Extending Structures for Gel'fand-Dorfman Bialgebras

Gel'fand-Dorfman bialgebra,which is both a Lie algebra and a Novikov algebra with some compatibility condition,appeared in the study of Hamiltonian pairs in completely integrable systems.They also emerged in the description of a class special Lie conformal algebras called quadratic Lie conformal algebras.In this paper,we investigate the extending structures problem for Gel'fand-Dorfman bialgebras,which is equivalent to some extending structures problem of quadratic Lie conformal algebras.Explicitly,given a Gel'fand-Dorfman bialgebra(A,o,[.,.]),this problem is how to describe and classify all Gel'fand-Dorfman bialgebra structures on a vector space E(A⊂E)such that(A,o,[.,.])is a subalgebra of E up to an isomorphism whose restriction on A is the identity map.Motivated by the theories of extending structures for Lie algebras and Novikov algebras,we construct an object gH2(V,A)to answer the extending structures problem by introducing the notion of a unified product for Gel'fand-Dorfman bialgebras,where V is a complement of A in E.In particular,we investigate the special case when dim(V)=1 in detail.

Trust-region based instantaneous optimal semi-active control of long-span spatially extended structures with MRF-04K damper

In the field of civil engineering, magnetorheological fluid （MRF） damper-based semi-active control systems have received considerable attention for use in protecting structures from natural hazards such as strong earthquakes and high winds. In this paper, the MRF damper-based semi-active control system is applied to a long-span spatially extended structure and its feasibility is discussed. Meanwhile, a _trust-region method based instantaneous optimal semi-active control algorithm （TIOC） is proposed to improve the performance of the semi-active control system in a multiple damper situation. The proposed TIOC describes the control process as a bounded constraint optimization problem, in which an optimal semi- active control force vector is solved by the trust-region method in every control step to minimize the structural responses. A numerical example of a railway station roof structure installed with MRF-04K dampers is presented. First, a modified Bouc- Wen model is utilized to describe the behavior of the selected MRF-04K damper. Then, two semi-active control systems, including the well-known clipped-optimal controller and the proposed TIOC controller, are considered. Based on the characteristics of the long-span spatially extended structure, the performance of the control system is evaluated under uniform earthquake excitation and travelling-wave excitation with different apparent velocities. The simulation results indicate that the MR fluid damper-based semi-active control systems have the potential to mitigate the responses of full-scale long-span spatially extended structures under earthquake hazards. The superiority of the proposed TIOC controller is demonstrated by comparing its control effectiveness with the clipped-optimal controller for several different cases.

A new extended structural compound based on saturated Wells-Dawson polyoxoanions

A new 3D extended structural compound, （dpdo）2H2{[Cu（2,2＇-bipy）212（P2W18O62）}.SH2O 1 （dpdo = 4,4＇-bipyridine-N,N＇- dioxide; 2,2＇-bipy = 2,2＇-bipyridine）, has been hydrothermally synthesized and characterized by elemental analyses, IR, TG analyses, cyclic voltammetry, and single-crystal X-my diffraction. Compound 1 is built up of [P2WlsO62]6- cluster as the structural motif covalently linked by [Cu（2,2＇-bipy）2]^2＋ coordination complexes to yield the 1D chains, which axe further in close contact forming a 3D supramolecular framework via aromatic π-π stacking interactions and extensive hydrogen-bonding interactions among polyoxoanions, coordinated 2,2＇-bipy organic ligands, free dpdo organic molecules and lattice water molecules.

An extended improved global structure model for influential node identification in complex networks

Accurate identification of influential nodes facilitates the control of rumor propagation and interrupts the spread of computer viruses.Many classical approaches have been proposed by researchers regarding different aspects.To explore the impact of location information in depth,this paper proposes an improved global structure model to characterize the influence of nodes.The method considers both the node’s self-information and the role of the location information of neighboring nodes.First,degree centrality of each node is calculated,and then degree value of each node is used to represent self-influence,and degree values of the neighbor layer nodes are divided by the power of the path length,which is path attenuation used to represent global influence.Finally,an extended improved global structure model that considers the nearest neighbor information after combining self-influence and global influence is proposed to identify influential nodes.In this paper,the propagation process of a real network is obtained by simulation with the SIR model,and the effectiveness of the proposed method is verified from two aspects of discrimination and accuracy.The experimental results show that the proposed method is more accurate in identifying influential nodes than other comparative methods with multiple networks.

Fracture Behavior of Epoxy Asphalt Pavement on Steel Bridges based on Optical Fiber Sensing Technology and Numerical Simulation

The distributed optical fiber sensing technology was used to investigate the fracture behavior of the Epoxy Asphalt Mixture. The spatial distribution and variation of the strain development with crack propagation were acquired using the brillouin optical time-domain reflectometer through the loading experiments of the composite beam structure. In addition, a finite element model of the composite beam structure was developed to analyze the mechanical responses of the epoxy asphalt mixture using the extended finite element method. The experimental results show that the development of crack propagation becomes instable with the increase of the load, and larger loads will generate deeper cracks. Moreover, the numerical results show that the mechanical response of the crack tip changes with the crack propagation, and the worst areas that subjected to crack damage are located on both sides of the composite beam structure.

Structure and chemical valence study of Sr_(n+1)Ru_nO_(3n+1)(n= 1, 2, ∞) series

Effect of structure parameter n and its coupling with the connection mode among RuO6 octahedra of Srn＋1RUnO3n＋1 （n = 1, 2, ∞） are investigated. The gradually enhanced rotation and tilting effect with increasing n are observed in Srn＋1RUnO3n＋1. Besides, the chemical valence of Ru is not changed, while the one of Sr gradually varies with increasing n, which highlights the great contribution of connection mode to the chemical environment. Our results show a strong n dependence on the connection mode between octahedra in Srn＋1RUnO3n＋1 （n = 1, 2, ∞）.

Extended X-ray absorption fine structure (EXAFS) of FAPbI_(3) for understanding local structure-stability relation in perovskite solar cells

Perovskite solar cells (PSCs) employing formamidinium lead iodide (FAPbI_(3)) have shown high efficiency.However,operational stability has been issued due to phase instability of α phase FAPbI_(3) at ambient temperature.Excess precursors in the perovskite precursor solution has been proposed to improve not only power conversion efficiency (PCE) but also device stability.Nevertheless,there is a controversial issue on the beneficial effect on PCE and/or stability between excess FAI and excess PbI_(2).We report here extended X-ray absorption fine structure (EXAFS) of FAPbI_(3) to study local structural change and explain the effect of excess precursors on photovoltaic performance and stability.Perovskite films prepared from the precursor solution with excess PbI_(2)shows better stability than those from the one with excess FAI,despite similar PCE.A rapid phase transition from α phase to non-perovskite δ phase is observed from the perovskite film formed by excess FAI.Furthermore,the (Pb-I) bond distance evaluated by the Pb L_(III)-edge EXAFS study is increased by excess FAI,which is responsible for the phase transition and poor device stability.This work can provide important insight into local structure-stability relation in the FAPbI_(3)-based PSCs.

Anomalies in the short-range local environment and atomic diffusion in single crystalline equiatomic CrMnFeCoNi highentropy alloy

Multi-edge extended X-ray absorption fine structure(EXAFS)spectroscopy combined with reverse Monte Carlo(RMC)simulations was used to probe the details of element-specific local coordinations and component-dependent structure relaxations in single crystalline equiatomic CrMnFeCoNi high-entropy alloy as a function of the annealing temperature.Two representative states,namely a high-temperature state,created by annealing at 1373 K,and a low-temperature state,produced by long-term annealing at 993 K,were compared in detail.Specific features identified in atomic configurations of particular principal components indicate variations in the local environment distortions connected to different degrees of compositional disorder at the chosen representative temperatures.The detected changes provide new atomistic insights and correlate with the existence of kinks previously observed in the Arrhenius dependencies of component diffusion rates in the CrMnFeCoNi high-entropy alloy.

Research Article Local structure and magnetic properties of a nanocrystalline Mnrich Cantor alloy thin film down to the atomic scale

The huge atomic heterogeneity of high-entropy materials along with a possibility to unravel the behavior of individual components at the atomic scale suggests a great promise in designing new compositionally complex systems with the desired multifunctionality.Herein,we apply multi-edge X-ray absorption spectroscopy(extended X-ray absorption fine structure(EXAFS),Xray absorption near edge structure(XANES),and X-ray magnetic circular dichroism(XMCD))to probe the structural,electronic,and magnetic properties of all individual constituents in the single-phase face-centered cubic(fcc)-structured nanocrystalline thin film of Cr_(20)Mn_(26)Fe_(18)Co_(19)Ni_(17)(at.%)high-entropy alloy on the local scale.The local crystallographic ordering and componentdependent lattice displacements were explored within the reverse Monte Carlo approach applied to EXAFS spectra collected at the K absorption edges of several constituents at room temperature.A homogeneous short-range fcc atomic environment around the absorbers of each type with very similar statistically averaged interatomic distances(2.54-2.55Å)to their nearest-neighbors and enlarged structural relaxations of Cr atoms were revealed.XANES and XMCD spectra collected at the L2,3 absorption edges of all principal components at low temperature from the oxidized and in situ cleaned surfaces were used to probe the oxidation states,the changes in the electronic structure,and magnetic behavior of all constituents at the surface and in the sub-surface volume of the film.The spin and orbital magnetic moments of Fe,Co,and Ni components were quantitatively evaluated.The presence of magnetic phase transitions and the co-existence of different magnetic phases were uncovered by conventional magnetometry in a broad temperature range.

Pd-Ni-P非晶合金多形性转变的成分依赖性

非晶合金复杂的化学成分特征为理解多形性转变带来了巨大挑战.在本文中,我们系统研究了(PdNi)_(100−x)P_(x)(15 at%<x<21 at%)非晶合金中加热诱导多形性转变的化学成分依赖性.差热分析与结构因子的演化规律表明重入型玻璃转变会随着P含量的增加(不超过17 at%)而逐渐被抑制,扩展X射线吸收精细结构分析拟合后的结构参数与原位升温同步辐射结果显示重入型玻璃转变的成分依赖性来源于金属–类金属键对(即Pd/Ni–P对)的成键能力差异以及由此导致的短程至中程有序化转变.这种成分依赖性可以导致重入型液-液转变和玻璃转变在Pd_(41.5)Ni_(41.5)P_(17)非晶合金中均可发生.本研究有助于加深对重入型玻璃转变原子机制的认识,同时澄清了对于Pd–Ni–P非晶合金体系中多形性转变结构起源的困惑.

HIGH SPEED INJECTION MOLDING OF HIGH DENSITY POLYETHYLENE—EFFECTS OF INJECTION SPEED ON STRUCTURE AND PROPERTIES

Thin wall samples of high density polyethylene （HDPE） were prepared via injection molding with different injection speeds ranging from 100 mm/s to 1200 mm/s. A significant decrease in the tensile strength and Young＇s modulus was observed with increasing injection speed. In order to investigate the mechanism behind this decrease, the orientation, molecular weight, molecular weight distribution, melt flow rate, crystallinity and crystal morphology of HDPE were characterized using two-dimensional wide-angle X-ray diffraction （2D-WAXD）, gel permeation chromatography （GPC）, capillary rheometry and differential scanning calorimetry （DSC）, respectively. It is demonstrated that the orientation, molecular weight, molecular weight distribution, melt flow rate and crystallinity have no obvious change with increasing injection speed. Nevertheless, the content of extended chain crystals or large folded chain crystals was found to decrease with increasing injection speed. Therefore, it is concluded that the decrease in tensile properties is mainly contributed by the reduced content of extended chain crystals or large folded chain crystals. This study provides industry with valuable information for the application of high speed injection molding.

Adsorption of Eu(Ⅲ) on titanate nanotubes studied by a combination of batch and EXAFS technique

The effects of pH,contact time and natural organic ligands on radionuclide Eu(Ⅲ) adsorption and mechanism on titanate nanotubes(TNTs) are studied by a combination of batch and extended X-ray absorption fine structure(EXAFS) techniques.Macroscopic measurements show that the adsorption is ionic strength dependent at pH < 6.0,but ionic strength independent at pH > 6.0.The presence of humic acid(HA) /fulvic acid(FA) increases Eu(Ⅲ) adsorption on TNTs at low pH,but reduces Eu(Ⅲ) adsorption at high pH.The results of EXAFS analysis indicate that Eu(Ⅲ) adsorption on TNTs is dominated by outer-sphere surface complexation at pH < 6.0,whereas by inner-sphere surface complexation at pH > 6.0.At pH < 6.0,Eu(Ⅲ) consists of ～ 9 O atoms at REu?O ≈ 2.40 in the first coordination sphere,and a decrease in NEu-O with increasing pH indicates the introduction of more asymmetry in the first sphere of adsorbed Eu(Ⅲ).At long contact time or high pH values,the Eu(Ⅲ) consists of ～2 Eu at REu-Eu ≈ 3.60 and ～ 1 Ti at REu-Ti ≈ 4.40 ,indicating the formation of inner-sphere surface complexation,surface precipitation or surface polymers.Surface adsorbed HA/FA on TNTs modifies the species of adsorbed Eu(Ⅲ) as well as the local atomic structures of adsorbed Eu(Ⅲ) on HA/FA-TNT hybrids.Adsorbed Eu(Ⅲ) on HA/FA-TNT hybrids forms both ligand-bridging ternary surface complexes(Eu-HA/FA-TNTs) as well as surface complexes in which Eu(Ⅲ) remains directly bound to TNT surface hydroxyl groups(i.e.,binary Eu-TNTs or Eu-bridging ternary surface complexes(HA/FA-Eu-TNTs)).The findings in this work are important to describe Eu(Ⅲ) interaction with nanomaterials at molecular level and will help to improve the understanding of Eu(Ⅲ) physicochemical behavior in the natural environment.

Study of local environment of Cu atoms in Fe_(73.5)Cu_1Nb_3Si_(13.5)B_9 alloy with different annealing temperature

The local environment of Cu atoms in Fe73.5Cu1Nb3Si13.5B9 alloy was investigated by extended X-ray absorption fine structure(EXAFS).Cu clusters began to order when the annealing temperature was around 733 K from the results of the Fourier transform curves.The fitting results showed that the first shell of the near fcc(face-centered cubic)Cu clusters only contained Cu atoms.The coordination number increased with the annealing temperature.Subsequently,the occupancy rate increased from 33.3%(annealed at 733 K)to 100% (annealed at 853 K).This local structural change of Cu atoms could probably affect the distribution of the bcc(body-centered cubic)α-Fe in Fe73.5Cu1Nb3Si13.5B9 alloy.

Al-driven peculiarities of local coordination and magnetic properties in single-phase Al_(x)-CrFeCoNi high-entropy alloys

Modern design of superior multi-functional alloys composed of several principal components requires in-depth studies of their local structure for developing desired macroscopic properties.Herein,peculiarities of atomic arrangements on the local scale and electronic states of constituent elements in the single-phase face-centered cubic(fcc)-and body-centered cubic(bcc)-structured high-entropy Alx-CrFeCoNi alloys(x=0.3 and 3,respectively)are explored by element-specific X-ray absorption spectroscopy in hard and soft X-ray energy ranges.Simulations based on the reverse Monte Carlo approach allow to perform a simultaneous fit of extended X-ray absorption fine structure spectra recorded at K absorption edges of each 3d constituent and to reconstruct the local environment within the first coordination shells of absorbers with high precision.The revealed unimodal and bimodal distributions of all five elements are in agreement with structure-dependent magnetic properties of studied alloys probed by magnetometry.A degree of surface atoms oxidation uncovered by soft X-rays suggests different kinetics of oxide formation for each type of constituents and has to be taken into account.X-ray magnetic circular dichroism technique employed at L2,3 absorption edges of transition metals demonstrates reduced magnetic moments of 3d metal constituents in the sub-surface region of in situ cleaned fcc-structured Al0.3-CrFeCoNi compared to their bulk values.Extended to nanostructured versions of multicomponent alloys,such studies would bring new insights related to effects of high entropy mixing on low dimensions.

A cost driven predictive maintenance policy for structural airframe maintenance

Airframe maintenance is traditionally performed at scheduled maintenance stops.The decision to repair a fuselage panel is based on a fixed crack size threshold,which allows to ensure the aircraft safety until the next scheduled maintenance stop.With progress in sensor technology and data processing techniques,structural health monitoring（SHM） systems are increasingly being considered in the aviation industry.SHM systems track the aircraft health state continuously,leading to the possibility of planning maintenance based on an actual state of aircraft rather than on a fixed schedule.This paper builds upon a model-based prognostics framework that the authors developed in their previous work,which couples the Extended Kalman filter（EKF） with a firstorder perturbation（FOP） method.By using the information given by this prognostics method,a novel cost driven predictive maintenance（CDPM） policy is proposed,which ensures the aircraft safety while minimizing the maintenance cost.The proposed policy is formally derived based on the trade-off between probabilities of occurrence of scheduled and unscheduled maintenance.A numerical case study simulating the maintenance process of an entire fleet of aircrafts is implemented.Under the condition of assuring the same safety level,the CDPM is compared in terms of cost with two other maintenance policies：scheduled maintenance and threshold based SHM maintenance.The comparison results show CDPM could lead to significant cost savings.

β-Nickel hydroxide cathode material for nano-suspension redox flow batteries

As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni（OH）2 nanoparticles as the cathode material, nano-sized β-Ni（OH）2 particles with well-controlled particle size and morphology were synthesized via the one-step precipitation of a NiCl2 precursor. The composition and morphology of the nanoparticles were characterized by scanning electronic microscopy （SEM） and X-ray diffraction （XRD）. The XRD patterns confirmed that β-Ni（OH）2 was successfully synthesized, while SEM results showed that the particle sizes range from 70 to 150 nm. To ensure that Ni（OH）2 could be employed in the nano-suspension flow battery, the electrochemical performance of the synthesized 13-Ni（OH）2 was initially tested in pouch cells through charge/discharge cycling. The phase transformations occurring during charge/discharge were investigated using in-situ X-ray absorption spectroscopy to obtain the shift in the oxidation state of Ni （X-ray adsorption near edge structure, XANES） and the distances between Ni and surrounding atoms in charged and discharged states （extended X-ray absorption fine structure, EXAFS）. XANES results indicated that the electrode in the discharged state was a mixture of phases because the edge position did not shift back completely. XAFS results further proved that the discharge capacity was provided by β-NiOOH and the ratio between β-Ni（OH）2 and γ-NiOOH in the electrode in the discharged state was 71：29. Preliminary nano-suspension tests in a lab-scale cell were conducted to understand the behavior of the nano-suspension during charge/discharge cycling and to optimize the operating conditions.