Mix design and expansion behavior of sulpho-aluminate expansive cementitious composite

Sulpho-aluminate expansive cementitious composite is proved to be one of the most effective ways to prevent concrete cracking too soon. Mix design of sulpho-aluminate expansive cementitious composite completely depends on experience and experiments at present. This method ignores the influence of expansion behavior which hinders the application of sulpho-aluminate expansive cementitious composite. The workability,free expansion property,flexural strength and compressive strength of sulpho-aluminate expansive cementitious composite have been investigated by tests. The relationship between expansion ratio and mix design parameters such as curing age,water-cement ratio and cement abundance coefficient is deduced according to the experimental statistics. A new simplified approach to mix design of sulpho-aluminate expansive cementitious composite is proposed as a reference for construction application,which avoids experiments and experience.

Effect of thermal-cooling cycle treatment on thermal expansion behavior of particulate reinforced aluminum matrix composites

Two micron SiC particles with angular and spherical shape and the sub-micron Al2O3 particles with spherical shape were introduced to reinforce 6061 aluminium by squeeze casting technology. Microstructures and effect of thermal-cooling cycle treatment （TCCT） on the thermal expansion behaviors of three composites were investigated. The results show that the composites are free of porosity and SiC/Al2O3 particles are distributed uniformly. Inflections at about 300℃ are observed in coefficient of thermal expansion （CTE） versus temperature curves of two SiCp/Al composites, and this characteristic is not affected by TCCT. The TCCT has significant effect on thermal expansion behavior of SiCp/Al composites and CTE of them after 3 cycles is lower than that of 1 or 5 cycles. However, no inflection is observed in Al2O3p/Al composite, while TCCT has effect on CTE of Al2O3p/Al composite. These results should be due to different relaxation behavior of internal stress in three composites.

Experimental Study on the Expansion Behavior of Full Aggregate Steel Slag Concrete

To improve the utilization rate of steel slag,this paper investigates the expansion behavior of Full Aggregate Steel Slag Concrete(FASSC).Orthogonal experiment was performed to analyze the effects of sand ratio,water-cement ratio,steel slag sand content,replacement particle size of steel slag sand,coarse steel slag content,and replacement particle size of coarse steel slag on the expansion rate of FASSC.Test results demonstrated that the expansion rate of FASSC decreased with a gradual increase in the replacement particle size of steel slag sand or the coarse steel slag content.With a gradual increase in the water-cement ratio or the steel slag sand content,the expansion rate of FASSC first increased and then decreased.As the sand ratio increased,the expansion rate of FASSC first decreased and then increased.Among these,the steel slag sand content and the replacement particle size of steel slag sand significantly affected the expansion rate of FASSC.The mix proportions of SSC for self-stressing CFST and shrinkage compensating SSC were suggested according to the experimental research.Additionally,a formula for approximately predicting the expansion rate of FASSC was proposed based on the single factor weighted fitting.

The Threshold Percolation Volume Fraction of Vitreous Silica on the Thermal Expansion Behavior of Quartz

In this work, it is shown how the additions of vitreous silica of particle size ?C.

Thermal Expansion Behavior of Poly(amide-imide)Films with Ultrahigh Tensile Strength and Ultralow CTE

A series of novel poly(amide-imide)(PAl)films with different amide contents were prepared from pyromellitic dianhydride and four amide-containing diamines.These PAl films exhibited excellent mechanical and thermal properties with tensile strength of 203.7-297.4 MPa and Tg above 407℃.The rigid backbone structures combined with strong intermolecular interactions provided PAl films with ultralow in-plane CTE values from-4.17 ppm/℃to-0.39 ppm/℃in the temperature range of 30-300℃.The correlation between thermal expansion behavior and aggregation structures of PAl film was investigated.The results suggested that hydrogen bonding interactions could be maintained even at high temperature,thus resulting in good dimension reversibility of films in multiple heating-cooling cycles.It is demonstrated that dimensional stabilities of PAl films are determined by the rigidity,orientation,and packing of molecular chains.Heat-resistant PAl films with ultralow CTE can be developed as flexible substrates by regulating backbones and aggregation structures for optoelectronic application.

Effect of Aggregation Structure on Thermal Expansion Behavior of Polyimide Films with Different Thickness

Polyimide films derived from representative PMDA/ODA were prepared with thickness ranging from 5 μm to 25 μm,and the effect of aggregation structure on thermal expansion behavior along different directions was studied.Both in-plane and out-of-plane linear thermal expansion(CTEand CTE) were respectively characterized by thermal mechanical analysis and FT-near-IR interference method.Volumetric and anisotropic behavior of thermal expan sion were also investigated.With increasing film thickness,CTEgradually increased from 32.2 ppm/℃ to46.1 ppm/℃ while CTEdecreased from 149.7 ppm/℃ to 128.2 ppm/℃.Volumetric thermal expansion of polyimide films was less sensitive to the va ried thickness,but anisotropy of thermal expansion was reduced.Polyimide film of 5 μm thickness showed large birefringence,indicating more considerable in-plane chain orientation anisotropy.Besides,molecular chains were more densely packed along in-plane direction when film thickness increased,while became loosely stacked in the out-of-plane direction.In contrast to the enhanced lateral chain packing for thicker film s,higher vertical chain packing order was found in thinner films.The variation of aggregation structure during thermal expansion procedure was analyzed by temperature-dependent WAXD.It is proved that thermal expansion behavior of thinner films could be largely attributed to molecular chain packing,whereas that may be influenced by many factors for thicker films in addition to the effect of chain packing.The results revealed that thermal expansion of films with thickness variation is closely related to molecular chain orientation and packing,which is associated with both chemistry and morphological structure of polyimide.

Effects of B addition on glass forming ability and thermal behavior of FePC-based bulk metallic glasses

The FePC-based bulk metallic glasses（BMGs）have been demonstrated to possess high plasticity and good soft magnetic properties.However,the relatively poor glass forming ability（GFA）and thermal stabilities limited their application in industries.The effects of microalloying with B in FePC-based BMGs on the GFA and thermal behaviors were systematically investigated.It was found that a small amount of B addition can dramatically enhance the GFA of FePC-based BMGs,which in turn leads to the critical maximum diameter up to 2 mm for full glass formation even using low cost raw materials.The underlying mechanism of the enhancement of GFA from the competing crystalline phase with amorphous phase,the average thermal expansion coefficient and dynamic viscosity were discussed in detail.

Bed expansion behavior and sensitivity analysis for super-high-rate anaerobic bioreactor

Bed expansion behavior and sensitivity analysis for super-high-rate anaerobic bioreactor （SAB） were performed based on bed expansion ratio （E）, maximum bed sludge content （Vpmax）, and maximum bed contact time between sludge and liquid （Tmax）. Bed expansion behavior models were established under bed unfluidization, fluidization, and transportation states. Under unfluidization state, Ewas 0, Vprnax was 4867 ml, and rmax was 844-3800 s. Under fluidization state, E, Vpmax, and Tmax were 5.28%-255.69%, 1368-4559 ml, and 104-732 s, respectively. Under transportation state, washout of granular sludge occurred and destabilized the SAB. During stable running of SAB under fluidization state, E correlated positively with superficial gas and liquid velocities （Ug and ul）, while Vpmax and Tmax correlated negatively. For E and Vpmax, the sensitivities of ug and ul were close to each other, while for Tmax, the sensitivity of ur was greater than that of Ug. The prediction from these models was a close match to the experimental data.

Influence of Re on the Properties of a NiCoCrAlY Coating Alloy

MCrAIY can serve as stand-alone overlay coatings or bond coats in thermal barrier coating systems, and its properties play a vital role in determining the performance of these coating systems. In order to further understand the behavior of MCrAIY coatings, several NiCoCrAIY model alloys with different levels of Re （0.3 wt%, O wt%, and 9 wt%） were investigated. Microstructural observation showed the addition of Re promoted the precipitation of Cr-rich phases, such as α-Cr and σ. The presence of α-Cr lowered the coefficient of thermal expansion （CTE） of the coating alloys, which could reduce the CTE mismatch at the scale-metal interface. The solid solution strengthening effect of Re is responsible for an increase in Rockwell hardness of the coating alloys. But the isothermal oxidation resistance at 1100℃ was deteriorated due to the precipitation of brittle α-Cr phase, a phase of inferior oxidation resistance compared with β-NiAI and γ-Ni.

Superelasticity and Tunable Thermal Expansion across a Wide Temperature Range

Materials that undergo a reversible change of crystal structure through martensitic transformation （MT） possess unusual functionalities including shape memory, superelasticity, and low/negative thermal ex- pansion. These properties have many advanced applications, such as actuators, sensors, and energy conversion, but are limited typically in a narrow temperature range of tens of Kelvin. Here we report that, by creating a nano-scale concentration modulation via phase separation, the MT can be rendered continuous by an in-situ elastic confinement mechanism. Through a model titanium alloy, we demon- strate that the elastically confined continuous MT has unprecedented properties, such as superelasticity from below 4.2 K to 500 K, fully tunable and stable thermal expansion, from positive, through zero, to negative, from below 4.2 K to 573 K, and high strength-to-modulus ratio across a wide temperature range. The elastic tuning on the MT, together with a significant extension of the crystal stability limit, provides new opportunities to explore advanced materials.

Promoted application potential of p-type Mg_(3)Sb_(1.5)Bi_(0.5)for thematched thermal expansion with its n-type counterpart

Recently,n-type Mg3Sb1.5Bi0.5-based thermoelectric materials have attracted considerable attention for their extraordinary thermoelectric performance.Ideally,thermoelectric generators should be made of the same material system to avoid thermal mismatch in the practical application.In this work,p-type Mg3Sb1.5Bi0.5 which has almost the same composition as the state-of-the-art n-type Mg3.2Sb1.5Bi0.49-Te0.01Mn0.01 was synthesized by ball milling and spark plasma sintering,and then Na was chosen as an acceptor dopant to optimize the carrier concentration and further improve the thermoelectric performance.Na0.0075Mg2.9925Sb1.5Bi0.5 sample gets the highest ZT of~0.5 at 773 K.While Na0.005Mg2.995Sb1.5Bi0.5 sample shows the highest average ZT of~0.29 in the temperature range of 300 e773 K and matched thermal expansion behavior with the state-of-the-art n-type Mg3.2Sb1.5Bi0.49-Te0.01Mn0.01,which is of great significance for practical applications.Taking the Joule and Thompson heat into account,a high theoretical conversion efficiency(η)of~9.5%was calculated for the thermoelectric module consists of the present p-type Na0.005Mg2.995Sb1.5Bi0.5 and the state-of-the-art n-type Mg3.2Sb1.5Bi0.49Te0.01Mn0.01 with the leg length of 2 mm,and cold and hot side temperature of 300 K and 773 K,respectively,which shows a good potential for the use of this class of materials in the midtemperature power generation applications.