Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular slu...Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular sludge bed(EGSB) process. The stability of the EGSB process was firstly conducted by laboratory experiment. TA ionization was the predominated factor influencing the acid-base balance of the system. High concentration of TA in wastewater resulted in sufficient buffering capacity to neutralize the volatile fatty acids(VFA) generated from substrate degradation and provided strong base for anaerobic system to resist the pH decrease below 6.5. VFA and UFA caused almost no inhibition on the anaerobic process and biogas production except that pH was below 6.35 and VFA was at its maximum value. Along with the granulating of the activated sludge, the efficiency of organic removal and production rate of biogas increased gradually and became more stable. After start-up, the efficiency of COD removal increased to 57%—64%, pH stabilized in a range of 7.99—8.04, and production rate of biogas was relatively high and stable. Sludge granulating, suitable influent of pH and loading were responsible for the EGSB stability. The variation of VFA concentration only resulted in neglectable rebound of pH, and the inhibition from VFA could be ignored in EGSB. The EGSB reactor was stable for TPD wastewater treatment.展开更多
The influence of up-flow velocity on the working state and characteristics of the granular sludge blanket in Interior Diversion Expanded Granular Sludge Blanket（ID-EGSB）reactor for treating brewery wastewater were s...The influence of up-flow velocity on the working state and characteristics of the granular sludge blanket in Interior Diversion Expanded Granular Sludge Blanket（ID-EGSB）reactor for treating brewery wastewater were studied in this paper.The results show that the proper up-flow velocity（Vup）should be 2.1-3.3 m/h with the COD concentration of 18215-18304 mg/L,while the sludge bed reactor is inflated with expansion rate of 43.7%.When the organic loading rate reaches to 18.22-18.30 kgCOD/(m<sup>3</sup>·d<sup>-1</sup>),COD removal rate remains stabilized above 85.3%and the reactor ran without plug展开更多
Sludge granulation is considered to be the most critical parameter governing successful operation of an upflow anaerobic sludge blanket and expanded granular sludge bed （EGSB） reactors. Pre-granulated seeding sludge...Sludge granulation is considered to be the most critical parameter governing successful operation of an upflow anaerobic sludge blanket and expanded granular sludge bed （EGSB） reactors. Pre-granulated seeding sludge could greatly reduce the required startup time. Two lab-scale and a pilot-scale EGSB reactors were operated to treat Shaoxing Wastewater Treatment Plant （SWWTP） containing wastewater from real engineering printing and dyeing with high pH and sulfate concentration. The microbiological structure and the particle size distribution in aerobic excess sludge, sanitary landfill sludge digested for one year, and the granular sludge of EGSB reactor after 400 d of operation were analyzed through scanning electron microscopy （SEM） and sieves. The lab-scale EGSB reactor seeded with anaerobic sludge after digestion for one year in landfill showed obviously better total chemical oxygen demand （TCOD） removal efficiency than one seeded with aerobic excess sludge after cation polyacrylamide flocculation-concentration and dehydration. The TCOD removed was 470.8 mg/L in pilot scale EGSB reactor at short hydraulic retention time of 15 h. SEM of sludge granules showed that the microbiological structure of the sludge from different sources showed some differences. SEM demonstrated that Methanobacterium sp. was present in the granules of pilot-scale EGSB and the granular sludge produced by landfill contained a mixture of anaerobic/anoxic organisms in abundance. The particle size distribution in EGSB demonstrated that using anaerobic granular sludge produced by sanitary landfill as the seeding granular sludge was feasible.展开更多
The disposal of waste brines has become a major challenge that hinders the wide application of ion- exchange resins in the water industry in recent decades. In this study, high sulfate removal efficiency （80%-90%） w...The disposal of waste brines has become a major challenge that hinders the wide application of ion- exchange resins in the water industry in recent decades. In this study, high sulfate removal efficiency （80%-90%） was achieved at the influent sulfate concentration of 3600 mg/L and 3% NaC1 after 145 days in an expanded granular sludge bed （EGSB） reactor. Furthermore, the feasibility of treating synthetic waste brine containing high levels of sulfate and nitrate was investigated in a single EGSB reactor during an operation period of 261 days. The highest nitrate and sulfate loading rate reached 6.38 and 5.78 kg/（m3-day） at SO42--S/NO3-N mass ratio of 4/3, and the corresponding removal efficiency was 99.97% and 82.26% at 3% NaC1, respectively. Meanwhile, 454-pyrosequencing technology was used to analyze the bacterial diversity of the sludge on the 240th day for stable operation of phase X. Results showed that a total of 9194 sequences were obtained, which could be affiliated to 14 phyla, including Proteobacteria, Firmicutes, Chlorobi, Bacteroidetes, Synergistetes and so on. Proteobacteria （77.66%） was the dominant microbial population, followed by Firmicutes （12.23%） and Chlorobi （2.71%）.展开更多
An expanded granular sludge bed （EGSB） reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with c...An expanded granular sludge bed （EGSB） reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate （VLR）, liquid up-flow velocity and sludge loading rate （SLR）. Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters： liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days＇ continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property.展开更多
分析了厌氧膨胀颗粒污泥床(EGSB)反应器处理竹浆制浆废水有机物的降解过程和启动规律,并对启动过程中厌氧颗粒污泥的基础性质、形态特征和微生物相进行了探讨和表征。结果表明,在废水水质逐渐变化和废水浓度逐渐提升的过程中,EGSB反应...分析了厌氧膨胀颗粒污泥床(EGSB)反应器处理竹浆制浆废水有机物的降解过程和启动规律,并对启动过程中厌氧颗粒污泥的基础性质、形态特征和微生物相进行了探讨和表征。结果表明,在废水水质逐渐变化和废水浓度逐渐提升的过程中,EGSB反应器对竹浆制浆废水COD有良好的去除效果,启动完成后期,CODCr去除率保持在68.5%以上,出水p H值为7.8~8.0,稍高于进水,反应器容积负荷为13.50 kg CODCr/(m^3·d),且处理后竹浆制浆废水获得了更佳的可生物降解性,其BOD/COD值较原水提高了46.9%;较接种污泥,启动后期颗粒污泥总量呈减少趋势,且沿反应器高度自下而上逐渐减少,而VS/TS值,中部污泥82.4%,顶部污泥73.5%,底部污泥56.7%,接种污泥44.6%,颗粒污泥活性较大程度改善;同时,启动后期颗粒污泥Ca含量的大幅度减少,Mg、Fe、Zn等含量的增加,也对改善反应器内污泥外观、尺寸、沉降性、强度及微生物群落的构建起到一定作用。展开更多
文摘Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular sludge bed(EGSB) process. The stability of the EGSB process was firstly conducted by laboratory experiment. TA ionization was the predominated factor influencing the acid-base balance of the system. High concentration of TA in wastewater resulted in sufficient buffering capacity to neutralize the volatile fatty acids(VFA) generated from substrate degradation and provided strong base for anaerobic system to resist the pH decrease below 6.5. VFA and UFA caused almost no inhibition on the anaerobic process and biogas production except that pH was below 6.35 and VFA was at its maximum value. Along with the granulating of the activated sludge, the efficiency of organic removal and production rate of biogas increased gradually and became more stable. After start-up, the efficiency of COD removal increased to 57%—64%, pH stabilized in a range of 7.99—8.04, and production rate of biogas was relatively high and stable. Sludge granulating, suitable influent of pH and loading were responsible for the EGSB stability. The variation of VFA concentration only resulted in neglectable rebound of pH, and the inhibition from VFA could be ignored in EGSB. The EGSB reactor was stable for TPD wastewater treatment.
文摘The influence of up-flow velocity on the working state and characteristics of the granular sludge blanket in Interior Diversion Expanded Granular Sludge Blanket（ID-EGSB）reactor for treating brewery wastewater were studied in this paper.The results show that the proper up-flow velocity（Vup）should be 2.1-3.3 m/h with the COD concentration of 18215-18304 mg/L,while the sludge bed reactor is inflated with expansion rate of 43.7%.When the organic loading rate reaches to 18.22-18.30 kgCOD/(m<sup>3</sup>·d<sup>-1</sup>),COD removal rate remains stabilized above 85.3%and the reactor ran without plug
基金Project supported by the Major Scientific Key Problem Program of Scientific Commission of Zhejiang Province,China(2004C13027).
文摘Sludge granulation is considered to be the most critical parameter governing successful operation of an upflow anaerobic sludge blanket and expanded granular sludge bed （EGSB） reactors. Pre-granulated seeding sludge could greatly reduce the required startup time. Two lab-scale and a pilot-scale EGSB reactors were operated to treat Shaoxing Wastewater Treatment Plant （SWWTP） containing wastewater from real engineering printing and dyeing with high pH and sulfate concentration. The microbiological structure and the particle size distribution in aerobic excess sludge, sanitary landfill sludge digested for one year, and the granular sludge of EGSB reactor after 400 d of operation were analyzed through scanning electron microscopy （SEM） and sieves. The lab-scale EGSB reactor seeded with anaerobic sludge after digestion for one year in landfill showed obviously better total chemical oxygen demand （TCOD） removal efficiency than one seeded with aerobic excess sludge after cation polyacrylamide flocculation-concentration and dehydration. The TCOD removed was 470.8 mg/L in pilot scale EGSB reactor at short hydraulic retention time of 15 h. SEM of sludge granules showed that the microbiological structure of the sludge from different sources showed some differences. SEM demonstrated that Methanobacterium sp. was present in the granules of pilot-scale EGSB and the granular sludge produced by landfill contained a mixture of anaerobic/anoxic organisms in abundance. The particle size distribution in EGSB demonstrated that using anaerobic granular sludge produced by sanitary landfill as the seeding granular sludge was feasible.
基金supported by the National Natural Science Foundation of China(No.51178215,51378251)the Jiangsu Provincial Natural Science Foundation(No.BK2011032,BK20130575)+1 种基金the Jiangxi Provincial Natural Science Foundation(No.2010GQC0106)the State Key Laboratory of Pollution Control and Resource Reuse Foundation(No.PCRRF12006)
文摘The disposal of waste brines has become a major challenge that hinders the wide application of ion- exchange resins in the water industry in recent decades. In this study, high sulfate removal efficiency （80%-90%） was achieved at the influent sulfate concentration of 3600 mg/L and 3% NaC1 after 145 days in an expanded granular sludge bed （EGSB） reactor. Furthermore, the feasibility of treating synthetic waste brine containing high levels of sulfate and nitrate was investigated in a single EGSB reactor during an operation period of 261 days. The highest nitrate and sulfate loading rate reached 6.38 and 5.78 kg/（m3-day） at SO42--S/NO3-N mass ratio of 4/3, and the corresponding removal efficiency was 99.97% and 82.26% at 3% NaC1, respectively. Meanwhile, 454-pyrosequencing technology was used to analyze the bacterial diversity of the sludge on the 240th day for stable operation of phase X. Results showed that a total of 9194 sequences were obtained, which could be affiliated to 14 phyla, including Proteobacteria, Firmicutes, Chlorobi, Bacteroidetes, Synergistetes and so on. Proteobacteria （77.66%） was the dominant microbial population, followed by Firmicutes （12.23%） and Chlorobi （2.71%）.
基金Supported by Key Project of the Tenth Five-Year Plan of the Ministry of Science and Technology of China (02-2-2)
文摘An expanded granular sludge bed （EGSB） reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate （VLR）, liquid up-flow velocity and sludge loading rate （SLR）. Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters： liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days＇ continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property.
文摘分析了厌氧膨胀颗粒污泥床(EGSB)反应器处理竹浆制浆废水有机物的降解过程和启动规律,并对启动过程中厌氧颗粒污泥的基础性质、形态特征和微生物相进行了探讨和表征。结果表明,在废水水质逐渐变化和废水浓度逐渐提升的过程中,EGSB反应器对竹浆制浆废水COD有良好的去除效果,启动完成后期,CODCr去除率保持在68.5%以上,出水p H值为7.8~8.0,稍高于进水,反应器容积负荷为13.50 kg CODCr/(m^3·d),且处理后竹浆制浆废水获得了更佳的可生物降解性,其BOD/COD值较原水提高了46.9%;较接种污泥,启动后期颗粒污泥总量呈减少趋势,且沿反应器高度自下而上逐渐减少,而VS/TS值,中部污泥82.4%,顶部污泥73.5%,底部污泥56.7%,接种污泥44.6%,颗粒污泥活性较大程度改善;同时,启动后期颗粒污泥Ca含量的大幅度减少,Mg、Fe、Zn等含量的增加,也对改善反应器内污泥外观、尺寸、沉降性、强度及微生物群落的构建起到一定作用。
