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Disasters of gas-coal spontaneous combustion in goaf of steeply inclined extra-thick coal seams 被引量:1
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作者 Qiming Zhang Enyuan Wang +2 位作者 Xiaojun Feng Shuxin Liu Dong Chen 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第10期4141-4153,共13页
In light of the escalating global energy imperatives,mining of challenging-to-access resources,such as steeply inclined extra-thick coal seams(SIEC),has emerged as one of the future trends within the domain of energy ... In light of the escalating global energy imperatives,mining of challenging-to-access resources,such as steeply inclined extra-thick coal seams(SIEC),has emerged as one of the future trends within the domain of energy advancement.However,there is a risk of gas and coal spontaneous combustion coupling disasters(GCC)within the goaf of SIEC due to the complex goaf structure engendered by the unique mining methodologies of SIEC.To ensure that SIEC is mined safely and efficiently,this study conducts research on the GCC within the goaf of SIEC using field observation,theoretical analysis,and numerical modeling.The results demonstrate that the dip angle,the structural dimensions in terms of width-to-length ratio,and compressive strength of the overlying rock are the key factors contributing to the goaf instability of SIEC.The gangue was asymmetrically filled,primarily accumulating within the central and lower portions of the goaf,and the filling height increased proportionally with the advancing caving height,the expansion coefficient,and the thickness of the surrounding rock formation.The GCC occurs in the goaf of SIEC,with an air-return side range of 41 m and an air-intake side range of 14 m,at the intersection area of the“<”-shaped oxygen concentration distribution(coal spontaneous combustion)and the“>”-shaped gas concentration distribution(gas explosion).The optimal nitrogen flow rate is 1000 m3/h with an injection port situated 25 m away from the working face for the highest nitrogen diffusion efficacy and lowest risk of gas explosion,coal spontaneous combustion,and GCC.It has significant engineering applications for ensuring the safe mining of SIEC threatened by the GCC. 展开更多
关键词 Steeply inclined extra-thick coal seams Gas explosion coal spontaneous combustion Coupling disaster Numerical simulation
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Analysis of the Risk of Water Breakout in the Bottom Plate of High-Intensity Mining of Extra-Thick Coal Seams
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作者 Shuo Wang Hongdong Kang Xinchen Wang 《Journal of Geoscience and Environment Protection》 2024年第5期81-91,共11页
In order to clarify the danger of water breakout in the bottom plate of extra-thick coal seam mining, 2202 working face of a mine in the west is taken as the research object, and it is proposed to use the on-site moni... In order to clarify the danger of water breakout in the bottom plate of extra-thick coal seam mining, 2202 working face of a mine in the west is taken as the research object, and it is proposed to use the on-site monitoring means combining borehole peeping and microseismic monitoring, combined with the theoretical analysis to analyze the danger of water breakout in the bottom plate. The results show that: 1) the theoretically calculated maximum damage depth of the bottom plate is 27.5 m, and its layer is located above the Austrian ash aquifer, which has the danger of water breakout;2) the drill hole peeping at the bottom plate of the working face shows that the depth of the bottom plate fissure development reaches 26 m, and the integrity of the water barrier layer has been damaged, so there is the risk of water breakout;3) for the microseismic monitoring of the anomalous area, the bottom plate of the return air downstream channel occurs in the field with a one-week lag, which shows that microseismic monitoring events may reflect the water breakout of the underground. This shows that the microseismic monitoring events can reflect the changes of the underground flow field, which can provide a reference basis for the early warning of water breakout. The research results can provide reference for the prediction of sudden water hazard. 展开更多
关键词 extra-thick coal Seam High-Intensity Mining Microseismic Monitoring Water-Surge Hazard Borehole Peeping
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Stability analysis of longwall top-coal caving face in extra-thick coal seams based on an innovative numerical hydraulic support model 被引量:1
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作者 Jun Guo Wenbo Huang +7 位作者 Guorui Feng Jinwen Bai Lirong Li Zi Wang Luyang Yu Xiaoze Wen Jie Zhang Wenming Feng 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第4期491-505,共15页
The relationship between support and surrounding rock is of great significance to the control of surrounding rock in mining process.In view of the fact that most of the existing numerical simulation methods construct ... The relationship between support and surrounding rock is of great significance to the control of surrounding rock in mining process.In view of the fact that most of the existing numerical simulation methods construct virtual elements and stress servo control to approximately replace the hydraulic support problem,this paper establishes a new numerical model of hydraulic support with the same working characteristics as the actual hydraulic support by integrating numerical simulation software Rhino,Griddle and FLAC3D,which can realize the simulation of different working conditions.Based on this model,the influence mechanism of the supporting strength of hydraulic support on surrounding rock stress regulation and coal stability in front of the top coal caving face in extra thick coal seam were researched.Firstly,under different support intensity,the abutment pressure of the bearing coal and the coal in front of it presents the “three-stage”evolution characteristics.The influence range of support intensity is 15%–30%.Secondly,1.5 MPa is the upper limit of impact that the support strength can have on the front coal failure area.Thirdly,within a displacement range of 2.76 m from the coal wall,a support strength of1.5 MPa provides optimal control of the horizontal displacement of the coal. 展开更多
关键词 Extremely thick coal seam Fully mechanized top coal caving Support strength Support-surrounding rock interaction
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Surrounding Rock Failure Mechanism and Control Technology of Gob-Side Entry with Triangle Coal Pillar at Island Longwall Panel in 15 m Extra-Thick Coal Seams
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作者 Hao Sun 《World Journal of Engineering and Technology》 2024年第2期373-388,共16页
Taking the return air roadway of Tashan 8204 isolated island working face as the background, the evolution law of the stress field in the surrounding rock of the widened coal pillar area roadway during the mining peri... Taking the return air roadway of Tashan 8204 isolated island working face as the background, the evolution law of the stress field in the surrounding rock of the widened coal pillar area roadway during the mining period of the isolated island working face is obtained through numerical simulation. The hazardous area of strong mine pressure under different coal pillar widths is determined. Through simulation, it is known that when the width of the coal pillar is less than 20 m, there is large bearing capacity on the coal side of the roadway entity. The force on the side of the coal pillar is relatively small. When the width of the coal pillar ranges from 25 m to 45 m, the vertical stress on the roadway and surrounding areas is relatively high. Pressure relief measures need to be taken during mining to reduce surrounding rock stress. When the width of the coal pillar is greater than 45 m, the peak stress of the coal pillar is located in the deep part of the surrounding rock, but it still has a certain impact on the roadway. It is necessary to take pressure relief measures to transfer the stress to a deeper depth to ensure the stability of the triangular coal pillar during the safe mining period of the working face. This provides guidance for ensuring the stability of the triangular coal pillar during the safe mining period of the working face. 展开更多
关键词 Island coal Face Evolution Law of Surrounding Rock Stress Field Strong Mine Pressure Hazardous Area
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Behaviors of overlying strata in extra-thick coal seams using top-coalcaving method 被引量:7
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作者 Bin Yu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2016年第2期238-247,共10页
Accidents such as support failure and excessive deformation of roadways due to drastic changes in strata behaviors are frequently reported when mining the extra-thick coal seams Nos.3e5 in Datong coal mine with top-co... Accidents such as support failure and excessive deformation of roadways due to drastic changes in strata behaviors are frequently reported when mining the extra-thick coal seams Nos.3e5 in Datong coal mine with top-coal caving method,which significantly hampers the mine's normal production.To understand the mechanism of strata failure,this paper presented a structure evolution model with respect to strata behaviors.Then the behaviors of strata overlying the extra-thick coal seams were studied with the combined method of theoretical analysis,physical simulation,and field measurement.The results show that the key strata,which are usually thick-hard strata,play an important role in overlying movement and may influence the mining-induced strata behaviors in the working face using top-coal caving method.The structural model of far-field key strata presents a 'masonry beam' type structure when'horizontal O-X' breakage type happens.The rotational motion of the block imposed radial compressive stress on the surrounding rock mass of the roadway.This can induce excessive deformation of roadway near the goaf.Besides,this paper proposed a pre-control technology for the hard roof based on fracture holes and underground roof pre-splitting.It could effectively reduce stress concentration and release the accumulated energy of the strata,when mining underground coal resources with top-coal caving method. 展开更多
关键词 extra-thick coal seam Datong mining area Large-space structure Near-and far-field strata Strata behavior Key strata
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Prediction of upper limit position of bedding separation overlying a coal roadway within an extra-thick coal seam 被引量:5
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作者 YAN Hong ZHANG Ji-xiong +2 位作者 LI Lin-yue FENG Rui-min LI Tian-tong 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第2期448-460,共13页
Failure of the surrounding rock around a roadway induced by roof separation is one major type of underground roof-fall accidents.This failure can especially be commonly-seen in a bottom-driven roadway within an extra-... Failure of the surrounding rock around a roadway induced by roof separation is one major type of underground roof-fall accidents.This failure can especially be commonly-seen in a bottom-driven roadway within an extra-thick coal seam("bottom-driven roadway"is used throughout for ease of reference),containing weak partings in their roof coal seams.To determine the upper limit position of the roof interlayer separation is the primary premise for roof control.In this study,a mechanical model for predicting the interlayer separation overlying a bottom-driven roadway within an extra-thick coal seam was established and used to deduce the vertical stress,and length,of the elastic,and plastic zones in the rock strata above the wall of the roadway as well as the formulae for calculating the deflection in different regions of rock strata under bearing stress.Also,an approach was proposed,calculating the stratum load,deflection,and limiting span of the upper limit position of the interlayer separation in a thick coal seam.Based on the key strata control theory and its influence of bedding separation,a set of methods judging the upper limit position of the roof interlayer separation were constructed.In addition,the theoretical prediction and field monitoring for the upper limit position of interlayer separation were conducted in a typical roadway.The results obtained by these two methods are consistent,indicating that the methods proposed are conducive to improving roof control in a thick coal seam. 展开更多
关键词 extra-thick coal seam bedding separation coal roadway roof fall mechanical model
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Strata behavior in extra-thick coal seam mining with upward slicing backfilling technology 被引量:1
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作者 Deng Xuejie Zhang Jixiong +1 位作者 Kang Tao Han Xiaole 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2016年第4期587-592,共6页
Based on the character of upward slicing backfilling mining and the condition of Gonggeyingzi coal mine in Inner Mongolia,this paper describes the studies of the strata behavior and the stress distribution in the proc... Based on the character of upward slicing backfilling mining and the condition of Gonggeyingzi coal mine in Inner Mongolia,this paper describes the studies of the strata behavior and the stress distribution in the process of backfilling mining in extra-thick coal seams.This was achieved by setting up and analyzing the elastic foundation beam model using the ABAQUS software.The results show that:(1) With the gradual mining of different slices,the roof appears to bend continuously but does not break.The vertical stress in the roof decreases and the decreasing amplitude reduces,while the tensile stress in the roof grows with the mining slices and the maximum tensile stress will not exceed the allowable tensile stress.(2) The front vertical stress at the working face exceeds the rear vertical stress and both show a trend of decrease with decreasing amplitude of decrease.(3) The slices mined early have more influence on the surrounding rock than the later ones.Similarly,the strata behavior experiences the same trend.The field measured data show that the roof does not break during the mining process,which is consistent with the conclusion. 展开更多
关键词 extra-thick coal seam Upward slicing backfilling mining Strata movement characteristics Strata behavior
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Numerical Study on an Applicable Underground Mining Method for Soft Extra-Thick Coal Seams in Thailand 被引量:4
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作者 Nay Zarlin Takashi Sasaoka +1 位作者 Hideki Shimada Kikuo Matsui 《Engineering(科研)》 2012年第11期739-745,共7页
The EGAT Mae Moh Mine is the largest open pit lignite mine in Thailand and it produces lignite about 16 million tons annually. In the near future, the pit limit of the mine will be reached and underground mine will th... The EGAT Mae Moh Mine is the largest open pit lignite mine in Thailand and it produces lignite about 16 million tons annually. In the near future, the pit limit of the mine will be reached and underground mine will then be developed through the open pit in the depth of 400 - 600 m from the surface. However, due to the challenges for underground mining such as poor geological conditions, extra thickness (20 - 30 m) of coal seams, and weak mechanical properties of coal seams and the surrounding rock, the success possibility of underground mining and an applicable underground mining method is being investigated at the present. The paper discusses the applicability of multi-slice bord-and-pillar method for the soft extra thick coal seams in the Mae Moh mine by means of numerical analyses using the 3D finite difference code “FLAC3D”. 展开更多
关键词 Multi-Slice Bord-and-Pillar Method SOFT extra-thick coal Seams Numerical Analyses FLAC3D
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Dynamic destabilization analysis based on AE experiment of deep-seated,steep-inclined and extra-thick coal seam 被引量:5
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作者 Fenhua Ren Xmgpmg Lai Meifeng Cai 《Journal of University of Science and Technology Beijing》 CSCD 2008年第3期215-219,共5页
No. 5 coal seam in Huating Coal Mine is a deep-seated, steep-inclined extra-thick coal seam where excavation disturbance is quite frequent. The maximum and minimum principal stresses differ widely. During mining, dyna... No. 5 coal seam in Huating Coal Mine is a deep-seated, steep-inclined extra-thick coal seam where excavation disturbance is quite frequent. The maximum and minimum principal stresses differ widely. During mining, dynamical destabilization happens frequently and induce tragedies. Based on the comparison between the acoustic emission (AE) experiment on dynamical destabilization of coal rock and the related in situ testing results, this article provides comprehensive analysis on the regular quantificational AE patterns (energy rate, total events) of coal rock destabilization in complex-variable environment. The comparison parameters include dynamic tension energy rate, deformation resistance to compression, and shear stress. 展开更多
关键词 coal seam acoustic emission (AE) DESTABILIZATION excavation disturbance
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Development of 3D top coal caving angle model for fully mechanized extra-thick coal seam mining 被引量:4
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作者 Hongfei Duan Lijuan Zhao +2 位作者 Haiyan Yang Yao Zhang Hongchun Xia 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2022年第5期1145-1152,共8页
During high-intensity,fully mechanized mining of extra-thick coal seam,the top coal would cave to a certain 3D form.Based on the data collected during drilling,a 3D model of top coal caving surface space was establish... During high-intensity,fully mechanized mining of extra-thick coal seam,the top coal would cave to a certain 3D form.Based on the data collected during drilling,a 3D model of top coal caving surface space was established to determine the relationship between the location of the stope roof and the caving surface,enabling the mathematical computation of the top caving angle(φ).The drilling method was employed to measure the top caving angle on two extra-thick fully mechanized coal caving faces under the conditions of three geological structures,namely,no geological structure,igneous rock structure,and fault structure.The results show that the value of top caving angle could be accurately estimated on-site with the 9-parameter 3D top coal caving surface model built with the drilling method.This method is a novel on-site measurement that can be easily applied.Our findings reveal that the characteristics of the coal-rock in the two mining faces are different;yet their caving angles follow the ruleφ_(igneous rock structure)<φ_(no geological structure)<φ_(fault structure).Finally,through the data fitting with two indexes(the top coal uniaxial compressive strength and the top caving angle),it is found that the relationship between the two indexes satisfies an exponential decay function. 展开更多
关键词 Space model Field measurement Top coal caving angle Uniaxial compressive strength Exponential decay function
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Mechanism and control technology of strong ground pressure behaviour induced by high-position hard roofs in extra-thick coal seam mining 被引量:10
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作者 Chao Pan Binwei Xia +2 位作者 Yujun Zuo Bin Yu Changnan Ou 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2022年第3期499-511,共13页
This work aimed at revealing the mechanism of strong ground pressure behaviour(SGPB)induced by high-position hard roof(HHR).Based on the supporting structures model of HHR,a modified voussoir beam mechanical model for... This work aimed at revealing the mechanism of strong ground pressure behaviour(SGPB)induced by high-position hard roof(HHR).Based on the supporting structures model of HHR,a modified voussoir beam mechanical model for HHR was established by considering the gangue support coefficient,through which the modified expressions of limit breaking span and breaking energy of HHR were deduced.Combined with the relationship between the dynamic-static loading stress of supporting body(hydraulic support and coal wall)and its comprehensive supporting strength,the criteria of ground pressure behaviour(GPB)induced by HHR were discussed.The types of Ⅰ_(1),Ⅰ_(2),Ⅱ_(1),andⅡ_(2) of GPB were interpreted.Results showed that types Ⅰ_(1) and Ⅰ_(2) were the main forms of SGPB in extra-thick coal seam mining.The main manifestation of SGPB was static stress,which was mainly derived from the instability of HHR rather than fracture.Accordingly,an innovative control technology was proposed,which can weaken static load by vertical-well separated fracturing HHR.The research results have been successfully applied to the 8101 working face in Tashan coal mine,Shanxi Province,China.The results of a digital borehole camera observation and stress monitoring proved the rationality of the GPB criteria.The control technology was successful,paving the way for new possibilities to HHR control for safety mining. 展开更多
关键词 Extra thick coal seam High-position hard roof Strong ground pressure behaviour Supporting structures Criteria of ground pressure behaviour Controlling effects
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Gas Drainage Technology in Fully Mechanized Caving Face with Horizontal Sublevel Mining in Steep and Extra-Thick Coal Seam
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作者 Bingxing Sun 《Open Journal of Geology》 2020年第9期957-970,共14页
This paper analyzes the gas source of the horizontally sectioned fully mechanized caving face in the steeply inclined and extra-thick seam of Adaohai Coal Mine, and numerically simulates the stress distribution and pr... This paper analyzes the gas source of the horizontally sectioned fully mechanized caving face in the steeply inclined and extra-thick seam of Adaohai Coal Mine, and numerically simulates the stress distribution and pressure relief of the lower section coal after the upper section working face is mined. It theoretically analyzed the reasonable layout of the drainage boreholes, and designed the drainage borehole layout accordingly. In the upper and lower section of the working face, the actual drainage effect of the boreholes was inspected, and the air exhaust gas volume in the working face was statistically analyzed. It was confirmed that the layout of boreholes was reasonable, the gas control effect of working face was greatly improved and fully met the needs of safe mining. The control effect was greatly improved and the need for safe mining was fully met, and thus a gas drainage technology suitable for the coal seam storage conditions and mining technology of the Adaohai Coal Mine was found. That is to say: the gas emission from the working face of the section mining mainly comes from its lower coal body. Pre-draining the lower coal body of the section and depressurizing gas interception and drainage are the key to effectively solve the problem of gas emission from the working face. Drainage boreholes in the working face of the section should be arranged at high and low positions. The high-level boreholes are located about 2 m from the top of the working face, and the high-level boreholes are about 9 m away from the top of the working face. Through the pre drainage of high and low-level boreholes in advance and the interception and pressure relief drainage, the gas control in the horizontal sublevel fully mechanized caving mining face in steep and extra thick coal seam can realize a virtuous cycle. 展开更多
关键词 Steeply Inclined Extra Thick Seam Horizontal Segmentation Top coal Caving The Source of the Gas Pressure Relief Gas Drainage
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Numerical analysis on the factors affecting post-peak characteristics of coal under uniaxial compression 被引量:2
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作者 Zhiguo Lu Wenjun Ju +1 位作者 Fuqiang Gao Taotao Du 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第1期42-60,共19页
The post-peak characteristics of coal serve as a direct reflection of its failure process and are essential parameters for evaluating brittleness and bursting liability.Understanding the significant factors that influ... The post-peak characteristics of coal serve as a direct reflection of its failure process and are essential parameters for evaluating brittleness and bursting liability.Understanding the significant factors that influence post-peak characteristics can offer valuable insights for the prevention of coal bursts.In this study,the Synthetic Rock Mass method is employed to establish a numerical model,and the factors affecting coal post-peak characteristics are analyzed from four perspectives:coal matrix mechanical parameters,structural weak surface properties,height-to-width ratio,and loading rate.The research identifies four significant influencing factors:deformation modulus,density of discrete fracture networks,height-to-width ratio,and loading rate.The response and sensitivity of post-peak characteristics to single-factor and multi-factor interactions are assessed.The result suggested that feasible prevention and control measures for coal bursts can be formulated through four approaches:weakening the mechanical properties of coal pillars,increasing the number of structural weak surfaces in coal pillars,reducing the width of coal pillars,and optimizing mining and excavation speed.The efficacy of measures aimed at weakening the mechanical properties of coal is successfully demonstrated through a case study on coal burst prevention using large-diameter borehole drilling. 展开更多
关键词 Post-peak behavior Synthetic rock mass coal bursts coal burst prevention
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Geological characteristics and exploration breakthroughs of coal rock gas in Carboniferous Benxi Formation,Ordos Basin,NW China 被引量:2
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作者 ZHAO Zhe XU Wanglin +8 位作者 ZHAO Zhenyu YI Shiwei YANG Wei ZHANG Yueqiao SUN Yuanshi ZHAO Weibo SHI Yunhe ZHANG Chunlin GAO Jianrong 《Petroleum Exploration and Development》 SCIE 2024年第2期262-278,共17页
To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin,this paper presents a systematic research on the coal rock distribution,coal ro... To explore the geological characteristics and exploration potential of the Carboniferous Benxi Formation coal rock gas in the Ordos Basin,this paper presents a systematic research on the coal rock distribution,coal rock reservoirs,coal rock quality,and coal rock gas features,resources and enrichment.Coal rock gas is a high-quality resource distinct from coalbed methane,and it has unique features in terms of burial depth,gas source,reservoir,gas content,and carbon isotopic composition.The Benxi Formation coal rocks cover an area of 16×104km^(2),with thicknesses ranging from 2 m to 25 m,primarily consisting of bright and semi-bright coals with primitive structures and low volatile and ash contents,indicating a good coal quality.The medium-to-high rank coal rocks have the total organic carbon(TOC)content ranging from 33.49%to 86.11%,averaging75.16%.They have a high degree of thermal evolution(Roof 1.2%-2.8%),and a high gas-generating capacity.They also have high stable carbon isotopic values(δ13C1of-37.6‰to-16‰;δ13C2of-21.7‰to-14.3‰).Deep coal rocks develop matrix pores such as gas bubble pores,organic pores,and inorganic mineral pores,which,together with cleats and fractures,form good reservoir spaces.The coal rock reservoirs exhibit the porosity of 0.54%-10.67%(averaging 5.42%)and the permeability of(0.001-14.600)×10^(-3)μm^(2)(averaging 2.32×10^(-3)μm^(2)).Vertically,there are five types of coal rock gas accumulation and dissipation combinations,among which the coal rock-mudstone gas accumulation combination and the coal rock-limestone gas accumulation combination are the most important,with good sealing conditions and high peak values of total hydrocarbon in gas logging.A model of coal rock gas accumulation has been constructed,which includes widespread distribution of medium-to-high rank coal rocks continually generating gas,matrix pores and cleats/fractures in coal rocks acting as large-scale reservoir spaces,tight cap rocks providing sealing,source-reservoir integration,and five types of efficient enrichment patterns(lateral pinchout complex,lenses,low-amplitude structures,nose-like structures,and lithologically self-sealing).According to the geological characteristics of coal rock gas,the Benxi Formation is divided into 8 plays,and the estimated coal rock gas resources with a buried depth of more than 2000 m are more than 12.33×10^(12)m^(3).The above understandings guide the deployment of risk exploration.Two wells drilled accordingly obtained an industrial gas flow,driving the further deployment of exploratory and appraisal wells.Substantial breakthroughs have been achieved,with the possible reserves over a trillion cubic meters and the proved reserves over a hundred billion cubic meters,which is of great significance for the reserves increase and efficient development of natural gas in China. 展开更多
关键词 coal rock gas coalbed methane medium-to-high rank coal CLEAT Ordos Basin Carboniferous Benxi Formation risk exploration
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Structural properties of residual carbon in coal gasification fine slag and their influence on flotation separation and resource utilization:A review 被引量:5
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作者 Rui Han Anning Zhou +4 位作者 Ningning Zhang Kaiqiang Guo Mengyan Cheng Heng Chen Cuicui Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期217-230,共14页
Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery a... Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental benefits.The structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of FS-RC.In this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle size.The reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is summarized.Separation methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the future.The design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the future.The high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization method.This review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the efficient flotation separation of FS,and the expansion of the field of the high value-added utilization of FS-RC. 展开更多
关键词 coal gasification fine slag residual carbon pore structure surface functional groups microcrystalline structure flotation sep-aration resource utilization
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Theoretical analysis of hydrogen solubility in direct coal liquefaction solvents 被引量:1
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作者 Xiaobin Zhang Aoqi Wang +1 位作者 Xingbao Wang Wenying Li 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期187-197,共11页
The cyclic hydrogenation technology in a direct coal liquefaction process relies on the dissolved hydrogen of the solvent or oil participating in the hydrogenation reaction.Thus,a theoretical basis for process optimiz... The cyclic hydrogenation technology in a direct coal liquefaction process relies on the dissolved hydrogen of the solvent or oil participating in the hydrogenation reaction.Thus,a theoretical basis for process optimization and reactor design can be established by analyzing the solubility of hydrogen in liquefaction solvents.Experimental studies of hydrogen solubility in liquefaction solvents are challenging due to harsh reaction conditions and complex solvent compositions.In this study,the composition and content of liquefied solvents were analyzed.As model compounds,hexadecane,toluene,naphthalene,tetrahydronaphthalene,and phenanthrene were chosen to represent the liquefied solvents in chain alkanes and monocyclic,bicyclic,and tricyclic aromatic hydrocarbons.The solubility of hydrogen X(mol/mol)in pure solvent components and mixed solvents(alkanes and aromatics mixed in proportion to the chain alkanes+bicyclic aromatic hydrocarbons,bicyclic saturated aromatic hydrocarbons+bicyclic aromatic hydrocarbons,and bicyclic aromatic hydrocarbons+compounds containing het-eroatoms composed of mixed components)are determined using Aspen simulation at temperature and pressure conditions of 373–523 K and 2–10 MPa.The results demonstrated that at high temperatures and pressures,the solubility of hydrogen in the solvent increases with the increase in temperature and pressure,with the pressure having a greater impact.Further-more,the results revealed that hydrogen is more soluble in straight-chain alkanes than in other solvents,and the solubility of eicosanoids reaches a maximum of 0.296.The hydrogen solubility in aromatic ring compounds decreased gradually with an increase in the aromatic ring number.The influence of chain alkanes on the solubility of hydrogen predominates in a mixture of solvents with different mixing ratios of chain alkanes and aromatic hydrocarbons.The solubility of hydrogen in mixed aromatic solvents is less than that in the corresponding single solvents.Hydrogen is less soluble in solvent compounds containing heteroatoms than in compounds without heteroatoms. 展开更多
关键词 Direct coal liquefaction Liquefaction solvents Process simulation Hydrogen solubility
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多功能CoAl-LDH/CdS光催化剂的制备及其性能研究 被引量:1
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作者 唐丹琪 阳敏 +3 位作者 朱子 张海燕 李铭 李佑稷 《功能材料》 CAS CSCD 北大核心 2024年第7期7166-7176,共11页
在能源危机和环境污染的双重挑战下,开发集能量转化和环境治理于一体的多功能光催化剂是促进太阳能-化学能转化的有效策略。采用正六边形的CoAl-LDH纳米薄片为载体,通过原位生长CdS纳米颗粒的方法,构建了CoAl-LDH/CdS的Ⅱ型异质结。利用... 在能源危机和环境污染的双重挑战下,开发集能量转化和环境治理于一体的多功能光催化剂是促进太阳能-化学能转化的有效策略。采用正六边形的CoAl-LDH纳米薄片为载体,通过原位生长CdS纳米颗粒的方法,构建了CoAl-LDH/CdS的Ⅱ型异质结。利用CoAl-LDH纳米薄片在可见光区域的宽普吸收性和良好载体的特性,结合CdS的高光量子产率,再通过异质结构的构建,获得了多功能CoAl-LDH/CdS光催化材料。并通过优化CdS的负载量,获得的CoAl-LDH/CdS-2光催剂降解罗丹明B的降解率最大(在光催化降解时间t=60 min时内,降解率=88.48%),分别是CdS和CoAl-LDH单体的1.18倍和8.62倍。其中CoAl-LDH/CdS-1的CO产量最高为39.02 mol/g,分别是纯CoAl-LDH和纯CdS的4.2倍和2.5倍,这主要归功于复合材料中CoAl-LDH纳米片和CdS纳米颗粒间紧密异质结构的构建,丰富的耦合界面大大降低了光生载流子的复合率,这为多功能光催化剂的开发提供了理论基础。 展开更多
关键词 coal-LDH CDS 异质结 光催化降解 CO 2还原
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Depositional Environment and Origin of Inertinite-rich Coal in the Ordos Basin
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作者 SHI Qingmin ZHAO Jun +5 位作者 JI Ruijun XUE Weifeng HAN Bo CAI Yue LI Chunhao CUI Shidong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第4期1064-1085,共22页
Inertinite-rich coal is widely distributed in the Ordos Basin,represented by the No.2 coal seam of the Middle Jurassic Yan'an Formation.This paper combined coal petrology and geochemistry to analyze the origin of ... Inertinite-rich coal is widely distributed in the Ordos Basin,represented by the No.2 coal seam of the Middle Jurassic Yan'an Formation.This paper combined coal petrology and geochemistry to analyze the origin of inertinite,changes in the coal-forming environment and control characteristics of wildfire.Research has shown that there are two forms of inertinite sources in the study area.Alongside typical fusinization,wildfire events also play a substantial role in inertinite formation.There are significant fluctuations in the coal-forming environment of samples at different depths.Coal samples were formed in dry forest swamp with low water levels and strong oxidation,which have a high inertinite content,and the samples formed in wet forest swamp and limnic showed low inertinite content.Conversely,the inertinite content of different origins does not fully correspond to the depositional environment characterized by dryness and oxidation.Nonpyrogenic inertinites were significantly influenced by climatic conditions,while pyrofusinite was not entirely controlled by climatic conditions but rather directly impacted by wildfire events.The high oxygen level was the main factor causing widespread wildfire events.Overall,the combination of wildfire activity and oxidation generates a high content of inertinite in the Middle Jurassic coal of the Ordos Basin. 展开更多
关键词 inertinite-rich coal WILDFIRE coal petrology geochemistry biomarkers depositional environment
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Geochemical and petrological studies of high sulfur coal and overburden from Makum coalfield (Northeast India) towards understanding and mitigation of acid mine drainage
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作者 Angana Mahanta Debashis Sarmah +6 位作者 Nilotpol Bhuyan Monikankana Saikia Sarat Phukan K.S.V.Subramanyam Ajit Singh Prasenjit Saikia Binoy K.Saikia 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第1期133-147,共15页
Opencast coal mining produces trash of soil and rock containing various minerals,that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drain... Opencast coal mining produces trash of soil and rock containing various minerals,that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drainage(AMD)through oxidation pyrite minerals.The current study entailed assessing the potential production of AMD from an opencast coal mining region in Northeast part of India.In order to have a comprehensive overview of the AMD problem in Makum coalfield,the physico-chemical,geochemical,and petrological characteristics of the coal and overburden(OB)samples collected from the Makum coalfield(Northeast India)were thoroughly investigated.The maceral compositions reveal that coal features all three groups of macerals(liptinite,vitrinite,and inertinite),with a high concentration of liptinite indicating the coal of perhydrous,thereby rendering it more reactive.Pyrite(FeS_(2))oxidation kinetics were studied by conducting the aqueous leaching experiments of coal and(OB)samples to interpret the chemical weathering under controlled laboratory conditions of various temperature and time periods,and to replicate the actual mine site leaching.Inductively coupled plasma-optical emission spectroscopy(ICP-OES)was operated to detect the disposal of some precarious elements from coal and OB samples to the leachates during our controlled leaching experiment.The Rare earth element(REE)enrichment in the samples shows the anthropogenic incorporation of the REE in the coal and OB.These experiments reveal the change in conductivity,acid producing tendency,total dissolved solid(TDS),total Iron(Fe)and dissolved Sulfate(SO_(4)^(2−))ions on progress of the leaching experiments.Moreover,the discharge of FeS_(2) via atmospheric oxidation in laboratory condition undergoes a significant growth with the rise of temperature of the reaction systems in the environment and follows pseudo first order kinetics.A bio-remediative strategies is also reported in this paper to mitigate AMD water by employing size-segregated powdered limestone and water hyacinth plant in an indigenously developed site-specific prototype station.Apart from neutralisation of AMD water,this eco-friendly AMD remediation strategy demonstrates a reduction in PHEs concentrations in the treated AMD water. 展开更多
关键词 Opencast mining Pyrite oxidation coal geochemistry coal petrology Rare earth elements AMD remediation
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Coal/Gangue Volume Estimation with Convolutional Neural Network and Separation Based on Predicted Volume and Weight
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作者 Zenglun Guan Murad S.Alfarzaeai +2 位作者 Eryi Hu Taqiaden Alshmeri Wang Peng 《Computers, Materials & Continua》 SCIE EI 2024年第4期279-306,共28页
In the coal mining industry,the gangue separation phase imposes a key challenge due to the high visual similaritybetween coal and gangue.Recently,separation methods have become more intelligent and efficient,using new... In the coal mining industry,the gangue separation phase imposes a key challenge due to the high visual similaritybetween coal and gangue.Recently,separation methods have become more intelligent and efficient,using newtechnologies and applying different features for recognition.One such method exploits the difference in substancedensity,leading to excellent coal/gangue recognition.Therefore,this study uses density differences to distinguishcoal from gangue by performing volume prediction on the samples.Our training samples maintain a record of3-side images as input,volume,and weight as the ground truth for the classification.The prediction process relieson a Convolutional neural network(CGVP-CNN)model that receives an input of a 3-side image and then extractsthe needed features to estimate an approximation for the volume.The classification was comparatively performedvia ten different classifiers,namely,K-Nearest Neighbors(KNN),Linear Support Vector Machines(Linear SVM),Radial Basis Function(RBF)SVM,Gaussian Process,Decision Tree,Random Forest,Multi-Layer Perceptron(MLP),Adaptive Boosting(AdaBosst),Naive Bayes,and Quadratic Discriminant Analysis(QDA).After severalexperiments on testing and training data,results yield a classification accuracy of 100%,92%,95%,96%,100%,100%,100%,96%,81%,and 92%,respectively.The test reveals the best timing with KNN,which maintained anaccuracy level of 100%.Assessing themodel generalization capability to newdata is essential to ensure the efficiencyof the model,so by applying a cross-validation experiment,the model generalization was measured.The useddataset was isolated based on the volume values to ensure the model generalization not only on new images of thesame volume but with a volume outside the trained range.Then,the predicted volume values were passed to theclassifiers group,where classification reported accuracy was found to be(100%,100%,100%,98%,88%,87%,100%,87%,97%,100%),respectively.Although obtaining a classification with high accuracy is the main motive,this workhas a remarkable reduction in the data preprocessing time compared to related works.The CGVP-CNN modelmanaged to reduce the data preprocessing time of previous works to 0.017 s while maintaining high classificationaccuracy using the estimated volume value. 展开更多
关键词 coal coal gangue convolutional neural network CNN object classification volume estimation separation system
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