We calculate the electron impact excitation of Ni-like gold by using the Dirac R-matrix theory, and the cor- responding collision strengths and effective collision strengths are obtained. In the calculations of the le...We calculate the electron impact excitation of Ni-like gold by using the Dirac R-matrix theory, and the cor- responding collision strengths and effective collision strengths are obtained. In the calculations of the level energy, （1sZ2sZ2p6）3sZ3p63d10, 3s23p63d94/, 3s23p53d104/, and 3s3p63d104/（l = 0, 1,2,3） configurations are included and 107 fine-structure levels are generated. In the calculations of the collision strengths, only the first 59 levels are included. Com- parisons are made with the distorted wave （DW） results of Zeng et al. for both collision strengths and effective collision strengths. For the collision strengths, the two sets of calculations are in excellent agreement for most of the transitions. However, because of the inclusion of the resonances, our effective collision strengths are generally several times larger than those of Zeng et al.. The accuracy of our calculations is assessed.展开更多
Excitation-emission matrix fluorescence spectroscopy (EEM) has been widely used to elucidate the origin and structure of humic substances in natural environments. Due to its high sensitivity, good selectivity and non-...Excitation-emission matrix fluorescence spectroscopy (EEM) has been widely used to elucidate the origin and structure of humic substances in natural environments. Due to its high sensitivity, good selectivity and non-destructive advantage, the EEM was applied to characterizing a commercial Fluka humic acid (FHA). The results showed that the EEMs of FHA has several Ex/Em peaks. Ionic strength (0- 0.05 mol/L KClO 4) exerted little effect on the fluorescence properties of FHA, while the concentrations (5-100 mg/L) of FHA and pH (2-12) had significant effects. A red shift in the longer wavelength peak region was observed when the concentrations or pH values increased. The fluorescence intensity increased with increasing pH, but slightly decreased in the case of pH= 5.0. The protonation constants (lgK’ HL) of peak B were calculated to be 3.57 and 3.13, indicating that peak B was due to carboxyl groups. The r (A/B) values range from 0.61 to 2.59. A strong linear relationship between r (A/B) and pH was also observed. This indicates that the fluorescence peaks A and B posses similar inherent fluorescence characteristics.展开更多
In this paper,an optimal nonlinear robust sliding mode control(ONRSMC)based on mixed H_(2)/H_(∞)linear matrix inequalities(LMIs)is designed for the excitation system in a“one machine-infinite bus system”(OMIBS)to e...In this paper,an optimal nonlinear robust sliding mode control(ONRSMC)based on mixed H_(2)/H_(∞)linear matrix inequalities(LMIs)is designed for the excitation system in a“one machine-infinite bus system”(OMIBS)to enhance system stability.Initially,the direct feedback linearization method is used to establish a mathematical model of the OMIBS incorporating uncertainties.ONRSMC is then designed for this model,employing the mixed H_(2)/H_(∞)LMIs.The chaos mapping-based adaptive salp swarm algorithm(CASSA)is introduced to fully optimize the parameters of the sliding mode control,ensuring optimal performance under a specified condition.CASSA demonstrates rapid convergence and reduced like-lihood of falling into local optima during optimization.Finally,ONRSMC is obtained through inverse transformation,exhibiting the advantages of simple structure,high reliability,and independence from the accuracy of system models.Four simulation scenarios are employed to validate the effectiveness and robustness of ONRSMC,including mechanical power variation,generator three-phase short circuit,transmission line short circuit,and generator parameter uncertainty.The results indicate that ONRSMC achieves optimal dynamic performance in various operating conditions,facilitating the stable operation of power systems following faults.展开更多
Employing both the Dirac R-matrix and the relativistic distorted wave with independent process and isolated reso- nance approaches, we report resonance enhanced electron impact excitation data （specifically, effectiv...Employing both the Dirac R-matrix and the relativistic distorted wave with independent process and isolated reso- nance approaches, we report resonance enhanced electron impact excitation data （specifically, effective collision strengths） among the lowest 41 levels from the n = 3 configurations of Cu XV. The results show that the latter approach can obtain resonance contributions reasonably well for most excitations of Cu XV, though a comparison between the two approaches shows that the close-coupling effects are truly significant for rather weak excitations, especially for two-electron excitations from the 3s3p4 to 3s23p23d configuration. Resonance contributions are significant （more than two orders of magnitude） for many excitations and dramatically influence the line intensity ratios associated with density diagnostics.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.11174213 and 11304266)
文摘We calculate the electron impact excitation of Ni-like gold by using the Dirac R-matrix theory, and the cor- responding collision strengths and effective collision strengths are obtained. In the calculations of the level energy, （1sZ2sZ2p6）3sZ3p63d10, 3s23p63d94/, 3s23p53d104/, and 3s3p63d104/（l = 0, 1,2,3） configurations are included and 107 fine-structure levels are generated. In the calculations of the collision strengths, only the first 59 levels are included. Com- parisons are made with the distorted wave （DW） results of Zeng et al. for both collision strengths and effective collision strengths. For the collision strengths, the two sets of calculations are in excellent agreement for most of the transitions. However, because of the inclusion of the resonances, our effective collision strengths are generally several times larger than those of Zeng et al.. The accuracy of our calculations is assessed.
文摘Excitation-emission matrix fluorescence spectroscopy (EEM) has been widely used to elucidate the origin and structure of humic substances in natural environments. Due to its high sensitivity, good selectivity and non-destructive advantage, the EEM was applied to characterizing a commercial Fluka humic acid (FHA). The results showed that the EEMs of FHA has several Ex/Em peaks. Ionic strength (0- 0.05 mol/L KClO 4) exerted little effect on the fluorescence properties of FHA, while the concentrations (5-100 mg/L) of FHA and pH (2-12) had significant effects. A red shift in the longer wavelength peak region was observed when the concentrations or pH values increased. The fluorescence intensity increased with increasing pH, but slightly decreased in the case of pH= 5.0. The protonation constants (lgK’ HL) of peak B were calculated to be 3.57 and 3.13, indicating that peak B was due to carboxyl groups. The r (A/B) values range from 0.61 to 2.59. A strong linear relationship between r (A/B) and pH was also observed. This indicates that the fluorescence peaks A and B posses similar inherent fluorescence characteristics.
基金supported by the National Natural Science Foundation of China(No.51979204 and No.52009096)the Fundamental Research Funds for the Central Universities(No.2042022kf1022)the Hubei Provincial Natural Science Foundation of China(No.2022CFD165).
文摘In this paper,an optimal nonlinear robust sliding mode control(ONRSMC)based on mixed H_(2)/H_(∞)linear matrix inequalities(LMIs)is designed for the excitation system in a“one machine-infinite bus system”(OMIBS)to enhance system stability.Initially,the direct feedback linearization method is used to establish a mathematical model of the OMIBS incorporating uncertainties.ONRSMC is then designed for this model,employing the mixed H_(2)/H_(∞)LMIs.The chaos mapping-based adaptive salp swarm algorithm(CASSA)is introduced to fully optimize the parameters of the sliding mode control,ensuring optimal performance under a specified condition.CASSA demonstrates rapid convergence and reduced like-lihood of falling into local optima during optimization.Finally,ONRSMC is obtained through inverse transformation,exhibiting the advantages of simple structure,high reliability,and independence from the accuracy of system models.Four simulation scenarios are employed to validate the effectiveness and robustness of ONRSMC,including mechanical power variation,generator three-phase short circuit,transmission line short circuit,and generator parameter uncertainty.The results indicate that ONRSMC achieves optimal dynamic performance in various operating conditions,facilitating the stable operation of power systems following faults.
基金supported by the National Natural Science Foundation of China(Grant Nos.11076009 and 11374062)the Chinese Association of Atomic and Molecular Data,the Chinese National Fusion Project for ITER(Grant No.2015GB117000)the Leading Academic Discipline Project of Shanghai,China(Grant No.B107)
文摘Employing both the Dirac R-matrix and the relativistic distorted wave with independent process and isolated reso- nance approaches, we report resonance enhanced electron impact excitation data （specifically, effective collision strengths） among the lowest 41 levels from the n = 3 configurations of Cu XV. The results show that the latter approach can obtain resonance contributions reasonably well for most excitations of Cu XV, though a comparison between the two approaches shows that the close-coupling effects are truly significant for rather weak excitations, especially for two-electron excitations from the 3s3p4 to 3s23p23d configuration. Resonance contributions are significant （more than two orders of magnitude） for many excitations and dramatically influence the line intensity ratios associated with density diagnostics.
