Experiment Study on the Exhaust-Gas Heat Exchanger for Small and Medium-Sized Marine Diesel Engine

This paper aims to design a special exchanger to recover the exhaust gas heat of marine diesel engines used in small and medium-sized fishing vessels,which can then be used to heat water up to 55°C–85°C for membrane desalination devices to produce fresh water.A new exhaust-gas heat exchanger of fins and tube,with a reinforced heat transfer tube section,unequal spacing fins,a mixing zone between the fin groups and four routes tube bundle,was designed.Numerical simulations were also used to provide reference information for structural design.Experiments were carried out for exhaust gas waste heat recovery from a marine diesel engine in an engine test bench utilizing the heat exchanger.The experimental results show that the difference between heat absorption by water and heat reduction of exhaust gas is less than 6.5%.After the water flow rate was adjusted,the exhaust gas waste heat recovery efficiency was higher than 70%,and the exhaust-gas heat exchanger’s outlet water temperature was 55°C–85°C at different engine loads.This means that the heat recovery from the exhaust gas of a marine diesel engine meets the requirement to drive a membrane desalination device to produce fresh water for fishers working in small and medium-sized fishing vessels.

Effect of exhaust gas recirculation and intake pre-heating on performance and emission characteristics of dual fuel engines at part loads

Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.

Key CO_(2)capture technology of pure oxygen exhaust gas combustion for syngas-fueled high-temperature fuel cells

Integrated gasification fuel cells(IGFCs)integrating high-temperature solid oxide fuel cell technology with CO_(2)capture processes represents highly-efficient power systems with negligible CO_(2)emissions.Flame burning with pure oxygen is an ideal method for fuel cell exhaust gas treatment,and this report describes experimental and numerical studies regarding an oxy-combustor for treating the exhaust gas of a 10 kW IGFC system anode.The applied simulation method was verified based on experiments,and the key performance indices of the combustor were studied under various conditions.It was determined that 315 K was the ideal condensation temperature to obtain flame stability.Under these pure oxygen flame burning conditions,CO was almost completely converted,and the dry mole fraction of CO_(2)after burning was C 0.958 when there was up to 5%excess O_(2).Overall,5%excess O_(2)was recommended to maximize CO_(2)capture and promote other environmental considerations.Additionally,the optimal tangential fuel jet angle to control the liner temperature was approximately 25°.The total fuel utilization had to be high enough to maintain the oxygen flame temperature of the anode exhaust gas below 1800 K to ensure that the system was environmentally friendly.The results presented herein have great value for designing IGFCs coupled with CO_(2)capture systems.

CeO_2-ZrO_2-La_2O_3-Al_2O_3 composite oxide and its supported palladium catalyst for the treatment of exhaust of natural gas engined vehicles

Composite supports CeO2-ZrO2-Al2O3（CZA） and CeO2-ZrO2-Al2O3-La2O3（CZALa） were prepared by co-precipitation method. Palladium catalysts were prepared by impregnation and their purification ability for CH4, CO and NOx in the mixture gas simulated the exhaust from natural gas vehicles （NGVs） operated under stoichiometric condition was investigated. The effect of La2O3 on the physicochemical properties of supports and catalysts was characterized by various techniques. The characterizations with X-ray diffraction （XRD） and Raman spectroscopy revealed that the doping of La2O3 restrained effectively the sintering of crystallite particles, maintained the crystallite particles in nanoscale and stabilized the crystal phase after calcination at 1000 ℃. The results of N2-adsorption, H2-temperatnre-programmed reduction （H2-TPR） and oxygen storage capacity （OSC） measurements indicated that La2O3 improved the textural properties, reducibility and OSC of composite supports. Activity testing results showed that the catalysts exhibit excellent activities for the simultaneous removal of methane, CO and NOx in the simulated exhaust gas. The catalysts supported on CZALa showed remarkable thermal stability and catalytic activity for the three pollutants, especially for NOx. The prepared palladium catalysts have high ability to remove NOx, CH4 and CO, and they can be used as excellent catalysts for the purification of exhaust from NGVs operated under stoichiometric condition. The catalysts reported in this work also have significant potential in industrial application because of their high performance and low cost.

Quantitative analysis and time-resolved characterization of simulated tokamak exhaust gas by laser-induced breakdown spectroscopy

Tokamak exhaust is an important part of the deuterium-tritium fuel cycle system in fusion reactions.In this work,we present a laser-induced breakdown spectroscopy(LIBS)-based method to monitor the gas compositions from the exhaust system in the tokamak device.Helium(He),a main impurity in the exhaust gas,was mixed with hydrogen(H_(2))in different ratios through a self-designed gas distribution system,and sealed into a measurement chamber as a standard specimen.A 532 nm wavelength laser pulse with an output power of 100 mJ was used for plasma excitation.The time-resolved LIBS is used to study the time evolution characteristics of the signal strength,signal-to-background ratio(SBR),signal-to-noise ratio(SNR)and relative standard deviation(RSD)of the helium and hydrogen characteristic lines.The Boltzmann twoline method was employed to estimate the plasma temperature of laser-induced plasma(LIP).The Stark-broadened profile of He I 587.56 nm was exploited to measure the electron density.From these studies,an appropriate time was determined in which the low RSD%was consistent with the high signal-to-noise ratio.The He I 587.56 nm and Hαemission lines with good signalto-noise ratio were extracted from the spectrum and used in the external standard method and internal standard method for quantitative analysis.The test results for mixed gas showed that the average relative error of prediction was less than 11.15%,demonstrating the great potential of LIBS in detecting impurities in plasma exhaust gas.

Design and optimization of exhaust gas aftertreatment system for a heavy-duty diesel engine

Diesel engines meeting the latest emission regulations must be equipped with exhaust gas aftertreatment system,including diesel oxidation catalysts(DOC),diesel particulate filters(DPF),and selective catalytic reduction(SCR).However,before the final integration of the aftertreatment system(DOC+DPF+SCR)and the diesel engine,a reasonable structural optimization of the catalytic converters and a large number of bench calibration tests must be completed,involving large costs and long development cycles.The design and optimization of the exhaust gas aftertreatment system for a heavy-duty diesel engine was proposed in this paper.Firstly,one-dimensional(1D)and threedimensional(3D)computational models of the exhaust gas aftertreatment system accounting for the structural parameters of the catalytic converters were established.Then based on the calibrated models,the effects of the converter’s structural parameters on their main performance indicators,including the conversion of various exhaust pollutants and the temperatures and pressure drops of the converters,were studied.Finally,the optimal design scheme was obtained.The temperature distribution of the solid substrates and pressure distributions of the catalytic converters were studied based on the 3D model.The method proposed in this paper has guiding significance for the optimization of diesel engine aftertreatment systems.

Combustion and emission characteristics of diesel/n-butanol blends with split-injection and exhaust gas recirculation stratification

Oxygen fuels have broad application prospects and great potential for realizing efficient and clean combustion,and hence this study applies diesel/n-butanol blends to explore the influence of split-injection strategy on combustion and emission characteristics.Simultaneously,changing the way of exhaust gas recirculation(EGR)gas introduction forms uneven in-cylinder components distribution,and utilizing EGR stratification optimizes the combustion process and allows better emission results.The results show that the split-injection strategy can reduce the NO_(x)emissions and keep smoke opacity low compared with the single injection,but the rise in accumulation mode particles is noticeable.NO_(x)emissions show an upward trend as the injection interval expands,while soot emissions are significantly reduced.The increase in pre-injection proportion causes the apparent low-temperature heat release,and the two-stage heat release can be observed during the process of main combustion heat release.More pre-injection mass makes NO_(x)gradually increase,but smoke opacity reaches the lowest point at 15%pre-injection proportion.EGR stratification can optimize the emission results under the split injection strategy,especially the considerable suppression of accumulation mode particulate emissions.Above all,fuel stratification coupled with EGR stratification is beneficial for further realizing the in-cylinder purification of pollutants.

Collaborative optimization of exhaust gas recirculation and Miller cycle of two-stage turbocharged marine diesel engines based on particle swarm optimization

To meet increasingly stringent emission standards and lower the brake-specific fuel consumption(BSFC)of marine engines,a collaborative optimization study of exhaust gas recirculation(EGR)and a Miller cycle coupled turbocharging system was carried out.In this study,a one-dimensional numerical model of the EGR,Miller cycle,and adjustable two-stage turbocharged engine based on WeiChai 6170 marine diesel engine was established.The particle swarm optimization algorithm was used to achieve multi-input and multi-objective comprehensive optimization,and the effects of EGR-coupled Miller regulation and high-pressure turbine bypass regulation on NO_(x)and BSFC were investigated.The results showed that a medium EGR rate-coupled medium Miller degree was better for the comprehensive optimization of NO_(x)and BSFC.At medium EGR rate and low turbine bypass rates,NO_(x)and BSFC were relatively balanced and acceptable.Finally,an optimal steady-state control strategy under full loads was proposed.With an increase in loads,the optimized turbine bypass rate and Miller degree gradually increased.Compared with the EGRonly system,the optimal system of EGR and Miller cycle coupled turbine bypass reduced NO_(x)by 0.87 g/(kW·h)and BSFC by 17.19 g/(kW·h)at 100%load.Therefore,the EGR and Miller cycle coupled adjustable two-stage turbocharging achieves NO_(x)and BSFC optimization under full loads.

EFFECTS OF COOLED EXTERNAL EXHAUST GAS RECIRCULATION ON DIESEL HOMOGENEOUS CHARGE COMPRESSION IGNITION ENGINE

The effects of cooled external exhaust gas recirculation （EGR） on the combustion and emission performance of diesel fuel homogeneous charge compression ignition （HCCI） are studied. Homogeneous mixture is formed by injecting fuel in-cylinder in the negative valve overlap （NVO） period. So, the HCCI combustion which has low NOx and smoke emission is achieved. Cooled external EGR can delay the start of combustion effectively, which is very useful for high cetane fuel （diesel） HCCI, because these fuels can easily self-ignition, which makes the start of combustion more early. External EGR can avoid the knock combustion of HCCI at high load which means that the EGR can expand the high load limit. HCCI maintains low smoke emission at various EGR rate and various load compared with conventional diesel engine because there is no fuel-rich area in cylinder.

Study of modeling theory of multiphase gas distribution in exhaust process of automobile

According to experiments and the phenomena that tailpipes often have dirty particulate matter, this paper takes dynamic theory analysis as its study aim, beginning with the description method of multiphase gas distribution differential equation. According to the characteristics that exhaust gas will flow with high velocity in a tailpipe, it is supposed that gas mass that differ largely will layer when flowing with high velocity in a tailpipe. This means the exhaust gas is mixed with particulate matter, gas with large mass （CO2,HC,NOx） and gas with small mass （CO,H2O,N2,O2）. The interface of two phase fluid will be become clearer as it flows in the pipe for a long distance. The fluid continuous equation between gas phase and solid phase and the mathematical relationship between the geometry parameter and the flowing are established by a multiphase gas flowing theory. Analyzing the interface and state of layers will provide a basic theory for developing a catalytic converter with high efficiency.

Optimization of Gas Turbine Exhaust Volute Flow Loss

The exhaust volute is a device that can change the exhaust direction of the ship’s gas turbine to reduce the flow loss of the high-temperature and high-speed turbine exhaust gas in the box-type exhaust volute,thereby improving its power output performance.This paper first investigates the internal flow field characteristics of the exhaust volute via numerical simulation and reveals the main source of the internal resistance loss of the volute.On the premise of not affecting the installation size of the volute and matching it with other components in the cabin,the design scheme of volute bottom shunt and volute chamfer are then optimized in accordance with the flow characteristics inside the volute.Numerical simulation results show that the partial flow structure at the bottom of the volute can effectively improve the low-velocity region and the vortex flow at the bottom of the volute,and the chamfered angle scheme can control the regular expansion and compression of the airflow.When the volute adopts the appropriate chamfer angle and the bottom split-flow structure,the total pressure loss can be reduced by 19.6%,and the static pressure recovery coefficient can be increased by 42.05%.

Effects of Exhaust Gas Recirculation on the Homogeneous Charge Combustion Process of n-Heptane at Different Load Conditions

Effects of exhaust gas recirculation （EGR） on homogeneous charge combustion of n-heptane was studied through simulation and experiment. Experiments were carried out in a single cylinder, four-stroke, air cooled engine and a single cylinder, two-stroke, water cooled engine. In the four-stroke engine, experiments of the effects of EGR were examined using heated N2 addition as a surrogate for external EGR and modifying engine to increase internal EGR. The ignition timing was sensitive to EGR due to thermal and chemical effects. EGR or extra air is a key factor in eliminating knock during mid-load conditions. For higher load operation the only way to avoid knock is to control reaction timing through the use of spark ignition. Experimental and modeling results from the two-stroke engine show that auto-ignition can be avoided by increasing the engine speed. The two-stroke engine experiments indicate that high levels of internal EGR can enable spark ignition at lean conditions. At higher load conditions, increasing the engine speed is an effective method to control transition from homogeneous charge compression ignition （HCCI） operation to non-HCCI operation and successful spark ignition of a highly dilute mixture can avoid serious knock.

Analysis of impulse electric field effect on organic exhaust gas decomposition

The technique of organic exhaust gas decomposition with impulse corono dischrge plasma has been investigated in this study. It has been discovered that the impulse electric field affected the decomposition efficiency with the secondary electron emission coefficient (δ) of the corona electrode as an intermediary: when the impulse voltage power ( W ) was fixed the corona electrode material with higher δ could induce higher decomposition efficiency. In these experiments, wolfram electrode which has the highest δ has really induced the highest decomposition efficiency.

Study on Influence of Gasoline Sulfur Content on Performance of Vehicle Exhaust Catalytic Converter

This paper has investigated the influence of gasoline sulfur content on durability of catalytic converter for vehicle exhaust gas. Two gasoline samples with different sulfur contents (equating to 150 μg/g and 50 μg/g of sulfur, respectively) were used to examine the durability and performance of catalytic converter on the bench test. The test results have revealed that in comparison to the influence of sulfur on ageing of catalytic converter the thermal ageing had a more remarkable impact on the performance of catalytic converter, and the performance of catalytic converter could be restored by high-temperature desulfurization process after ageing by the high-sulfur gasoline sample (containing 150 μg/g of sulfur) .

Exhaust gas energy recovery system of pneumatic driving automotive engine

Almost the same quantity to net output work of energy has been carried out and wasted by exhaust gas in typical automotive engine. Recovering the energy from exhaust gas and converting to mechanical energy will dramatically increase the heat efficiency and decrease the fuel consumption. With the increasing demand of fuel conservation, exhaust gas energy recovery technologies have been a hot topic. At present, many researches have been focused on heating or cooling the cab, mechanical energy using and thermo-electronic converting. Unfortunately, the complicated transmission of mechanical energy using and the depressed efficiency of thermo-electronic converting restrict their widely applying. In this paper, a kind of exhaust gas energy recovery system of pneumatic driving automotive engine, in which highly compressed air acts as energy storing and converting carrier, has been established. Pneumatic driving motor can produce moderate speed and high torque output, which is compatible for engine using. The feasibility has been certificated by GT-Power simulation and laboratory testes. The technologies about increasing recovery efficiency have been discussed in detail. The results demonstrated that the in parallel exhaust gas energy recovery system, which is similar to the compound turbo-charger structure can recovery 8 to 10 percent of rated power output. At last, a comprehensive system, which includes Rankine cycle based power wheel cycle unit etc., has been introduced.

Retrofit of 350-MW Supercritical Boiler Based on the Analysis on Exhaust Gas Temperature

Since the first batch of 350-MW supercritical utility boilers was put into operation, the exhaust flue gas temperature of the boilers has always been higher than the designed value. The main reason is that the heat absorbed by the air heater is not sufficient. In Huaneng Dongfang Power Plant, the exhaust flue gas temperature is lowered through modifications to the economizer and the air heater. The experimental results reveal that every year, each boiler could save 3 850 tons of standard coal and reduce 85 tons of SO2 and 9 000 tons of CO2 respectively after retrofit.

Correlation of Performance, Exhaust Gas Temperature and Speed of a Spark Ignition Engine Using Kiva4

The objective of this study was to investigate performance characteristics of a spark ignition engine, particularly, the correlation between performance, exhaust gas temperature and speed, using Kiva4. Test data to validate kiva4 simulation results were conducted on a 3-cylinder, four-stroke Volkswagen (VW) Polo 6 TSI 1.2 gasoline engine. Three different tests were, therefore, carried out. In one set, variations in exhaust gas temperature were studied by varying the engine load, while keeping the engine speed constant. In another test, exhaust gas temperature variations were studied by keeping the engine at idling whilst varying the speeds. A third test involved studying variations in exhaust gas temperature under a constant load with variable engine speeds. To study variations in exhaust gas temperatures under test conditions, a basic grid/mesh generator, K3PREP, was employed to write an itape17 file comprising of a 45° asymmetrical mesh. This was based on the symmetry of the combustion chamber of the engine used in carrying out experimental tests. Simulations were therefore performed based on the input parameters established in the conducted tests. Simulations with the kiva4 code showed a significant predictability of the performance characteristics of the engine. This was evident in the appreciable agreement obtained in the simulation results when compared with the test data, under the considered test conditions. A percentage error, between experimental results and results from simulations with the kiva4 code of only between 2% to 3% was observed.

Acoustic Resonance in Exhaust Gas Economizer Tube Bundles Prediction and Suppression of Resonance

The tendency for air column resonance generation in structures with a constant volume behind a tube array like that of an exhaust gas economizer has been reported, but many points remain unclear with respect to the mechanism and conditions that generate acoustical resonance. When acoustical resonance is generated, in reality, prevention and suppression measures are implemented by inserting a baffle plate into the ducts through a process of trial and error. The purpose of this study is to clarify the mechanism of generation of acoustical resonance, and to establish an appropriate measure to prevent such resonance. Noise generated in an exhaust gas economizer was correlated with the flow inside the tube array and experimentally analyzed, and the mechanism for resonance generation was considered. In addition, the effectiveness of a baffle plate positioned in order to prevent resonance was investigated. We have successfully employed a single baffle plate to suppress resonance.

Application of Tunable Diode Laser Absorption Spectroscopy with Optical Hollow Fiber to Engine Exhaust Gas Measurement

In recent years, tighter regulation has been already enforced on harmful substances such as NOx, CO, and particles. Considering the above situation, it is important to monitor controlling factors of engine systems in order to improve efficiencies of their operations. As to car engines, an increasing concern in environmental issues such as air pollution, global warming and petroleum depletion has helped drive researches into various ways. Laser diagnostics has been applied to measure species concentration in the actual industrial fields. However there are several challenges to proceed in applying laser diagnostics to practical application. Especially stability of the measurement system is one of the most difficult issues. The purpose of this research is the development of a prompt measurement technique which can be applicable to various engine conditions. The Tunable Diode Laser Absorption Spectroscopy （TDLAS） using the hollow fiber has been developed to satisfy above requirements. By using a hollow fiber, misalignment of an optical axis and vulnerability of measurement environment such as vibration can be greatly reduced with sensitive and fast response features. It was demonstrated that this method can be applicable to measure gas compositions in engine exhaust with a range of millisecond response time. A sensitive method using tunable UV diode laser absorption spectroscopy was also discussed to detect NOx in exhausts.

Analysis of Non-Selective Catalyst Reduction Performance with Dedicated Exhaust Gas Recirculation

Rich burn industrial natural gas engines offer best in class post catalyst emissions by using a non-selective catalyst reduction aftertreatment technology. However, they operate with reduced power density when compared to lean burn engines. Dedicated exhaust gas recirculation (EGR) offers a possible pathway for rich burn engines to use non-selective catalyst reduction aftertreatment technology without sacrificing power density. In order to achieve best in class post catalyst emissions, the precious metals and washcoat of a non-selective catalyst must be designed according to the expected exhaust composition of an engine. In this work, a rich burn industrial natural gas engine operating with dedicated EGR was paired with a commercially available non-selective catalyst. At rated brake mean effective pressure (BMEP) the air-fuel ratio was swept between rich and lean conditions to compare the catalyst reduction efficiency and post catalyst emissions of rich burn and dedicated EGR combustion. It was found that due to low oxides of nitrogen (NOx) emissions across the entire air-fuel ratio range, dedicated EGR offers a much larger range of air-fuel ratios where low regulated emissions can be met. Low engine out NOx also points towards a possibility of using an oxidation catalyst rather than a non-selective catalyst for dedicated EGR applications. The location of the NOx-CO tradeoff was shifted to more rich conditions using dedicated EGR.