Anion exchange membranes with a semi-interpenetrating polymer network using 1,6-dibromohexane as bifunctional crosslinker
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作者 Aijie Li Zhanliang Wang +6 位作者 Zhihao Si Lu Lu Peipei Huang Jinhong Liu Songyuan Yao Peiyong Qin Xinmiao Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第8期199-208,共10页
An anion exchange membrane(AEM)is generally expected to possess high ion exchange capacity(IEC),low water uptake(WU),and high mechanical strength when applied to electrodialysis desalination.Among different types of A... An anion exchange membrane(AEM)is generally expected to possess high ion exchange capacity(IEC),low water uptake(WU),and high mechanical strength when applied to electrodialysis desalination.Among different types of AEMs,semi-interpenetrating polymer networks(SIPNs)have been suggested for their structural superiorities,i.e.,the tunable local density of ion exchange groups for IEC and the restrained leaching of hygroscopic groups by insolubility for WU.Unfortunately,the conventional SIPN AEMs still struggle to balances IEC,WU,and mechanical strength simultaneously,due to the lack of the compact crosslinking region.In this work,we proposed a novel SIPN structure of polyvinylidene difluoride/polyvinylimidazole/1,6-dibromohexane(PVDF/PVIm/DBH).On the one hand,DBH with two cationic groups of imidazole groups are introduced to enhance the ion conductivity,which is different from the conventional monofunctional modifier with only one cationic group.On the other hand,DBH has the ability to bridge with PVIm,where the mechanical strength of the resulting AEM is increased by the increase of crosslinking degree.Results show that a low WU of 38.1%to 62.6%,high IEC of 2.12—2.22 mmol·g^(-1),and excellent tensile strength of 3.54—12.35 MPa for PVDF/PVIm/DBH membrane are achieved.This work opens a new avenue for achieving the high-quality AEMs. 展开更多
关键词 Anion exchange membrane Polyvinylidene difluoride ELECTRODIALYSIS Semi-interpenetrating polymer networks
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Electrochemical synthesis of trimetallic nickel-iron-copper nanoparticles via potential-cycling for high current density anion exchange membrane water-splitting applications
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作者 Ziqi Zhang Sheng Wan +4 位作者 Hanbo Wang Jinghan He Ruige Zhang Yuhang Qi Haiyan Lu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期535-542,I0012,共9页
Hydrogen is known for its elevated energy density and environmental compatibility and is a promising alternative to fossil fuels.Alkaline water electrolysis utilizing renewable energy sources has emerged as a means to... Hydrogen is known for its elevated energy density and environmental compatibility and is a promising alternative to fossil fuels.Alkaline water electrolysis utilizing renewable energy sources has emerged as a means to obtain high-purity hydrogen.Nevertheless,electrocatalysts used in the process are fabricated using conventional wet chemical synthesis methods,such as sol-gel,hydrothermal,or surfactantassisted approaches,which often necessitate intricate pretreatment procedures and are vulnerable to post-treatment contamination.Therefore,this study introduces a streamlined and environmentally conscious one-step potential-cycling approach to generate a highly efficient trimetallic nickel-iron-copper electrocatalyst in situ on nickel foam.The synthesized material exhibited remarkable performance,requiring a mere 476 mV to drive electrochemical water splitting at 100 mA cm^(-2)current density in alkaline solution.Furthermore,this material was integrated into an anion exchange membrane watersplitting device and achieved an exceptionally high current density of 1 A cm^(-2)at a low cell voltage of2.13 V,outperforming the noble-metal benchmark(2.51 V).Additionally,ex situ characterizations were employed to detect transformations in the active sites during the catalytic process,revealing the structural transformations and providing inspiration for further design of electrocatalysts. 展开更多
关键词 Electrocatalytic water splitting Hydrogen evolution reaction Oxygen evolution reaction Electrochemical synthesis Anion exchange membrane
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Noninvasive Characterization of Metabolic Changes in Ischemic Stroke Using Z-spectrum-fitted Multiparametric Chemical Exchange Saturation Transfer-weighted Magnetic Resonance Imaging 被引量:1
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作者 Zhen-xiong WANG Xin-hua WEI +2 位作者 Ke-jia CAI Wen-zhen ZHU Chang-liang SU 《Current Medical Science》 SCIE CAS 2023年第5期970-978,共9页
Objective This study aimed to noninvasively characterize the metabolic alterations in ischemic brain tissues using Z-spectrum-fitted multiparametric chemical exchange saturation transfer-weighted magnetic resonance im... Objective This study aimed to noninvasively characterize the metabolic alterations in ischemic brain tissues using Z-spectrum-fitted multiparametric chemical exchange saturation transfer-weighted magnetic resonance imaging(CEST-MRI).Methods Three sets of Z-spectrum data with saturation power(B_(1))values of 1.5,2.5,and 3.5µT,respectively,were acquired from 17 patients with ischemic stroke.Multiple contrasts contributing to the Z-spectrum,including fitted amide proton transfer(APT_(fitted)),+2 ppm peak(CEST@2ppm),concomitantly fitted APT_(fitted) and CEST@2ppm(APT&CEST@2ppm),semisolid magnetization transfer contrast(MT),aliphatic nuclear Overhauser effect(NOE),and direct saturation of water(DSW),were fitted with 4 and 5 Lorentzian functions,respectively.The CEST metrics were compared between ischemic lesions and contralateral normal white matter(CNWM),and the correlation between the CEST metrics and the apparent diffusion coefficient(ADC)was assessed.The differences in the Z-spectrum metrics under varied B1 values were also investigated.Results Ischemic lesions showed increased APTfitted,CEST@2ppm,APT&CEST@2ppm,NOE,and DSW as well as decreased MT.APT&CEST@2ppm,MT,and DSW showed a significant correlation with ADC[APT&CEST@2ppm at the 3 B_(1) values:R=0.584/0.467/0.551;MT at the 3 B_(1) values:R=−0.717/−0.695/−0.762(4-parameter fitting),R=−0.734/−0.711/−0.785(5-parameter fitting);DSW of 4-/5-parameter fitting:R=0.794/0.811(2.5µT),R=0.800/0.790(3.5µT)].However,the asymmetric analysis of amide proton transfer(APT_(asym))could not differentiate the lesions from CNWM and showed no correlation with ADC.Furthermore,the Z-spectrum contrasts varied with B_(1).Conclusion The Z-spectrum-fitted multiparametric CEST-MRI can comprehensively detect metabolic alterations in ischemic brain tissues. 展开更多
关键词 chemical exchange saturation transfer Z-spectrum ischemic stroke
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Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell 被引量:2
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作者 Chao Liu Zhen Geng +6 位作者 Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期348-369,I0009,共23页
Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,t... Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed. 展开更多
关键词 HYDROGEN Water electrolysis Anion exchange membrane Electrolysis cell
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Proton‑Prompted Ligand Exchange to Achieve High‑Efficiency CsPbI_(3) Quantum Dot Light‑Emitting Diodes 被引量:1
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作者 Yanming Li Ming Deng +2 位作者 Xuanyu Zhang Lei Qian Chaoyu Xiang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期53-62,共10页
CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improv... CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improvement of device performance.Traditional in-situ ligand replacement and ligand exchange after synthesis were often difficult to control.Here,we proposed a new ligand exchange strategy using a proton-prompted insitu exchange of short 5-aminopentanoic acid ligands with long-chain oleic acid and oleylamine ligands to obtain stable small-size CsPbI_(3)QDs.This exchange strategy maintained the size and morphology of CsPbI_(3)QDs and improved the optical properties and the conductivity of CsPbI_(3)QDs films.As a result,high-efficiency red QD-based light-emitting diodes with an emission wavelength of 645 nm demonstrated a record maximum external quantum efficiency of 24.45%and an operational half-life of 10.79 h. 展开更多
关键词 CsPbI_(3) perovskite quantum dots Light-emitting diodes Ligand exchange Proton-prompted in-situ exchange
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Solar wind ion charge state distributions and compound cross sections for solar wind charge exchange X-ray emission 被引量:1
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作者 Dimitra Koutroumpa 《Earth and Planetary Physics》 EI CSCD 2024年第1期105-118,共14页
Solar Wind Charge eXchange X-ray(SWCX) emission in the heliosphere and Ea rth’s exosphere is a hard to avoid signal in soft Xray obse rvations of astrophysical targets.On the other hand,the X-ray imaging possibilitie... Solar Wind Charge eXchange X-ray(SWCX) emission in the heliosphere and Ea rth’s exosphere is a hard to avoid signal in soft Xray obse rvations of astrophysical targets.On the other hand,the X-ray imaging possibilities offered by the SWCX process has led to an increasing number of future dedicated space missions for investigating the solar wind-terrestrial inte ractions and magnetospheric interfaces.In both cases,accurate modelling of the SWCX emission is key to correctly interpret its signal,and remove it from obse rvations,when needed.In this paper,we compile solar wind abundance measurements from ACE for different solar wind types,and atomic data from literature,including charge exchange cross-sections and emission probabilities,used fo r calculating the compound cross-section a for the SWCX X-ray emission.We calculate a values for charge-exchange with H and He,relevant to soft X-ray energy bands(0.1-2.0 keV)for various solar wind types and solar cycle conditions. 展开更多
关键词 solar wind charge exchange X-rays MAGNETOSPHERE HELIOSPHERE
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Currencies of greater interest for central Asian economies:an analysis of exchange market pressure amid global and regional interdependence
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作者 Devendra Kumar Jain Naqeeb Ur‑Rehman +1 位作者 Omonjon Ganiev Kapil Arora 《Financial Innovation》 2023年第1期1275-1292,共18页
Central Asian Economies(CAEs)have diverse exchange rate policies.They have recorded higher volatility in the foreign exchange market since inception.High volatility of the transition era has drifted these economies to... Central Asian Economies(CAEs)have diverse exchange rate policies.They have recorded higher volatility in the foreign exchange market since inception.High volatility of the transition era has drifted these economies towards partial dollarization.Monetary authorities in CAEs,(already have a challenge of maintaining monetary policy autonomy)have a gigantic task of price stability and stopping the spread of dollarization.This study is directed towards assessing the drivers and the determinants of foreign exchange market pressure in CAEs.The results,based on panel data analysis and the System GMM model,have provided useful insights about the exchange market pressure determinants particularly USD,Euro,Ruble,and Renminbi.The results show that China and Russia exchange market pressure has a negative effect on the exchange market pressure of CAEs.While the dollar index shows a positive impact on the exchange market pressure of CAEs.Overall,the findings imply that China and Russia currency appreciation results in a trade deficit across CAEs.The policy implication suggests that the floating exchange rate regime(inflation targeting regime)is not in favor of CAEs,and they must use managed-float to reduce their trade deficits. 展开更多
关键词 exchange market pressures Central Asian economies exchange markets Financial market Interdependence Transition economies
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Comparative Gas Exchange of Ulmus crassifolia (Cedar Elm, Ulmaceae) and Ungnadia speciosa (Mexican Buckey, Sapindaceae) at Ambient and Elevated Levels of Light, CO2 and Temperature
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作者 Matthew B. Grunstra Oscar W. Van Auken 《American Journal of Plant Sciences》 2023年第6期691-709,共19页
Ulmus crassifolia Nutt. (Cedar elm, Ulmaceae) is a tree found in central and east Texas, northern Mexico, east to Florida, and north to southern Missouri and Oklahoma. Ungnadia speciosa Endl. (Mexican-buckeye, Sapinda... Ulmus crassifolia Nutt. (Cedar elm, Ulmaceae) is a tree found in central and east Texas, northern Mexico, east to Florida, and north to southern Missouri and Oklahoma. Ungnadia speciosa Endl. (Mexican-buckeye, Sapindaceae) is a shrub or small tree found in woodlands and savannas of central and western Texas, southern New Mexico and northern Mexico. In central Texas, both species are found in Juniperus ashei/Quercus virginiana woodlands or savannas or also at low density in inter-canopy grassland gaps or patches. Environmental conditions in this area are stressful because of shallow soils, high summer temperatures, and inconsistent low rainfall. Currently, both species have a low density in these areas, and Ulmus crassifolia is usually a tree, while Ungnadia speciosa is a woody understory shrub. This study suggests U. crassifolia and U. speciosa are tolerant or intermediate species, with juveniles starting in shade. Maximum photosynthetic rate (A<sub>max</sub>), dark respiration (R<sub>d</sub>), intercellular CO<sub>2</sub>, light saturation (L<sub>sp</sub>) and water use efficiency significantly increased when light levels and CO<sub>2</sub> concentrations were elevated for both species, but not when temperatures were elevated. Stomatal conductance decreased when the CO<sub>2</sub> concentration doubled, but there were few effects from elevated temperature. These findings suggest that U. speciosa and U. crassifolia should be more common and imply that they will have a higher density in a future high CO<sub>2</sub> environment. 展开更多
关键词 Light Response Gas exchange Photosynthesis Respiration Water Use Efficiency
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Two methods for separating the magnetospheric solar wind charge exchange soft X-ray emission from the diffuse X-ray background 被引量:2
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作者 YingJie Zhang TianRan Sun +5 位作者 JenniferACarter WenHao Liu Steve Sembay ShuiNai Zhang Li Ji Chi Wang 《Earth and Planetary Physics》 EI CSCD 2024年第1期119-132,共14页
Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is propo... Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is proposed as a new technique to study the magnetosphere using panoramic soft X-ray imaging.To better prepare for the data analysis of upcoming magnetospheric soft X-ray imaging missions,this paper compares the magnetospheric SWCX emission obtained by two methods in an XMM-Newton observation,during which the solar wind changed dramatically.The two methods differ in the data used to fit the diffuse X-ray background(DXB)parameters in spectral analysis.The method adding data from the ROSAT All-Sky Survey(RASS)is called the RASS method.The method using the quiet observation data is called the Quiet method,where quiet observations usually refer to observations made by the same satellite with the same target but under weaker solar wind conditions.Results show that the spectral compositions of magnetospheric SWCX emission obtained by the two methods are very similar,and the changes in intensity over time are highly consistent,although the intensity obtained by the RASS method is about 2.68±0.56 keV cm^(-2)s^(-1)sr^(-1)higher than that obtained by the Quiet method.Since the DXB intensity obtained by the RASS method is about 2.84±0.74 keV cm^(-2)s^(-1)sr^(-1)lower than that obtained by the Quiet method,and the linear correlation coefficient between the difference of SWCX and DXB obtained by the two methods in diffe rent energy band is close to-1,the diffe rences in magnetospheric SWCX can be fully attributed to the diffe rences in the fitted DXB.The difference between the two methods is most significant when the energy is less than 0.7 keV,which is also the main energy band of SWCX emission.In addition,the difference between the two methods is not related to the SWCX intensity and,to some extent,to solar wind conditions,because SWCX intensity typically va ries with the solar wind.In summary,both methods are robust and reliable,and should be considered based on the best available options. 展开更多
关键词 solar wind charge exchange(SWCX) ROSAT All-Sky Survey(RASS) soft X-ray X-ray imaging MAGNETOSPHERE
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Effects of drip and flood irrigation on carbon dioxide exchange and crop growth in the maize ecosystem in the Hetao Irrigation District,China 被引量:1
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作者 LI Chaoqun HAN Wenting PENG Manman 《Journal of Arid Land》 SCIE CSCD 2024年第2期282-297,共16页
Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation metho... Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation methods on carbon dioxide(CO_(2))exchange and crop growth in this region.The experimental site was divided into drip and flood irrigation zones.The irrigation schedules of this study aligned with the local commonly used irrigation schedule.We employed a developed chamber system to measure the diurnal CO_(2)exchange of maize plants during various growth stages under both drip and flood irrigation methods.From May to September in 2020 and 2021,two sets of repeated experiments were conducted.In each experiment,a total of nine measurements of CO_(2)exchange were performed to obtain carbon exchange data at different growth stages of maize crop.During each CO_(2)exchange measurement event,CO_(2)flux data were collected every two hours over a day-long period to capture the diurnal variations in CO_(2)exchange.During each CO_(2)exchange measurement event,the biological parameters(aboveground biomass and crop growth rate)of maize and environmental parameters(including air humidity,air temperature,precipitation,soil water content,and photosynthetically active radiation)were measured.The results indicated a V-shaped trend in net ecosystem CO_(2)exchange in daytime,reducing slowly at night,while the net assimilation rate(net primary productivity)exhibited a contrasting trend.Notably,compared with flood irrigation,drip irrigation demonstrated significantly higher average daily soil CO_(2)emission and greater average daily CO_(2)absorption by maize plants.Consequently,within the maize ecosystem,drip irrigation appeared more conducive to absorbing atmospheric CO_(2).Furthermore,drip irrigation demonstrated a faster crop growth rate and increased aboveground biomass compared with flood irrigation.A strong linear relationship existed between leaf area index and light utilization efficiency,irrespective of the irrigation method.Notably,drip irrigation displayed superior light use efficiency compared with flood irrigation.The final yield results corroborated these findings,indicating that drip irrigation yielded higher harvest index and overall yield than flood irrigation.The results of this study provide a basis for the selection of optimal irrigation methods commonly used in the Hetao Irrigation District.This research also serves as a reference for future irrigation studies that consider measurements of both carbon emissions and yield simultaneously. 展开更多
关键词 carbon dioxide exchange maize growth drip irrigation harvest index net primary productivity Hetao Irrigation District
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An Efficient Three-Party Authenticated Key Exchange Procedure Using Chebyshev Chaotic Maps with Client Anonymity
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作者 Akshaykumar Meshram Monia Hadj Alouane-Turki +1 位作者 N.M.Wazalwar Chandrashekhar Meshram 《Computers, Materials & Continua》 SCIE EI 2023年第6期5337-5353,共17页
Internet of Things(IoT)applications can be found in various industry areas,including critical infrastructure and healthcare,and IoT is one of several technological developments.As a result,tens of billions or possibly... Internet of Things(IoT)applications can be found in various industry areas,including critical infrastructure and healthcare,and IoT is one of several technological developments.As a result,tens of billions or possibly hundreds of billions of devices will be linked together.These smart devices will be able to gather data,process it,and even come to decisions on their own.Security is the most essential thing in these situations.In IoT infrastructure,authenticated key exchange systems are crucial for preserving client and data privacy and guaranteeing the security of data-in-transit(e.g.,via client identification and provision of secure communication).It is still challenging to create secure,authenticated key exchange techniques.The majority of the early authenticated key agreement procedure depended on computationally expensive and resource-intensive pairing,hashing,or modular exponentiation processes.The focus of this paper is to propose an efficient three-party authenticated key exchange procedure(AKEP)using Chebyshev chaotic maps with client anonymity that solves all the problems mentioned above.The proposed three-party AKEP is protected from several attacks.The proposed three-party AKEP can be used in practice for mobile communications and pervasive computing applications,according to statistical experiments and low processing costs.To protect client identification when transferring data over an insecure public network,our three-party AKEP may also offer client anonymity.Finally,the presented procedure offers better security features than the procedures currently available in the literature. 展开更多
关键词 Client anonymity Chebyshev chaotic maps authenticated key exchange statistical experiment Galois fields
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EBAKE-SE: A novel ECC-based authenticated key exchange between industrial IoT devices using secure element
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作者 Chintan Patel Ali Kashif Bashir +1 位作者 Ahmad Ali AlZubi Rutvij Jhaveri 《Digital Communications and Networks》 SCIE CSCD 2023年第2期358-366,共9页
Industrial IoT(IIoT)aims to enhance services provided by various industries,such as manufacturing and product processing.IIoT suffers from various challenges,and security is one of the key challenge among those challe... Industrial IoT(IIoT)aims to enhance services provided by various industries,such as manufacturing and product processing.IIoT suffers from various challenges,and security is one of the key challenge among those challenges.Authentication and access control are two notable challenges for any IIoT based industrial deployment.Any IoT based Industry 4.0 enterprise designs networks between hundreds of tiny devices such as sensors,actuators,fog devices and gateways.Thus,articulating a secure authentication protocol between sensing devices or a sensing device and user devices is an essential step in IoT security.In this paper,first,we present cryptanalysis for the certificate-based scheme proposed for a similar environment by Das et al.and prove that their scheme is vulnerable to various traditional attacks such as device anonymity,MITM,and DoS.We then put forward an interdevice authentication scheme using an ECC(Elliptic Curve Cryptography)that is highly secure and lightweight compared to other existing schemes for a similar environment.Furthermore,we set forth a formal security analysis using the random oracle-based ROR model and informal security analysis over the Doleve-Yao channel.In this paper,we present comparison of the proposed scheme with existing schemes based on communication cost,computation cost and security index to prove that the proposed EBAKE-SE is highly efficient,reliable,and trustworthy compared to other existing schemes for an inter-device authentication.At long last,we present an implementation for the proposed EBAKE-SE using MQTT protocol. 展开更多
关键词 Internet of things AUTHENTICATION Elliptic curve cryptography Secure key exchange Message Queuing telemetry transport
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基于KE/AHP/GRA的儿童娱乐家具产品设计研究
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作者 陈罗辉 陈雅琦 《家具与室内装饰》 北大核心 2024年第7期48-56,共9页
为了更有效地解决当下儿童娱乐家具产品普遍存在的设计问题,本研究运用感性工学(KE)从家具产品提取样本得到感性需求,通过SPSS 26.0对感性词汇进行分类,找到影响设计的视觉因子;运用层次分析法(AHP)和熵值法对需求层次结构进行构建并得... 为了更有效地解决当下儿童娱乐家具产品普遍存在的设计问题,本研究运用感性工学(KE)从家具产品提取样本得到感性需求,通过SPSS 26.0对感性词汇进行分类,找到影响设计的视觉因子;运用层次分析法(AHP)和熵值法对需求层次结构进行构建并得到重要权重需求;然后运用灰度关联分析法(GRA)量化各指标之间的关联度,找出影响可持续性的关键因素,为设计方案提供决策评价分析,最后经由设计实践对上述研究予以实证。KE/AHP/GRA三者所建立的集成模型的运用,充分彰显了设计的科学性与客观性,为推动儿童娱乐家具的可持续设计开辟了新的研究路径。 展开更多
关键词 ke/AHP/GRA 儿童玩具 娱乐家具
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Influence of initial check, information exchange, final accuracy check, reaction information nursing on the psychology of elderly with lung cancer 被引量:1
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作者 Cui Jiang Jing Ma +1 位作者 Wen He Hai-Ying Zhang 《World Journal of Clinical Cases》 SCIE 2024年第4期737-745,共9页
BACKGROUND As one of the fatal diseases with high incidence,lung cancer has seriously endangered public health and safety.Elderly patients usually have poor self-care and are more likely to show a series of psychologi... BACKGROUND As one of the fatal diseases with high incidence,lung cancer has seriously endangered public health and safety.Elderly patients usually have poor self-care and are more likely to show a series of psychological problems.AIM To investigate the effectiveness of the initial check,information exchange,final accuracy check,reaction(IIFAR)information care model on the mental health status of elderly patients with lung cancer.METHODS This study is a single-centre study.We randomly recruited 60 elderly patients with lung cancer who attended our hospital from January 2021 to January 2022.These elderly patients with lung cancer were randomly divided into two groups,with the control group taking the conventional propaganda and education and the observation group taking the IIFAR information care model based on the conventional care protocol.The differences in psychological distress,anxiety and depression,life quality,fatigue,and the locus of control in psychology were compared between these two groups,and the causes of psychological distress were analyzed.RESULTS After the intervention,Distress Thermometer,Hospital Anxiety and Depression Scale(HADS)for anxiety and the HADS for depression,Revised Piper’s Fatigue Scale,and Chance Health Locus of Control scores were lower in the observation group compared to the pre-intervention period in the same group and were significantly lower in the observation group compared to those of the control group(P<0.05).After the intervention,Quality of Life Questionnaire Core 30(QLQ-C30),Internal Health Locus of Control,and Powerful Others Health Locus of Control scores were significantly higher in the observation and the control groups compared to the pre-intervention period in their same group,and QLQ-C30 scores were significantly higher in the observation group compared to those of the control group(P<0.05).CONCLUSION The IIFAR information care model can help elderly patients with lung cancer by reducing their anxiety and depression,psychological distress,and fatigue,improving their tendencies on the locus of control in psychology,and enhancing their life qualities. 展开更多
关键词 Initial check information exchange final accuracy check reaction information care model Lung cancer Mental health
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格上无非交互式零知识证明的两轮三方PAKE协议
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作者 尹新媛 郑小建 熊金波 《计算机应用》 CSCD 北大核心 2024年第3期805-810,共6页
针对现有基于格的三方口令认证密钥交换(PAKE)协议通信轮次较多、执行效率较低等问题,提出一种格上无非交互式零知识证明的两轮三方PAKE协议。首先,利用非适应性近似平滑投影哈希函数实现密钥交换,在不使用非交互式零知识(NIZK)证明的... 针对现有基于格的三方口令认证密钥交换(PAKE)协议通信轮次较多、执行效率较低等问题,提出一种格上无非交互式零知识证明的两轮三方PAKE协议。首先,利用非适应性近似平滑投影哈希函数实现密钥交换,在不使用非交互式零知识(NIZK)证明的前提下,降低协议的通信轮数;其次,利用哈希值和投影哈希值构造会话密钥,不需要使用随机预言机,避免了随机预言机导致的潜在口令猜测攻击。在标准模型下给出所提协议的形式化安全证明。仿真结果表明,与基于格的三方PAKE协议相比,所提协议的执行时间在客户端缩短了89.2%~98.6%,在服务器端缩短了19.0%~91.6%。验证了所提协议能够抵抗量子攻击,具有较高的执行效率,同时减少了协议通信轮数。 展开更多
关键词 三方密钥交换 口令认证密钥交换 非交互式零知识 可证明安全
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Petrology of Spinel-Lherzolite Xenoliths from Mazéléand Others Northen Xenoliths Localities of Cameroon Volcanic Line: Exchange Reactions and Equilibrium State
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作者 Nguihdama Dagwai Kamgang Pierre +2 位作者 Mbowou Gbambié Isaac Bertrand Chazot Gilles Ngounouno Ismaïla 《Open Journal of Geology》 CAS 2024年第5期629-653,共25页
The alkaline volcanism of the Cameroon Volcanic Line in its northern domain has raised many fresh enclaves of peridotites. The samples selected come from five (05) different localities (Liri, in the plateau of Kapsiki... The alkaline volcanism of the Cameroon Volcanic Line in its northern domain has raised many fresh enclaves of peridotites. The samples selected come from five (05) different localities (Liri, in the plateau of Kapsiki, Mazélé in the NE of Ngaoundéré, Tello and Ganguiré in the SE of Ngaoundéré and Likok, locality located in the west of Ngaoundé). The peridotite enclaves of the above localities show restricted mineralogical variation. Most are four-phase spinel-lherzolites, indicating that this is the main lithology that forms the lithospheric mantle below the shallow zone. No traces of garnet or primary plagioclase were detected, which strongly limits the depth range from which the rock fragments were sampled. The textures and the wide equilibrium temperatures (884˚C - 1115˚C) indicate also entrainment of lherzolite xenoliths from shallow depths within the lithosphere and the presence of mantle diapirism. The exchange reactions and equilibrium state established in this work make it possible to characterize the chemical composition of the upper mantle of each region and test the equilibrium state of the phases between them. Variations of major oxides and incompatible elemental concentrations in clinopyroxene indicate a primary control by partial melting. The absence of typical “metasomatic” minerals, low equilibration temperatures and enriched LREE patterns indicate that the upper mantle below septentrional crust of Cameroun underwent an event of cryptic metasomatic enrichment prior to partial melting. The distinctive chemical features, LREE enrichment, strong U, Ce and Pr, depletion relative to Ba, Nb, La, Pb, and T, fractionation of Zr and Hf and therefore ligh high Zr/Hf ratio, low La/Yb, Nb/La and Ti/Eu are all results of interaction of refractory peridotite residues with carbonatite melts. 展开更多
关键词 XENOLITHS Upper Mantle Northern Region Adamawa Cameroon Volcanic Line exchange Reaction
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Towards high-performance and robust anion exchange membranes(AEMs)for water electrolysis:Super-acid-catalyzed synthesis of AEMs
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作者 Geun Woong Ryoo Sun Hwa Park +3 位作者 Ki Chang Kwon Jong Hun Kang Ho Won Jang Min Sang Kwon 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期478-510,I0012,共34页
The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen pro... The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen production technologies,anion exchange membrane water electrolyzer(AEMWE)has emerged as a next-generation technology known for its high hydrogen production efficiency and its ability to use non-metal catalysts.However,this technology faces significant challenges,particularly in terms of the membrane durability and low ionic conductivity.To address these challenges,research efforts have focused on developing membranes with a new backbone structure and anion exchange groups to enhance durability and ionic conductivity.Notably,the super-acid-catalyzed condensation(SACC)synthesis method stands out due to its user convenience,the ability to create high molecular weight(MW)polymers,and the use of oxygen-tolerant organic catalysts.Although the synthesis of anion exchange membranes(AEMs)using the SACC method began in 2015,and despite growing interest in this synthesis approach,there remains a scarcity of review papers focusing on AEMs synthesized using the SACC method.The review covers the basics of SACC synthesis,presents various polymers synthesized using this method,and summarizes the development of these polymers,particularly their building blocks including aryl,ketone,and anion exchange groups.We systematically describe the effects of changes in the molecular structure of each polymer component,conducted by various research groups,on the mechanical properties,conductivity,and operational stability of the membrane.This review will provide insights into the development of AEMs with superior performance and operational stability suitable for water electrolysis applications. 展开更多
关键词 Green hydrogen production Water electrolysis Anion exchange membrane water electrolyzer(AEMWE) Anion exchange membranes(AEMs) Super-acid-catalyzed condensation(SACC)
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Influence of Al_(2)O_(3)/SiO_(2) Ratio on the Structure and Properties of Na^(+)/K^(+)Ion Exchange Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) Glasses
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作者 吴建磊 CHEN Junzhu +4 位作者 TIAN Xiaokun LI Jiahao GAO Wenkai YUE Yunlong 康俊峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期606-612,共7页
In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)... In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)O_(3)/SiO_(2) ratio,the simple structural units Q_(1) and Q_(2) transformed into highly aggregated structural units Q_(3) and Q_(4),indicating the increase of polymerization degree of glass network.Meanwhile,the coefficient of thermal expansion decreased from 9.23×10^(-6)℃^(-1) to 8.88×10^(-6)℃^(-1).The characteristic temperatures such as melting,forming,softening and glass transition temperatures increased with the increase of Al_(2)O_(3)/SiO_(2) ratio,while the glasses working temperature range became narrow.The increasing Al_(2)O_(3)/SiO_(2) ratio and prolonging ion-exchange time enhanced the surface compressive stress(CS)and depth of stress layer(DOL).However,the increase of ion exchange temperature increased the DOL and decreased the CS affected by stress relaxation.There was a good linear relationship between stress relaxation and surface compressive stress.Chemical strengthening significantly improved the hardness of glasses,which reached the maximum value of(622.1±10)MPa for sample with Al_(2)O_(3)/SiO_(2) ratio of 0.27 after heat treated at 410℃for 2 h. 展开更多
关键词 network structure viscosity ion exchange aluminosilicate glass
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Simulation of charge-exchange induced NBI losses on EAST
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作者 Zhanhong LIN Feng WANG +3 位作者 Ming XU Chaofeng SANG Chen ZHANG Zhengxiong WANG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第9期133-147,共15页
The neutral beam injection is widely adopted in tokamaks as a key heating tool,playing a crucial role in generating burning plasmas.However,the loss of beam ions can damage the first wall and reduce the heating effici... The neutral beam injection is widely adopted in tokamaks as a key heating tool,playing a crucial role in generating burning plasmas.However,the loss of beam ions can damage the first wall and reduce the heating efficiency,resulting in failure to maintain steady-state conditions.In this work,the effect of neutral particles in the edge on fast ions generated by NBI in the Experimental Advanced Superconducting Tokamak(EAST)device is studied using the particle tracer code(PTC).The poloidal distribution of neutral particles is calculated by edge plasma simulation code SOLPS-ITER.In this simulation,four beam lines in EAST are considered:co-current tangential(co-tang),co-current perpendicular(co-perp),counter-current tangential(ctr-tang)and counter-current perpendicular(ctr-perp).It is shown that,in the absence of neutral particles,the loss fraction of ctr-injection is considerably higher than that of the co-injection.When considering the neutral particles,it is found that the ctr-perp injection demonstrates a significant variation in particles loss fraction(ranging from 18.56%to 25.42%)compared to the other three injection configurations.In terms of the loss fraction induced by neutral particles,ctr-injection exceeds co-injection,and perpendicular configuration exceeds tangential configuration.Furthermore,the difference of charge exchange ratios of three different energy(full energy,half energy,one third energy)of the four injections can be attributed to variations in the poloidal trajectories associated with each of these injections.Moreover,approximately half of fast ions which undergo neutralization directly lose to the first wall while the rest re-enter the bulk plasma and re-ionize.Except for the ctr-tang injection,the reionization ions from the other three injections exhibit effective confinement. 展开更多
关键词 NBI charge exchange fast ion loss
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The exchange interaction between neighboring quantum dots:physics and applications in quantum information processing
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作者 Zheng Zhou Yixin Li +3 位作者 Zhiyuan Wu Xinping Ma Shichang Fan Shaoyun Huang 《Journal of Semiconductors》 EI CAS CSCD 2024年第10期20-34,共15页
Electron spins confined in semiconductor quantum dots(QDs)are one of potential candidates for physical implementation of scalable quantum information processing technologies.Tunnel coupling based inter exchange intera... Electron spins confined in semiconductor quantum dots(QDs)are one of potential candidates for physical implementation of scalable quantum information processing technologies.Tunnel coupling based inter exchange interaction between QDs is crucial in achieving single-qubit manipulation,two-qubit gate,quantum communication and quantum simulation.This review first provides a theoretical perspective that surveys a general framework,including the Helter−London approach,the Hund−Mulliken approach,and the Hubbard model,to describe the inter exchange interactions between semiconductor quantum dots.An electrical method to control the inter exchange interaction in a realistic device is proposed as well.Then the significant achievements of inter exchange interaction in manipulating single qubits,achieving two-qubit gates,performing quantum communication and quantum simulation are reviewed.The last part is a summary of this review. 展开更多
关键词 exchange interaction quantum dots tunnel coupling quantum computation
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