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A Brief Study on pH, Exchangeable Ca<sup>2+</sup>and Mg<sup>2+</sup>in Farmlands under Tobacco-Rice Rotation in Xuancheng City of South Anhui 被引量:5
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作者 Anqi Wang Ka Lin +9 位作者 Chengxin Ma Qin Gao Qifa Zhu Xuejun Ji Guo Zhang Lin Xue Chaolong Zu Chaoqiang Jiang Jia Shen Decheng Li 《Agricultural Sciences》 2018年第4期480-488,共9页
pH, exchangeable Ca2+ and Mg2+ of soil can influence the yield and quality of flue-cured tobacco. Xuancheng city is the dominant tobacco-planting region in Anhui province since 2008. A general soil survey was conducte... pH, exchangeable Ca2+ and Mg2+ of soil can influence the yield and quality of flue-cured tobacco. Xuancheng city is the dominant tobacco-planting region in Anhui province since 2008. A general soil survey was conducted in Xuancheng city to understand the current situations of pH, exchangeable Ca2+ and Mg2+ of farmlands under tobacco-rice rotation and to decide whether continuous applying dolomite powders to abate soil acidification. In total 124 topsoil samples (0-20 cm) were collected from the typical farmlands and soil pH, exchangeable Ca2+ and Mg2+ were measured. The results showed that soil pH and Ca2+ and Mg2+ in Xuancheng city were generally in the suitable grades, pH ranged from 4.56 to 8.42 with an average of 5.87, exchangeable Ca2+ ranged from 1.01 cmol(1/2Ca2+) kg-1 to 100.55 cmol(1/2Ca2+) kg-1 with an average of 11.07 cmol(1/2Ca2+) kg-1, and exchangeable Mg2+ ranged from 0.14 cmol(1/2Mg2+) kg-1 to 2.86 cmol(1/2Mg2+) kg-1 with an average of 0.81 cmol(1/2Mg2+) kg-1, all spanned from the low grades to the high grades. To the whole Xuancheng city, 37.10%, 62.10% and 72.58% of the surveyed farmlands were in the low grades of pH, exchangeable Ca2+ and Mg2+, respectively, while 52.42%, 25.00% and 20.97% of the farmlands were in the suitable grades, respectively. pH had an extremely significantly positive Napierian logarithm correlation with exchangeable Ca2+ and an extremely significantly positive power correlation with exchangeable Mg2+. In total about 338.2 kg·hm-2 of Ca2+ and 202.4 kg·hm-2 of Mg2+ are annually input into the farmlands, while about 110.4 kg·hm-2 of Ca2+ and 7.4 kg·hm-2 of Mg2+ are annually moved out from the farmlands, exchangeable Ca2+ and Mg2+ were annually increased by 225.2 kg·hm-2 and 187.6 kg·hm-2 in the farmlands, respectively. It is necessary to monitor the farmlands dynamically in order to decide whether continuous applying dolomite powders which should be dependent upon the specific conditions of individual farmlands. 展开更多
关键词 PH exchangeable Ca2+ and Mg2+ DOLOMITE Powders Farmlands Tobacco-Rice Rotation Xuancheng CITY
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Comparison and Evaluation of Two Analytical Methods for Cation Exchange Capacity and Exchangeable Sodium Percentage of Five Soil Types in Central Sudan 被引量:3
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作者 Jamal Elfaki Mohamed Gafer +1 位作者 Magboul Sulieman Mushtaha Ali 《Open Journal of Soil Science》 2015年第12期311-318,共8页
Twenty-six soil samples were collected from five soil profiles at different climatological and ecological regions in central Sudan. Soil profile was dug in each studied area and morphological profile description was c... Twenty-six soil samples were collected from five soil profiles at different climatological and ecological regions in central Sudan. Soil profile was dug in each studied area and morphological profile description was carried out for different horizons. All samples were analyzed using two different methods to determine Cation Exchange Capacity (CEC) and exchangeable sodium percentage (ESP). Statistical analysis (T-test) was used in order to investigate the differences between soil samples for the studied locations. Significant differences appeared when compared the two methods for CEC determination at Gedaref area, Wad Medani and Nile flood plain and that appeared in evaluation of ESP at Nile flood plain and Shambat area. The results also revealed that, the developed method used in this study was more practical, simple and reliable for determination of CEC and ESP as the currently used in most soil laboratories. In addition, it will be safer than the other methods in some problematic soils. The adoption of this developed method is advisable because it is less time consuming as it omits the washing step. In contrast, the old method cannot be a good substitute in laboratories which have no possibility to determine sodium by using flame photometer. We conclude that when the developed method is used to determine CEC and ESP time will be saved, that fewer amounts of chemicals will be used and that accurate results will be achieved. 展开更多
关键词 ECOLOGICAL REGIONS CENTRAL SUDAN CATION Exchange Capacity exchangeable Sodium PERCENTAGE
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Stochastic ordering of medians in exchangeable trivariate normal vectors
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作者 Ahad Jamalizadeh Mohsen Madadi +1 位作者 Mehdi Amiri N.Balakrishnan 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2016年第2期148-156,共9页
In this paper, we establish the stochastic ordering of median from an exchangeable trivaxiate normal vector based on the strength of the correlation coefficient. Specifically, by considering two exchangeable trivariat... In this paper, we establish the stochastic ordering of median from an exchangeable trivaxiate normal vector based on the strength of the correlation coefficient. Specifically, by considering two exchangeable trivariate normal vectors with different correlation coefficients, we show that the absolute value of the median in the vector with smaller correlation coefficient is stochastically smaller than the absolute value of the median in the vector with larger correlation coefficient. We prove this result by utilizing skew-normal distributions. 展开更多
关键词 Stochastic ordering exchangeable trivariate normal distribution Order statistics MEDIAN Skew-normal distribution 2nd skew-normal distribution.
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Non-uniform Berry-Esseen bound by unbounded exchangeable pairs approach
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作者 LIU Da-li LI Zheng +1 位作者 WANG Han-chao CHEN Zeng-jing 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2021年第2期256-268,共13页
In this paper,a new technique is introduced to obtain non-uniform Berry-Esseen bounds for normal and nonnormal approximations by unbounded exchangeable pairs.This technique does not rely on the concentration inequalit... In this paper,a new technique is introduced to obtain non-uniform Berry-Esseen bounds for normal and nonnormal approximations by unbounded exchangeable pairs.This technique does not rely on the concentration inequalities developed by Chen and Shao[4,5]and can be applied to the quadratic forms and the general Curie-Weiss model. 展开更多
关键词 non-uniform Berry-Esseen bounds Stein's method exchangeable pairs
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Gnedenko-Raikov’s Theorem Fails for Exchangeable Sequences
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作者 George Stoica Deli Li 《Applied Mathematics》 2012年第12期2019-2021,共3页
We study the connection between the central limit theorem and law of large numbers for exchangeable sequences, and provide a counterexample to the Gnedenko-Raikov theorem for such sequences.
关键词 exchangeable SEQUENCES Central LIMIT THEOREM WEAK LAW of Large NUMBERS
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Study on Exchangeable Cation Determining Base Saturation Percentage of Soil in South China
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作者 Anqi Wang Xiangzhen Kong +2 位作者 Xiaodong Song Bing Ju Decheng Li 《Agricultural Sciences》 2020年第1期17-26,共10页
Base saturation percentage (BSP) is an important soil chemical index in soil fertility and soil taxonomy. However, it is still unclear what exchangeable cation dominates BSP of soil in south China. Therefore, in this ... Base saturation percentage (BSP) is an important soil chemical index in soil fertility and soil taxonomy. However, it is still unclear what exchangeable cation dominates BSP of soil in south China. Therefore, in this study, the data of BSPs and exchangeable H+, Al3+, Ca2+, Mg2+, K+ and Na+ of 109 and 45 horizon samples of 50 and 28 soil species in red soil and yellow soil groups in the Database of Chinese Soil Species were used to explore further the characteristics of BSPs and exchangeable cations as well as the correlation between BSPs and exchangeable cations. The results showed that the concentrations of exchangeable cations in both red soil and yellow soil groups were in an order of Al3+ (4.55 ± 1.47 and 4.22 ± 1.2 cmol(+)/kg) > Ca2+ (0.32 ± 0.21 and 0.36 ± 0.24 cmol(+)/kg) > H+ (0.23 ± 0.13 and 0.19 ± 0.10 cmol(+)/kg) > K+ (0.16 ± 0.09 and 0.16 ± 0.11 cmol(+)/kg) > Mg2+ (0.13 ± 0.09 and 0.11 ± 0.08 cmol(+)/kg) > Na+ (0.08 ± 0.06 and 0.11 ± 0.06 cmol(+)/kg). For red soil group, Al3+ concentration was significantly higher than those of other exchangeable cations, Ca2+ and H+ concentrations were significantly higher than those of K+, Mg2+ and Na+;while for yellow soil group, Ca2+, H+ and K+ concentrations were significantly higher than those of Mg2+ and K+. BSP of red soil group was codetermined by Ca2+, Al3+, Mg2+ and Na+, with the contributions of 33.81%, 19.82% and 14.49%, respectively;while BSP of yellow soil group was codetermined by Al3+, Ca2+, Mg2+, K+ and Na+, with the contributions of 24.91%, 21.55%, 19.91% and 14.21%, respectively. A higher concentration of exchangeable cation does not mean the higher importance of the cation to soil BSP. 展开更多
关键词 Base SATURATION PERCENTAGE (BSP) exchangeable CATIONS Correlation Red SOIL Yellow SOIL South China
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Changes in Soil pH and Exchangeable Acidity of Selected Parent Materials as Influenced by Amendments in South East of Nigeria
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作者 Mabel Ifeoma Onwuka Uzochukwu Victor Ozurumba Ogadimma Simonpeter Nkwocha 《Journal of Geoscience and Environment Protection》 2016年第5期80-88,共9页
Soil chemical degradation caused by acidity is a serious constraint to food production in most parts of the Tropics. It was in the bid to proffer solution to this that the present study was conceived. Anincubation stu... Soil chemical degradation caused by acidity is a serious constraint to food production in most parts of the Tropics. It was in the bid to proffer solution to this that the present study was conceived. Anincubation study was conducted at the laboratory of Soil Science and Meteorology Department of Michael Okpara University of Agriculture Umudike. The aim was to ascertain the effect of amendments namely: Control (no amendment), Biochar, Ash, Lime, Biochar + Poultry Manure, Ash + Poultry Manure and Lime + Poultry Manure, on soil pH and exchangeable acidity of Sandstone, Shale and Alluvium. The rate of application was 1.43 g for the sole amendments and 0.72 g each for the combined amendments to give an equivalent of 2 t/ha. They were applied to 100 g of the soil and replicated three times in a Completely Randomized Design. The incubation study lasted for eighty-four days, the pH and exchangeable acidity were determined at fourteen days intervals. The result obtained revealed that all the treatments increased the soil pH and decreased the exchangeable acidity over the control. In all parent materials, applied Lime and Lime + Pm significantly (p < 0.05) gave the highest pH of 6.6, 6.9 and 7.2 for Shale, Sandstone and Alluvium respectively on the 28<sup>th</sup> day of incubation which, was the time, the maximum pH value was attained. Biochar and Biochar + Pm were considered the appropriate amendments because the pH values they gave were towards neutral, unlike that of Lime and Lime + Pm that were towards alkaline. It is recommended that field trial of this work is conducted. 展开更多
关键词 Parent Materials PH exchangeable Acidity and Amendments
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Soil exchangeable base cations along a chronosequence of Caragana microphylla plantation in a semi-arid sandy land,China 被引量:11
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作者 YuGe ZHANG ZhuWen XU +1 位作者 DeMing JIANG Yong JIANG 《Journal of Arid Land》 SCIE CSCD 2013年第1期42-50,共9页
As a pioneer leguminous shrub species for vegetation re-establishment, Caragana microphylla is widely distributed in the semi-fixed and fixed sandy lands of the Horqin region, North China. C. microphylla planta- tions... As a pioneer leguminous shrub species for vegetation re-establishment, Caragana microphylla is widely distributed in the semi-fixed and fixed sandy lands of the Horqin region, North China. C. microphylla planta- tions modify organic carbon (SOC), nitrogen (N) and phosphorus dynamics, bulk density and water-holding capacity and biological activities in soils, but little is known with regard to soil exchange properties. Variation in soil ex- changeable base cations was examined under C. microphylla plantations with an age sequence of 0, 5, 10, and 22 years in the Horqin Sandy Land, and at the depth of 0-10, 10-20, and 20-30 cm, respectively. C. microphylla has been planted on the non-vegetated sand dunes with similar physical-chemical soil properties. The results showed that exchangeable calcium (Ca), magnesium (Mg), and potassium (K), and cation exchange capacity (CEC) were significantly increased, and Ca saturation tended to decrease, while Mg and K saturations were increased with the plantation years. No difference was observed for exchangeable sodium (Na) neither with plantation years nor at soil depths. Of all the base cations and soil layers, exchangeable K at the depth of 0-10 cm accumulated most quickly, and it increased by 1.76, 3.16, and 4.25 times, respectively after C. microphylla was planted for 5, 10, and 22 years. Exchangeable Ca, Mg, and K, and CEC were significantly (P〈0.001) and positively correlated with SOC, total N, pH and electrical conductivity (EC). Soil pH and SOC are regarded as the main factors influencing the variation in ex- changeable cations, and the preferential absorption of cations by plants and different leaching rates of base cations that modify cation saturations under C. microphylla plantation. It is concluded that as a nitrogen-fixation species, C. microphylla plantation is beneficial to increasing exchangeable base cations and CEC in soils, and therefore can improve soil fertility and create favorable microenvironments for plants and creatures in the semi-arid sandy land ecosystems. 展开更多
关键词 cation exchange capacity soil organic carbon soil pH soil fertility Caragana microphylla ecological restoration
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Influence of Types and Charges of Exchangeable Cations on Ciprofloxacin Sorption by Montmorillonite 被引量:2
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作者 吴青峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第3期516-522,共7页
As one of the most important soil components, montmorillonite plays a vital role in transport and retention of organic pollutants in soils. Ciprofloxacin (CIP), an antibiotic of fluoroquiolones, has been frequently ... As one of the most important soil components, montmorillonite plays a vital role in transport and retention of organic pollutants in soils. Ciprofloxacin (CIP), an antibiotic of fluoroquiolones, has been frequently detected in water and soil environments due to its wide use in human and veterinary medicine. In this study, the adsorption of CIP onto different homoionic montmorillonite such as Na-, Ca- and Al-MMT was investigated, and the influence of types and charges of exchangeable cations in the interlayer of montmorillonite on CIP adsorption was evaluated. The results showed that different homoionic montmorillonite exhibited different sorption capacity of CIP. At pH 3, the sorption capacity of CIP decreased in the order Na-MMT Ca-MMT Al-MMT, following the lyotropic series. When solution pH increased to 11, the sorption capacity of CIP followed the order Ca-MMT Al-MMT Na-MMT. Accompanying CIP adsorption on Ca-MMT, a certain amount of Ca2+ was released into solution. Compared to pH 3, the lower Ca concentration in solution at pH 11 indicated that the adsorption of CIP on Ca-MMT at strong alkaline pH was no longer via cation exchange, and surface complexation or cation bridging might contribute to CIP adsorption. The adsorption of CIP on Na- and Ca-MMT at pH 3 and 11 resulted in the expansion of d-spacing, indicative of intercalation of CIP into the interlayer space of the montmorillonite. However, a decrease of d-spacing was observed when CIP adsorbed on Al-MMT at pH 11, which might be attributed to the dissolution of Al-CIP complex formed between CIP and Al3+ in the interlayer of montmorillonite. The results suggest that the types and charges of exchangeable cations in the interlayer of montmorillonite play an important role in CIP adsorption on montmorillonite. 展开更多
关键词 antibiotic cation exchange COMPLEXATION INTERCALATION SORPTION
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On the apparent line-of-sight alignment of the peak X-ray intensity of the magnetosheath and the tangent to the magnetopause,as viewed by SMILE-SXI 被引量:2
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作者 Andrew Read 《Earth and Planetary Physics》 EI CSCD 2024年第1期155-172,共18页
The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible f... The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible from the position of SMILE are created for a range of solar wind densities by using 3 years of the SMILE mission orbit,together with models of the expected X-ray emissivity from the Earth’s magnetosheath.Results from global magnetohydrodynamic simulations and a simple model for exospheric neutral densities are used to compare the locations of the lines of sight along which integrated soft X-ray intensities peak with the lines of sight lying tangent to surfaces(defined here to be the magnetopause)along which local soft X-ray intensities peak or exhibit their strongest gradients,or both,for strongly southward interplanetary magnetic field conditions when no depletion or low-latitude boundary layers are expected.Where,in the parameter space of the various times and seasons,orbital phases,solar wind conditions,and magnetopause models,the alignment of the X-ray emission peak with the magnetopause tangent is good,or is not,is presented.The main results are as follows.The spacecraft needs to be positioned well outside the magnetopause;low-altitude times near perigee are not good.In addition,there are seasonal aspects:dayside-apogee orbits are generally very good because the spacecraft travels out sunward at high altitude,but nightside-apogee orbits,behind the Earth,are bad because the spacecraft only rarely leaves the magnetopause.Dusk-apogee and dawnapogee orbits are intermediate.Dayside-apogee orbits worsen slightly over the first three mission years,whereas nightside-apogee orbits improve slightly.Additionally,many more times of good agreement with the peak-to-tangent hypothesis occur when the solar wind is in a high-density state,as opposed to a low-density state.In a high-density state,the magnetopause is compressed,and the spacecraft is more often a good distance outside the magnetopause. 展开更多
关键词 X-rays MAGNETOSPHERE MAGNETOSHEATH MAGNETOPAUSE Solar wind Magnetosphere Ionosphere Link Explorer(SMILE) Earth solar wind charge exchange
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Solar wind ion charge state distributions and compound cross sections for solar wind charge exchange X-ray emission 被引量:1
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作者 Dimitra Koutroumpa 《Earth and Planetary Physics》 EI CSCD 2024年第1期105-118,共14页
Solar Wind Charge eXchange X-ray(SWCX) emission in the heliosphere and Ea rth’s exosphere is a hard to avoid signal in soft Xray obse rvations of astrophysical targets.On the other hand,the X-ray imaging possibilitie... Solar Wind Charge eXchange X-ray(SWCX) emission in the heliosphere and Ea rth’s exosphere is a hard to avoid signal in soft Xray obse rvations of astrophysical targets.On the other hand,the X-ray imaging possibilities offered by the SWCX process has led to an increasing number of future dedicated space missions for investigating the solar wind-terrestrial inte ractions and magnetospheric interfaces.In both cases,accurate modelling of the SWCX emission is key to correctly interpret its signal,and remove it from obse rvations,when needed.In this paper,we compile solar wind abundance measurements from ACE for different solar wind types,and atomic data from literature,including charge exchange cross-sections and emission probabilities,used fo r calculating the compound cross-section a for the SWCX X-ray emission.We calculate a values for charge-exchange with H and He,relevant to soft X-ray energy bands(0.1-2.0 keV)for various solar wind types and solar cycle conditions. 展开更多
关键词 solar wind charge exchange X-rays MAGNETOSPHERE HELIOSPHERE
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The magnetosheath at high spectral resolution 被引量:1
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作者 K.D.Küntz D.Koutroumpa +4 位作者 W.R.Dunn A.Foster F.S.Porter D.G.Sibeck B.Walsh 《Earth and Planetary Physics》 EI CSCD 2024年第1期234-246,共13页
While we eagerly anticipate SMILE’s(Solar wind Magnetosphere Ionosphere Link Explorer)unprecedented X-ray observations of the Earth’s magnetosheath and the initiation of a new era of magnetospheric research,it seems... While we eagerly anticipate SMILE’s(Solar wind Magnetosphere Ionosphere Link Explorer)unprecedented X-ray observations of the Earth’s magnetosheath and the initiation of a new era of magnetospheric research,it seems appropriate to look ahead to the abilities of the next generation of astrophysics missions.Of these,the Line Emission Mapper(LEM),a large aperture micro-calorimeter based mission,is currently planned to be able to observe the magnetosheath at high spectral resolution(~2 eV).With a field of view of~30′,LEM will allow higher spatial resolution and higher cadence measurement of the motion of a very small portion of the magnetopause over relatively short periods of time(multiple hours),complementing SMILE’s global mapping.LEM’s strength is its spectral resolution.It will be able to measure the abundance of a broad range of elements and ionization states,many of which are inaccessible to current in situ instruments,and will be able to separate the emission from the magnetosheath from the emission from the cosmic X-ray background using the difference in their relative velocities. 展开更多
关键词 MAGNETOSHEATH charge exchange solar wind abundances
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Two methods for separating the magnetospheric solar wind charge exchange soft X-ray emission from the diffuse X-ray background 被引量:1
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作者 YingJie Zhang TianRan Sun +5 位作者 JenniferACarter WenHao Liu Steve Sembay ShuiNai Zhang Li Ji Chi Wang 《Earth and Planetary Physics》 EI CSCD 2024年第1期119-132,共14页
Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is propo... Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is proposed as a new technique to study the magnetosphere using panoramic soft X-ray imaging.To better prepare for the data analysis of upcoming magnetospheric soft X-ray imaging missions,this paper compares the magnetospheric SWCX emission obtained by two methods in an XMM-Newton observation,during which the solar wind changed dramatically.The two methods differ in the data used to fit the diffuse X-ray background(DXB)parameters in spectral analysis.The method adding data from the ROSAT All-Sky Survey(RASS)is called the RASS method.The method using the quiet observation data is called the Quiet method,where quiet observations usually refer to observations made by the same satellite with the same target but under weaker solar wind conditions.Results show that the spectral compositions of magnetospheric SWCX emission obtained by the two methods are very similar,and the changes in intensity over time are highly consistent,although the intensity obtained by the RASS method is about 2.68±0.56 keV cm^(-2)s^(-1)sr^(-1)higher than that obtained by the Quiet method.Since the DXB intensity obtained by the RASS method is about 2.84±0.74 keV cm^(-2)s^(-1)sr^(-1)lower than that obtained by the Quiet method,and the linear correlation coefficient between the difference of SWCX and DXB obtained by the two methods in diffe rent energy band is close to-1,the diffe rences in magnetospheric SWCX can be fully attributed to the diffe rences in the fitted DXB.The difference between the two methods is most significant when the energy is less than 0.7 keV,which is also the main energy band of SWCX emission.In addition,the difference between the two methods is not related to the SWCX intensity and,to some extent,to solar wind conditions,because SWCX intensity typically va ries with the solar wind.In summary,both methods are robust and reliable,and should be considered based on the best available options. 展开更多
关键词 solar wind charge exchange(SWCX) ROSAT All-Sky Survey(RASS) soft X-ray X-ray imaging MAGNETOSPHERE
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Simulation of the SMILE Soft X-ray Imager response to a southward interplanetary magnetic field turning 被引量:1
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作者 Andrey Samsonov Graziella Branduardi-Raymont +3 位作者 Steven Sembay Andrew Read David Sibeck Lutz Rastaetter 《Earth and Planetary Physics》 EI CSCD 2024年第1期39-46,共8页
The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)Soft X-ray Imager(SXI)will shine a spotlight on magnetopause dynamics during magnetic reconnection.We simulate an event with a southward interplanetary magne... The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)Soft X-ray Imager(SXI)will shine a spotlight on magnetopause dynamics during magnetic reconnection.We simulate an event with a southward interplanetary magnetic field turning and produce SXI count maps with a 5-minute integration time.By making assumptions about the magnetopause shape,we find the magnetopause standoff distance from the count maps and compare it with the one obtained directly from the magnetohydrodynamic(MHD)simulation.The root mean square deviations between the reconstructed and MHD standoff distances do not exceed 0.2 RE(Earth radius)and the maximal difference equals 0.24 RE during the 25-minute interval around the southward turning. 展开更多
关键词 MAGNETOPAUSE magnetic reconnection solar wind charge exchange southward interplanetary magnetic field numerical modeling Solar wind Magnetosphere Ionosphere Link Explorer(SMILE) Soft X-ray Imager
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Proton‑Prompted Ligand Exchange to Achieve High‑Efficiency CsPbI_(3) Quantum Dot Light‑Emitting Diodes
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作者 Yanming Li Ming Deng +2 位作者 Xuanyu Zhang Lei Qian Chaoyu Xiang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期53-62,共10页
CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improv... CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improvement of device performance.Traditional in-situ ligand replacement and ligand exchange after synthesis were often difficult to control.Here,we proposed a new ligand exchange strategy using a proton-prompted insitu exchange of short 5-aminopentanoic acid ligands with long-chain oleic acid and oleylamine ligands to obtain stable small-size CsPbI_(3)QDs.This exchange strategy maintained the size and morphology of CsPbI_(3)QDs and improved the optical properties and the conductivity of CsPbI_(3)QDs films.As a result,high-efficiency red QD-based light-emitting diodes with an emission wavelength of 645 nm demonstrated a record maximum external quantum efficiency of 24.45%and an operational half-life of 10.79 h. 展开更多
关键词 CsPbI_(3) perovskite quantum dots Light-emitting diodes Ligand exchange Proton-prompted in-situ exchange
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Towards high-performance and robust anion exchange membranes(AEMs)for water electrolysis:Super-acid-catalyzed synthesis of AEMs
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作者 Geun Woong Ryoo Sun Hwa Park +3 位作者 Ki Chang Kwon Jong Hun Kang Ho Won Jang Min Sang Kwon 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期478-510,I0012,共34页
The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen pro... The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen production technologies,anion exchange membrane water electrolyzer(AEMWE)has emerged as a next-generation technology known for its high hydrogen production efficiency and its ability to use non-metal catalysts.However,this technology faces significant challenges,particularly in terms of the membrane durability and low ionic conductivity.To address these challenges,research efforts have focused on developing membranes with a new backbone structure and anion exchange groups to enhance durability and ionic conductivity.Notably,the super-acid-catalyzed condensation(SACC)synthesis method stands out due to its user convenience,the ability to create high molecular weight(MW)polymers,and the use of oxygen-tolerant organic catalysts.Although the synthesis of anion exchange membranes(AEMs)using the SACC method began in 2015,and despite growing interest in this synthesis approach,there remains a scarcity of review papers focusing on AEMs synthesized using the SACC method.The review covers the basics of SACC synthesis,presents various polymers synthesized using this method,and summarizes the development of these polymers,particularly their building blocks including aryl,ketone,and anion exchange groups.We systematically describe the effects of changes in the molecular structure of each polymer component,conducted by various research groups,on the mechanical properties,conductivity,and operational stability of the membrane.This review will provide insights into the development of AEMs with superior performance and operational stability suitable for water electrolysis applications. 展开更多
关键词 Green hydrogen production Water electrolysis Anion exchange membrane water electrolyzer(AEMWE) Anion exchange membranes(AEMs) Super-acid-catalyzed condensation(SACC)
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Influence of Al_(2)O_(3)/SiO_(2) Ratio on the Structure and Properties of Na^(+)/K^(+)Ion Exchange Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) Glasses
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作者 吴建磊 CHEN Junzhu +4 位作者 TIAN Xiaokun LI Jiahao GAO Wenkai YUE Yunlong 康俊峰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期606-612,共7页
In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)... In this work,the structure,viscosity and ion-exchange process of Na_(2)O-MgO-Al_(2)O_(3)-SiO_(2) glasses with different Al_(2)O_(3)/SiO_(2) molar ratios were investigated.The results showed that,with increasing Al_(2)O_(3)/SiO_(2) ratio,the simple structural units Q_(1) and Q_(2) transformed into highly aggregated structural units Q_(3) and Q_(4),indicating the increase of polymerization degree of glass network.Meanwhile,the coefficient of thermal expansion decreased from 9.23×10^(-6)℃^(-1) to 8.88×10^(-6)℃^(-1).The characteristic temperatures such as melting,forming,softening and glass transition temperatures increased with the increase of Al_(2)O_(3)/SiO_(2) ratio,while the glasses working temperature range became narrow.The increasing Al_(2)O_(3)/SiO_(2) ratio and prolonging ion-exchange time enhanced the surface compressive stress(CS)and depth of stress layer(DOL).However,the increase of ion exchange temperature increased the DOL and decreased the CS affected by stress relaxation.There was a good linear relationship between stress relaxation and surface compressive stress.Chemical strengthening significantly improved the hardness of glasses,which reached the maximum value of(622.1±10)MPa for sample with Al_(2)O_(3)/SiO_(2) ratio of 0.27 after heat treated at 410℃for 2 h. 展开更多
关键词 network structure viscosity ion exchange aluminosilicate glass
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Dynamic modeling of cavitation bubble clusters:Effects of evaporation,condensation,and bubble-bubble interaction
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作者 许龙 姚昕锐 沈阳 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期527-535,共9页
We present a dynamic model of cavitation bubbles in a cluster,in which the effects of evaporation,condensation,and bubble-bubble interactions are taken into consideration.Under different ultrasound conditions,we exami... We present a dynamic model of cavitation bubbles in a cluster,in which the effects of evaporation,condensation,and bubble-bubble interactions are taken into consideration.Under different ultrasound conditions,we examine how the dynamics of cavitation bubbles are affected by several factors,such as the locations of the bubbles,the ambient radius,and the number of bubbles.Herein the variations of bubble radius,energy,temperature,pressure,and the quantity of vapor molecules are analyzed.Our findings reveal that bubble-bubble interactions can restrict the expansion of bubbles,reduce the exchange of energy among vapor molecules,and diminish the maximum internal temperature and pressure when bursting.The ambient radius of bubbles can influence the intensities of their oscillations,with clusters comprised of smaller bubbles creating optimal conditions for generating high-temperature and high-pressure regions.Moreover,an increase in the number of bubbles can further inhibit cavitation activities.The frequency,pressure and waveform of the driving wave can also exert a significant influence on cavitation activities,with rectangular waves enhancing and triangular waves weakening the cavitation of bubbles in the cluster.These results provide a theoretical basis for understanding the dynamics of cavitation bubbles in a bubble cluster,and the factors that affect their behaviors. 展开更多
关键词 bubble dynamics bubble-bubble interaction mass exchange ultrasound waveform
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Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell
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作者 Chao Liu Zhen Geng +6 位作者 Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期348-369,I0009,共23页
Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,t... Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed. 展开更多
关键词 HYDROGEN Water electrolysis Anion exchange membrane Electrolysis cell
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Influence of exchange bias on spin torque ferromagnetic resonance for quantification of spin–orbit torque efficiency
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作者 赵乾 张腾飞 +6 位作者 何斌 李子木 张森富 于国强 王建波 刘青芳 魏晋武 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期688-694,共7页
Antiferromagnet(AFM)/ferromagnet(FM)heterostructure is a popular system for studying the spin–orbit torque(SOT)of AFMs.However,the interfacial exchange bias field induces that the magnetization in FM layer is noncoll... Antiferromagnet(AFM)/ferromagnet(FM)heterostructure is a popular system for studying the spin–orbit torque(SOT)of AFMs.However,the interfacial exchange bias field induces that the magnetization in FM layer is noncollinear to the external magnetic field,namely the magnetic moment drag effect,which further influences the characteristic of SOT efficiency.In this work,we study the SOT efficiencies of IrMn/NiFe bilayers with strong interfacial exchange bias by using spin-torque ferromagnetic resonance(ST-FMR)method.A full analysis on the AFM/FM systems with exchange bias is performed,and the angular dependence of magnetization on external magnetic field is determined through the minimum rule of free energy.The ST-FMR results can be well fitted by this model.We obtained the relative accurate SOT efficiencyξ_(DL)=0.058 for the IrMn film.This work provides a useful method to analyze the angular dependence of ST-FMR results and facilitates the accurate measurement of SOT efficiency for the AFM/FM heterostructures with strong exchange bias. 展开更多
关键词 ANTIFERROMAGNETS spin-orbit torque exchange bias spin torque ferromagnetic resonance
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